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    • 9. 发明专利
    • DE69940611D1
    • 2009-04-30
    • DE69940611
    • 1999-12-07
    • MORI YUZO
    • MORI YUZOISHIKAWA TOSHIO
    • H01L21/3063B08B3/02C25D11/32C25F1/00C25F3/00H01L21/00
    • With the present invention, clean processing can be performed, without leaving any impurities behind on the surface of a material, or washing can be performed in which fine impurity metals adhering to the material surface are completely removed, using just the hydroxide ions in ultra-pure water. With the present invention, the hydroxide ion density is increased and reaction substances produced through bonding with hydroxide ions are quickly removed from the surface, preventing re-adhesion and allowing processing and washing to be performed more efficiently. A material and a high pressure nozzle are disposed a specific distance apart from each other inside a washing tank containing only ultra-pure water, an ion exchange material or catalyst material that increases the amount of hydroxide ions is provided between the processing surface of said workpiece and the distal end of the high pressure nozzle facing said surface, and a voltage is applied using the high pressure nozzle as the cathode and the material as the anode. A high-speed shear flow of ultra-pure water sprayed from the high pressure nozzle is generated near the surface of the material, hydroxide ions produced from the ultra-pure water are supplied to the workpiece surface, and the material is subjected to removal processing or to oxide film formation processing by means of a chemical elution reaction or oxidation reaction brought about by the hydroxide ions.