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    • 1. 发明授权
    • Methods for the separation of compounds from acidic aqueous solutions
    • 从酸性水溶液中分离化合物的方法
    • US06238462B1
    • 2001-05-29
    • US09353202
    • 1999-07-14
    • Steven A. DunwoodyLei JiangDale R. PowersFreddie G. Prince
    • Steven A. DunwoodyLei JiangDale R. PowersFreddie G. Prince
    • B01D5314
    • B01D53/64C03B19/1446C03B37/0144C03B37/01846C03B2201/31
    • A method is disclosed for recovering germanium from a gaseous mixture which includes a germanium-containing compound in vapor or particulate form, acid in vapor form, and water vapor. The gaseous mixture is contacted with a liquid containing water under conditions effective to dissolve the germanium-containing compound in the liquid. The acidity of the resulting liquid mixture is increased under conditions effective to vaporize the germanium-containing compound. The vaporized germanium-containing compound is contacted with one or more aqueous solutions under conditions effective to dissolve and precipitate the germanium-containing compound in at least one of the one or more aqueous solutions, and the resulting precipitate is separated from the at least one of the one or more aqueous solutions. The methods described herein are particularly well suited for recovering germanium from the waste gases produced during optical waveguide manufacturing processes. Germanium recovered by this method can thereafter be used in the production of semiconductors, optical waveguide fibers and optical components.
    • 公开了一种用于从气体混合物中回收锗的方法,所述气体混合物包括蒸气或颗粒形式的含锗化合物,蒸汽形式的含酸化合物和水蒸气。 在有效溶解含锗化合物的液体中的条件下,气态混合物与含有液体的液体接触。 所得液体混合物的酸度在有效蒸发含锗化合物的条件下增加。 蒸发的含锗化合物在有效溶解和沉淀至少一种一种或多种水溶液中的含锗化合物的条件下与一种或多种水溶液接触,并将所得沉淀物从至少一种 一种或多种水溶液。 本文描述的方法特别适用于从光波导制造过程中产生的废气中回收锗。 然后通过该方法回收的锗可以用于半导体,光波导纤维和光学部件的制造。
    • 3. 发明授权
    • Halocarbon abatement system for a glass manufacturing facility
    • 玻璃制造设施的卤化碳减排系统
    • US06752974B2
    • 2004-06-22
    • US10120281
    • 2002-04-10
    • Steven A. DunwoodyJeffrey E. Taylor
    • Steven A. DunwoodyJeffrey E. Taylor
    • A62D300
    • B01D53/75B01D53/68B01D2257/204B01D2257/2042B01D2257/2045B01D2257/2047Y02C20/30
    • The invention relates to a method of treating a substantially gaseous halo-containing compound of an effluent of a glass manufacturing facility and a system for such method. The method includes the step of oxidizing the halo-containing compound to form a hydrogen and halo-containing compound. The method also includes the step of adsorbing a halogen of the hydrogen and halo-containing compound on a surface. The system includes at least one glass manufacturing apparatus which the operation of the apparatus in glass manufacturing generates an effluent which comprises a substantially gaseous halo-containing compound. The system also includes an oxidizer in fluid communication to receive the halo-containing compound and oxidize the compound to transform the halo-containing compound into a hydrogen and halo-containing compound. The system further includes a scrubber for receiving said hydrogen and halo-containing compound and absorbing the halogen from the hydrogen and halo-containing compound.
    • 本发明涉及一种处理玻璃制造设备的流出物的基本上气态含卤化合物的方法和用于这种方法的系统。 该方法包括氧化含卤素化合物以形成氢和含卤素的化合物的步骤。 该方法还包括在表面上吸附氢和含卤化合物的卤素的步骤。 该系统包括至少一个玻璃制造设备,其中玻璃制造中的设备的操作产生包含基本上气态的含卤素化合物的流出物。 该系统还包括流体连通以接收含卤素化合物并氧化化合物以将含卤素化合物转化为氢和含卤素的化合物的氧化剂。 该系统还包括用于接收所述氢和含卤素化合物并从氢和含卤素化合物吸收卤素的洗涤器。