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91. 发明授权

US5783645A Non-sticky prepolymerized catalyst, and use thereof in production of non-sticky resin 失效
标题翻译：非粘性预聚合催化剂及其在生产非粘性树脂中的应用
公开(公告)号：US5783645A
公开(公告)日：1998-07-21
申请号：US666641
申请日：1996-06-18
申请人： Edgar Chapman Baker , Jose Fernando Cevallos-Candau , Eric Allan Lucas , John Gregory Victor , Allan Noshay
发明人： Edgar Chapman Baker , Jose Fernando Cevallos-Candau , Eric Allan Lucas , John Gregory Victor , Allan Noshay
IPC分类号： C08F2/34 , C08F4/60 , C08F4/631 , C08F4/64 , C08F4/658 , C08F4/659 , C08F4/6592 , C08F4/685 , C08F8/00 , C08F10/00 , C08F210/02 , C08F210/16 , C08F210/18 , C08F255/00 , C08F255/02
CPC分类号： C08F255/02 , C08F10/00 , C08F210/16 , C08F255/00 , C08F210/18 , Y10S525/902 , Y10S526/901 , Y10S526/904 , Y10S526/905 , Y10T428/2982 , Y10T428/2991 , Y10T428/2998
摘要： A colorable resin particle having an outer shell of a non-sticky polymer and an inner core of a sticky polymer produced in a gas phase fluidized bed reactor at or above the sticking temperature of the sticky polymer using a non-sticky prepolymerized catalyst and processes for producing the colorable resin and the non-sticky prepolymerized catalyst.
摘要翻译：一种可着色的树脂颗粒，其具有非粘性聚合物的外壳和在气相流化床反应器中产生的粘性聚合物的内芯，其粘度聚合物的粘合温度高于或高于使用非粘性预聚合催化剂的方法制造可着色树脂和非粘性预聚合催化剂。

92. 发明授权

US5767034A Olefin polymerization catalyst with additive comprising aluminum-silicon composition, calixarene derivatives or cyclodextrin derivatives 失效
标题翻译：具有包含铝 - 硅组合物，杯芳烃衍生物或环糊精衍生物的添加剂的烯烃聚合催化剂
公开(公告)号：US5767034A
公开(公告)日：1998-06-16
申请号：US656028
申请日：1996-05-31
申请人： Antonio Diaz-Barrios , Jose Liscano , Marianela Trujillo , Giuseppe Agrifoglio , Jose Orlando Matos
发明人： Antonio Diaz-Barrios , Jose Liscano , Marianela Trujillo , Giuseppe Agrifoglio , Jose Orlando Matos
IPC分类号： C08F4/654 , C08F4/642 , C08F4/651 , C08F4/658 , C08F10/00 , C08F110/02 , B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60
CPC分类号： C08F110/02 , C08F10/00
摘要： An olefin polymerization catalyst includes a halogen-containing magnesium compound; a titanium compound; and an additive selected from the group consisting of (a) a mixture of an aluminum alkoxide compound and polydimethylsiloxane, (b) an aluminosiloxane, (c) the reaction product of an aluminum alkyl and a calixarene, (d) the reaction product of an aluminum alkyl and a cyclodextrin, and mixtures of (a)-(d).
摘要翻译：烯烃聚合催化剂包括含卤素的镁化合物; 钛化合物; 和（a）烷氧基铝化合物和聚二甲基硅氧烷的混合物，（b）铝硅氧烷，（c）烷基铝和杯芳烃的反应产物，（d）反应产物烷基铝和环糊精，以及（a） - （d）的混合物。

93. 发明授权

US5648422A Process for the (co)polymerization of olefins 失效
标题翻译：烯烃（共）聚合方法
公开(公告)号：US5648422A
公开(公告)日：1997-07-15
申请号：US461691
申请日：1995-06-05
申请人： Gianni Collina , Tiziano Dall'Occo , Maurizio Galimberti , Enrico Albizzati , Luciano Noristi
发明人： Gianni Collina , Tiziano Dall'Occo , Maurizio Galimberti , Enrico Albizzati , Luciano Noristi
IPC分类号： C08F4/658 , C08F2/42 , C08F2/48 , C08F4/642 , C08F4/654 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/06 , C08F110/06 , C08F297/08 , C08F210/16
CPC分类号： C08F297/08 , C08F10/00 , C08F10/06 , C08F110/06 , C08F2410/05 , C08F4/65912
摘要： Multistage process for the polymerization of one or more olefins of the formula CH.sub.2 .dbd.CHR, in which R is hydrogen or an alkyl, cycloalkyl or aryl group having from 1 to 10 carbon atoms, comprising:(A) a first stage of polymerization, in which a first olefin polymer is prepared in the presence of titanium catalyst or vanadium catalyst;(B) a treatment stage in which the catalyst used previously is deactivated and in which a metallocene compound is supported on the olefin polymer produced in stage (A); and(C) a second stage of polymerization in which one or more olefins are polymerized in the presence of the product obtained from stage (B).
摘要翻译：用于聚合一种或多种式CH 2 = CHR的烯烃的多级方法，其中R是氢或具有1至10个碳原子的烷基，环烷基或芳基，其包含：（A）第一阶段聚合其中在钛催化剂或钒催化剂存在下制备第一种烯烃聚合物; （B）其中先前使用的催化剂失活并且茂金属化合物负载在阶段（A）中制备的烯烃聚合物上的处理阶段; 和（C）第二阶段的聚合反应，其中一种或多种烯烃在得自级（B）的产物存在下聚合。

94. 发明授权

US5618771A Components and catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的组分和催化剂
公开(公告)号：US5618771A
公开(公告)日：1997-04-08
申请号：US469734
申请日：1995-06-06
申请人： Sandro Parodi , Roberto Nocci , Umberto Giannini , Pier Camillo Barbe , Umberto Scata
发明人： Sandro Parodi , Roberto Nocci , Umberto Giannini , Pier Camillo Barbe , Umberto Scata
IPC分类号： C08F4/00 , B01J31/38 , C08F4/02 , C08F4/04 , C08F4/60 , C08F4/64 , C08F4/646 , C08F4/649 , C08F4/65 , C08F4/651 , C08F4/654 , C08F4/658 , C08F10/00 , C08F10/06 , C08F110/06
CPC分类号： C08F10/00 , Y02P20/52
摘要： Disclosed are catalysts for the polymerization of alpha-olefins which comprise the reaction product of:(a) an Al alkyl compound;(b) a silicon compound containing at least a Si--OR or Si--OCOR or Si--NR.sub.2 bond, R being a hydrocarbyl radical;(c) a solid comprising, as essential support, a Mg dihalide in active form and, supported thereon, a Ti halide or a halo-Ti-alcoholate and a particular, selected type of electron-donor compound.
摘要翻译：公开了用于α-烯烃聚合的催化剂，其包括以下反应产物：（a）Al烷基化合物; （b）至少含有Si-OR或Si-OCOR或Si-NR2键的硅化合物，R为烃基; （c）固体，其包含活性形式的二卤化镁作为必需的载体，并且其上载有Ti卤化物或卤代钛醇化物和特定的选择类型的电子给体化合物。

95. 发明授权

US5608019A Temperature control of MW in olefin polymerization using supported metallocene catalyst 失效
标题翻译：使用负载金属茂催化剂在烯烃聚合中的温度控制
公开(公告)号：US5608019A
公开(公告)日：1997-03-04
申请号：US148309
申请日：1993-11-08
申请人： Subrahmanyam Cheruvu , Frederick Y. Lo
发明人： Subrahmanyam Cheruvu , Frederick Y. Lo
IPC分类号： C08F4/642 , C08F2/34 , C08F4/619 , C08F4/6192 , C08F4/628 , C08F4/648 , C08F4/658 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F210/02 , C08F210/16 , C08J5/18 , C08L23/00 , C08L23/08 , C08L23/16
CPC分类号： C08F10/02 , C08F210/16 , C08J5/18 , C08L23/0815 , C08F4/61912 , C08F4/61916 , C08F4/61922 , C08F4/65912 , C08F4/65916 , C08F4/65922 , C08F4/65925 , C08J2323/08 , C08L2314/06 , Y10S526/901 , Y10S526/905
摘要： In gas phase polymerizations and copolymerizations of ethylene, temperature controls the molecular weight, expressed as MI (wherein MI is measured according to ASTM D-1238 Condition E), of the resin product. Increase in polymerization temperature produces decrease in MI; whereas, decrease in polymerization temperature produces increase in MI.
摘要翻译：在乙烯的气相聚合和共聚中，温度控制树脂产物的MI（其中MI根据ASTM D-1238条件E测量）表示的分子量。聚合温度的升高导致MI降低; 而聚合温度的降低导致MI增加。

96. 发明授权

US5589539A Process for preparing an in situ polyethylene blend 失效
标题翻译：制备原位聚乙烯共混物的方法
公开(公告)号：US5589539A
公开(公告)日：1996-12-31
申请号：US343849
申请日：1994-11-23
申请人： Burkhard E. Wagner , Arakalgud V. Ramamurthy
发明人： Burkhard E. Wagner , Arakalgud V. Ramamurthy
IPC分类号： C08F2/00 , C08F2/34 , C08F4/60 , C08F4/658 , C08F10/00 , C08F10/02 , C08F210/16 , C08L23/04 , C08L23/08 , C08L23/16 , C08F297/08
CPC分类号： C08F210/16 , C08L23/04 , C08L2205/02 , C08L23/0815 , C08L2308/00
摘要： A process for the production of an in situ particulate polyethylene blend comprising contacting a magnesium/titanium based catalyst system including a particulate precursor with one or more alpha-olefins in each of two or more reactors connected in series, in the gas phase, under polymerization conditions, with the provisos that:(a) the particulate precursor has a particle size distribution span of no greater than about 1.5 as introduced into the first reactor in the series;(b) ethylene is introduced into each reactor;(c) optionally, an alpha-olefin having at least 3 carbon atoms is introduced into at least one reactor;(d) the mixture of ethylene polymer matrix and active catalyst formed in the first reactor in the series is transferred to the subsequent reactors in the series; and(e) the polymerization conditions in each reactor are such that a high molecular weight polymer is formed in at least one reactor and a low molecular weight polymer is formed in at least one other reactor wherein the ratio of molecular weights of the high molecular weight polymer to low molecular weight polymer in the final product is at least about 8:1.
摘要翻译：一种生产原位颗粒聚乙烯混合物的方法，其包括在聚合过程中使包含颗粒前体的镁/钛基催化剂体系与在气相中串联连接的两个或更多个反应器的每一个中的一个或多个α-烯烃条件，条件是：（a）颗粒前体的粒度分布跨度不大于约1.5，引入到该系列的第一反应器中; （b）将乙烯引入每个反应器中; （c）任选地，将具有至少3个碳原子的α-烯烃引入至少一个反应器中; （d）将串联的第一反应器中形成的乙烯聚合物基质和活性催化剂的混合物转移到该系列的后续反应器中; 和（e）每个反应器中的聚合条件使得在至少一个反应器中形成高分子量聚合物，并且在至少一个其他反应器中形成低分子量聚合物，其中高分子量的分子量聚合物与最终产物中的低分子量聚合物的摩尔比为至少约8:1。

97. 发明授权

US5583189A Polymerization processes 失效
标题翻译：聚合工艺
公开(公告)号：US5583189A
公开(公告)日：1996-12-10
申请号：US441912
申请日：1995-05-16
申请人： Rolf L. Geerts , Syriac J. Palackal , Ted M. Pettijohn , Robert M. Infield
发明人： Rolf L. Geerts , Syriac J. Palackal , Ted M. Pettijohn , Robert M. Infield
IPC分类号： C08F4/658 , C08F4/52 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F4/655 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F4/628
CPC分类号： C08F10/00 , C08F4/61912 , C08F4/61916 , C08F4/6192
摘要： In accordance with the present invention, there is provided catalyst systems and processes for preparing such catalyst systems comprising reacting a metallocene compound, a solid organoaluminoxy product, and an organometal compound. Further there is provided processes for the polymerization of olefins using the catalyst systems.
摘要翻译：根据本发明，提供了催化剂体系和制备这种催化剂体系的方法，包括茂金属化合物，固体有机铝氧化物产物和有机金属化合物的反应。此外，提供了使用催化剂体系进行烯烃聚合的方法。

98. 发明授权

US5578540A Catalyst for the preparation of elastomeric ethylene-propylene copolymers 失效
标题翻译：用于制备弹性体乙烯 - 丙烯共聚物的催化剂
公开(公告)号：US5578540A
公开(公告)日：1996-11-26
申请号：US595451
申请日：1996-02-05
申请人： Viviano Banzi , Gianni Loberti
发明人： Viviano Banzi , Gianni Loberti
IPC分类号： C08F4/60 , C08F4/654 , C08F4/658 , C08F10/00 , C08F210/16 , B01J31/38
CPC分类号： C08F210/16
摘要： Solid component of a catalyst for the synthesis of elastomeric Ethylene-Propylene copolymers typically amorphous, basically consisting of a Titanium compound supported on a solid component mainly consisting of MgCl.sub.2, prepared by a process which comprises putting a solution (I), basically consisting of an organometallic compound of Aluminium diluted with aliphatic hydrocarbons, in contact with a solution (II) containingan anhydrous Magnesium halide in a composition of solvents selected from halohydrocarbons and aromatic hydrocarbons and relative mixtures, in the presence of an Aluminium trihalide;a tetravalent Titanium compound having general formula Ti(OR).sub.4-n X.sub.n.
摘要翻译：用于合成弹性体乙烯 - 丙烯共聚物的固体组分通常是无定形的，基本上由负载在主要由MgCl 2组成的固体组分上的钛化合物组成，该方法包括将基本上由在三卤化铝的存在下，用选自卤代烃和芳族烃的溶剂组合物中含有无水卤化镁的溶液（II）和相对混合物与脂族烃稀释的铝的有机金属化合物接触; 具有通式Ti（OR）4-nXn的四价钛化合物。

99. 发明授权

US5561091A High activity polyethylene catalyst prepared from an alcohol and silicon tetrachloride 失效
标题翻译：由醇和四氯化硅制备的高活性聚乙烯催化剂
公开(公告)号：US5561091A
公开(公告)日：1996-10-01
申请号：US432879
申请日：1995-05-02
申请人： Robert I. Mink , Thomas E. Nowlin
发明人： Robert I. Mink , Thomas E. Nowlin
IPC分类号： C08F4/658 , C08F210/00 , C08F210/02 , C08F210/16 , C08F4/656
CPC分类号： C08F210/16 , Y02P20/52
摘要： A catalyst composition for producing linear low density polyethylene with relatively narrower molecular weight distributions is described. The catalyst is formed by treating silica having reactive OH groups with a dialkylmagnesium in a solvent for said dialkylmagnesium; then adding to said magnesium-containing support a mixture of ROH and SiCl.sub.4 to form an intermediate which is subsequently treated with a transition metal to form a transition metal-containing intermediate, the catalyst precursor. The catalyst precursor is activated with a trialkylaluminum compound.
摘要翻译：描述了一种生产具有相对较窄分子量分布的线性低密度聚乙烯的催化剂组合物。通过在二烷基镁的溶剂中用二烷基镁处理具有反应性OH基团的二氧化硅形成催化剂; 然后向所述含镁载体中加入ROH和SiCl 4的混合物以形成中间体，随后用过渡金属处理以形成含过渡金属的中间体催化剂前体。催化剂前体用三烷基铝化合物活化。

100. 发明授权

US5541271A Process for preparing polyolefins 失效
标题翻译：聚烯烃的制备方法
公开(公告)号：US5541271A
公开(公告)日：1996-07-30
申请号：US380149
申请日：1995-01-30
申请人： Akira Sano , Shiraishi Takeichi , Kunihiro Suzuki , Mitsuo Okamoto , Katsumi Usui , Hiroyuki Shimizu , Kazuo Matsuura
发明人： Akira Sano , Shiraishi Takeichi , Kunihiro Suzuki , Mitsuo Okamoto , Katsumi Usui , Hiroyuki Shimizu , Kazuo Matsuura
IPC分类号： C08F4/658 , C08F2/34 , C08F4/60 , C08F10/00
CPC分类号： C08F10/00 , Y10S526/901
摘要： A polyolefin having superior particle properties such as an extremely high bulk density, a large average particle diameter and a narrow particle size distribution, and having a narrow molecular weight distribution, is obtained in high yield, by polymerizing an olefin, using a catalyst comprising a solid catalyst component and an organometallic compound, the solid catalyst component being obtained by reacting a) a silicon oxide and/or an aluminum oxide, the reaction product of an organomagnesium compound and a compound of the general formula Me(OR).sub.n X.sub.Z-n, and a titanium compound, in the presence of ROH, and further reacting the resulting reaction product with a compound of the general formula AlR.sub.q X.sub.3-q.
摘要翻译：通过聚合烯烃，可以高收率地获得具有优异的颗粒性能如聚合密度高，平均粒径大，粒度分布窄，分子量分布狭窄的聚烯烃，固体催化剂组分和有机金属化合物，所述固体催化剂组分通过使a）氧化硅和/或氧化铝，有机镁化合物与通式Me（OR）n XZ-n的化合物的反应产物，和钛化合物，在ROH存在下进一步使所得反应产物与通式AlRqX 3-q的化合物反应。

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