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    • 93. 发明申请
    • High Discharge Capacity Lithium Battery
    • 高放电容量锂电池
    • US20110250490A1
    • 2011-10-13
    • US13165816
    • 2011-06-22
    • Jack W. Marple
    • Jack W. Marple
    • H01M2/02H01M6/04
    • H01M4/381H01M2/0217H01M2/022H01M2/0225H01M2/14H01M2/1653H01M2/18H01M4/02H01M4/40H01M4/581H01M4/5815H01M6/10H01M6/14H01M6/16H01M2004/028H01M2006/5094
    • A lithium/iron disulfide electrochemical battery cell with a high discharge capacity. The cell has a lithium negative electrode, an iron disulfide positive electrode and a nonaqueous electrolyte. The positive electrode mixture containing the iron disulfide contains highly packed solid materials, with little space around the solid particles, to provide a high concentration of iron disulfide within the mixture. The separator is thin, to allow more space within the cell for active materials, yet strong enough to prevent short circuits between the positive and negative electrodes under abusive conditions, even when swelling of the cathode during cell discharge places additional stressed on the separator. As a result, the ratio of the interfacial capacity of the positive electrode to the electrode interfacial volume is high, as is the actual capacity on low rate/low power and high rate/high power discharge.
    • 具有高放电容量的锂/二硫化铁电池电池。 电池具有锂负极,二硫化铁正极和非水电解质。 含有二硫化铁的正极混合物含有高密度的固体物质,在固体颗粒周围几乎没有空间,从而在混合物内提供高浓度的二硫化铁。 分离器薄,以允许活性材料中的电池内的更多空间,但是足够强大以防止在恶劣条件下正极和负极之间的短路,即使在电池放电期间阴极膨胀时,分离器附加应力也会增加。 结果,正极的界面容量与电极界面体积的比率高,低速率/低功率和高速率/高功率放电的实际容量也是如此。
    • 94. 发明授权
    • Nonaqueous electrolyte secondary battery, nonaqueous electrolyte, and charging method therefor
    • 非水电解质二次电池,非水电解质及其充电方法
    • US08026000B2
    • 2011-09-27
    • US11656486
    • 2007-01-23
    • Masato IwanagaYukihiro OkiKoji AbeKazuhiro Miyoshi
    • Masato IwanagaYukihiro OkiKoji AbeKazuhiro Miyoshi
    • H01M6/04
    • H01M10/0567H01M4/131H01M4/485H01M4/505H01M4/525H01M10/0569H01M2300/004
    • A nonaqueous electrolyte secondary battery of the invention has a positive electrode having a positive electrode active material, a negative electrode, and a nonaqueous electrolyte having electrolyte salt in a nonaqueous solvent. The electric potential of the positive electrode active material is 4.4 to 4.6 V relative to lithium, and the nonaqueous electrolyte contains a compound expressed by structural formula (I) below. The quantity of compound added is preferably 0.1% to 2% by mass. Also, the positive electrode active material preferably comprises a mixture of a lithium-cobalt composite oxide which is LiCoO2 containing at least both zirconium and magnesium and a lithium-manganese-nickel composite oxide that has a layer structure and contains at least both manganese and nickel. Thanks to such structure, a nonaqueous electrolyte secondary battery can be provided that is charged to charging termination potential of 4.4 to 4.6 V relative to lithium and that has enhanced overcharging safety.[Chemical Formula 1]
    • 本发明的非水电解质二次电池具有正极,具有正极活性物质,负极和非水电解质,在非水溶剂中具有电解质盐。 正极活性物质的电位相对于锂为4.4〜4.6V,非水电解质含有下述结构式(I)表示的化合物。 化合物的添加量优选为0.1质量%〜2质量%。 此外,正极活性物质优选包含锂 - 钴复合氧化物的混合物,其为至少含有锆和镁的两种LiCoO 2和具有层结构并且至少包含锰和镍两者的锂锰镍复合氧化物的混合物 。 由于这样的结构,可以提供非水电解质二次电池,其相对于锂充电至4.4至4.6V的充电终止电位,并且具有增强的过充电安全性。 [化学式1]
    • 95. 发明申请
    • IONIC ADDITIVES FOR ELECTROCHEMICAL DEVICES USING INTERCALATION ELECTRODES
    • 用于电化学电极的离子添加剂
    • US20110189548A1
    • 2011-08-04
    • US12699182
    • 2010-02-03
    • Kang Conrad Xu
    • Kang Conrad Xu
    • H01M6/16H01M6/00H01M6/04
    • H01M6/00H01M6/04H01M6/16
    • An electrochemical cell comprising a cathode comprising an electrode active material that reversibly intercalates and de-intercalates any of cations and molecules; an anode comprising an electrode active material that reversibly intercalates and de-intercalates any of cations, anions, and molecules; a separator material that separates the cathode from the anode; and an electrolyte comprising a base electrolyte composition, an ionic compound additive, and a solvent comprising any of aqueous and non-aqueous electrolyte solvents, wherein the additive dissolves in the base electrolyte composition as well a majority of the aqueous or non-aqueous electrolyte solvents, wherein the additive comprises a solubility of at least approximately 0.01 in the base electrolyte composition, wherein the additive dissociates into corresponding cations and anions upon dissolution, and wherein the cations originate from a metal element and reduce to an elemental form at a potential that is at least approximately 0.50 V above that of lithium.
    • 一种电化学电池,包括阴极,其包括可逆地插入和脱嵌任何阳离子和分子的电极活性材料; 阳极,其包括电极活性材料,其可逆地插入和脱嵌任何阳离子,阴离子和分子; 隔离材料,其将阴极与阳极分离; 以及包含基础电解质组合物,离子化合物添加剂和包含任何水性和非水电解质溶剂的溶剂的电解质,其中所述添加剂也溶解在基础电解质组合物中以及大部分水性或非水电解质溶剂 其中所述添加剂包含在所述基础电解质组合物中至少约0.01的溶解度,其中所述添加剂在溶解时解离成相应的阳离子和阴离子,并且其中所述阳离子源自金属元素,并且以潜在的形式降低为元素形式, 至少比锂的大约0.50V。
    • 97. 发明授权
    • All-solid-state battery
    • 全固态电池
    • US07914932B2
    • 2011-03-29
    • US11678157
    • 2007-02-23
    • Toshihiro YoshidaHiroyuki KatsukawaShigeto Okada
    • Toshihiro YoshidaHiroyuki KatsukawaShigeto Okada
    • H01M6/04H01M6/18H01M4/58
    • H01M4/5825H01M4/136H01M10/052H01M10/0562H01M2300/0068
    • An all-solid-state battery having a high output power and a long life, exhibiting high safety, and being produced at a low cost is provided. The all-solid-state battery has a cathode comprising a cathode material, an anode comprising an anode material, and a solid electrolyte layer comprising a solid electrolyte, wherein the cathode material, the anode material, and the solid electrolyte are a compound shown by the following formulas (1), (2), and (3), respectively: MaN1bX1c   (1) MdN2eX2f   (2) MgN3hX3i   (3) wherein M represents H, Li, Na, Mg, Al, K, or Ca and X1, X2, and X3 are polyanions, each of N1 and N2 is at least one atom selected from the group consisting of transition metals, Al, and Cu, and N3 is at least one atom selected from the group consisting of Ti, Ge, Hf, Zr, Al, Cr, Ga, Fe, Sc, and In.
    • 提供具有高输出功率和长寿命,高安全性并且以低成本生产的全固态电池。 全固态电池具有包括阴极材料的阴极,包括阳极材料的阳极和包含固体电解质的固体电解质层,其中阴极材料,阳极材料和固体电解质是由 分别为下式(1),(2)和(3):MaN1bX1c(1)MdN2eX2f(2)MgN3hX3i(3)其中M表示H,Li,Na,Mg,Al,K或Ca和X1, X2和X3是聚阴离子,N1和N2中的每一个是选自过渡金属,Al和Cu中的至少一个原子,N 3是选自Ti,Ge,Hf, Zr,Al,Cr,Ga,Fe,Sc和In。