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91. 发明授权

US5777184A Preparation of fluoroalkyl compounds and their derivatives 失效
标题翻译：氟烷基化合物及其衍生物的制备
公开(公告)号：US5777184A
公开(公告)日：1998-07-07
申请号：US882061
申请日：1997-06-25
申请人： Michael Van Der Puy , Alagappan Thenappan
发明人： Michael Van Der Puy , Alagappan Thenappan
IPC分类号： C07C17/00 , C07C29/149 , C07C45/54 , C07C67/11 , C07C21/18
CPC分类号： C07C45/54 , C07C17/00 , C07C29/149 , C07C67/11
摘要： A process for producing a fluorinated olefin having the formula: CH.sub.3-a F.sub.a CH.dbd.CHCl where a=1,2 or 3, said process comprising catalytically reacting a chlorinated organic compound with a fluorination agent under conditions sufficient to form said hydrofluorocarbon compound, said chlorinated organic compound having the formula: CH.sub.b Cl.sub.c F.sub.d CH.sub.e CHCl.sub.e where b=0, 1 or 2; c=0, 1, 2, or 3; d=0, 1, 2 or 3; and e=1 or 2 with the provisos that b+c+d=3, c+e>1 and b+e
摘要翻译：一种制备具有下式的CH3-aFaCH = CHCl的氟化烯烃的方法，其中a = 1,2或3，所述方法包括在足以形成所述氢氟烃化合物的条件下将氯化有机化合物与氟化剂催化反应，所述氯化有机物具有下式的化合物：CHbClcFdCHeCHCle其中b = 0,1或2; c = 0,1,2或3; d = 0,1,2或3; e = 1或2，条件是b + c + d = 3，c + e> 1，b + e <4。

92. 发明授权

US5763698A Process for reducing the fluorine content of hydrofluorocarbons and hydrohalofluorocarbons 失效
公开(公告)号：US5763698A
公开(公告)日：1998-06-09
申请号：US552962
申请日：1995-11-03
申请人： Leo Ernest Manzer , V. N. Mallikarjuna Rao , Steven Henry Swearingen
发明人： Leo Ernest Manzer , V. N. Mallikarjuna Rao , Steven Henry Swearingen
IPC分类号： B01J23/26 , B01J27/12 , C07B61/00 , C07C17/00 , C07C17/20 , C07C17/21 , C07C17/23 , C07C19/10 , C07C21/04 , C07C21/18 , C07C19/08
CPC分类号： C07C17/21 , C07C17/00 , C07C17/206
摘要： The fluorine content of an acyclic saturated compound of the formula C.sub.n F.sub.a X.sub.b H.sub.c (wherein each X is independently selected from the group consisting of Cl and Br, and wherein n is 1 to 6, a is 1 to 13, b is 0 to 12, c is 1 to 9, and a+b+c equals 2n+2) is reduced by reacting the acyclic saturated compound with HCl in the vapor phase at an elevated temperature in the presence of a catalyst, the mole ratio of HCl to the acyclic saturated compound being at least about 1:1.

93. 发明授权

US5736012A Process for the preparation of a fluorinated acid 失效
标题翻译：制备氟化酸的方法
公开(公告)号：US5736012A
公开(公告)日：1998-04-07
申请号：US711774
申请日：1996-09-10
申请人： Alagappan Thenappan , Michael Van Der Puy
发明人： Alagappan Thenappan , Michael Van Der Puy
IPC分类号： C07C51/215 , C07C17/00 , C07C51/00 , C07C51/16 , C07C51/31
CPC分类号： C07C51/215
摘要： A process for the preparation of a fluorinated acid such as trifluoroacetic acid, including admixing an hydrofluorocarbon, such as 1,1,1-trifluoroethane, with chlorine, an oxidizing agent and an additive to prevent or minimize decomposition; and irradiating the reaction mixture with a light source having a wavelength ranging from 2000 .ANG. to 14000 .ANG..
摘要翻译：一种制备氟化酸如三氟乙酸的方法，包括将氢氟烃如1,1,1-三氟乙烷与氯，氧化剂和添加剂混合以防止或最小化分解; 并用波长范围从2000安格到14000埃的光源照射反应混合物。

94. 发明授权

US5728902A Method for manufacturing 1,1,1,3,3-pentafluoropropene 失效
标题翻译：制备1,1,1,3,3-五氟丙烯的方法
公开(公告)号：US5728902A
公开(公告)日：1998-03-17
申请号：US696527
申请日：1996-08-14
申请人： Hirokazu Aoyama , Akinori Yamamoto , Noriaki Shibata
发明人： Hirokazu Aoyama , Akinori Yamamoto , Noriaki Shibata
IPC分类号： B01J23/44 , B01J27/232 , C07B61/00 , C07C17/00 , C07C17/354 , C07C17/363 , C07C19/08 , C07C21/18
CPC分类号： C07C17/00 , C07C17/363
摘要： A method for manufacturing 1,1,1,3,3-pentafluoropropene comprises the steps of adding 2-trifluoromethyl-3,3,3-trifluoropropionic acid under the presence of metal carbonate and/or metal hydrogencarbonate in an aprotic solvent at reaction temperature particularly from 40.degree. C. to 80.degree. C., of refining resulting reaction products to obtain 1,1,1,3,3-pentafluoropropene, and further of coexisting a desiccating agent therein. According to the method, 1,1,1,3,3-pentafluoropropene can be manufactured through industrially efficient and cost-effective way using 2-trifluoromethyl-3,3,3-trifluoropropionic acid as a raw material.
摘要翻译：制备1,1,1,3,3-五氟丙烯的方法包括在金属碳酸盐和/或金属碳酸氢盐存在下，在非质子传递溶剂中，在反应温度下加入2-三氟甲基-3,3,3-三氟丙酸特别是从40℃到80℃，精制所得反应产物得到1,1,1,3,3-五氟丙烯，并进一步在其中共存干燥剂。根据该方法，可以使用2-三氟甲基-3,3,3-三氟丙酸作为原料，以工业上有效且成本有效的方式制造1,1,1,3,3-五氟丙烯。

95. 发明授权

US5714654A Method of Producing 1,1,1,3,3-pentafluoropropane and/or 1,1,3,3,3-pentafluoropropene 失效
标题翻译：生产1,1,1,3,3-五氟丙烷和/或1,1,3,3,3-五氟丙烯的方法
公开(公告)号：US5714654A
公开(公告)日：1998-02-03
申请号：US549816
申请日：1995-12-08
申请人： Akinori Yamamoto , Eiji Seki , Hirokazu Aoyama , Tatsuo Nakada
发明人： Akinori Yamamoto , Eiji Seki , Hirokazu Aoyama , Tatsuo Nakada
IPC分类号： B01J23/40 , B01J23/44 , C07B61/00 , C07C17/00 , C07C17/23 , C07C17/354 , C07C19/08 , C07C21/18
CPC分类号： C07C19/08 , C07C17/00 , C07C17/23 , C07C17/354
摘要： A method is proposed for producing 1,1,1,3,3-pentafluoropropane, in which 1,1,3,3,3-pentafluoropropene is reduced at a temperature between 40.degree. C. and 300.degree. C. by reacting it with hydrogen in a gas phase in the presence of a palladium catalyst. Further, a method is proposed for producing 1,1,1,3,3-pentafluoropropane and/or 1,1,3,3,3-pentafluoropropene, in which the raw material 2-chloro-1,1,3,3,3-pentafluoropropene is hydrogenated especially at a temperature between 30.degree. C. and 450.degree. C. in the presence of a catalyst composed of at least one metal selected from palladium, platinum and rhodium. Further, a method is proposed of producing 1,1,3,3,3-pentafluoropropene, in which 1,1,1,3,3-pentafluoro-2,3-dichloropropane is dechlorinated by using hydrogen in the presence of a metal oxide catalyst. Based on these production methods, 1,1,1,3,3-pentafluoropropane and/or 1,1,3,3,3-pentafluoropropene can thus be produced with high yield rates.
摘要翻译： PCT No.PCT / JP94 / 00865 Sec。 371 1995年12月8日第 102（e）日期1995年12月8日PCT 1994年5月30日PCT PCT。公开号WO94 / 29251 日期1994年12月22日提出一种制备1,1,1,3,3-五氟丙烷的方法，其中1,1,3,3,3-五氟丙烯在40℃至300℃的温度下还原通过在钯催化剂的存在下在气相中与氢反应。此外，提出了制造1,1,1,3,3-五氟丙烷和/或1,1,3,3,3-五氟丙烯的方法，其中原料2-氯-1,1,3,3- 在由至少一种选自钯，铂和铑的金属组成的催化剂的存在下，特别在30℃至450℃的温度下氢化3-五氟丙烯。此外，提出了一种制备1,1,3,3,3-五氟丙烯的方法，其中1,1,1,3,3-五氟-2,3-二氯丙烷在金属存在下通过使用氢而脱氯氧化物催化剂。基于这些制造方法，可以以高产率制造1,1,1,3,3-五氟丙烷和/或1,1,3,3,3-五氟丙烯。

96. 发明授权

US5683978A Saturated linear polyfluorohydrocarbons in cleaning compositions 失效
标题翻译：饱和的线性多氟烃在清洁组合物中
公开(公告)号：US5683978A
公开(公告)日：1997-11-04
申请号：US460020
申请日：1995-06-02
申请人： Carl George Krespan , V. N. Mallikarjuna Rao
发明人： Carl George Krespan , V. N. Mallikarjuna Rao
IPC分类号： B01D12/00 , B01J23/40 , C07B61/00 , C07C17/00 , C07C17/23 , C07C17/278 , C07C17/354 , C07C19/08 , C11D3/24 , C11D7/30 , H05K3/26 , C11D7/50 , C23G5/02 , C23G5/028
CPC分类号： C07C19/08 , C07C17/23 , C07C17/278 , C07C17/354
摘要： The compounds CF.sub.3 CHFCHFCF.sub.2 CF.sub.3, CF.sub.3 CH.sub.2 CHFCF.sub.2 CF.sub.3, CF.sub.3 CHFCH.sub.2 CF.sub.2 CF.sub.3, CF.sub.3 CHFCHFCF.sub.2 CF.sub.2 CF.sub.3, CF.sub.3 CH.sub.2 CHFCF.sub.2 CF.sub.2 CF.sub.3, CF.sub.3 CHFCH.sub.2 CF.sub.2 CF.sub.2 CF.sub.3, CF.sub.3 CF.sub.2 CH.sub.2 CHFCF.sub.2 CF.sub.3, CF.sub.3 CF.sub.2 CHFCHFCF.sub.2 CF.sub.2 CF.sub.3, CF.sub.3 CHFCHFCF.sub.2 CF.sub.2 CF.sub.2 CF.sub.3, CF.sub.3 CHFCH.sub.2 CF.sub.2 CF.sub.2 CF.sub.2 CF.sub.3, CF.sub.3 CH.sub.2 CHFCF.sub.2 CF.sub.2 CF.sub.2 CF.sub.3, CF.sub.3 CF.sub.2 CHFCH.sub.2 CF.sub.2 CF.sub.2 CF.sub.3, and CF.sub.3 CF.sub.2 CH.sub.2 CHFCF.sub.2 CF.sub.2 CF.sub.3 ; and compositions thereof. Catalytic processes using Group VIII metals are disclosed for reacting selected olefinic starting materials with hydrogen to produce as the major products dihydropolyfluoroalkanes or trihydropolyfluoroalkanes wherein the hydrogens are positioned on two adjacent carbon atoms; as are processes using iodine and/or hydrogen iodide in the reduction of selected olefinic starting materials to dihydropolyfluoroalkanes or trihydropolyfluoroalkanes.
摘要翻译：化合物CF3CHFCHFCF2CF3，CF3CH2CHFCF2CF3，CF3CHFCH2CF2CF3，CF3CHFCHFCF2CF2CF3，CF3CH2CHFCF2CF2CF3，CF3CHFCH2CF2CF2CF3，CF3CF2CH2CHFCF2CF3，CF3CF2CHFCHFCF2CF2CF3，CF3CHFCHFCF2CF2CF2CF3，CF3CHFCH2CF2CF2CF2CF3，CF3CH2CHFCF2CF2CF2CF3，CF3CF2CHFCH2CF2CF2CF3，和CF3CF2CH2CHFCF2CF2CF3; 及其组合物。公开了使用第VIII族金属的催化方法，用于使所选的烯属起始原料与氢气反应，以产生主要产物二氢多氟烷烃或三氢多氟烷烃，其中氢位于两个相邻的碳原子上; 以及使用碘和/或碘化氢将选择的烯属原料还原成二氢多氟烷烃或三氢多氟烷烃的方法也是如此。

97. 发明授权

US5629462A Hydrodehalogenation catalysts and their preparation and use 失效
标题翻译：氢化脱卤催化剂及其制备与应用
公开(公告)号：US5629462A
公开(公告)日：1997-05-13
申请号：US459593
申请日：1995-06-02
申请人： V. N. Mallikarjuna Rao
发明人： V. N. Mallikarjuna Rao
IPC分类号： B01J23/52 , B01J21/18 , B01J23/40 , B01J37/16 , B01J37/18 , C07B61/00 , C07C17/00 , C07C17/23 , C07C19/08 , C07C19/10
CPC分类号： B01J37/18 , B01J21/18 , B01J23/40 , B01J23/52 , B01J37/16 , C07C17/23
摘要： A carbon-supported metal hydrodehalogenation catalyst is disclosed which is prepared by impregnating a carbon support having an ash content of less than about 0.2% by weight (based on the weight of said support) with a combination of metals consisting essentially of from 5 to 95 parts by weight gold and from 95 to 5 parts by weight total ruthenium, rhodium, palladium, osmium, iridium, and/or platinum; and treating said impregnated carbon composition to dry the composition and to provide metal of said combination in a reduced state, the impregnation of treatment being accomplished at a temperature of about 350.degree. C. or less. The advantageous use of the catalyst for the catalytic hydrogenolysis of fluorohalocarbons and fluorohalohydrocarbons is also disclosed.
摘要翻译：公开了一种碳载金属加氢脱卤催化剂，其通过用基本上由5至95的金属组合浸渍具有小于约0.2重量％（基于所述载体的重量）的灰分含量的碳载体制备重金属和95至5重量份总钌，铑，钯，锇，铱和/或铂; 并且处理所述浸渍的碳组合物以干燥所述组合物并且以降低的状态提供所述组合的金属，所述浸渍处理在约350℃或更低的温度下完成。还公开了催化剂用于氟代卤代烃和氟代卤代烃的催化氢解的有利用途。

98. 发明授权

US5608128A Production methods of 1,1,1,4,4,4-hexsfluoro-2-butene compounds and 1,1,1,4,4,4,-hexafluorobutane 失效
标题翻译： 1,1,1,4,4,4-六氟-2-丁烯化合物和1,1,1,4,4,4 - 六氟丁烷的制备方法
公开(公告)号：US5608128A
公开(公告)日：1997-03-04
申请号：US495662
申请日：1995-07-27
申请人： Tatsuo Nakada , Hirokazu Aoyama , Seiji Takubo
发明人： Tatsuo Nakada , Hirokazu Aoyama , Seiji Takubo
IPC分类号： C07B61/00 , C07C17/00 , C07C17/06 , C07C17/08 , C07C17/10 , C07C17/23 , C07C17/354 , C07C19/08 , C07C21/18 , C07C29/08 , C07C17/013 , C07C21/04
CPC分类号： C07C21/18 , C07C17/06 , C07C17/08 , C07C17/10 , C07C17/354 , C07C19/08 , C12C11/02
摘要： The present invention provides a production method of obtaining the mixture of 1,1,1,4,4,4-hexafluoro-2,3-dichloro-2-butene, 1,1,1,4,4,4-hexafluoro-2-chloro-2-butene and 1,1,1,4,4,4-hexafluoro-2-butene (1,1,1,4,4,4-hexafluoro-2-butene compounds) by reacting at least one of butane, butene and butadiene with chlorine and HF in the presence of a suitable catalyst, and also a production method of obtaining 1,1,1,4,4,4-hexafluorobutane by reducing said products in the presence of a noble metal catalyst. According to these methods, 1,1,1,4,4,4-hexafluorobutane, a compound useful for a blowing agent, cleaning agent or heating medium as an alternative to HCFC, can be obtained at a high selectivity rate; and 1,1,1,4,4,4-hexafluoro-2-butene compounds including 1,1,1,4,4,4-hexafluoro-2,3-dichloro-2-butene, 1,1,1,4,4,4-hexafluoro-2-chloro-2-butene and 1,1,1,4,4,4-hexafluoro-2-butene, which are obtained as reaction intermediates in the production method of 1,1,1,4,4,4-hexafluorobutane and can be used as industrial intermediate chemicals for medicine and agricultural chemicals, can be produced less costly at high yields in a single step process.
摘要翻译： PCT No.PCT / JP94 / 00068 Sec。 371日期：1995年7月27日 102（e）日期1995年7月27日PCT 1994年1月19日PCT PCT。出版物WO94 / 17020 日期1994年8月4日本发明提供了获得1,1,1,4,4,4-六氟-2,3-二氯-2-丁烯，1,1,1,4,4 ，4-六氟-2-氯-2-丁烯和1,1,1,4,4,4-六氟-2-丁烯（1,1,1,4,4,4-六氟-2-丁烯化合物）通过在合适的催化剂存在下使丁烷，丁烯和丁二烯中的至少一种与氯和HF反应，以及通过在存在下还原所述产物来获得1,1,1,4,4,4-六氟丁烷的制备方法的贵金属催化剂。根据这些方法，可以以高选择率获得1,1,1,4,4,4-六氟丁烷，可用于发泡剂的化合物，清洗剂或作为HCFC替代物的加热介质; 和1,1,1,4,4,4-六氟-2-丁烯化合物，包括1,1,1,4,4,4-六氟-2,3-二氯-2-丁烯，1,1,1， 4,4,4-六氟-2-氯-2-丁烯和1,1,1,4,4,4-六氟-2-丁烯，其作为反应中间体在1,1,1 ，4,4,4-六氟丁烷，可用作医药和农药的工业中间体化学品，可以在单步过程中以高产率生产成本较低。

99. 发明授权

US5600036A 2-trifluoromethyl-4-chlorobenzalchloride and 2-methyl-3-nitro-5-chlorobenzotrifluoride useful as intermediates for preparing 2-methyl-3-aminobenzotrifluoride 失效
标题翻译： 2-三氟甲基-4-氯二氯二氯甲烷和2-甲基-3-硝基-5-氯三氟甲苯，用作制备2-甲基-3-氨基三氟甲苯的中间体
公开(公告)号：US5600036A
公开(公告)日：1997-02-04
申请号：US467678
申请日：1995-06-06
申请人： Takayuki Nishimiya , Masatomi Kanai , Toshikazu Kawai
发明人： Takayuki Nishimiya , Masatomi Kanai , Toshikazu Kawai
IPC分类号： B01J23/44 , C07B61/00 , C07C17/00 , C07C17/12 , C07C17/23 , C07C25/13 , C07C205/12 , C07C209/36 , C07C211/52 , C07C205/06
CPC分类号： C07C201/08 , C07C17/12 , C07C17/23 , C07C209/36 , C07C25/13
摘要： 2-Trifluoromethyl-4-chloro-benzalchloride and 2-methyl-3-nitro-5-chlorobenzotrifluoride, are intermediates in a process of preparing 2-methyl-3-aminobenzo-trifluoride. In this process, 2-trifluoromethyl-4-chlorobenzal-chloride is prepared by chlorinating o-trifluoromethylbenzalhalide, and 2-methyl-3-nitro-5-chlorobenzotrifluoride is prepared at first by hydrogenating the 2-trifluoro-methyl-4-chlorobenzalhalide to form a 2-methyl-5-monochlorobenzotrifluoride and then by nitrating the 2-methyl-5-monochlorobenzotrifluoride. Following this process, 2-methyl-3-aminobenzotrifluoride (MA-BTF) is prepared by hydrogenating the 2-methyl-3-nitro-5-chlorobenzotrifluoride. The thus prepared 2-methyl-3-aminobenzotrifluoride is useful as an intermediate in preparing medicines, agricultural chemicals and other chemical products.
摘要翻译： 2-三氟甲基-4-氯 - 亚苄基氯和2-甲基-3-硝基-5-氯三氟甲苯是制备2-甲基-3-氨基苯并三氟化氮的中间体。在此过程中，通过氯化邻 - 三氟甲基苯甲酰卤来制备2-三氟甲基-4-氯二氯苄氯，首先通过将2-三氟甲基-4-氯亚苄基卤化氢氢化成2-甲基-3-硝基-5-氯三氟甲苯形成2-甲基-5-单氯三氟甲苯，然后硝化2-甲基-5-单氯三氟甲苯。在该方法之后，通过氢化2-甲基-3-硝基-5-氯三氟甲苯来制备2-甲基-3-氨基三氟甲苯（MA-BTF）。由此制备的2-甲基-3-氨基三氟甲苯可用作制备药物，农药和其它化学产品的中间体。

100. 发明授权

US5569796A Process for producing fluorinated saturated hydrocarbon 失效
标题翻译：氟化饱和烃的制备方法
公开(公告)号：US5569796A
公开(公告)日：1996-10-29
申请号：US406904
申请日：1995-03-29
申请人： Toshiro Yamada , Yasuhiro Mitsuda
发明人： Toshiro Yamada , Yasuhiro Mitsuda
IPC分类号： C07C17/00 , C07C17/23 , C07C19/08
CPC分类号： C07C17/00 , C07C17/23
摘要： A fluorinated saturated hydrocarbon represented by the formula (2): ##STR1## wherein R and R' represent a perfluoroalkyl group or both R and R' are bonded together to form a perfluoroalkylene group which is a part of a ring, is industrially advantageously produced with good operating characteristics by reacting a fluorinated unsaturated hydrocarbon represented by the formula (1):R --CF.dbd.CF-R' (1)wherein R and R' are as defined above, with hydrogen in the presence of a platinum catalyst.
摘要翻译： PCT No.PCT / JP93 / 01395 Sec。 371日期1995年3月29日 102（e）1995年3月29日PCT 1993年9月30日PCT公布。出版物WO94 / 07829 日期：1994年04月14日由式（2）表示的氟化饱和烃：其中R和R'代表全氟烷基或R和R'都结合在一起形成全氟亚烷基，通过使由式（1）表示的氟化不饱和烃：R -CF = CF-R'（1）（其中R和R'如上定义）与氢反应，在工业上有利地产生具有良好操作特性的铂催化剂的存在。

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