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11. 发明授权

US08993700B2 Fluorescent polymers of 7-hydroxycoumarin compounds, chemical sensors comprising them, and polymerizable fluorescent compound of 7-hydroxycoumarin 有权
标题翻译： 7-羟基香豆素化合物的荧光聚合物，包含它们的化学传感器和7-羟基香豆素的可聚合荧光化合物
公开(公告)号：US08993700B2
公开(公告)日：2015-03-31
申请号：US13498090
申请日：2010-09-24
申请人： Pierrick Buvat , Lucie Malosse , Alain Siove , Dominique Ades
发明人： Pierrick Buvat , Lucie Malosse , Alain Siove , Dominique Ades
IPC分类号： C08F24/00 , C07D311/00 , C09B69/10 , C09B57/02 , G01N33/52
CPC分类号： G01N21/64 , C08F220/68 , C09B57/02 , C09B69/109 , G01N33/0037 , G01N33/0047 , G01N33/0057 , G01N33/52 , G01N2201/06113 , G01N2201/068 , Y02A50/245 , Y10T428/2982 , Y10T436/163333 , Y10T436/173076
摘要： Polymers and copolymers of polymerizable fluorescent compounds of 7-hydroxycoumarin such as Ethyl-2-methacrylate Umbelliferone-4-acetate are provided. In addition, a sensor comprising this polymer notably for detecting and/or assaying nitrated and organophosphorus compounds, explosives, and toxic compounds is provided.
摘要翻译：提供了7-羟基香豆素的可聚合荧光化合物如2-乙基-2-甲基丙烯酸甲基松香酮-4-乙酸酯的聚合物和共聚物。此外，提供了包含该聚合物的传感器，其特别用于检测和/或测定硝化和有机磷化合物，爆炸物和有毒化合物。

12. 发明申请

US20140246094A1 ASYMMETRIC CYANINE DYES FOR PHOTOVOLTAIC APPLICATIONS 审中-公开
标题翻译：用于光伏应用的不对称氰基染料
公开(公告)号：US20140246094A1
公开(公告)日：2014-09-04
申请号：US14240981
申请日：2012-08-24
申请人： Giuseppe Caputo
发明人： Giuseppe Caputo
IPC分类号： H01G9/20 , C09B57/02 , C09B57/00
CPC分类号： C09B57/00 , C09B23/0075 , C09B23/0091 , C09B23/10 , C09B23/105 , C09B57/008 , C09B57/02 , C09B69/008 , H01G9/2031 , H01G9/2059 , H01L51/0064 , Y02E10/542 , Y02E10/549
摘要： Asymmetric dyes of the D-π-A type have the Formula (1), including the valence tautomers thereof. The dyes of Formula (1) are suitable for use in dye-sensitized solar cells (DSSC), in photoelectrochemical devices or in photonic devices. A solar cell and a device for photoelectric conversion contain an asymmetric dye of Formula (1). The dyes of Formula (1) are also suitable for conjugating with optically active nanoparticles (NP).
摘要翻译： D-型p型-A型的不对称染料具有式（1），包括其价态互变异构体。式（1）的染料适用于染料敏化太阳能电池（DSSC），光电化学装置或光子器件。太阳能电池和光电转换装置含有式（1）的不对称染料。式（1）的染料也适用于与光学活性纳米粒子（NP）缀合。

13. 发明授权

US5405976A Benzpyrylium squarylium and croconylium dyes, and processes for their preparation and use 失效
标题翻译： Benzyrylium squarylium和croconylium dye，及其制备和使用的方法
公开(公告)号：US5405976A
公开(公告)日：1995-04-11
申请号：US126427
申请日：1993-09-24
申请人： Stephen J. Telfer , Robert P. Short , Stephen G. Stroud , Anthony J. Puttick , Socorro; M. Ramos , Michael J. Zuraw
发明人： Stephen J. Telfer , Robert P. Short , Stephen G. Stroud , Anthony J. Puttick , Socorro; M. Ramos , Michael J. Zuraw
IPC分类号： B41M5/26 , B41M5/385 , B41M5/392 , B41M5/40 , B41M5/46 , C09B57/00 , C09B57/02 , G11B7/244 , C07D311/58 , C07D335/06 , C07D405/10
CPC分类号： B41M5/465 , C09B57/007 , C09B57/02 , G11B7/244 , B41M5/26 , B41M5/3854 , B41M5/392 , Y10S430/145
摘要： Dyes comprising an inner salt of a compound of the formula:Q.sup.1 =Z-Q.sup.2wherein:Q.sup.1 is a 4-(benz[b]-4H-pyrylium)methylidene, 4-(benz[b]-4H-thiopyrylium)methylidene or 4-(benz[b]-4H-selenopyrylium)methylidene grouping;Z is a 1,3-(2-hydroxy-4-oxo-2-cyclobutylidene) hydroxide or 1,3-(2-hydroxy-4,5-dioxo-2-cyclopentylidene) hydroxide ring; andQ.sup.2 is a 4-(benz[b]-4H-pyran-4-ylidene)methyl, 4-(benz[b]-4H-thiopyran-4-ylidene)methyl or 4-(benz[b]-4H-selenopyran-4-ylidene)methyl grouping;wherein at least one of the groupings Q.sup.1 and Q.sup.2 carries at its 2-position a substituent in which a non-aromatic carbon atom is bonded directly to the benzpyrylium, benzthiopyrylium or benzselenopyrylium nucleus, subject to the proviso that if this 2-substituent contains an aromatic nucleus, this aromatic nucleus is not conjugated with the benzpyrylium, benzthiopyrylium or benzselenopyrylium nucleus to which it is attached, are useful as visible and near infra-red absorbers, having high extinction coefficients and improved solubility in polymeric media.
摘要翻译：染料，其包含下式化合物的内盐：Q1 = Z-Q2其中：Q1是4-（苯并[b] -4H-吡喃鎓）亚甲基，4-（苯并[b] -4H-硫代吡啶鎓）亚甲基或 4-（苯并[b] -4H-硒代吡咯鎓）亚甲基; Z是1,3-（2-羟基-4-氧代-2-环亚丁基）氢氧化物或1,3-（2-羟基-4,5-二氧代-2-亚环戊基）氢氧化物环; 并且Q2是4-（苯并[b] -4H-吡喃-4-亚基）甲基，4-（苯并[b] -4H-噻喃-4-亚基）甲基或4-（苯并[b] 硒代吡喃-4-亚基）甲基; 其中分组Q1和Q2中的至少一个在其2-位上带有非芳族碳原子直接键合到苯并吡喃鎓，苯并硫代吡喃鎓或苯并硒吡喃鎓核的取代基，条件是如果该2-取代基含有芳香核，该芳香核不与其连接的苯并吡喃鎓，苯并硫代吡喃鎓或苯并硒吡喃鎓核共轭，可用作可见光和近红外吸收剂，具有高消光系数和在聚合物介质中改善的溶解性。

14. 发明授权

US5084580A Polycylic dyes 失效
标题翻译：多晶染料
公开(公告)号：US5084580A
公开(公告)日：1992-01-28
申请号：US410630
申请日：1989-09-21
申请人： Ronald W. Kenyon , David F. Newton , Derek Thorp
发明人： Ronald W. Kenyon , David F. Newton , Derek Thorp
IPC分类号： C07D487/04 , C07D491/048 , C07D493/04 , C07D495/04 , C09B57/00 , C09B57/02
CPC分类号： C09B57/00
摘要： Compounds of the Formula VII: ##STR1## wherein; X.sup.1 and X.sup.2 are each independently selected from H, cyano, alkyl, alkoxy, aryl, carbamoyl, sulphamoyl, COOH and carboxylic acid ester;Z.sup.1 and Z.sup.2 are both --O--;R.sup.1 and R.sup.2 are each independently selected from H, or an optionally substituted alkyl, alkenyl, cycloalkyl, aryl and aralkyl group; orR.sup.1 and R.sup.2 together with the N atom to which they are attached, form a heterocycle;R.sup.4, R.sup.5, R.sup.7 and R.sup.8 are each independently selected from E, halogen, or an optionally substituted alkyl, alkenyl and alkoxy group orR.sup.1 and R.sup.4 or R.sup.2 and R.sup.5 together with the N atom and the two carbon atoms in Ring B to which they are attached form a heterocycle fused to Ring B; orR.sup.1 and R.sup.7 or R.sup.2 and R.sup.8 together with the N atom and the two carbon atoms in Ring A to which they are attached form a heterocycle fused to Ring A; orR.sup.6 is selected from H, halogen, or an optionally substituted alkyl or alkoxy group and a group NR.sup.1 R.sup.2 in which each of R.sup.1 and R.sup.2 are independently as hereinbefore described, and where R.sup.6 is NR.sup.1 R.sup.2, R.sup.6 is the same or different from the NR.sup.1 R.sup.2 group present in Ring B.These compounds are suitable for the coloration of polyester textile material in shades from green through to reddish-blue.

15. 发明授权

US4764622A Light-collecting coumarin derivatives 失效
标题翻译：聚光香豆素衍生物
公开(公告)号：US4764622A
公开(公告)日：1988-08-16
申请号：US920482
申请日：1986-10-17
申请人： Uwe Claussen , Horst Harnisch
发明人： Uwe Claussen , Horst Harnisch
IPC分类号： C08K5/00 , C08K5/315 , C09B57/02 , C09K11/06 , C07D235/18 , C07D263/56 , C07D277/66 , C07D309/34
CPC分类号： C09K11/06 , C08K5/0041 , C08K5/315 , C09B57/02
摘要： A light-collecting system, which contains a coumarin derivative of the formula ##STR1## in which T denotes O or NR.sub.4,R.sub.4 represents hydrogen, optionally substituted aryl, cycloalkyl or aralkyl,R.sub.1 denotes a carbocyclic or heterocyclic 5 or 6 membered ring bonded via a C.atom, or a 5 or 6 membered heterocyclic ring which is bonded via a N atom and is rotationally asymmetrical to an axis placed through the coumarin/N-heterocyclic bond, the 5 or 6 membered rings may carry non-ionic substituents and for an optionally substituted benzene ring or naphthalene ring to be fused to the said rings;X signifies ##STR2## or --OR.sub.2 ', R.sub.2 represents hydrogen, alkyl, cycloalkyl, aralkyl or aryl, hydrocarbon radicals may be substituted, andR.sub.3, in addition to having the definitions given for R.sub.2, also signifies a radical of the formulaeR.sub.6 --(X).sub.n --CO-- or R.sub.7 --(X).sub.n --SO.sub.2 --R.sub.6 and R.sub.7 represent alkyl, cycloalkyl, aryl or aralkyl, the hydrocarbon radicals may be substituted,X represents NH or O andn represents O or 1, orR.sub.2 and R.sub.3 together with the N atom and optionally with the inclusion of further hetero-atoms form a 5 or 6 membered ring, this ring may carry non-ionic substituents and an optionally substituted benzene ring or naphthalene ring may be fused thereto, orR.sub.2 and R.sub.3 together form a di-unsaturated radical of the formula ##STR3## R.sub.8 represents optionally substituted alkyl, aryl, cycloalkyl or aralkyl, andR.sub.2 ' signifies optionally substituted alkyl, alkenyl, cycloalkyl, aryl or aralkyl,and their use in light-collecting systems.
摘要翻译：含有式“IMAGE”的香豆素衍生物的光收集系统，其中T表示O或NR4，R4表示氢，任选取代的芳基，环烷基或芳烷基，R1表示碳环或杂环的5或6元环， C原子或5或6元杂环，其通过N原子键合并且与通过香豆素/ N-杂环键放置的轴旋转不对称，所述5或6元环可以携带非离子取代基，任选取代的苯环或萘环与所述环稠合; X表示或-OR2'，R2表示氢，烷基，环烷基，芳烷基或芳基，烃基可以被取代，R3除了具有给定的R2的定义外，还表示式R6- （X）n-CO-或R7-（X）n-SO2-R6和R7代表烷基，环烷基，芳基或芳烷基，烃基可以被取代，X代表NH或O，n代表O或1或R2 和R3与N原子一起并且任选地包含另外的杂原子形成5或6元环，该环可以带有非离子取代基，并且任选取代的苯环或萘环可以与其稠合，或者R 2和 R3一起形成下式的二不饱和基团R 8表示任选取代的烷基，芳基，环烷基或芳烷基，R 2表示任选取代的烷基，烯基，环烷基，芳基或芳烷基，以及它们在光收集系统中的用途。

16. 发明授权

US4544496A Light-collecting system using coumarin derivatives as energy converters 失效
公开(公告)号：US4544496A
公开(公告)日：1985-10-01
申请号：US500795
申请日：1983-06-06
申请人： Uwe Claussen , Horst Harnisch
发明人： Uwe Claussen , Horst Harnisch
IPC分类号： C08K5/00 , C08K5/315 , C09B57/02 , C09K11/06 , C09K11/02
CPC分类号： C09K11/06 , C08K5/0041 , C08K5/315 , C09B57/02
摘要： A light-collecting system, characterized in that it contains a coumarin derivative of the formula ##STR1## in which T denotes O or NR.sub.4, in whichR.sub.4 represents hydrogen, optionally substituted aryl, optionally substituted cycloalkyl or optionally substituted aralkyl,R.sub.1 denotes a carbocyclic or heterocyclic 5-membered or 6-membered ring bonded via a C atom, or a 5-membered or 6-membered heterocyclic ring which is bonded via a N atom and is rotationally asymmetrical to an axis placed through the coumarin/N-heterocyclic bond, it being possible for the said 5-membered or 6-membered rings to carry non-ionic substituents and for an optionally substituted benzene ring or an optionally substituted naphthalene ring to be fused to the said rings;X signifies ##STR2## or --OR.sub.2 ', in which R.sub.2 represents hydrogen, alkyl, cycloalkyl, aralkyl or aryl, it being possible for the said hydrocarbon radicals to be substituted, and R.sub.3, in addition to having the definitions given for R.sub.2, also signifies a radical of the formulaeR.sub.6 --(X).sub.n --CO--orR.sub.7 --(X).sub.n --SO.sub.2 -- in whichR.sub.6 and R.sub.7 represent alkyl, cycloalkyl, aryl or aralkyl, it being possible for the said hydrocarbon radicals to be substituted,X represents NH or O andn represents 0 or 1, orR.sub.2 and R.sub.3 together with the N atom and optionally with the inclusion of further hetero-atoms form a 5-membered or 6-membered ring, it being possible for this ring to carry non-ionic substituents and for an optionally substituted benzene ring or an optionally substituted naphthalene ring to be fused thereto, orR.sub.2 and R.sub.3 together form a di-unsaturated radical of the formula ##STR3## in which R.sub.8 represents optionally substituted alkyl, optionally substituted aryl, optionally substituted cycloalkyl or optionally substituted aralkyl, andR.sub.2 ' signifies optionally substituted alkyl, alkenyl, optionally substituted cycloalkyl, optionally substituted aryl or optionally substituted aralkyl,and the use of coumarin derivatives in light-collecting systems.

17. 发明授权

US4299959A Fluorescent pigments 失效
标题翻译：荧光颜料
公开(公告)号：US4299959A
公开(公告)日：1981-11-10
申请号：US8703
申请日：1979-01-31
申请人： Nalin B. Desai
发明人： Nalin B. Desai
IPC分类号： C07D311/58 , C09B57/00 , C09B57/02 , C07D311/66 , C07D239/72 , C07D405/04 , C07D487/00
CPC分类号： C07C255/00 , C07D311/58 , C09B57/02
摘要： A fluorescent pigment consisting of N-substituted iminocoumarins of the general formula I, ##STR1## wherein X.sub.1 is a cyano group, a carboxamido group or an aryl or a heteroaryl radical linked directly or through a --CO or --SO.sub.2 group,X.sub.2 is an amino group, hydroxy group or an alkoxy group and when it is an amino group, may carry an optionally substituted alkylene or alkylidene group bound in ortho position to the nitrogen atom and in para position with respect to the coumarin oxygen atom,X.sub.3 is a hydrogen atom, a halogen atom or a cyano group andX.sub.4 is a functionally converted carboxyl groups. The new dyestuffs dye polyester fiber in orange or red shades with good fastness.
摘要翻译：由通式I的N-取代亚氨基香豆素，其中X 1是氰基，甲酰胺基或直接或通过-CO或-SO 2基团连接的芳基或杂芳基组成的荧光颜料， X 2为氨基，羟基或烷氧基，当为氨基时，可携带任选取代的亚烷基或亚烷基，该亚烷基或亚烷基在邻位与氮原子结合，并且相对于香豆素氧原子结合在对位是氢原子，卤原子或氰基，X 4是功能转化的羧基。新型染料以橙色或红色色调染色涤纶纤维，色牢度好。

18. 发明授权

US4244872A Coumarin dyestuffs 失效
标题翻译：香豆素染料
公开(公告)号：US4244872A
公开(公告)日：1981-01-13
申请号：US953562
申请日：1978-10-23
申请人： Berthold Gertisser , Beat Henzi
发明人： Berthold Gertisser , Beat Henzi
IPC分类号： C09B69/00 , C07D311/16 , C07D491/04 , C09B57/02
CPC分类号： C07D491/04 , C07D311/16 , C09B57/02
摘要： Disclosed are cationic dyestuffs being coumarin or coumarinimide derivatives free from sulpho groups, bearing a 7-amino group and being characterized by having, in the 3-position, a cationic group of formula (a), ##STR1## in which A.sup..crclbar. signifies an anion,eitherR.sub.5 .degree. signifies hydrogen or optionally substituted alkyl or cycloalkyl, andR.sub.6 .degree. signifies hydrogen, or optionally substituted alkyl or cycloalkyl, or, where R.sub.5 .degree. is hydrogen, also hydroxy, naphthyl, optionally substituted amino or alkoxy, or phenyl monosubstituted by phenoxy, chlorophenoxy,benzyl, amino or C.sub.1 -C.sub.4 alkylamino,orR.sub.5 .degree. and R.sub.6 .degree., together with the nitrogen to which they are attached, signify a non-aromatic heterocycle,and the dotted line indicates that the positive charge is not localized, their productionand use for dyeing and printing basic dyeable substrates, plastics and paper, particularly acid modified polyester substrates. They give dyeings of yellow to greenish yellow which fluoresce in the yellow to greenish yellow band.
摘要翻译：公开了阳离子染料是不含磺胺基的香豆素或香豆素酰亚胺衍生物，带有7-氨基并且其特征在于在3-位上具有式（a）的阳离子基团，其中A （ - ）表示阴离子，R 5表示氢或任选取代的烷基或环烷基，R 6表示氢或任选取代的烷基或环烷基，或其中R 5是氢时，也可以是羟基，萘基，任选取代的氨基或烷氧基，或被苯氧基，氯苯氧基，苄基，氨基或C1-C4烷基氨基单独取代的苯基，或者R5，R6和它们所连接的氮一起表示非芳族杂环，虚线表示阳性电荷不局限性，它们的生产和使用用于染色和印刷基本可染色基材，塑料和纸，特别是酸改性聚酯基材。它们将黄色染色成黄绿色，黄色至黄绿色带发出荧光。

19. 发明授权

US4138401A [3,2-g] Pyranoquinoline derivatives 失效
标题翻译： {8 3,2-g {9 {0吡咯并喹啉衍生物
公开(公告)号：US4138401A
公开(公告)日：1979-02-06
申请号：US671236
申请日：1976-03-29
申请人： Peter R. Hammond , Erhard J. Schimitschek , John A. Trias
发明人： Peter R. Hammond , Erhard J. Schimitschek , John A. Trias
IPC分类号： C07D491/04 , C07D491/052 , C09B57/02 , H01S3/213
CPC分类号： C07D491/04 , C09B57/02 , H01S3/213
摘要： 2-Keto-6,7,8,9-tetrahydro-2H-pyrano(3,2-g)-quinoline and 2-keto-9-methyl-,8,9-tetrahydro-2H-pyrano(3,2-g)-quinoline, compounds useful as laser dyes, are prepared from 7-hydroxy-1,2,3,4-tetrahydroquinoline.
摘要翻译： 2-酮基-6,7,8,9-四氢-2H-吡喃并（3,2-g） - 喹啉和2-酮-9-甲基-6,7,8,9-四氢-2H-吡喃并（3 ，2-g） - 喹啉，可用作激光染料的化合物，由7-羟基-1,2,3,4-四氢喹啉制备。

20. 发明授权

US4055568A Dyes of the coumarin series 失效
标题翻译：香豆素系列染料
公开(公告)号：US4055568A
公开(公告)日：1977-10-25
申请号：US693187
申请日：1976-06-07
申请人： Manfred Patsch , Christos Vamvakaris
发明人： Manfred Patsch , Christos Vamvakaris
IPC分类号： C09B57/02 , D06P1/16 , D06P5/28 , C07D419/00
CPC分类号： C09B57/02 , D06P5/006
摘要： Dyes of the formula: ##STR1## in which Z is unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aralkyl, aryl or heteroaryl or a radical of the formula ##STR2## Z.sup.1, Z.sup.2, Z.sup.3 and Z.sup.4 are hydrogen or unsubstituted or substituted alkyl, cycloalkyl, aralkyl or aryl;Z.sup.1 and Z.sup.2 or Z.sup.3 and Z.sup.4 may together with the nitrogen form a heterocyclic ring;Z.sup.1 and Z.sup.2 together with the nitrogen may be a saturated unsubstituted or substituted 5-membered or 6-membered ring condensed on in the ortho-position to the nitrogen;B is unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aralkyl, aryl or heteroaryl; andX is imino or oxygen.The dyes give brilliant yellow dyeings having good fastness properties on textile materials, particularly polyester materials, and in plastics.
摘要翻译：式（I）其中Z是未取代或取代的烷基，烯基，环烷基，芳烷基，芳基或杂芳基或下式的基团的化合物：其中Z 1，Z 2，Z 3和Z 4的基团是氢或未取代的或未取代的取代的烷基，环烷基，芳烷基或芳基; Z 1和Z 2或Z 3和Z 4可以与氮一起形成杂环; Z1和Z2与氮一起可以是在与氮原子相邻的位置上稠合的饱和的未取代或取代的5元或6元环; B是未取代或取代的烷基，烯基，环烷基，芳烷基，芳基或杂芳基; X是亚氨基或氧。

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