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    • 27. 发明授权
    • Process for the dyeing of synthetic fibrous materials from organic
solvents using azo dyes
    • 使用偶氮染料从有机溶剂中染色合成纤维材料的方法
    • US3961885A
    • 1976-06-08
    • US412017
    • 1973-11-01
    • Walter BirkeFranz SchonWilli Steckelberg
    • Walter BirkeFranz SchonWilli Steckelberg
    • C09B29/32D06P1/90C09B27/00
    • D06P1/908Y10S8/921Y10S8/922Y10S8/924Y10S8/926Y10S8/927
    • A process for the continuous dyeing of textile materials consisting of or containing synthetic fibrous materials of the group consisting of high molecular polyamides, polyolefines, polyacrylonitriles, polyurethanes, polyvinylchlorides, polyvinylacetates, cellulose-2 1/2-acetate, cellulose-triacetate and high molecular polyesters from organic solvents, which comprises impregnating the said fibrous materials with organic dyebaths containing at least one dyestuff of the formula ##SPC1##In which R is linear or branched alkylcarbonyl of 4 to 18 carbon atoms, X is oyxgen or sulfur, Y is a direct linkage or NH, A is linear or branched alkylene of 1 to 4 carbon atoms unsubstituted or substituted by methoxy, ethoxy, phenoxy or R as defined above, B is (1) phenyl unsubstituted or substituted by fluorine, chlorine, bromine, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, trifluoromethyl, cyano, carboalkoxy, nitro, acetyl, benzoyl or phenyl, or (2) napthyl, R.sub.1 is hydrogen or nitro, and R.sub.2 is hydrogen, chlorine, bromine or methyl, and heating the impregnated fibrous materials to a temperature between 100.degree.C and 240.degree.C.
    • 由高分子量聚酰胺,聚烯烃,聚丙烯腈,聚氨酯,聚氯乙烯,聚乙酸乙烯酯,纤维素-21-乙酸酯,纤维素三乙酸酯和高分子量的聚合物组成的组合物或包含合成纤维材料的织物的连续染色的方法 聚酯包括用含有至少一种式IN的化合物的有机染料浸渍所述纤维材料,其中R是具有4至18个碳原子的直链或支链烷基羰基,X是奥克斯或硫,Y是直接连接或 NH,A是未经取代或被甲氧基,乙氧基,苯氧基或如上定义的R取代的1至4个碳原子的直链或支链亚烷基,B是(1)未取代或被氟,氯,溴,1-4位烷基取代的苯基 碳原子数1〜4的烷氧基,三氟甲基,氰基,烷氧羰基,硝基,乙酰基,苯甲酰基或苯基,或(2)萘基,R1为氢或硝基,R2为 氢,氯,溴或甲基,并将浸渍的纤维材料加热至100℃至240℃的温度。
    • 28. 发明授权
    • Basic styryl dyes free from sulphonic acid groups, their production and
use
    • 基础皮炎染色体不含硫酸组,其生产和使用
    • US3957767A
    • 1976-05-18
    • US479121
    • 1974-06-13
    • Viktor Kaeppeli
    • Viktor Kaeppeli
    • C09B23/14C07D209/04
    • C09B23/145Y10S8/927
    • Novel basic, styryl dyes containing no sulphonic acid groups and of formula ##SPC1##In which the radicals R, which may be the same or different, signify unsubstituted or substituted hydrocarbon radicals,R.sub.1 signifies an unsubstituted or substituted alkyl radical,EitherI. R.sub.6 signifies a hydrogen atom,R.sub.2 signifies an unsubstituted alkyl radical or an alkyl radical substituted by one or more halogen atoms or cyano, aryl or alkoxy radicals,AndR.sub.3 signifies an unsubstituted alkyl radical, an alkyl radical substituted by one or more halogen atoms or cyano, aryl or alkoxy radicals, an unsubstituted aryl radical or an aryl radical substituted by one or more halogen atoms or alkyl alloxy or cyano radicals.Ii. R.sub.6 signifies a hydrogen atom, and R.sub.2 and R.sub.3 together with the nitrogen atom to which they are attached signify a saturated or partially saturated, heterocyclic ring of 5 to 7 ring members,Or iii. R.sub.2 signifies an unsubstituted alkyl radical or an alkyl radical substituted by one or more halogen atoms or cyano, aryl or alkoxy radicals, and R.sub.3 and R.sub.6, together with the nitrogen atom and carbon atom to which they are attached and the carbon to which the nitrogen atom is attached, signify a saturated or partially saturated, heterocyclic ring of 5 to 7 ring members,X. R.sub.4 signifies a hydrogen atom or an unsubstituted or substituted alkyl radical, and R.sub.5 signifies an unsubstituted or substituted alkyl or aryl radical,Or y. R.sub.4 and R.sub.5, together with the nitrogen atom to which they are attached, signify a saturated or partially saturated, heterocyclic ring of 5 to 7 ring members,R.sub.7 signifies a hydrogen or halogen atom, or an unsubstituted or substituted alkyl radical,A.sup.n.sup.- signifies an anion,And the rings B and D may optionally be further substituted by one or more non-water-solubilizing substituents.The dyes are useful for dyeing polyacrylonitrile, acrylonitrile copolymer, synthetic polyamide and polyester fibres, modified by the introduction of acid groups, plastic materials, synthetic and natural resins, leather and paper.
    • 30. 发明授权
    • Certain 2-amino-nicotinonitrile derivatives
    • 某些2-氨基 - 烟腈衍生物
    • US3947463A
    • 1976-03-30
    • US521530
    • 1974-11-06
    • Erwin FleckensteinErnst HeinrichReinhard Mohr
    • Erwin FleckensteinErnst HeinrichReinhard Mohr
    • C07D401/06C07D401/12C07D413/04C07D213/57
    • C07D413/04C07D401/06C07D401/12Y10S8/917Y10S8/922Y10S8/927
    • Compounds of the formulaWherein X is aliphatic, cycloaliphatic, aromatic, aralkyl, hetaryl, hetarylalkyl or hydrogen; Y is aliphatic, aromatic, aralkyl, --COOR.sub.1, --COR.sub.2, ##EQU1## --SO.sub.2 R.sub.2, ##EQU2## --CN, --NH.sub.2, --NO, --NO.sub.2 or hydrogen with the proviso that when Y is hydrogen, X is other than hydrogen; Z.sub.1 is cyano, ##EQU3## --NH--OR.sub.10, ##EQU4## --OR.sub.12, --SR.sub.12 or --SO.sub.2 R.sub.12 and Z.sub.2 is chlorine, bromine, cyano, hydroxy, mercapto, --OR.sub.12, --SR.sub.12, ##EQU5## --NH--OR.sub.10 or ##EQU6## R.sub.1 is aliphatic; R.sub.2 is aliphatic, cycloaliphatic, aromatic, aralkyl or heterocyclic; R.sub.1 and R.sub.4 when taken separately are hydrogen, aliphatic, cycloaliphatic, aromatic or aralkyl; R.sub.3 and R.sub.4 when taken together with the nitrogen atom to which they are attached form a heterocyclic moiety; R.sub.5 and R.sub.6 when taken separately are aliphatic, aromatic, aralkyl, heterocyclic or hydrogen; R.sub.5 and R.sub.6 when taken together with the nitrogen atom to which they are attached are heterocyclic; R.sub.7 is hydrogen, aliphatic or aromatic; R.sub.8 and R.sub.9 are aliphatic or aromatic, R.sub.10 is hydrogen, aliphatic or aralkyl, R.sub.11 is aliphatic and R.sub.12 is aliphatic, aromatic or aralkyl; R.sub.10 and R.sub.11 when taken together with the nitrogen atom to which they are attached are heterocyclic.
    • 式WH的化合物是脂族,脂环族,芳族,芳烷基,杂芳基,杂芳基烷基或氢; Y是脂族的,芳族的,芳烷基,-COOR 1,-COR 2,R 3 -CO-N角,R 4 -SO 2 R 2,R 3 -SO 2 -N取代基,R 4 -CN,-NH 2,-NO,-NO 2或氢,条件是 当Y是氢时,X不是氢; Z 1是氰基,R 5 -N ANGLE,R 6 R 7 R 8 ANGLE NN ANGLE,R 9 -NH-OR 10,OR 10 -N ANGLE,R 11 -OR 12,-SR 12或-SO 2 R 12,Z 2是氯,溴,氰基,羟基,巯基,-OR 12 ,-SR 12,R 5 -SO 2 R 12,-N ANGLE,R 6 R 7 R 8 ANGLE NN ANGLE,R 9 -NH-OR 10或OR 10 -N角; R11 R1是脂肪族的; R2是脂族,脂环族,芳族,芳烷基或杂环; 单独使用时,R 1和R 4为氢,脂族,脂环族,芳族或芳烷基; 当与它们所连接的氮原子一起形成杂环部分时,R 3和R 4; R5和R6分别为脂族,芳族,芳烷基,杂环或氢时; 当与它们所连接的氮原子一起取代时,R 5和R 6是杂环的; R7是氢,脂族或芳族; R8和R9是脂族或芳族的,R10是氢,脂族或芳烷基,R11是脂族的,R12是脂族的,芳族的或芳烷基; 当与它们所连接的氮原子一起取代时,R 10和R 11是杂环的。