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    • 7. 发明授权
    • Novel dye salts of cationic dyes, having thiocyanatometallate or
cyanatometallate complex anions for spin dyeing acid modified
polyacrylonitrile
    • 阳离子染料的新型染料盐,具有硫氰酸金属盐酸盐或氰酸金属盐酸盐复合阴离子用于纺丝染色酸改性聚丙烯腈
    • US4732573A
    • 1988-03-22
    • US945761
    • 1986-12-23
    • Kurt HohmannPeter MischkeWolfgang Teige
    • Kurt HohmannPeter MischkeWolfgang Teige
    • C09B69/02C09B69/06C09B23/10D01F6/18D06P3/76
    • C09B69/06Y10S8/927
    • Dye salts of a mono- or polycationic dye where the anion conforms to a general formula (1) or (2)[Me (XCN).sub.4 ].sup.2(-) (1)[Me (SCN).sub.6 ].sup.n(-) (2)in whichMe in the formula (1) is the divalent zinc cation, the divalent iron cation, the divalent cobalt cation, the divalent tin cation or the divalent copper cation, andMe in the formula (2) stands for the divalent iron cation, the divalent nickel cation or the trivalent iron cation,X stands for an oxygen or sulfur atom andn depending on the valency of the corresponding metal cation, denotes the number 4 or 3.The novel dye salts can be obtained for example from aqueous solution or suspension by reacting the corresponding cationic dye which has a customary anion with a metal cation Me donor compound and an alkali metal thiocyanate or cyanate, alkaline earth metal thiocyanate or cyanate or ammonium thiocyanate or cyanate. They are used in particular in the spin-dyeing of acid-modified polyacrylonitrile and copolymers thereof.
    • 阴离子符合通式(1)或(2)[Me(XCN)4] 2( - )(1)[Me(SCN)6] n( - )(1)的单 - 或多阳离子染料的染料盐 2)其中式(1)中的Me是二价锌阳离子,二价铁阳离子,二价钴阳离子,二价锡阳离子或二价铜阳离子,和式(2)中的Me代表二价铁 阳离子,二价镍阳离子或三价铁阳离子,X代表氧或硫原子,n取决于相应的金属阳离子的化合价,表示数4或3.新的染料盐可以例如由水溶液 通过使具有常规阴离子的相应的阳离子染料与金属阳离子Me给体化合物和碱金属硫氰酸盐或氰酸盐,碱土金属硫氰酸盐或氰酸盐或硫氰酸铵或氰酸铵反应而使溶液或悬浮液反应。 它们特别用于酸改性聚丙烯腈的旋染和其共聚物。