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    • 21. 发明授权
    • High modulus bio-based polymer formulations
    • 高模量生物基聚合物配方
    • US08552081B2
    • 2013-10-08
    • US12133272
    • 2008-06-04
    • David A. BoylesMohammad S. Al-Omar
    • David A. BoylesMohammad S. Al-Omar
    • C08F2/48C08G63/48
    • C08F220/32C08F222/02
    • The present invention is a high modulus bio-based polymer plastic composition or mixture and methods of preparing the same. The composition is formed from the reaction of a bio-based epoxidized triglyceride oil, an energy activated catalyst and a bio-based non-aromatic cross-linking compound to form a structural polymer plastic. The bio-based epoxidized triglyceride oil is selected from a bio-based epoxidized triglyceride or a bio-based acrylated epoxidized triglyceride. The non-aromatic cross-linking compound is selected from itaconic acid or itaconic anhydride, and the energy activated catalyst is activated by UV radiation or heat.
    • 本发明是高模量生物基聚合物塑料组合物或混合物及其制备方法。 该组合物由生物基环氧化甘油三酸酯油,能量活化催化剂和生物基非芳族交联化合物的反应形成,以形成结构聚合物塑料。 生物基环氧化甘油三酸酯油选自生物基环氧化甘油三酸酯或生物基丙烯酸酯化的环氧化甘油三酸酯。 非芳香族交联化合物选自衣康酸或衣康酸酐,能量活化催化剂通过UV辐射或热激活。
    • 22. 发明授权
    • Thermoplastic elastomer composition
    • 热塑性弹性体组合物
    • US08536271B2
    • 2013-09-17
    • US12848519
    • 2010-08-02
    • Koichi KawaguchiNaoyuki Morooka
    • Koichi KawaguchiNaoyuki Morooka
    • C08G63/48C08L29/04
    • C08L29/04B60C1/0008C08K5/372C08K5/3725C08K5/42C08L23/0861C08L51/04C08L2205/22Y10T152/10234C08L2666/24C08L2666/04
    • An object of the present invention is, in a thermoplastic elastomer composition in which a modified rubber is dispersed and filled in an ethylene-vinyl alcohol copolymer matrix in order to improve the low-temperature durability of the ethylene-vinyl alcohol copolymer, to reduce the extrusion load during extrusion molding thereof into a film without deteriorating the low-temperature durability. The present invention is a thermoplastic elastomer composition comprising an ethylene-vinyl alcohol copolymer (A) and a modified rubber (B) dispersed in the ethylene-vinyl alcohol copolymer (A), wherein the modified rubber (B) has an acid anhydride group or epoxy group and is dynamically cross-linked by a compound (C) having at least two amino groups. This thermoplastic elastomer composition can be suitably used in the production of an inner liner of a pneumatic tire.
    • 本发明的目的在于,为了提高乙烯 - 乙烯醇共聚物的低温耐久性,将改性橡胶分散填充在乙烯 - 乙烯醇共聚物基体中的热塑性弹性体组合物中, 将其挤出成型时的挤出负荷变成膜而不劣化低温耐久性。 本发明是一种包含分散在乙烯 - 乙烯醇共聚物(A)中的乙烯 - 乙烯醇共聚物(A)和改性橡胶(B))的热塑性弹性体组合物,其中改性橡胶(B)具有酸酐基或 并且通过具有至少两个氨基的化合物(C)动态交联。 该热塑性弹性体组合物可以适用于充气轮胎的内衬的制造。
    • 23. 发明授权
    • Modification of the surface chemistry of macromolecular species in the presence of a conjugated guanidine
    • 在共轭胍存在下改性大分子物质的表面化学性质
    • US08530544B2
    • 2013-09-10
    • US12736293
    • 2009-03-27
    • Vincent GaudFabien Rouge
    • Vincent GaudFabien Rouge
    • B01J8/02C01B21/06C08F283/00C08F283/04C08F290/14C08G18/00C08G18/08C08G18/18C08G63/48C08G63/91C08G65/32C08G73/02C08K9/00C08L67/00C08L71/00C08L71/02C08L75/00C08L83/00
    • C08J7/16B01J31/0251
    • The present invention relates to a method for preparing macromolecular species with a modified surface, comprising a step (e) in which macromolecular species (M), initially carrying —OH and/or —SH functions, are brought into contact with: a catalyst (C) carrying at least one conjugated guanidine function; and reactive species (E), comprising reactive groups including: (i) at least one group including an a,b-unsaturated carbonyl group C═C—C═O and/or an a,b-unsaturated thiocarbonyl group C═C—C═S; and/or (ii) at least one heterocyclic group comprising from 3 to 5 ring members, said group being selected from cyclic ethers, cyclic thioethers and aziridine rings; and/or (iii) at least one group selected from isocyanate —N═C═O or thioisocyanate —N═C═S groups, and trivalent groups of formula >C═CZ—, where Z is an electron-withdrawing group. The invention also relates to the macromolecular species with a modified surface that are obtained in this context.
    • 本发明涉及一种制备具有改性表面的高分子物质的方法,其包括步骤(e),其中最初携带-OH和/或-SH官能团的高分子物质(M)与下列物质接触:催化剂 C)携带至少一种共轭胍功能; 和反应性物质(E),其包含反应性基团,包括:(i)至少一个包括a,b不饱和羰基C = C-C = O和/或a,b-不饱和硫代羰基C = C-C = S的基团; 和/或(ii)至少一个包含3至5个环成员的杂环基,所述基团选自环醚,环硫醚和氮丙啶环; 和/或(iii)选自异氰酸酯-N = C = O或硫代异氰酸酯-N = C = S基团中的至少一个基团和式C = CZ-的三价基团,其中Z为吸电子基团。 本发明还涉及在本文中获得的具有改性表面的大分子物质。
    • 25. 发明授权
    • Composition for coating and molded product using the same
    • 用于涂料的组合物和使用其的模塑制品
    • US08519052B2
    • 2013-08-27
    • US13696842
    • 2011-04-04
    • Kazuhiro OkamotoKazuya Egawa
    • Kazuhiro OkamotoKazuya Egawa
    • C08G63/48
    • C09D109/10C08L23/0869C08L55/02C08L67/00C08L2205/03
    • The present invention provides a resin composition for coating which is capable of exhibiting an excellent balance between coatability, impact resistance, moldability and chemical resistance, and capable of attaining a good coating appearance, for example, even when a large-size molded product is coated. The resin composition for coating according to the present invention comprises 84.9 to 98.9 parts by mass of the below-mentioned rubber-reinforced vinyl-based resin [A], 1 to 8 parts by mass of a polyester resin [B] and 0.1 to 7.1 parts by mass of a copolymer [C] of ethylene, a (meth)acrylic acid ester and carbon monoxide (with the proviso that a total amount of the components [A], [B] and [C] ([A] +[B] +[C]) is 100 parts by mass): [Rubber-reinforced vinyl-based resin [A]]A rubber-reinforced vinyl-based resin comprising a rubber-reinforced copolymer resin [A1] obtained by polymerizing a vinyl-based monomer [b1] in the presence of a rubber polymer [a], or comprising the rubber-reinforced copolymer resin [A1] obtained by polymerizing the vinyl-based monomer [b1] in the presence of the rubber polymer [a], and a (co)polymer [A2] of a vinyl-based monomer [b2].
    • 本发明提供一种涂布用树脂组合物,其能够在涂布性,耐冲击性,成型性和耐化学性之间表现出优异的平衡,并且即使当涂布大尺寸模制品时也能获得良好的涂层外观 。 根据本发明的涂料用树脂组合物含有下述橡胶强化乙烯基类树脂[A] 84.9〜98.9质量份,聚酯树脂[B] 1〜8质量份,0.1〜7.1质量份 乙烯,(甲基)丙烯酸酯和一氧化碳的共聚物[C]质量份(条件是组分[A],[B]和[C]([A] + [ B] + [C])为100质量份):[橡胶强化乙烯基系树脂[A]]:橡胶强化乙烯系树脂,其含有通过使乙烯基系树脂聚合而得到的橡胶增强共聚物树脂[ 在橡胶聚合物[a]的存在下,或者包含在橡胶聚合物[a]的存在下聚合乙烯基类单体[b1]而获得的橡胶增强共聚物树脂[A1],以及 乙烯基类单体[b2]的(共)聚合物[A2]。
    • 26. 发明授权
    • Biocomposite materials and methods for making the same
    • 生物复合材料及其制造方法
    • US08507606B2
    • 2013-08-13
    • US11983516
    • 2007-11-09
    • Jay W. GrateJungbae Kim
    • Jay W. GrateJungbae Kim
    • A61K47/48C08G63/48C08G63/91C08L89/00
    • C12N11/14C12N11/06C12N11/08
    • A particle (and a composition that includes a plurality of the particles) that includes at least one polypeptide molecule and at least one polymer covalently bound to the polypeptide molecule so as to form a polymer shell substantially encompassing the polypeptide molecule, wherein the particle does not define a dimension greater than about 1 μm. One example for making the particle includes modifying the polypeptide molecule to provide α, β-ethylenically unsaturated terminal functional groups, mixing the modified polypeptide molecule with a silicon-containing polymerizable compound, and subjecting the resulting mixture to conditions sufficient for polymerizing the polymerizable compound to form the particle.
    • 包含至少一种多肽分子和至少一种与多肽分子共价结合的聚合物的颗粒(和包含多个颗粒的组合物),以形成基本上包含该多肽分子的聚合物壳,其中该颗粒不 定义大于1um的尺寸。 制备该颗粒的一个实例包括修饰多肽分子以提供α,β-烯键式不饱和末端官能团,将修饰的多肽分子与含硅的可聚合化合物混合,并将所得混合物进行足以使可聚合化合物聚合的条件 形成粒子。
    • 30. 发明授权
    • Heat-setting ink composition for offset printing process
    • 胶版印刷工艺用热固性油墨组合物
    • US08309628B2
    • 2012-11-13
    • US11917808
    • 2006-06-16
    • Yuichi KatauraTomohide KatohNaoki KodairaKousuke Naganuma
    • Yuichi KatauraTomohide KatohNaoki KodairaKousuke Naganuma
    • A61L15/62C08K5/00C08K5/01C08K5/09C08K5/10C08K5/11C08L53/00C08L91/00C08G63/20C08G63/48C08G63/91C09D5/00C09D11/00H01B3/44
    • C09D11/03
    • The object of the present invention is to provide an ink composition for heatset offset printing which has an excellent drying property, does not cause skinning during storage of ink composition, and has excellent stability on press in printing. The present invention is an ink composition for heatset offset printing containing a pigment, a binder resin, a petroleum solvent, and at least one kind of vegetable oil component selected from the group consisting of a vegetable oil and a fatty acid ester thereof, the content of the vegetable oil component being 20% by mass or less, and the ink composition further containing: 0.008 to 0.7% by mass of a metal soap drier based on the mass of the metal contained in the drier; 0.008 to 12% by mass of at least one kind selected from the group consisting of a polyvalent carboxylic acid, a derivative thereof, tocopherol, and tocotrienol; and 0.08 to 12% by mass of a phenolic antioxidant.
    • 本发明的目的是提供一种具有优异的干燥性能的热固性胶版印刷用油墨组合物,在油墨组合物的储存期间不会引起剥离,并且在印刷时具有优异的稳定性。 本发明是一种含有颜料,粘合剂树脂,石油溶剂和选自植物油及其脂肪酸酯的至少一种植物油成分的热固性胶版印刷用油墨组合物,其含量 的植物油成分为20质量%以下,并且所述油墨组合物还含有:基于所述干燥机中所含的金属质量的金属皂干燥剂为0.008〜0.7质量% 0.008〜12质量%的选自多元羧酸,其衍生物,生育酚和生育三烯酚的至少一种; 和0.08〜12质量%的酚类抗氧化剂。