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31. 发明授权

US5677417A Tetraaroxyperylene-3,4,9,10-tetracarboxylic polyimides 失效
标题翻译：四环氧基-3,4,9,10-四羧酸聚酰亚胺
公开(公告)号：US5677417A
公开(公告)日：1997-10-14
申请号：US513769
申请日：1995-08-29
申请人： Klaus Muellen , Dobrinka Todorova Dotcheva , Markus Klapper
发明人： Klaus Muellen , Dobrinka Todorova Dotcheva , Markus Klapper
IPC分类号： C09K11/06 , C07D493/06 , C07D519/00 , C08G73/10 , C08L79/08 , C09B57/08 , C09B69/10 , C08G69/08
CPC分类号： C07D493/06 , C08G73/1067 , C08G73/1082 , C09B69/102
摘要： Polymeric tetraaroxyperylene-3,4,9,10-tetracarboxylic diimides of the formula I ##STR1## (R.sup.1 : denotes identical or different aryl radicals which may be substituted by cyano, nitro, halogen, C.sub.1 -C.sub.18 -alkoxy, C.sub.5 -C.sub.7 -cycloalkyl and/or C.sub.1 -C.sub.18 -alkyl and may each contain up to 24 carbon atoms; R.sup.2 : denotes C.sub.2 -C.sub.30 -alkylene groups whose carbon chain may be interrupted by from 1 to 10 oxygen atoms in ether function or by a phenylene or cyclohexylene group, or optionally C.sub.1 -C.sub.10 -alkylene- or oxygen-bridged C.sub.6 -C.sub.30 -arylene or cyclohexylene radicals; n: is from 2 to 100), preparation thereof and use thereof and also tetraaroxypery-lene-3,4,9,10-tetracarboxylic dianhydrides as intermediates therefor.
摘要翻译： PCT No.PCT / EP94 / 01345 Sec。 371日期1995年8月29日 102（e）日期1995年8月29日PCT 1994年4月28日PCT PCT。公开号WO94 / 25504 PCT 日期：1994年11月10日式I的聚合四环氧基-3,4,9,10-四羧酸二酰亚胺（R 1：表示可以被氰基，硝基，卤素，C 1 -C 18烷基取代的相同或不同的芳基，烷氧基，C 5 -C 7 - 环烷基和/或C 1 -C 18烷基，并且各自含有至多24个碳原子; R 2表示其碳链可以被醚功能中的1至10个氧原子间隔的C 2 -C 30亚烷基或通过亚苯基或亚环己基，或任选的C 1 -C 10 - 亚烷基或氧桥连的C 6 -C 30亚芳基或亚环己基; n：为2至100），其制备及其用途以及四亚甲基 - 内烯-3 ，4,9,10-四羧酸二酐作为其中间体。

32. 发明授权

US5565551A Non-azo naphthalimide dyes and uses for same 失效
标题翻译：非偶氮萘酰胺染料及其用途相同
公开(公告)号：US5565551A
公开(公告)日：1996-10-15
申请号：US433092
申请日：1995-05-03
申请人： David E. Lewis , Ronald E. Utecht , Millard M. Judy , J. Lester Matthews
发明人： David E. Lewis , Ronald E. Utecht , Millard M. Judy , J. Lester Matthews
IPC分类号： A61K39/00 , A61L2/00 , C07D221/14 , C07D401/06 , C07D403/06 , C07D405/06 , C07D409/06 , C07D417/12 , C07D473/00 , C09B57/08 , C07K1/00 , C07K14/00 , C07K16/00 , C07K17/00 , C08H1/00
CPC分类号： C07D221/14 , A61L2/0011 , A61L2/0082 , C09B57/08 , Y10S514/885
摘要： A class of predominantly hydrophobic non-azo N-substituted 1,8-naphthalimide compounds, each bearing, at its 3-position, a nucleofuge and, at its 4-position, a heteroatomic electron-releasing group. The heteroatomic electron-releasing group is being characterized as having a heteroatom directly linked to the 4-position of the ring, and having at least one hydrogen directly attached to the heteroatom. Upon activation by an activating agent in an environment independent of the presence or absence of oxygen, these compounds generate activated species. The activated species initiate chemical changes in lipid bilayer membranes of viruses and other target cells. These changes can eradicate viruses and other target cells. The activated species can also cause structural changes in lipid and any associated proteins and polypeptides at a level beneath the surface of the membrane, leading to polymerization and crosslinking.
摘要翻译：一类主要疏水性的非偶氮N-取代的1,8-萘二甲酰亚胺化合物，各自在其3位具有核离子和在其4位上具有杂原子电子释放基团。杂原子电子释放基团的特征在于具有直接连接到环的4-位的杂原子，并且具有至少一个氢直接连接到杂原子上。在独立于氧的存在或不存在的环境中通过活化剂活化时，这些化合物产生活化的物质。活化物质引发病毒和其他靶细胞脂质双层膜的化学变化。这些变化可以根除病毒和其他靶细胞。活化的物质还可以在膜的表面下方的水平下引起脂质和任何相关蛋白质和多肽的结构变化，导致聚合和交联。

33. 发明授权

US5071483A Process for the preparation of pigment preparations of the anthanthrone series 失效
标题翻译：制备ANTHANTHRONE系列染料制剂的方法
公开(公告)号：US5071483A
公开(公告)日：1991-12-10
申请号：US409522
申请日：1989-09-19
申请人： Erwin Dietz , Manfred Urban , Siegfried Schiessler
发明人： Erwin Dietz , Manfred Urban , Siegfried Schiessler
IPC分类号： C09B3/60 , B01F17/16 , B01F17/32 , C09B57/00 , C09B57/04 , C09B57/08 , C09B57/12 , C09B67/20 , C09B67/22
CPC分类号： C09B67/0033
摘要： A process for the preparation of pigment preparations of the anthanthrone series, which comprises subjecting anthanthrone crude pigments to aqueous pearl milling in the presence of dispersants of the formulaeQ.sub.1 -[A.sub.1 -X].sub.n (I)and/or[Q.sub.2 -A.sub.2 ].sub.z -Y (II)in which in formula (I) Q.sub.1 is the radical of an anthanthrone, azo, isoindolinone, diketopyrrolopyrrole or perinone compound, A.sub.1 is a direct bond or --O--, --S--, --NR.sub.3, --CO--, --SO.sub.2 --, --CR.sub.4 R.sub.5 -- or arylene, X is a group ##STR1## or a heterocyclic radical having at least one nitrogen atom, and R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are hydrogen atoms or saturated or unsaturated alkyl groups and n is 1 to 4, and in formula (II) Q.sub.2 is a radical of the formula ##STR2## in which R.sub.1 is hydrogen, halogen, alkyl, alkoxy or cyano, or, in the case that m.sub.1 >1, R.sub.1 can also be a combination of these substituents, R.sub.2 is hydrogen, halogen, an alkyl, alkoxy or cyano or, in the case that m.sub.2 >1, R.sub.2 can also be a combination of these substituents, m.sub.1 and m.sub.2 are 1 to 4, A.sub.2 is --(CH.sub.2).sub.p --, CR.sub.8 R.sub.9 --, arylene, --O--, --NR.sub.10 --, --CO-- or --SO.sub.2 --, in which p is from 1 to 6, R.sub.8, R.sub.9 and R.sub.10 are hydrogen or alkyl, Y is dimethylamino or diethylamino or an imidazole or piperazine radical and z is 1 or 2, and subjecting the suspensions of the prepigment preparations obtained to a heat treatment at temperatures from 20.degree. to 200.degree. C.
摘要翻译：一种制备蒽烷系列颜料制剂的方法，该方法包括在式Q1- [A1-X] n（I）和/或[Q2-A2]的分散剂存在下使蒽醌粗颜料进行水珍珠研磨，其中式（I）中的QY（II）Q1为蒽醌，偶氮，异吲哚啉酮，二酮吡咯并吡咯或百草酮化合物的基团，A1为直接键或-O - ， - S - ， - NR 3，-CO-， - SO 2 - ，-CR 4 R 5 - 或亚芳基，X是具有至少一个氮原子的基团，或者R 3，R 4，R 5，R 6和R 7是氢原子或饱和或不饱和烷基，n是1 至（4）中，并且在式（II）中，Q2是下式的基团，其中R 1是氢，卤素，烷基，烷氧基或氰基，或者在m1> 1的情况下，R 1也可以是这些取代基R2是氢，卤素，烷基，烷氧基或氰基，或者在m2≥1的情况下，R2也可以是这些取代基的组合，m1和m2是1-4，A2是 - （CH2）p - ，CR8R9-，亚芳基，-O-，-NR 10 - ， - CO-或-SO 2 - ，其中p为1至6，R 8，R 9和R 10为氢或烷基，Y为二甲基氨基或二乙基氨基或咪唑或哌嗪基，z为为1或2，对得到的预标准剂的悬浮液进行20〜200℃的热处理。

34. 发明授权

US4451398A Dyes containing imidazolymethylene groups 失效
标题翻译：含有咪唑聚亚甲基的染料
公开(公告)号：US4451398A
公开(公告)日：1984-05-29
申请号：US233479
申请日：1981-02-11
申请人： Manfred Patsch , Manfred Ruske
发明人： Manfred Patsch , Manfred Ruske
IPC分类号： C09B1/00 , C09B3/00 , C09B5/00 , C09B7/00 , C09B11/04 , C09B19/02 , C09B29/00 , C09B31/00 , C09B35/00 , C09B47/12 , C09B48/00 , C09B57/02 , C09B57/06 , C09B57/08 , C09B57/12 , C09B69/00 , D21C5/02 , D21H21/28 , C09B15/00 , C09B25/00
CPC分类号： C09B29/00 , C09B1/00 , C09B11/04 , C09B19/02 , C09B3/00 , C09B31/00 , C09B35/00 , C09B47/12 , C09B48/00 , C09B5/00 , C09B57/02 , C09B57/06 , C09B57/08 , C09B57/12 , C09B69/00 , C09B7/00 , D21C5/022 , D21H21/28 , Y02W30/648 , Y10S8/919
摘要： Dyes of the formula ##STR1## where R.sup.1 is hydrogen, C.sub.1 -C.sub.6 -alkyl or C.sub.2 -C.sub.6 -alkenyl, R.sup.2 and R.sup.3 independently of one another are hydrogen, C.sub.1 -C.sub.5 -alkyl or C.sub.2 -C.sub.5 -alkenyl, R.sup.4 is C.sub.1 -C.sub.12 -alkyl or hydroxy-C.sub.2 -C.sub.4 -alkyl, X.sup..crclbar. is one equivalent of an anion, mis from 0 to 5 and n is from 0 to 5, with 1.ltoreq.(m+n).ltoreq.5, and F is an (m+n)-valent radical of a monoazo dye, a disazo dye, a polyazo dye, a quinophthalone, a bis-dioxazine, a compound of the 5,6-arylo-2-pyrone series, a naphtholactam dye, a triphenylmethane dye, a xanthene dye, a phthalocyanine, an indigoid, an anthraquinone dye containing one or more phenyl or naphthyl groups, a more highly fused carbonyl-containing dye, a quinacridone, a perylene-3,4,9,10-tetracarboxylic acid diimide, an anthrapyrimidine, a pyrazoloanthrone, a diaminonaphthoquinone, a naphthazarine or a naphthalene-1,4,5,8-tetracarboxylic acid diimide.The dyes give brilliant wet-fast colorations on cellulose-containing fiber material, especially on paper. When used for wet-end coloring of paper, the waste water is virtually or completely colorless.
摘要翻译：其中R 1是氢，C 1 -C 6 - 烷基或C 2 -C 6 - 烯基，R 2和R 3彼此独立的式（I）的染料是氢，C 1 -C 5 - 烷基或C 2 -C 5 - 烯基，R 4 是C 1 -C 12 - 烷基或羟基-C 2 - C 4 - 烷基，X（ - ）是1当量的阴离子，0至5的错，n为0至5，且1（=（m + n） / = 5，F是单偶氮染料，双偶氮染料，多偶氮染料，喹酞酮，双二恶嗪，5,6-芳氧基-2-吡喃酮的化合物的（m + n）系列，萘内酰胺染料，三苯基甲烷染料，呫吨染料，酞菁，靛类，含有一个或多个苯基或萘基的蒽醌染料，更高熔融的含羰基染料，喹吖啶酮，苝-3,4 ，9,10-四羧酸二酰亚胺，蒽并嘧啶，吡唑烷酮，二氨基萘醌，萘并噻唑或萘-1,4,5,8-四羧酸二酰亚胺。这些染料在含纤维素的纤维材料上，特别是在纸上产生了明亮的湿快色。当用于纸张的湿端着色时，废水几乎或完全无色。

35. 发明授权

US4336383A 1-1-Binaphthyl-4,4',5,5',8,8'-hexacarboxylic acid compounds, method of preparation and use thereof for the synthesis of asymmetric derivatives of 3,4,9,10-perylenetetracarboxylic acid, and for dyeing and printing of textile materials 失效
公开(公告)号：US4336383A
公开(公告)日：1982-06-22
申请号：US147600
申请日：1980-05-07
申请人： Georgy N. Vorozhtsov , Natalia N. Masanova , Nikolai B. Feldbljum , Vasily I. Alexeev , Vadim A. Shigalevsky , Georgy G. Solomatin , Olga I. Shulepova , Galina G. Khaitun , Nadezhda V. Gordeeva
发明人： Georgy N. Vorozhtsov , Natalia N. Masanova , Nikolai B. Feldbljum , Vasily I. Alexeev , Vadim A. Shigalevsky , Georgy G. Solomatin , Olga I. Shulepova , Galina G. Khaitun , Nadezhda V. Gordeeva
IPC分类号： C07D471/06 , C07D471/16 , C09B57/08 , C09B57/12 , D06P1/00 , C07D519/00 , C07D487/06 , C07D487/16 , C07D487/22
CPC分类号： C07D471/06 , C09B57/08 , C09B57/12 , D06P1/0048
摘要： 1,1'-Binaphthyl-4,4',5,5',8,8'-hexacarboxylic acid compounds having the following formula: ##STR1## wherein R.sub.1 is hydrogen, halogen, or alkyl; when X is oxygen, Y is hydrogen, alkyl, a cycloalkyl, or an aryl containing at least one substituent from the group including: halogen, alkyl, or alkoxy, when X is nitrogen, Y is ##STR2## wherein R.sub.2 is hydrogen, halogen, or alkyl; Y being linked to X with the formation of a benzimidazole cycle.The method for preparing the compounds according to the present invention resides in the treatment of that 1,1'-binaphthyl-4,4',5,5',8,8'-hexacarboxylic acid anhydride with an alkali to give a corresponding salt which is condensed with orthophenylenediamines upon heating at reflux at a pH of from 6.3 to 6.8. The resulting benzimidazole-1,1'-binaphthyl-4,4',5,5',8,8'-hexacarboxylic acid anhydride having the formula: ##STR3## wherein R.sub.1 is hydrogen, halogen, or alkyl, is isolated and condensed with an amine or ortho-phenylenediamines in an excess of the amine, in water or an organic solvent, followed by isolation of the desired product.The compounds according to the present invention are employed for the synthesis of asymmetric compounds of 3,4,9,10-perylenetetracarboxylic acid, as well as for dyeing and printing of textile materials with the formation, on the material, of asymmetric compounds of 3,4,9,10-perylenetetracarboxylic acid having the following formula: ##STR4## wherein R.sub.1 is hydrogen, halogen, or alkyl; when X is oxygen, Y is hydrogen, alkyl, cycloalkyl, or aryl containing at least one substituent from the group including; halogen, alkyl, or alkoxy, when X is nitrogen, Y is ##STR5## where R.sub.2 is hydrogen, halogen, or alkyl; Y being linked with X to form a benzimidazole cycle.The compounds according to the present invention dye textile materials to various shades of violet color.

36. 发明授权

US4210757A Novel naphthoylene-perinones disperse dyestuffs 失效
标题翻译：新型萘二甲酸乙二醇酯分散染料
公开(公告)号：US4210757A
公开(公告)日：1980-07-01
申请号：US846287
申请日：1977-10-28
申请人： Siegfried Dengler , Peter Loew , Christian Zickendraht , Hansrudolf Schwander
发明人： Siegfried Dengler , Peter Loew , Christian Zickendraht , Hansrudolf Schwander
IPC分类号： C09B3/02 , C09B3/10 , C09B5/02 , C09B5/24 , C09B55/00 , C09B57/08 , C09B57/12 , C09B69/00 , C07D471/06
CPC分类号： C09B5/24 , C09B3/02 , C09B3/10 , C09B5/02 , C09B55/00 , C09B55/003 , C09B57/08 , C09B57/12 , C09B69/00
摘要： Dyestuffs of the formula (I) ##STR1## wherein F represents a ring system with at least 3 rings which are angularly condensed with one another, n is 1, 2 or 3, and R, R.sub.1 and R.sub.2 represent optionally substituted alkyl groups which can be interrupted by heteroatoms and also represent cycloalkyl, aralkyl, aryl or heterocyclic radicals, R and R.sub.1 can also represent hydrogen atoms, R.sub.1 and R.sub.2, together with the nitrogen atom, are able to form a ring with 5 or 6 members, and R and R.sub.2 can combine to form a nitrogen-containing heterocycle.
摘要翻译：式（I）的染料其中F表示具有至少3个彼此成角度缩合的环的环系，n为1,2或3，R 1，R 2和R 2表示任选取代的烷基可以被杂原子中断并且也表示环烷基，芳烷基，芳基或杂环基团的基团，R和R 1也可以表示氢原子，R 1和R 2与氮原子一起能够形成具有5或6个成员的环，并且R和R 2可以结合形成含氮杂环。

37. 发明授权

US4190726A Polycyclic dyestuffs 失效
标题翻译：多环染料
公开(公告)号：US4190726A
公开(公告)日：1980-02-26
申请号：US915020
申请日：1978-06-13
申请人： Detlef-Ingo Schutze , Klaus Wunderlich
发明人： Detlef-Ingo Schutze , Klaus Wunderlich
IPC分类号： C09B57/00 , C09B57/08 , C07D471/22
CPC分类号： C09B57/08 , Y10S8/922
摘要： In spite of their pigment character, dyestuffs of the formula ##STR1## are outstandingly suitable for dyeing synthetic fibres, in particular polyester fibres, by customary methods, strong yellow dyeings with good fastness to light and sublimation being obtained. In the abovementioned formula:R.sub.1 and R.sub.3 denote hydrogen, alkyl, aralkyl, alkoxyalkyl, alkoxycarbonyl, alkoxycarbonylalkyl or aryl,R.sub.2 and R.sub.4 denote alkylcarbonyl, arylcarbonyl, alkoxycarbonyl, --CN or --CONX.sub.1 X.sub.2,X.sub.1 denotes hydrogen, alkyl, aralkyl, aryl or cycloalkyl andX.sub.2 denotes hydrogen or alkyl.
摘要翻译：尽管它们具有颜料特性，但是通过常规方法对式（IMAGE）的染料非常适合用于染色合成纤维，特别是聚酯纤维，得到具有良好的耐光牢度和升华性的强黄色染色。在上述式中：R 1和R 3表示氢，烷基，芳烷基，烷氧基烷基，烷氧基羰基，烷氧基羰基烷基或芳基，R 2和R 4表示烷基羰基，芳基羰基，烷氧基羰基，-CN或-CONX 1 X 2，X 1表示氢，烷基，芳烷基，芳基或环烷基 X2表示氢或烷基。

38. 发明授权

US4081446A Process for the preparation of 4-amino-1,8-naphthalic acid-N-arylimides 失效
标题翻译：制备4-氨基-1,8-萘二甲酸-N-芳基酰亚胺的方法
公开(公告)号：US4081446A
公开(公告)日：1978-03-28
申请号：US728923
申请日：1976-10-04
申请人： Theodor Papenfuhs
发明人： Theodor Papenfuhs
IPC分类号： C07D221/14 , C09B57/08
CPC分类号： C07D221/14 , C09B57/08
摘要： 4-Amino-1,8-naphthalic acid-N-arylamides are obtained by reacting 4-halo-1,8-naphthalic acid-N-arylamides with ammonia in an anhydrous polar organic solvent. The products are colorants for solvents or daylight-fluorescence pigments.
摘要翻译：通过4-卤代-1,8-萘二甲酸-N-芳基酰胺与氨在无水极性有机溶剂中反应获得4-氨基-1,8-萘二甲酸-N-芳基酰胺。该产品是溶剂或日光荧光颜料的着色剂。

39. 发明授权

US4049376A Dyed copolyesters and method of making 失效
标题翻译：染色共聚酯及其制备方法
公开(公告)号：US4049376A
公开(公告)日：1977-09-20
申请号：US729749
申请日：1976-10-06
申请人： Alain Yves Le Pape
发明人： Alain Yves Le Pape
IPC分类号： C08G63/00 , C08G63/685 , C08L23/00 , C08L67/00 , C08L77/00 , C08L101/00 , C09B19/02 , C09B48/00 , C09B57/08 , C09B57/12 , C09B69/10 , D01F6/84 , D06P3/52
CPC分类号： C08G63/685 , C09B19/02 , C09B48/00 , C09B57/08 , C09B57/12 , C09B69/10 , Y10S8/04 , Y10S8/922
摘要： New dyed copolyesters and their preparation are disclosed.The copolyesters are characterized in that their macromolecular chains include dye moieties chosen from among those of the formulae: ##STR1## in which X is a hydrogen atom or a hydroxy group; X' is a halogen atom; Y is an alkoxy residue, Z.sub.1 is a hydrogen atom or a halogen atom or an alkyl or alkoxy residue and Z.sub.2 is a hydrogen atom or an acylamino residue.These copolyesters can be converted into textile fibers or be used for dyeing of bulk plastic materials and synthetic fibers.
摘要翻译：公开了新染色的共聚酯及其制备方法。

40. 发明授权

US3920387A Dinaphthyl derivatives, method of producing same and application thereof 失效
标题翻译：二萘基衍生物，其制备方法及其应用
公开(公告)号：US3920387A
公开(公告)日：1975-11-18
申请号：US42554573
申请日：1973-12-17
申请人： DOKUNIKHIN NIKOLAI STEPANOVICH , VOROZHTSOV GEORGY NIKOLAEVICH
发明人： DOKUNIKHIN NIKOLAI STEPANOVICH , VOROZHTSOV GEORGY NIKOLAEVICH
IPC分类号： C07D221/14 , C07D471/06 , C07D519/00 , C09B5/62 , C09B57/08 , C09B57/12 , D06P1/22 , C07D221/18
CPC分类号： C07D221/14 , C07D471/06 , C09B5/62 , C09B57/08 , C09B57/12 , D06P1/227 , Y10S8/918
摘要： WHERE X1, X2 and X3, X4 represent a group O C-Y-C O, wherein Y is an imino group, either unsubstituted or containing substituents. Said derivatives are employed for producing perylenetetracarboxylic acid derivatives either in their free form or directly on a textile material in the process of dyeing or textile printing.

Novel dinaphthyl derivatives characterized by the general formula
摘要翻译：以通式X 1，X 2和X 3，X 4为特征的新型二萘基衍生物代表基团O = C-Y-C = O，其中Y是亚氨基，未取代或含有取代基。

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