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31. 发明授权

US4777303A Alcohols production by hydrogenation of carboxylic acids 失效
标题翻译：醇通过氢化羧酸生产
公开(公告)号：US4777303A
公开(公告)日：1988-10-11
申请号：US848998
申请日：1986-04-07
申请人： Melanie Kitson , Peter S. Williams
发明人： Melanie Kitson , Peter S. Williams
IPC分类号： C07C27/04 , B01J23/00 , B01J23/656 , C07B61/00 , C07C27/00 , C07C29/136 , C07C29/149 , C07C31/08 , C07C31/10 , C07C67/00 , C07C67/08
CPC分类号： C07C29/149 , Y10S502/525
摘要： An alcohol and/or a carboxylic acid ester is (are) produced from a C.sub.2 to C.sub.12 carboxylic acid by contacting the carboxylic acid at elevated temperature and pressure with hydrogen in the presence of a heterogeneous catalyst characterized in that the catalyst comprises a first component which is either molybdenum or tungsten and a second component which is a noble metal of Group VIII of the Periodic Table of the Elements, optionally on a support, for example a high surface area graphitized carbon.
摘要翻译：通过在多相催化剂的存在下使升高的温度和压力下的羧酸与氢接触，由C2-C12羧酸制备醇和/或羧酸酯，其特征在于催化剂包含第一组分，是钼或钨，第二组分是元素周期表第VIII族的贵金属，任选地在载体上，例如高表面积石墨化碳。

32. 发明授权

US4671798A 1,2,3,4,4a,5,8,8a-octahydro-2,2,6,8-tetramethyl-1-naphthalenol, its use as perfuming ingredient and process for making same 失效
标题翻译： 1,2,3,4,4a，5,8,8a-八氢-2,2,6,8-四甲基-1-萘酚，其用作加香成分及其制备方法
公开(公告)号：US4671798A
公开(公告)日：1987-06-09
申请号：US716078
申请日：1985-03-26
申请人： Claudio Tarchini
发明人： Claudio Tarchini
IPC分类号： C07C29/136 , A61K8/34 , A61Q13/00 , C07C27/00 , C07C29/143 , C07C35/36 , C07C45/00 , C07C45/69 , C07C45/72 , C07C49/603 , C07C49/637 , C07C67/00 , C11B9/00 , C11D3/50 , D06M13/02 , D06M13/144 , D06M13/152 , D06P3/80 , C07C35/22 , C11D9/00 , C11D17/00
CPC分类号： C11B9/0053 , C07C35/36 , C07C45/69 , C07C45/72 , C07C49/603 , C07C49/637
摘要： Bicyclic carbinol of formula ##STR1## or 1,2,3,4,4a,5,8,8a-octahydro-2,2,6,8-tetramethyl-1-naphthalenol possesses useful odorous properties and it can be used advantageously as perfuming ingredient. A two-step process for its synthesis is disclosed starting from 2-methylpenta-1,3-diene and 6,6-dimethyl-cyclohex-2-en-1-one.
摘要翻译：具有式（I）或1,2,3,4,4a，5,8,8a-八氢-2,2,6,8-四甲基-1-萘酚的双环甲醇具有有用的气味性质，它可以是有利地用作加香成分。公开了从2-甲基戊-1,3-二烯和6,6-二甲基 - 环己-2-烯-1-酮开始合成的两步法。

33. 发明授权

US4652685A Hydrogenation of lactones to glycols 失效
标题翻译：内酯氢化成二醇
公开(公告)号：US4652685A
公开(公告)日：1987-03-24
申请号：US798498
申请日：1985-11-15
申请人： James N. Cawse , Norman E. Johnson , Michael T. Whitaker
发明人： James N. Cawse , Norman E. Johnson , Michael T. Whitaker
IPC分类号： C07B61/00 , B01J23/00 , C07C27/00 , C07C29/136 , C07C29/149 , C07C67/00 , C07C31/20
CPC分类号： C07C29/149
摘要： Lactones, particularly gamma-butyrolactone, are hydrogenated in the vapor phase to glycols over a copper chromite catalyst.
摘要翻译：内酯，特别是γ-丁内酯，在亚铬酸铜催化剂中，在气相中被氢化成二醇。

34. 发明授权

US4594462A Preparation of butane-1,4-diol 失效
标题翻译：丁烷-1,4-二醇的制备
公开(公告)号：US4594462A
公开(公告)日：1986-06-10
申请号：US748998
申请日：1985-06-26
申请人： Rolf Schnabel , Hans-Martin Weitz
发明人： Rolf Schnabel , Hans-Martin Weitz
IPC分类号： C07C29/136 , B01J23/00 , B01J23/72 , C07B61/00 , C07C27/00 , C07C29/149 , C07C31/20 , C07C67/00
CPC分类号： C07C29/149
摘要： Butane-1,4-diol is prepared by catalytic hydrogenation of dibutyl succinate by a process in which hydrogenation is terminated before complete conversion is reached, butanol is distilled off from the reaction mixture, the liquid distillation residue is cooled to below 108.degree. C., the upper phase, which is formed as a result of phase separation and essentially consists of dibutyl succinate, is recycled to the hydrogenation, and the butane-1,4-diol is obtained from the lower phase, which essentially consists of this compound, by fractional distillation under reduced pressure.
摘要翻译：丁烷-1,4-二醇通过二丁基琥珀酸二丁酯的催化氢化制备，其中在完成转化之前终止氢化的方法，从反应混合物中蒸馏出丁醇，将液体蒸馏残余物冷却至低于108℃。作为相分离结果而形成的上层，由琥珀酸二丁酯基本上由二丁基琥珀酸酯组成，再循环到氢化中，丁烷-1,4-二醇由下层得到，该相基本上由该化合物组成，通过减压下的分馏。

35. 发明授权

US4584419A Process for the production of butane-1,4-diol 失效
标题翻译：制备丁烷-1,4-二醇的方法
公开(公告)号：US4584419A
公开(公告)日：1986-04-22
申请号：US673797
申请日：1984-11-21
申请人： Mohammad Sharif , Keith Turner
发明人： Mohammad Sharif , Keith Turner
IPC分类号： C07C29/132 , B01J31/00 , C07B61/00 , C07C27/00 , C07C29/149 , C07C29/17 , C07C31/20 , C07C67/00 , C07D315/00 , C07D317/08 , H02P25/06 , C07C29/136
CPC分类号： C07D315/00 , C07C29/149 , C07C29/177 , C07D317/08
摘要： A process for the production of butane-1,4-diol comprises hydrogenating a di(C.sub.1 to C.sub.3 alkyl) ester of a C.sub.4 dicarboxylic acid, e.g. an ester of a but-2-en-1,4-dioic acid, such as diethyl maleate, in the vapor phase at a temperature of from about 150.degree. C. to about 240.degree. C. and at a pressure in the range of from about 25 bar to about 75 bar in the presence of a reduced copper chromite catalyst, and recovering resulting butane-1,4-diol containing reaction product. The catalyst contains, before reduction, from about 25 to about 45% by weight of copper and from about 20 to about 35% by weight of chromium and preferably has an internal surface area of at least about 30 sq. m. per gram. The process is preferably conducted in two or more reaction zones, which are preferably operated adiabatically, the feed temperature to the first zone being higher than that to at least one subsequent reaction zone.
摘要翻译：制备丁烷-1,4-二醇的方法包括使C4二羧酸的二（C1-C3烷基）酯例如氢化。异丁烯-1,4-二酸如马来酸二乙酯的酯在气相中在约150℃至约240℃的温度和在在还原的亚铬酸铜催化剂存在下，从约25巴至约75巴，并回收得到的含丁烷-1,4-二醇的反应产物。催化剂在还原前含有约25至约45重量％的铜和约20至约35重量％的铬，优选具有至少约30平方米的内表面积。每克。该方法优选在两个或更多个反应区中进行，优选以绝热方式操作，第一区的进料温度高于至少一个后续反应区的进料温度。

36. 发明授权

US4421939A Production of ethanol from acetic acid 失效
标题翻译：从乙酸生产乙醇
公开(公告)号：US4421939A
公开(公告)日：1983-12-20
申请号：US434562
申请日：1982-10-15
申请人： Ben W. Kiff , David J. Schreck
发明人： Ben W. Kiff , David J. Schreck
IPC分类号： C07C29/136 , B01J31/00 , C07C1/24 , C07C27/00 , C07C29/149 , C07C31/08 , C07C67/00
CPC分类号： C07C29/149 , C07C1/24 , C07C67/04 , C07C2521/02 , C07C2527/173
摘要： Ethanol is produced from acetic acid by esterifying the acetic acid with an olefin having at least 4 carbon atoms, hydrogenating the ester obtained into ethanol and a higher alcohol having at least 4 carbon atoms, removing the ethanol, dehydrating the higher alcohol back to the original olefin and recycling the olefin to esterify the acetic acid.
摘要翻译：乙酸通过用具有至少4个碳原子的烯烃酯化乙酸来制备乙醇，将得到的酯氢化成乙醇和具有至少4个碳原子的高级醇，除去乙醇，使高级醇脱水回原来烯烃并再循环烯烃以酯化乙酸。

37. 发明授权

US4385185A .beta.-.gamma.-Unsaturated ketones and isoprenoid 2,6 diones, a process for producing the same and their use as fragrant and flavoring substances 失效
标题翻译： β-γ-不饱和酮和类异戊二烯2,6-二酮，其生产方法及其作为芳香和调味物质的用途
公开(公告)号：US4385185A
公开(公告)日：1983-05-24
申请号：US245574
申请日：1981-03-20
申请人： Helmut Gebauer , Walter Hafner
发明人： Helmut Gebauer , Walter Hafner
IPC分类号： C07C43/13 , A23L27/20 , A61K8/34 , A61K8/35 , A61Q13/00 , C07C27/00 , C07C29/136 , C07C29/143 , C07C29/145 , C07C31/125 , C07C33/02 , C07C33/30 , C07C41/00 , C07C43/178 , C07C45/00 , C07C45/67 , C07C45/68 , C07C49/20 , C07C49/203 , C07C49/213 , C07C49/217 , C07C49/255 , C07C49/557 , C07C49/587 , C07C49/76 , C07C67/00 , C07C69/587 , C11B9/00 , C07C49/21
CPC分类号： C11B9/0015 , C07C33/02 , C07C45/67 , C07C45/68 , C07C49/203 , C07C49/217 , C07C49/255
摘要： Compounds of the general formula I: ##STR1## wherein R.sub.1 and R.sub.2 are equal or different alkyl-, alkoxyalkyl-, or aryl groups, or together form a ring; R.sub.3 is an allyl or benzyl radical; and R.sub.4 and R.sub.5 represent hydrogen, alkyl, alkoxyalkyl, alkenyl or further compounds of the formula II: ##STR2## wherein R.sub.1, R.sub.2, R.sub.4 and R.sub.5 have the meaning indicated above and R.sub.6 stands for hydrogen or methyl or to compounds which are modified by the addition of hydrogen to at least one olefinic or carbonylic double bond of compounds of the general formula I or II. The invention also relates to a process for preparing the new compounds. The compounds of the general formula II are obtained by thermal treatment of a selection of compounds of formula I, for which R.sub.3 stands for the allyl or methallyl radical. The compounds according to the invention are used as fragrant and flavoring substances.
摘要翻译：通式I的化合物：其中R 1和R 2是相同或不同的烷基 - ，烷氧基烷基 - 或芳基，或一起形成环; R3是烯丙基或苄基; 并且R 4和R 5表示氢，烷基，烷氧基烷基，烯基或式II的其它化合物：其中R1，R2，R4和R5具有上述含义，R6代表氢或甲基或被修饰的化合物通过向通式I或II化合物的至少一个烯属或羰基双键加氢。本发明还涉及一种制备新化合物的方法。通式II的化合物通过热处理选择的式I化合物获得，其中R3代表烯丙基或甲代烯丙基。根据本发明的化合物用作香料和调味物质。

38. 发明授权

US4367346A Method for synthesis of long-chain alcohols 失效
标题翻译：合成长链醇的方法
公开(公告)号：US4367346A
公开(公告)日：1983-01-04
申请号：US256626
申请日：1981-04-23
申请人： Dane K. Parker
发明人： Dane K. Parker
IPC分类号： C07C27/00 , C07C29/00 , C07C29/147 , C07C31/125 , C07C45/56 , C07C49/385 , C07C51/00 , C07C51/60 , C07C53/126 , C07C67/00 , C07D295/023 , C07C29/136
CPC分类号： C07D295/023 , C07C29/147 , C07C45/56 , C07C49/385 , C07C51/00 , C07C51/60 , C07C53/126
摘要： This invention is concerned with the preparation of long-chain carboxylic acids and alcohols from cyclododecanone and acyl chlorides. More specifically, this invention relates to a process for the preparation of 1-triacontanol, CH.sub.3 (CH.sub.2).sub.28 CH.sub.2 OH. Triacontanol acts as a growth stimulant on a wide range of plants to increase dry weight gains, water uptake, water use efficiency and protein synthesis in treated plants.
摘要翻译：本发明涉及从环十二烷酮和酰基氯制备长链羧酸和醇。更具体地，本发明涉及制备1-三十烷醇，CH 3（CH 2）28 CH 2 OH的方法。三十烷醇在广泛的植物上作为生长兴奋剂，以增加处理植物中的干重增加，吸水率，水分利用效率和蛋白质合成。

39. 发明授权

US4341909A Preparation of low molecular weight polyhydroxyl compounds 失效
标题翻译：低分子量多羟基化合物的制备
公开(公告)号：US4341909A
公开(公告)日：1982-07-27
申请号：US301609
申请日：1981-09-14
申请人： Gottfried Schneider , Kuno Wagner , Hanns P. Muller
发明人： Gottfried Schneider , Kuno Wagner , Hanns P. Muller
IPC分类号： C07C27/00 , A61K8/30 , A61K8/34 , A61K8/35 , A61K8/72 , B01J31/00 , C07B61/00 , C07C29/136 , C07C29/14 , C07C29/38 , C07C31/18 , C07C45/00 , C07C45/75 , C07C47/19 , C07C49/17 , C07C67/00 , C07H3/02 , C08G18/00 , C08G18/54 , C12N1/20 , C08G18/14 , C08G18/32
CPC分类号： C07H3/02 , C07C45/00 , C07C45/75
摘要： A process is disclosed for preparing mixtures of low molecular weight polyhydroxyl compounds and optionally hydroxyaldehydes and ketones by condensing formaldehyde hydrate with itself in the presence of(A) soluble or insoluble lead(II) salts or of divalent lead attached to a high molecular weight carrier; and(B) a co-catalyst, comprising a mixture of hydroxyaldehydes and hydroxyketones obtainable by condensation of formaldehyde, which mixture contains at least 75%, by weight, of C.sub.3 to C.sub.6 compounds and is characterized by the following molar ratios:Compounds having 3 carbon atoms/compounds having 4 carbon atoms from 0.5:1 to 2.0:1;Compounds having 4 carbon atoms/compounds having 5 carbon atoms from 0.2:1 to 2.0:1;Compounds having 5 carbon atoms/compounds having 6 carbon atoms from 0.5:1 to 5.0:1.The pH of the reaction mixture is held at from 6.0 to 7.0 until from 10 to 60% conversion has occurred and is then lowered to between 4.0 to 6.0 until 90-100% conversion has occurred. The reaction is then stopped by inactivating the catalyst.
摘要翻译：公开了一种通过在（A）可溶性或不溶性铅（II）盐或附着于高分子量载体上的二价铅的存在下将甲醛水合物与其自身缩合来制备低分子量多羟基化合物和任选的羟基醛和酮的混合物的方法 ; 和（B）助催化剂，其包含可通过甲醛缩合获得的羟基醛和羟基酮的混合物，该混合物含有至少75重量％的C3至C6化合物，其特征在于以下摩尔比：具有3个碳原子数/碳原子数为5：1〜2.0：1的化合物; 具有4个碳原子的化合物/具有5个碳原子的化合物从0.2:1至2.0:1; 具有5个碳原子的化合物/具有6个碳原子的化合物从0.5:1至5.0:1。反应混合物的pH值保持在6.0至7.0，直至发生10至60％的转化率，然后降至4.0至6.0直至发生90-100％转化。然后通过使催化剂失活来停止反应。

40. 发明授权

US4325974A .beta., .gamma.-Dihydropolyprenyl alcohol and hypotensive pharmaceutical composition containing same 失效
标题翻译： β，γ-二氢脯氨酸醇和含有其的降血糖药物组合物
公开(公告)号：US4325974A
公开(公告)日：1982-04-20
申请号：US96355
申请日：1979-11-21
申请人： Isao Yamatsu , Shinya Abe , Yuichi Inai , Toshiji Igarashi , Yoshikage Nakajima
发明人： Isao Yamatsu , Shinya Abe , Yuichi Inai , Toshiji Igarashi , Yoshikage Nakajima
IPC分类号： A61K31/045 , A61P9/12 , C07C27/00 , C07C29/00 , C07C29/147 , C07C33/02 , C07C33/025 , C07C51/08 , C07C57/03 , C07C67/00 , C07C253/00 , C07C255/07 , C07C255/23 , C07C29/136
CPC分类号： C07C255/00 , C07C29/147 , C07C33/02 , C07C51/08 , C07C57/03
摘要： .beta., .gamma.-Dihydropolyprenyl alcohols of the general formula: ##STR1## wherein n represents an integer of 8 to 10, exhibit hypotensive activity and anti-hepatic disease-activity.
摘要翻译： β，γ-二氢聚芴醇，其通式如下：其中n表示8至10的整数，表现出降血压活性和抗肝脏疾病活性。

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