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    • 41. 发明申请
    • Method For The Dissolving And Rapid Hydrolyzing Of Lignocellulose Biomass, Device Thereof And Use Of the Same
    • 用于溶解和快速水解木质素纤维素生物质的方法及其使用方法
    • US20130274527A1
    • 2013-10-17
    • US13876941
    • 2011-07-04
    • Zhen Fang
    • Zhen Fang
    • C13K1/02C07C29/00
    • C13K1/02C07C29/00C08H8/00C09K3/00C12P7/10C12P2201/00C12P2203/00Y02E50/16Y02E50/17
    • A method for the dissolving and rapid hydrolyzing of the lignocellulose biomass and the device thereof are disclosed. The lignocellulose biomass is put in the pure water and rapidly heated to 330˜403° C., and then 89˜99% of the lignocellulose biomass is dissolved and rapidly hydrolyzed to saccharide in 3.38˜21.79 s. The following hydrolysis reaction can be carried out under the homogeneous phase condition for the dissolving of the lignocellulose biomass. At the same time, the solvated biomass could be easily used in the high pressure flow reactor to continuously pretreat the biomass and hydrolyze for producing saccharide, other biofuel and product. The present invention doesn't need any catalyst and doesn't pollute the environment, furthermore the process is simple and the cost is low, and it belongs to green, continuable industry encouraged by the state, and a good prospect of market application could be taken on.
    • 公开了一种用于溶解和快速水解木质纤维素生物质的方法及其装置。 将木质纤维素生物质放入纯水中,迅速加热至330〜403℃,然后将木质纤维素生物质的89〜99%溶解并迅速水解成糖,为3.38〜21.79s。 以下水解反应可以在均相条件下进行,用于溶解木质纤维素生物质。 同时,溶剂化生物质可以容易地用于高压流动反应器中,以连续预处理生物质,并水解生产糖,其他生物燃料和产品。 本发明不需要任何催化剂,不污染环境,而且工艺简单,成本低,属于国家鼓励绿色,可持续发展的行业,市场应用前景广阔 被带走
    • 44. 发明申请
    • High Vinyl Terminated Propylene Based Oligomers
    • 高乙烯基终止丙烯基低聚物
    • US20130066103A1
    • 2013-03-14
    • US13670085
    • 2012-11-06
    • Patrick BRANTDonna J. CROWTHERAndrew G. NARVAEZ
    • Patrick BRANTDonna J. CROWTHERAndrew G. NARVAEZ
    • C07C2/24C07C2/38C07C45/00C07C29/00C07C67/04C07C209/00
    • C08F210/06C08F210/16C08F2500/20C08F2500/02
    • This invention relates to a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(−0.94(mole % ethylene incorporated)+100), when 10 to 60 mole % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mole % ethylene is present in the co-oligomer, and 3) X=(1.83*(mole % ethylene incorporated)−83), when 70 to 90 mole % ethylene is present in the co-oligomer. This invention also relates to a homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum. This invention also relates to a process of making homo-oligomer, comprising propylene, wherein the productivity is greater than 4500 g/mmol Hf (or Zr)/hour.
    • 本发明涉及Mn为300〜30,000g / mol,包含10-90mol%丙烯和10-90mol%乙烯的共低聚物,其中低聚物具有至少X%的烯丙基链末端,其中:1) 当共聚低聚物中存在10至60摩尔%的乙烯时,X =( - 0.94(摩尔%乙烯掺入)+100),和2)X = 45,当大于60且小于70摩尔%时存在乙烯 在共低聚物中,3)X =(1.83 *(摩尔%乙烯掺入)-83),当共聚低聚物中存在70至90摩尔%的乙烯时。 本发明还涉及包含丙烯的均聚物,其中低聚物具有:至少93%的烯丙基链端,约500至约20,000g / mol的Mn,异丁基链端至烯丙基乙烯基的比例为0.8: 1至1.2:1.0和小于100ppm的铝。 本发明还涉及制备包含丙烯的均聚物的方法,其中生产率大于4500g / mmol Hf(或Zr)/小时。