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1. 发明授权

US09331351B2 Solid oxide fuel cell device 有权
标题翻译：固体氧化物燃料电池装置
公开(公告)号：US09331351B2
公开(公告)日：2016-05-03
申请号：US12788878
申请日：2010-05-27
申请人： Katsuhisa Tsuchiya , Toshiharu Otsuka , Tsukasa Shigezumi , Toshiharu Ooe , Kiyotaka Nakano , Yoshiyuki Kawamura
发明人： Katsuhisa Tsuchiya , Toshiharu Otsuka , Tsukasa Shigezumi , Toshiharu Ooe , Kiyotaka Nakano , Yoshiyuki Kawamura
IPC分类号： H01M8/04 , H01M8/06 , C01B3/38 , H01M8/24 , H01M8/12
CPC分类号： H01M8/0618 , C01B3/38 , C01B2203/0244 , C01B2203/066 , C01B2203/1058 , C01B2203/1064 , C01B2203/1258 , C01B2203/1276 , C01B2203/1609 , C01B2203/1619 , C01B2203/1685 , C01B2203/169 , H01M8/0271 , H01M8/04022 , H01M8/04223 , H01M8/04225 , H01M8/04228 , H01M8/04268 , H01M8/0432 , H01M8/04776 , H01M8/0625 , H01M8/2428 , H01M8/243 , H01M8/2484 , H01M2008/1293 , Y02E60/50 , Y02E60/525
摘要： To provide a solid oxide fuel cell device capable of smooth transition from a startup state to an electrical generating state. The present invention is a solid oxide fuel cell device (1) for generating electricity, having a fuel cell module (2); a reformer (20), a fuel supply device (38); a water supply device (28), a generating oxidant gas supply device (45), and a controller (110) for controlling the fuel supply device and water supply device at the time of startup when the fuel cell module solid oxide fuel cell unit is raised to a temperature at which electrical generation is possible; whereby the controller controls the fuel supply device during the SR operation such that electrical generation is started after reducing the fuel supply flow rate prior to starting electrical generation.
摘要翻译：提供能够从启动状态平滑过渡到发电状态的固体氧化物型燃料电池元件。本发明是一种具有燃料电池模块（2）的发电用固体氧化物型燃料电池装置（1）。重整器（20），燃料供给装置（38）; 供水装置（28），发电氧化剂气体供给装置（45），以及控制器（110），其用于在燃料电池模块固体氧化物型燃料电池单元为起动时控制启动时的燃料供给装置和供水装置升至可能发电的温度; 由此控制器在SR操作期间控制燃料供应装置，使得在开始发电之前降低燃料供应流量之后开始发电。

2. 发明授权

US09105891B2 Fuel cell system and control method for fuel cell system 有权
标题翻译：燃料电池系统及其控制方法
公开(公告)号：US09105891B2
公开(公告)日：2015-08-11
申请号：US13521898
申请日：2011-01-11
申请人： Hideo Nagaosa
发明人： Hideo Nagaosa
IPC分类号： H01M8/04 , C01B3/04 , H01M8/06 , H01M8/10
CPC分类号： H01M8/04492 , C01B3/047 , C01B2203/066 , C01B2203/1604 , C01B2203/1685 , C01B2203/1695 , H01M8/04 , H01M8/045 , H01M8/04611 , H01M8/04641 , H01M8/04776 , H01M8/06 , H01M8/0612 , H01M2008/1095 , Y02E60/364 , Y02E60/50
摘要： A fuel cell system includes a fuel cell of a solid polymer type that generates power by using a hydrogen-containing gas as a fuel gas, a reformer that generates the fuel gas by reforming ammonia, and a supply amount ratio control unit that controls a supply amount ratio of oxygen and ammonia to be supplied the reformer.
摘要翻译：燃料电池系统包括通过使用含氢气体作为燃料气体而产生电力的固体聚合物类型的燃料电池，通过重整氨生成燃料气体的重整器和控制供给的供给量控制单元供应重整器的氧和氨的量比。

3. 发明授权

US08906564B2 Hydrogen generator, fuel cell system, and method for operating hydrogen generator 有权
标题翻译：氢发生器，燃料电池系统和操作氢发生器的方法
公开(公告)号：US08906564B2
公开(公告)日：2014-12-09
申请号：US13142525
申请日：2010-03-30
申请人： Akinori Yukimasa , Junji Morita , Akinari Nakamura
发明人： Akinori Yukimasa , Junji Morita , Akinari Nakamura
IPC分类号： H01M8/06 , C01B3/38
CPC分类号： H01M8/0618 , C01B3/384 , C01B2203/0233 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/1058 , C01B2203/1064 , C01B2203/12 , C01B2203/1288 , C01B2203/1609 , C01B2203/1619 , C01B2203/1685 , C01B2203/169 , Y02E60/50 , Y02P20/128
摘要： The possibility of carbon deposition from a raw material gas is made lower than before in a pressure compensating operation carried out after stopping the stop process of a hydrogen generator and a fuel cell system including the hydrogen generator.The hydrogen generator includes: a raw material supply unit (102, 103) configured to function to block supply of a raw material; a steam supply unit (104, 105) configured to function to block supply of steam; a reformer 108 including a reforming catalyst 109 and configured to generate a hydrogen-containing gas by using the raw material supplied from the raw material supply unit and the steam supplied from the steam supply unit; a closing unit 116 configured to block at least a gas passage provided downstream of the reformer; and a controller 140 configured to execute a pressure compensating operation in which: during stop of the hydrogen generator, with hydrogen contained in the reformer, the supply of the raw material from the raw material supply unit and the supply of the steam from the steam supply unit are blocked, and the closing unit is closed; and to compensate a pressure decrease in the reformer due to a temperature decrease in the reformer after the closing of the closing unit, with the hydrogen contained in the reformer, the steam is supplied from the steam supply unit to the reformer.
摘要翻译：在停止氢发生器和包括氢发生器的燃料电池系统的停止处理之后执行的压力补偿操作中，从原料气体中进行碳沉积的可能性比以前低。氢发生器包括：原料供给单元（102,103），其被配置为阻止原料的供给; 蒸汽供应单元（104,105），其构造成用于阻止蒸汽的供应; 重整器108，其包括重整催化剂109，其构造为通过使用从原料供给单元供给的原料和从蒸汽供给单元供给的蒸汽来生成含氢气体; 闭合单元116，其构造成阻挡设置在重整器的下游的至少一个气体通道; 以及控制器140，被配置为执行压力补偿操作，其中：在氢发生器停止期间，包含在重整器中的氢，来自原料供应单元的原料的供应和来自蒸汽供应源的蒸汽的供应单元被封闭，关闭单元关闭; 并且为了补偿由于在关闭单元关闭之后重整器中的温度降低导致的重整器中的压力降低，包含在重整器中的氢气将蒸汽从蒸汽供应单元供应到重整器。

4. 发明授权

US08771387B2 Systems and methods for solar-thermal gasification of biomass 有权
标题翻译：生物质太阳能热气化的系统和方法
公开(公告)号：US08771387B2
公开(公告)日：2014-07-08
申请号：US12796045
申请日：2010-06-08
申请人： Wayne Simmons , Christopher Perkins , Zoran Jovanovic
发明人： Wayne Simmons , Christopher Perkins , Zoran Jovanovic
IPC分类号： B01J7/00
CPC分类号： C01B3/384 , B01J19/0013 , B01J19/0033 , B01J19/2445 , B01J19/245 , B01J2219/00117 , B01J2219/00186 , C01B3/22 , C01B3/34 , C01B2203/0216 , C01B2203/0233 , C01B2203/061 , C01B2203/0811 , C01B2203/1241 , C01B2203/1685 , C01B2203/84 , C07C29/15 , C07C29/1518 , C10G2/30 , C10G2/32 , C10G3/00 , C10G2300/1014 , C10G2300/1025 , C10G2300/807 , C10J3/00 , C10J3/466 , C10J3/482 , C10J3/485 , C10J3/506 , C10J3/54 , C10J3/56 , C10J3/58 , C10J3/60 , C10J3/62 , C10J3/721 , C10J3/723 , C10J3/82 , C10J3/84 , C10J2200/09 , C10J2200/15 , C10J2200/158 , C10J2300/0906 , C10J2300/0909 , C10J2300/0916 , C10J2300/094 , C10J2300/0973 , C10J2300/0976 , C10J2300/0989 , C10J2300/0993 , C10J2300/1223 , C10J2300/123 , C10J2300/1284 , C10J2300/1292 , C10J2300/1621 , C10J2300/1659 , C10J2300/1665 , C10J2300/1693 , C10J2300/1853 , C10J2300/1861 , C10K1/024 , C10L1/04 , C10L2200/0492 , C10L2290/02 , C10L2290/04 , C10L2290/06 , C10L2290/08 , C10L2290/28 , C10L2290/42 , C10L2290/50 , C10L2290/52 , C10L2290/547 , F24S20/20 , Y02B40/18 , Y02E10/41 , Y02E50/18 , Y02E50/32 , Y02P20/129 , Y02P20/134 , Y02P20/136 , Y02P20/145 , Y02P30/20 , Y02T50/678 , C07C31/04
摘要： A method, apparatus, and system for a solar-driven chemical plant that may include a solar thermal receiver having a cavity with an inner wall, where the solar thermal receiver is aligned to absorb concentrated solar energy from one or more of 1) an array of heliostats, 2) solar concentrating dishes, and 3) any combination of the two. Some embodiments may include a solar-driven chemical reactor having multiple reactor tubes located inside the cavity of solar thermal receiver, wherein a chemical reaction driven by radiant heat occurs in the multiple reactor tubes, and wherein particles of biomass are gasified in the presence of a steam (H2O) carrier gas and methane (CH4) in a simultaneous steam reformation and steam biomass gasification reaction to produce reaction products that include hydrogen and carbon monoxide gas using the solar thermal energy from the absorbed concentrated solar energy in the multiple reactor tubes.
摘要翻译：一种用于太阳能驱动的化学设备的方法，装置和系统，其可以包括具有内壁的空腔的太阳能热接收器，其中太阳能热接收器对准以从1）阵列中的一个或多个吸收集中的太阳能的定日镜，2）太阳能集中盘，3）两者的任何组合。一些实施例可以包括太阳能驱动的化学反应器，其具有位于太阳能热接收器的空腔内的多个反应器管，其中在多个反应器管中发生由辐射热驱动的化学反应，并且其中生物质颗粒在蒸汽（H 2 O）载气和甲烷（CH4），同时进行蒸汽重整和蒸汽生物质气化反应，以产生包含氢气和一氧化碳气体的反应产物，使用来自多个反应器管中吸收的浓缩太阳能的太阳能热能。

5. 发明授权

US08501102B2 Hydrogen generator and startup method thereof 有权
标题翻译：氢发生器及其启动方法
公开(公告)号：US08501102B2
公开(公告)日：2013-08-06
申请号：US13062471
申请日：2010-08-26
申请人： Akira Maenishi , Yukimune Kani , Yuji Mukai
发明人： Akira Maenishi , Yukimune Kani , Yuji Mukai
IPC分类号： G05D23/00 , B01J8/00
CPC分类号： H01M8/0618 , C01B3/384 , C01B3/48 , C01B2203/0233 , C01B2203/0283 , C01B2203/044 , C01B2203/066 , C01B2203/0816 , C01B2203/0822 , C01B2203/0827 , C01B2203/1058 , C01B2203/107 , C01B2203/1241 , C01B2203/1288 , C01B2203/1604 , C01B2203/1619 , C01B2203/1685 , C01B2203/82 , H01M8/04373 , H01M8/04776 , H01M8/0625 , H01M8/0631 , Y02P20/128
摘要： A hydrogen generator is described, which comprises: a material supply device (4); a water supply device (5); an evaporator (10); a reforming catalyst layer (1) for generating reformed gas; a CO removing catalyst layer (2) configured to reduce the amount of carbon monoxide contained in the reformed gas generated by the reforming catalyst layer (1); a combustor (3) for heating the reforming catalyst layer (1) and the CO removing catalyst layer (2); a reforming temperature detector (9) for detecting the temperature of the reforming catalyst layer (1); a heater (7) for heating the CO removing catalyst layer (2); a CO removing temperature detector (8) for detecting the temperature of the CO removing catalyst layer (2); and a controller (16) configured to perform control such that the heater (7) heats the CO removing catalyst layer at the time of start-up and such that if the temperature detected by the CO removing temperature detector (8) becomes greater than or equal to a first specified value, the combustor (3) heats the reforming catalyst layer (1) and the CO removing catalyst layer (2), and if the temperature detected by the reforming temperature detector (9) becomes greater than or equal to a second specified value, the water supply device (5) starts supplying of water.
摘要翻译：描述了氢发生器，其包括：材料供应装置（4）; 供水装置（5）; 蒸发器（10）; 用于产生重整气体的重整催化剂层（1）; 配置为减少由所述重整催化剂层（1）产生的重整气体中所含的一氧化碳的量的CO除去催化剂层（2）; 用于加热重整催化剂层（1）和CO去除催化剂层（2）的燃烧器（3）; 用于检测重整催化剂层（1）的温度的重整温度检测器（9）; 用于加热所述CO除去催化剂层（2）的加热器（7）; 用于检测除氧催化剂层（2）的温度的CO去除温度检测器（8）; 以及控制器（16），被配置为执行控制，使得加热器（7）在启动时加热CO去除催化剂层，并且如果由CO去除温度检测器（8）检测到的温度变得大于或等于等于第一规定值时，燃烧器（3）加热重整催化剂层（1）和CO除去催化剂层（2），如果由重整温度检测器（9）检测的温度变得大于或等于第二规定值，供水装置（5）开始供水。

6. 发明申请

US20130118077A1 STEAM/CARBON RATIO DETECTION AND CONTROL 审中-公开
标题翻译：蒸汽/碳比检测与控制
公开(公告)号：US20130118077A1
公开(公告)日：2013-05-16
申请号：US13261553
申请日：2010-07-02
申请人： Michael T. Lines , John L. Preston
发明人： Michael T. Lines , John L. Preston
IPC分类号： C10J1/20
CPC分类号： C10J1/20 , C01B3/384 , C01B3/48 , C01B2203/0233 , C01B2203/0283 , C01B2203/0415 , C01B2203/0465 , C01B2203/066 , C01B2203/1241 , C01B2203/1619 , C01B2203/1685 , C01B2203/169 , H01M8/0618 , H01M8/0631
摘要： Steam is provided to the primary inlet (16) of an ejector (13), which also receives natural gas at a secondary inlet (28). A computer responds to a signal (37) indicating current in the load of a fuel cell as well as a signal (43) indicating temperature of a steam reformer (10) to move a linear actuator (23) to control a needle (21) that adjusts the size of the steam orifice. Reformate is fed to a separator scrubber (48) which cools the reformate to its dew point indicated by a sensor (71). From that, a controller (25) generates the fuel/carbon ratio for display (84) and to bias a signal on a line (24) regulating the amount of steam passing through an ejector (13) to the inlet (11) of the reformer. Alternatively, the reformate may be cooled to its dew point by a controllable heat exchanger (58a) in response to pressure (94) and temperature (71) signals.
摘要翻译：蒸汽被提供到喷射器（13）的主入口（16），其也在次级入口（28）处接收天然气。计算机响应指示燃料电池的负载中的电流的信号（37）以及指示蒸汽重整器（10）的温度以移动线性致动器（23）以控制针（21）的信号（43）调整蒸汽孔的尺寸。重整物进料到分离器洗涤器（48），其将重整产物冷却到由传感器（71）指示的露点。由此，控制器（25）产生用于显示（84）的燃料/碳比，并且将通过喷射器（13）的蒸汽量的管线（24）上的信号偏置到入口（11）改良者或者，可以通过响应于压力（94）和温度（71）信号的可控热交换器（58a）将重整产物冷却至其露点。

7. 发明申请

US20120288776A1 FUEL CELL SYSTEM AND CONTROL METHOD FOR FUEL CELL SYSTEM 有权
标题翻译：燃料电池系统及燃料电池系统控制方法
公开(公告)号：US20120288776A1
公开(公告)日：2012-11-15
申请号：US13521898
申请日：2011-01-11
申请人： Hideo Nagaosa
发明人： Hideo Nagaosa
IPC分类号： H01M8/06 , H01M8/04
CPC分类号： H01M8/04492 , C01B3/047 , C01B2203/066 , C01B2203/1604 , C01B2203/1685 , C01B2203/1695 , H01M8/04 , H01M8/045 , H01M8/04611 , H01M8/04641 , H01M8/04776 , H01M8/06 , H01M8/0612 , H01M2008/1095 , Y02E60/364 , Y02E60/50
摘要： A fuel cell system includes a fuel cell of a solid polymer type that generates power by using a hydrogen-containing gas as a fuel gas, a reformer that generates the fuel gas by reforming ammonia, and a supply amount ratio control unit that controls a supply amount ratio of oxygen and ammonia to be supplied the reformer.
摘要翻译：燃料电池系统包括通过使用含氢气体作为燃料气体而产生电力的固体聚合物类型的燃料电池，通过重整氨生成燃料气体的重整器和控制供给的供给量控制单元供应重整器的氧和氨的量比。

8. 发明申请

US20120272575A1 FUEL REFORMING SYSTEM AND CONTROL METHOD OF FUEL REFORMING SYSTEM 审中-公开
标题翻译：燃油改造系统及燃油改造系统控制方法
公开(公告)号：US20120272575A1
公开(公告)日：2012-11-01
申请号：US13520687
申请日：2011-01-11
申请人： Takatoshi Masui
发明人： Takatoshi Masui
IPC分类号： C10L3/00
CPC分类号： C01B3/32 , C01B3/384 , C01B2203/0233 , C01B2203/066 , C01B2203/0822 , C01B2203/0827 , C01B2203/1276 , C01B2203/1288 , C01B2203/1633 , C01B2203/1685 , C01B2203/169 , H01M8/0625 , Y02P20/128
摘要： A fuel reforming system includes a reformer that produces fuel gas that includes hydrogen by reforming a reforming fuel by a steam reforming reaction using reforming water, and; supply amount regulating means for regulating an amount of the reforming water supplied to the reformer; pressure detecting means for detecting a gas pressure in the reformer; and correcting means for correcting the amount of supplied reforming water with the supply amount regulating means based on a fluctuation amount in the gas pressure detected by the pressure detecting means.
摘要翻译：燃料重整系统包括重整器，其通过使用重整水通过蒸汽重整反应重整重整燃料而产生包括氢的燃料气体; 供给量调节装置，用于调节供给至重整器的重整水的量; 压力检测装置，用于检测重整器中的气体压力; 以及校正装置，用于基于由压力检测装置检测到的气体压力的波动量，用供给量调节装置校正供应的重整水的量。

9. 发明授权

US08282907B2 Hydrogen generation processes and apparatus and control system 失效
标题翻译：氢气生成过程及设备及控制系统
公开(公告)号：US08282907B2
公开(公告)日：2012-10-09
申请号：US12375991
申请日：2007-07-06
申请人： Kishore J. Doshi , Robert J. Sanger
发明人： Kishore J. Doshi , Robert J. Sanger
IPC分类号： C01B3/22 , C01B3/24 , C01B3/26
CPC分类号： C01B3/382 , C01B2203/0244 , C01B2203/0283 , C01B2203/0405 , C01B2203/043 , C01B2203/044 , C01B2203/0844 , C01B2203/0894 , C01B2203/1229 , C01B2203/1241 , C01B2203/1685 , C01B2203/84
摘要： Hydrogen generators and processes for operating hydrogen generators using partial oxidation/steam reforming of fuel are provided that can achieve desirable Net Hydrogen Efficiencies over a range of fuels and hydrogen product production rates and purities. Superheated steam for the reformer feed is provided through indirect heat exchange with the reformate and through indirect heat exchange with a flue gas. The relative portions of superheated steam from each heat exchange is adjusted to enhance Net Hydrogen Efficiency as a demand condition such as hydrogen product production rate or purity changes, and cooler oxygen-containing gas is used to avoid precombustion temperatures in the reformer feed.
摘要翻译：提供氢发生器和使用部分氧化/蒸汽重整燃料来操作氢发生器的方法，其能够在一系列燃料和氢气产物生产率和纯度上实现理想的净氢效率。用于重整器进料的过热蒸汽通过与重整产物的间接热交换并通过与烟道气的间接热交换来提供。调整来自每个热交换的过热蒸汽的相对部分以提高净氢效率，作为诸如氢产物生产速率或纯度变化的需求条件，并且使用较冷的含氧气体以避免重整器进料中的预燃温度。

10. 发明授权

US08206857B2 Fuel cell combined heat and power generation 有权
标题翻译：燃料电池组合发电和发电
公开(公告)号：US08206857B2
公开(公告)日：2012-06-26
申请号：US11819205
申请日：2007-06-26
申请人： Dingrong Bai , Jean-Guy Chouinard , David Elkaïm
发明人： Dingrong Bai , Jean-Guy Chouinard , David Elkaïm
IPC分类号： H01M8/18
CPC分类号： H01M8/0618 , C01B3/384 , C01B3/48 , C01B2203/0233 , C01B2203/0288 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0827 , C01B2203/127 , C01B2203/1657 , C01B2203/1676 , C01B2203/1685 , C01B2203/169 , H01M8/04029 , H01M8/04358 , H01M8/04373 , H01M8/04738 , H01M8/04776 , H01M8/04955 , H01M8/0662 , H01M2008/1095 , H01M2250/402 , H01M2250/405 , Y02B90/12 , Y02B90/16
摘要： A cogeneration system having flexible and controllable cogeneration loops. There is a first cogeneration loop to recover heat from a fuel cell power module, thereby producing a heat to electricity ratio between 0 and approximately 1.0. There is a second cogeneration loop to produce supplemental thermal energy for hot water generation and/or space heating. This loop can be connected or disconnected via switching valves depending on the thermal demands of hot water and/or space heating. This loop can also be useful to control the fuel processor temperature to prevent it from being overheated in cases when the fuel cell has low fuel utilization efficiency. With this second loop, it becomes possible to adjust the heat to electricity ratio at any desirable levels such as more than 2. It is also possible to produce the hot water at a higher temperature or superheated steam, which would have been difficult if only the first loop is used.
摘要翻译：具有灵活可控的热电联产循环的热电联产系统。存在用于从燃料电池功率模块回收热量的第一热电联产回路，从而产生介于0和约1.0之间的热电比。存在第二热电联产循环，以产生用于热水产生和/或空间加热的补充热能。根据热水和/或空间加热的热需求，可以通过开关阀将该回路连接或断开。在燃料电池具有低燃料利用效率的情况下，该回路也可用于控制燃料处理器温度以防止其过热。利用该第二回路，可以以任何所需的水平（例如大于2）将热电比进行调节。也可以在较高温度下生产热水或过热蒸汽，如果只有使用第一个循环。

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