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51. 发明授权

US6022935A Preparation of polymers of alk-1-enes in the presence of a supported metallocene catalyst system and of antistatic agent 失效
标题翻译：在负载型金属茂催化剂体系和抗静电剂的存在下制备烷-1-烯的聚合物
公开(公告)号：US6022935A
公开(公告)日：2000-02-08
申请号：US839811
申请日：1997-04-18
申请人： David Fischer , Helmut Frank , Martin Lux , Roland Hingmann , Gunther Schweier
发明人： David Fischer , Helmut Frank , Martin Lux , Roland Hingmann , Gunther Schweier
IPC分类号： C08F4/64 , C08F2/34 , C08F2/44 , C08F4/602 , C08F4/639 , C08F4/6392 , C08F4/642 , C08F4/646 , C08F4/6592 , C08F4/68 , C08F10/00 , C08F10/06 , C08F110/06 , C08F210/16 , C08J5/18 , D01F6/04 , D01F6/06 , D01F6/30
CPC分类号： C08J5/18 , C08F10/00 , C08F10/06 , D01F6/04 , D01F6/06 , D01F6/30 , B60K2015/03576 , C08F110/06 , C08F210/16 , C08F4/63908 , C08F4/63912 , C08F4/63916 , C08F4/63927 , C08J2323/04 , C08J2323/10 , Y10S526/901 , Y10S526/902
摘要： Polymers of C.sub.2 -C.sub.12 -alk-1-enes are prepared at from -50 to 300.degree. C. and from 0.5 to 3000 bar in the presence of a catalyst system by a process in which the catalyst system used is one which containsA) an inorganic or organic carrier,B) a metallocene complex,C) a compound forming metallocenium ions andD) if required, a metal compound of the general formula IM.sup.1 (R.sup.1).sub.r (R.sup.2).sub.s (R.sup.3).sub.t I whereM.sup.1 is an alkali metal, an alkaline earth metal or a metal of main group III of the Periodic Table,R.sup.1 is hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.15 -aryl, alkylaryl or arylalkyl, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,R.sup.2 and R.sup.3 are each hydrogen, halogen, C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.15 -aryl, alkylaryl, arylalkyl or alkoxy, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,r is an integer from 1 to 3 ands and t are integers from 0 to 2, the sum r+s+t corresponding to the valency of M.sup.1,and in which an antistatic agent is used.
摘要翻译：在催化剂体系的存在下，在-50至300℃和0.5至3000巴下制备C 2 -C 12烷-1-烯的聚合物，其中使用的催化剂体系是含有A）无机或有机载体，B）茂金属络合物，C）形成金属茂离子的化合物和D）如果需要，通式为IM1（R1）r（R2）s（R3）t1的金属化合物，其中M1为碱金属，碱土金属或元素周期表第Ⅲ族金属的金属，R1是氢，C1-C10烷基，C6-C15 - 芳基，烷基芳基或芳基烷基，它们在烷基中具有1-10个碳原子，芳基中的6至20个碳原子，R 2和R 3各自为氢，卤素，C 1 -C 10 - 烷基，C 6 -C 15 - 芳基，烷基芳基，芳基烷基或烷氧基，每个在烷基中具有1-10个碳原子，6 至20个碳原子，r为1至3的整数，s和t为0至2的整数，r + s + t的总和对应于M1的化合价，其中抗静电剂用来。

52. 发明授权

US6022916A Processing stabilizer formulations 失效
标题翻译：加工稳定剂配方
公开(公告)号：US6022916A
公开(公告)日：2000-02-08
申请号：US288670
申请日：1994-08-09
申请人： William P. Enlow , Roger W. Avakian
发明人： William P. Enlow , Roger W. Avakian
IPC分类号： B29C47/68 , B29K23/00 , C08J5/18 , C08J7/14 , C08K5/098 , C08K5/49 , C08K5/51 , C08K5/527 , C08K5/56 , C08L23/00 , D01D1/10 , D01F1/10 , D01F6/04 , D01F6/06
CPC分类号： C08J5/18 , C08K5/098 , C08K5/527 , D01D1/10 , D01F1/10 , D01F6/04 , D01F6/06 , C08J2323/02
摘要： Melt extrusion processes involving phosphite stabilized polyolefin compositions subject to solid by-product formation during melt extrusion are improved by the addition of a metal salt of a lactic acid to the composition. The processes involving the improved compositions exhibit reduced levels of screen pack plugging during fiber and film extrusion processes than that achieved with fatty acid salts, such as calcium stearate.
摘要翻译：通过向组合物中加入乳酸金属盐，可以改善在熔融挤出过程中经受固体副产物形成的亚磷酸酯稳定的聚烯烃组合物的熔融挤出方法。涉及改进的组合物的方法在纤维和膜挤出过程中显示出比用脂肪酸盐（例如硬脂酸钙）实现的屏幕包装堵塞水平降低的程度。

53. 发明授权

US6013742A Process for producing improved random propylene copolymers 失效
标题翻译：制备改进的无规丙烯共聚物的方法
公开(公告)号：US6013742A
公开(公告)日：2000-01-11
申请号：US969278
申请日：1997-11-13
申请人： Stephan Huffer , Meinolf Kersting , Franz Langhauser , Rainer Alexander Werner , Patrik Muller , Jurgen Kerth
发明人： Stephan Huffer , Meinolf Kersting , Franz Langhauser , Rainer Alexander Werner , Patrik Muller , Jurgen Kerth
IPC分类号： C08F4/658 , C08F4/02 , C08F4/64 , C08F4/654 , C08F210/06 , C08F210/16 , D01F6/06 , C08F4/18
CPC分类号： C08F210/16 , C08F210/06
摘要： A process for preparing random propylene copolymers containing copolymerized C.sub.2 -C.sub.10 -alk-1-enes by polymerization of propylene and C.sub.2 -C.sub.10 -alk-1-enes in the presence of a Ziegler-Natta catalyst system comprising a titanium-containing solid component a) comprising a compound of magnesium, a halogen, silica gel as support and a carboxylic ester as electron donor compound, and also, as cocatalysts, an aluminum compound b) and a further electron donor compound c), where propylene and the C.sub.2 -C.sub.10 -alk-1-enes are polymerized with one another at from 50 to 100.degree. C. at pressures in the range from 15 to 40 bar and mean residence times of from 0.5 to 5 hours and the support used in the titanium-containing solid component is a silica gel which has a mean particle diameter of from 5 to 200 .mu.m, a mean particle diameter of the primary particles of from 1 to 10 .mu.m and voids or channels having a mean diameter of from 1 to 10 .mu.m, which voids or channels have a macroscopic proportion by volume based on the total particle in the range from 5 to 20%.
摘要翻译：在含有含钛固体组分a的齐格勒 - 纳塔催化剂体系存在下，通过丙烯和C 2 -C 10 - 烷-1-烯的聚合制备含共聚的C 2 -C 10 - 烷-1-烯的无规丙烯共聚物的方法），其包含镁，卤素，硅胶作为载体的化合物和作为电子给体化合物的羧酸酯，以及作为助催化剂的铝化合物b）和另外的电子给体化合物c），其中丙烯和C 2 -C 10 α-烷-1-烯在50至100℃下以15至40巴的压力和0.5至5小时的平均停留时间彼此聚合，并且在含钛固体组分中使用的载体是平均粒径为5〜200μm，一次粒子的平均粒径为1〜10μm，平均粒径为1〜10μm的通道的硅胶，其中，空隙或通道具有基于体积的宏观比例总颗粒在5至20％的范围内。

54. 发明授权

US5985196A Flash spinning process and flash spinning solution 失效
标题翻译：闪纺工艺和闪纺解决方案
公开(公告)号：US5985196A
公开(公告)日：1999-11-16
申请号：US9292
申请日：1998-01-20
申请人： Hyunkook Shin , Roger Keith Siemionko
发明人： Hyunkook Shin , Roger Keith Siemionko
IPC分类号： D01D5/11 , D01F6/04 , D01F6/06 , D01F6/30 , D01F6/32
CPC分类号： D01F6/32 , D01D5/11 , D01F6/04 , D01F6/06 , D01F6/30
摘要： A process for producing plexifilamentary products by spinning from a spin fluid of a polyolefin dissolved in a primary spin agent selected from the group consisting of 1,1,2-trichloro-2,2-difluoroethane and isomers thereof; 1,1,3-trichloro-2,2,3,3-tetrafluoropropane and isomers thereof; 1,2-dichloro-3,3,3-trifluoropropane and isomers thereof; and 1,2-dichloro-l-fluoroethylene; and a co-spin agent; and also a spin fluid of a polyolefin dissolved in a primary spin agent selected from the group consisting of 1,1,2-trichloro-2,2-difluoroethane and isomers thereof; 1,1,3-trichloro-2,2,3,3-tetrafluoropropane and isomers thereof; 1,2-dichloro-3,3,3-trifluoropropane and isomers thereof; and 1,2-dichloro-1-fluoroethylene; and a co-spin agent.
摘要翻译：通过从溶解在选自1,1,2-三氯-2,2-二氟乙烷及其异构体的初级旋转剂中的聚烯烃的旋转流体纺丝来生产有色玻璃纤维产品的方法; 1,1,3-三氯-2,2,3,3-四氟丙烷及其异构体; 1,2-二氯-3,3,3-三氟丙烷及其异构体; 和1,2-二氯-1-氟乙烯; 和共转移剂; 以及溶解在选自1,1,2-三氯-2,2-二氟乙烷及其异构体的一级旋转剂中的聚烯烃旋转流体; 1,1,3-三氯-2,2,3,3-四氟丙烷及其异构体; 1,2-二氯-3,3,3-三氟丙烷及其异构体; 和1,2-二氯-1-氟乙烯; 和共 - 旋转剂。

55. 发明授权

US5945215A Propylene polymer fibers and yarns 失效
标题翻译：丙烯聚合物纤维和纱线
公开(公告)号：US5945215A
公开(公告)日：1999-08-31
申请号：US927384
申请日：1997-09-12
申请人： Bruce Howard Bersted , Richard Tutt Norris, Jr. , Leonid Slutsker , Ty Jackson Stokes
发明人： Bruce Howard Bersted , Richard Tutt Norris, Jr. , Leonid Slutsker , Ty Jackson Stokes
IPC分类号： D01F6/06 , D02G3/44 , D04H13/00 , D02G3/00
CPC分类号： D02G3/445 , Y10T428/2913 , Y10T428/2969
摘要： Propylene polymer fibers are characterized by a unique crystalline microstructure as determined by small angle X-ray diffraction. The fibers and yarns comprising same exhibit improved recovery from compression and bending and are suited for a wide range of applications including geotextile, apparel and upholstery fabrics, carpet yarns and other textile products.
摘要翻译：丙烯聚合物纤维的特征在于通过小角度X射线衍射测定的独特的结晶微结构。包含它们的纤维和纱线表现出从压缩和弯曲的改善的恢复，并且适用于广泛的应用，包括土工织物，服装和室内装饰织物，地毯纱线和其它纺织品。

56. 发明授权

US5869180A Melt-spun abrasion-resistant monofilaments 失效
标题翻译：熔纺耐磨单丝
公开(公告)号：US5869180A
公开(公告)日：1999-02-09
申请号：US774828
申请日：1996-12-27
申请人： Jurgen Budenbender , Eckhard Gartner
发明人： Jurgen Budenbender , Eckhard Gartner
IPC分类号： A01D34/73 , D01F1/10 , D01F6/06 , D01F6/46 , D01F6/60 , D01F6/62 , D01F6/90 , D01F6/92 , D21F1/00 , D21F7/08 , D02G3/00 , B26D1/00 , D32B7/00
CPC分类号： D21F1/0027 , D01F6/46 , D01F6/90 , D01F6/92 , Y10S162/90 , Y10T428/2913 , Y10T428/2929 , Y10T428/2931 , Y10T428/2969 , Y10T442/20 , Y10T442/444 , Y10T442/602 , Y10T442/637 , Y10T83/9292
摘要： The invention relates to melt-spun monofilaments of polyamide, polyester or polypropylene as filament-forming polymers with improved abrasion resistance and their use for producing technical materials or use as wire.
摘要翻译：本发明涉及聚酰胺，聚酯或聚丙烯的熔纺单丝，作为具有改善耐磨性的长丝形成聚合物及其用于生产技术材料或用作线材的用途。

57. 发明授权

US5849231A Melt extrusion process 失效
标题翻译：熔融挤出工艺
公开(公告)号：US5849231A
公开(公告)日：1998-12-15
申请号：US38400
申请日：1993-03-29
申请人： William P. Enlow
发明人： William P. Enlow
IPC分类号： B29C47/00 , B29C47/68 , B29K23/00 , B29L7/00 , B29L31/00 , C08J5/00 , C08J5/18 , C08K5/1515 , C08L23/00 , D01D1/10 , D01F1/10 , D01F6/04 , D01F6/06 , D01F6/46
CPC分类号： C08J5/18 , D01D1/10 , D01F1/10 , D01F6/04 , D01F6/06 , C08J2323/02
摘要： Melt extrusion processes involving phosphite stabilized polyolefin compositions subject to solid by-product formation during melt extrusion are improved by the addition of an epoxidized ester of a fatty acid to the composition. The processes involving the improved compositions exhibit reduced levels of screen pack plugging during fiber and film extrusion processes than that achieved with fatty acid salts, such as calcium stearate.
摘要翻译：通过向组合物中加入脂肪酸的环氧化酯，可改进涉及在熔融挤出过程中受固体副产物形成的亚磷酸酯稳定的聚烯烃组合物的熔融挤出方法。涉及改进的组合物的方法在纤维和膜挤出过程中显示出比用脂肪酸盐（例如硬脂酸钙）实现的屏幕包装堵塞水平降低的程度。

58. 发明授权

US5846654A High tenacity, high elongation polypropylene fibers, their manufacture, and use 失效
标题翻译：高强度，高伸长率的聚丙烯纤维，其制造和使用
公开(公告)号：US5846654A
公开(公告)日：1998-12-08
申请号：US652717
申请日：1996-05-30
申请人： James P. Modrak
发明人： James P. Modrak
IPC分类号： D01F6/06 , D01F6/30 , D02G3/00
CPC分类号： D01F6/06 , D01F6/30 , Y10T428/2916 , Y10T428/2967
摘要： Spinning polypropylene at relatively high temperatures with delayed quenching, and drawing at relatively high temperatures with moderate draw ratios, provides fibers having an improved tensile factor, especially improved elongation, and can be used to produce fibers also having a high tenacity. The fibers are particularly useful for reinforcement applications when provided in the form of staple fibers and exhibit a tensile factor TE.sup.0.50 of at least about 60, where T is tenacity (gpd) and E is elongation (percent), especially those having a tenacity of at least about 8 gpd and/or an elongation of at least about 25%, and most especially those having a tenacity of at least about 10 gpd and elongations of 50% to 400%.
摘要翻译：在相对较高的温度下用延迟淬火纺丝聚丙烯，并在相当高的温度下以适中的拉伸比进行拉伸，提供具有改进的拉伸系数，特别是改进的伸长率的纤维，并且可以用于生产也具有高强度的纤维。当以短纤维形式提供时，纤维特别可用于增强应用，并且表现出至少约60的拉伸系数TE0.50，其中T是韧度（gpd），E是伸长率（百分比），特别是具有韧性的那些至少约8gpd和/或至少约25％的伸长率，最特别是具有至少约10gpd的韧度和50％至400％的伸长率的那些。

59. 发明授权

US5804625A Fluorochemical and hydrocarbon surfactant blends as hydrophilic additives to thermoplastic polymers 失效
标题翻译：氟化合物和烃表面活性剂共混物作为热塑性聚合物的亲水性添加剂
公开(公告)号：US5804625A
公开(公告)日：1998-09-08
申请号：US646791
申请日：1996-05-21
申请人： John A. Temperante , Thomas P. Klun , Alton J. Gasper
发明人： John A. Temperante , Thomas P. Klun , Alton J. Gasper
IPC分类号： A61F13/511 , A61F13/49 , A61L15/24 , B32B5/02 , C08J5/18 , D01F1/10 , D01F6/04 , D01F6/06 , D01F6/46 , D01F6/60 , D01F6/62 , D01F6/70 , D04H1/42 , C08K5/54 , C08K5/20 , C08K5/36 , C08K5/48
CPC分类号： D01F6/70 , A61L15/24 , C08J5/18 , D01F1/10 , D01F6/04 , D01F6/06 , D01F6/60 , D01F6/62 , D04H1/4291 , D04H1/4334 , D04H1/435 , D04H1/4358 , D04H1/4382
摘要： This invention provides durably hydrophilic, thermoplastic fiber comprising a thermoplastic polymer, such as polyamide, polyurethane, or polyolefin, e.g., polypropylene, and a mixture of: (a) one or more fluoroaliphatic group-containing nonionic surfactants and (b) one or more nonionic, non-fluorinated, polyoxyethylene group-containing surfactants that contain between 20 and 80 weight percent polyoxyethylene. The mixture of the surfactants (a) and (b) is present in the fiber in an amount sufficient to impart durable hydrophilicity to the fiber at its surface. Durably hydrophilic films and durably hydrophilic fabrics and webs constructed from said fibers are also disclosed.
摘要翻译：本发明提供了包含热塑性聚合物如聚酰胺，聚氨酯或聚烯烃（例如聚丙烯）的耐久亲水性热塑性纤维，和（a）一种或多种含氟脂族基团的非离子表面活性剂和（b）一种或多种含有20至80重量％聚氧乙烯的非离子，非氟化的含聚氧乙烯基团的表面活性剂。表面活性剂（a）和（b）的混合物以足以赋予纤维在其表面上持久的亲水性的量存在于纤维中。还公开了由所述纤维构成的耐久亲水性膜和耐久亲水织物和纤维网。

60. 发明授权

US5804304A Radiation visbroken polypropylene and fibers made therefrom 失效
标题翻译：辐射减粘聚丙烯和由其制成的纤维
公开(公告)号：US5804304A
公开(公告)日：1998-09-08
申请号：US908761
申请日：1997-08-08
申请人： Stephen D. Williams , Hee Ju Yoo
发明人： Stephen D. Williams , Hee Ju Yoo
IPC分类号： C08J3/28 , B29C45/00 , C08F8/00 , C08F8/50 , C08F10/06 , C08F110/06 , C08F210/06 , C08J5/18 , C08L23/10 , D01F6/06 , D04H1/4291 , D04H1/56 , D04H3/007 , D02G3/00 , C08F6/00
CPC分类号： D01F6/06 , C08F10/06 , C08F8/50 , C08J3/28 , C08L23/0815 , C08L23/142 , D04H1/4291 , D04H1/56 , D04H3/007 , C08F110/06 , C08F210/06 , C08J2323/10 , Y10T428/2913 , Y10T428/2967 , Y10T442/60 , Y10T442/68 , Y10T442/696
摘要： A propylene homopolymer having a stick-point of 30 cm or less during melt spinning, an oligomer content of less than 1500 ppm without postpolymerization treatment to remove oligomers, and a melt flow rate greater than 300 dg/min is prepared by radiation visbreaking in a multistage fluidized bed reactor. The polymer is subjected to irradiation in the substantial absence of oxygen, followed by a multistage treatment in the presence of a controlled amount of oxygen. The radiation visbreaking process can also be applied to other propylene polymer materials. The propylene polymer materials produced by this radiation visbreaking process can be used, for example, for extrusion coating, film production, and injection molding.
摘要翻译：在熔融纺丝期间具有30cm或更小的粘点的丙烯均聚物，低于1500ppm的低聚物含量，而不进行后聚合处理以除去低聚物，并且熔体流动速率大于300dg / min，通过辐射减粘裂化多级流化床反应器。在基本不存在氧的情况下对聚合物进行照射，然后在受控量的氧的存在下进行多级处理。辐射减粘裂化工艺也可应用于其他丙烯聚合物材料。通过该辐射减粘裂化方法制造的丙烯聚合物材料可用于例如挤出涂布，膜生产和注射成型。

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