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    • 61. 发明授权
    • Light-sensitive copying material and method for the production of
colored relief images
    • 感光复印材料和生产彩色浮雕图像的方法
    • US4144067A
    • 1979-03-13
    • US826738
    • 1977-08-22
    • Hans RuckertRainer Unholz
    • Hans RuckertRainer Unholz
    • G03F7/016G03F3/10G03F7/021G03F7/038G03C5/00G03C1/52G03C1/68G03C11/00
    • G03F3/10G03F7/0215
    • This invention relates to an improvement in a light-sensitive copying material, the copying layer of which comprises a water-soluble, curable binder and a diazonium salt polycondensation product of recurring units of the general types (A-N.sub.2 X) and (B) which are linked to one another by intermediate members which have two bonds and are derived from a carbonyl compound capable of undergoing a condensation reaction, wherein A is the radical of a compound which contains at least two isocyclic or heterocyclic aromatic rings and is able to undergo a condensation reaction, at least at one point in the molecule, with formaldehyde in an acid medium, B is the radical of a compound which is free of diazonium groups and is able to undergo a condensation reaction, at least at one point in the molecule, with formaldehyde in an acid medium, and X is the anion of an acid which forms a water-soluble salt with the condensation product, the improvement being that fish glue is the water-soluble, curable binder. The invention also relates to a process for the production of colored relief images.
    • 本发明涉及一种光敏复印材料的改进,其复印层包括水溶性可固化粘合剂和一般类型(A-N2X)和(B)的重复单元的重氮盐缩聚产物,其中 通过具有两个键并由能够进行缩合反应的羰基化合物衍生的中间成员彼此连接,其中A是含有至少两个环状或杂环芳族环的化合物的基团,并且能够经历 在酸性介质中至少在分子中的一个位置上与甲醛进行缩合反应,B是不含重氮基团且能够进行缩合反应的化合物的基团,至少在分子中的一个点处, 在酸性介质中具有甲醛,X是与缩合产物形成水溶性盐的酸的阴离子,改进之处在于,鱼胶是水溶性的,可固化的 恩德 本发明还涉及生产彩色浮雕图像的方法。
    • 63. 发明授权
    • Copolymer of glycidyl methacrylate and allyl glycidyl ether
    • 甲基丙烯酸缩水甘油酯和烯丙基缩水甘油醚的共聚物
    • US4071671A
    • 1978-01-31
    • US697654
    • 1976-06-18
    • Sheldon I. SchlesingerVeronica Cochran
    • Sheldon I. SchlesingerVeronica Cochran
    • C08F216/14C08F220/32G03F7/021G03F7/038
    • C08F220/32C08F216/1416G03F7/0217G03F7/038Y10T428/31855
    • Copolymers of glycidyl methacrylate and allyl glycidyl ether having pendant epoxy groups, having an inherent viscosity of at least about 0.25, preferably within the range of about 0.25 to about 0.38, and an epoxy equivalent of at least about 0.65 epoxide equivalent per 100g. of polymer are provided which upon admixture with a radiation-sensitive aryldiazonium salt provide compositions which exhibit improved sensitivity, curing rates and other properties. Articles for recording and storing information from a laser source and other articles such as microfilm are derived from such compositions by subjecting a coated substrate to an energy source of sufficient intensity to decompose the radiation-sensitive catalyst and thus effect polymerization via the epoxy groups of the copolymer.
    • 具有侧链环氧基的缩水甘油基甲基丙烯酸酯和烯丙基缩水甘油醚的共聚物,其特性粘度为至少约0.25,优选在约0.25至约0.38的范围内,环氧当量为至少约0.65环氧当量/ 100g。 的聚合物,其与辐射敏感的芳基重氮盐混合,提供显示出提高的灵敏度,固化速率和其它性质的组合物。 用于记录和存储来自激光源和诸如微缩胶片的其它制品的信息的制品是通过将涂覆的基材经受足够强度的能量源来分解辐射敏感催化剂,从而通过经由 共聚物。
    • 64. 发明授权
    • Diazo resin composition with phosphor pigments and process for the manufacture of a screen for cathode ray tubes
    • 具有磷光体颜料的重氮树脂组合物和用于制造阴极射线管屏幕的方法
    • US3915707A
    • 1975-10-28
    • US41826673
    • 1973-11-23
    • HOECHST AG
    • GESSWEIN EBERHARDMOLLER WERNERRUCKERT HANS
    • C09K11/02C09D5/22G03F7/021H01J29/20H01J29/22G03C5/18G03C1/54
    • G03F7/021H01J29/225Y10S430/11Y10S430/127
    • This invention relates to a light-sensitive copying composition for the manufacture of screens for cathode ray tubes, comprising a dispersion of a phosphor pigment in an aqueous solution of a hydrophilic cross-linkable binder and a sensitizer, the sensitizer being a condensation product of an aromatic diazonium compound containing recurrent units of the general types A-N2X and B, which are connected by methylene groups, said units A-N2X being derived from compounds of the general formula (R1-R3)pR2N2X wherein X is the anion of an aliphatic monosulfonic acid with one to six carbon atoms, P IS AN INTEGER FROM 1 TO 3, R1 is a carbocyclic or heterocyclic aromatic group, having at least one condensable position, R2 is an arylene group of the benzene or naphthalene series, R3 is either a single bond or one of the following groups: -(CH2)q-NR4-(CH2)q-NR4-(CH2)r-NR5-O-(CH2)r-NR4-S-(CH2)r-NR4-O-R6-O-O-S-CO -NR4-SO2-NR4wherein Q IS AN INTEGER FROM 0 TO 5, R IS AN INTEGER FROM 2 TO 5, R4 is either hydrogen, or an alkyl group with one to five carbon atoms, or an aralkyl group with seven to 12 carbon atoms, or an aryl group with six to 12 carbon atoms, R5 is hydrogen or an alkyl group with one to five carbon atoms, and R6 is an arylene group with six to 12 carbon atoms AND SAID UNITS B being radicals, free of diazonium groups, of the following compounds: aromatic amines, phenols, thiophenols, phenol ethers, aromatic thioethers, aromatic hydrocarbons, aromatic heterocyclic compounds, or organic acid amides. The invention also includes a process for the manufacture of a screen for a cathode ray tube employing the novel light-sensitive composition.
    • 本发明涉及一种用于制造阴极射线管屏幕的光敏复印组合物,其包括在亲水性可交联粘合剂和敏化剂的水溶液中的荧光颜料的分散体,所述敏化剂是 芳族重氮化合物,其含有通过亚甲基连接的一般类型A-N2X和B的复发单元,所述单元A-N2X衍生自通式(R1-R3)pR2-N2X的化合物,其中X为 具有1至6个碳原子的脂肪族单磺酸,P 1为1至3的整数,R 1为具有至少一个可缩合位置的碳环或杂环芳族基团,R 2为苯或萘系列的亚芳基,R 3为 单键或以下组之一:
    • 65. 发明授权
    • Polymeric n-carbonyl sulfonamides in photopolymerizable compositions and process for preparation
    • 可聚合的组合物中的聚合的N-羰基磺酰胺和制备方法
    • US3725356A
    • 1973-04-03
    • US3725356D
    • 1971-06-02
    • KALLE AG
    • KLUPFEL KLUDERS WSTEPPAN H
    • C08F28/00G03C1/76G03F7/021G03F7/032C08G22/02C08G22/04G03C1/70
    • G03F7/032C08F28/00G03C1/76G03F7/021Y10S430/107
    • This invention relates to novel polymers and to a method of producing the same. The polymers are of reduced specific viscosity between 0.05 and 3.0, preferably between 0.2 and 1.0 dl/g., measured at 25* C. using a 1 percent solution in dioxane, contain substituted N-carbonyl sulfonyl groups in their side chains, and are composed of statistically distributed recurrent structural units OF Formula I'' and/or Formula II'' and/or Formula III'' wherein R is a saturated aliphatic alkyl or alkoxy group each with one to six carbon atoms which may be substituted by one to three halogen atoms, or a cycloaliphatic alkyl group, or an aryl or aryloxy group each with six or 10 carbon atoms which may be substituted up to 3 times by halogen atoms and/or alkyl or alkoxy groups with one to six carbon atoms, R'' is a hydrogen atom or a methyl group, X is an oxygen atom or an imino group, A is a phenylene group or an alkylene group with one to four carbon atoms, N IS AN INTEGER FROM 1 TO 4, AND M IS 1, OR MAY BE 0 WHEN X is an imino group, AND WHICH MAY FURTHER COMPRISE, IN A STATISTICAL DISTRIBUTION, RECURRENT STRUCTURAL UNITS OF THE TYPE WHEREIN A. R1 is a hydrogen atom or a methyl group, R2 is a hydrogen atom, and R3 is a nitrile group, a phenyl group, an amino-carboxyl group, an alkyl carboxyl group with two to 12 carbon atoms, or an acyloxy group with two to 12 carbon atoms, or B. R1 is an alkyl carboxymethyl group with three to 13 carbon atoms, R2 is a hydrogen atom, and R3 is an alkyl carboxyl group with two to 12 carbon atoms, or C. R1 is a hydrogen atom, and R2 and R3 are both alkyl carboxyl groups with two to 12 carbon atoms.
    • 本发明涉及新颖的聚合物及其制备方法。 聚合物的比粘度在0.05至3.0之间,优选在0.2至1.0dl / g之间,在25℃下使用1%的二恶烷溶液测量,其侧链中含有取代的N-羰基磺酰基,并且分别为 由式I'和/或式II'和/或式III'的统计分布的复发结构单元组成,其中R是可以被一至三个卤素原子取代的具有一至六个碳原子的饱和脂族烷基或烷氧基 ,或脂环族烷基,或每个具有六个或十个碳原子的芳基或芳氧基,其可被卤素原子和/或具有1-6个碳原子的烷基或烷氧基取代至多3次,R'是氢 原子或甲基,X是氧原子或亚氨基,A是亚苯基或具有1-4个碳原子的亚烷基,N是1到4的整数,M是1或可以是0 当X是亚胺基时,可以进一步包含在统计学中 分布,类型的回收结构单元A. R1是氢原子或甲基,R2是氢原子,R3是腈基,苯基,氨基 - 羧基,烷基羧基与两个 至12个碳原子或具有2至12个碳原子的酰氧基,或B.R 1是具有3至13个碳原子的烷基羧甲基,R2是氢原子,R3是具有2至12个碳原子的烷基羧基 原子或C.R1是氢原子,R2和R3都是具有2至12个碳原子的烷基羧基。