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81. 发明申请

US20150136691A1 METHOD FOR PREPARING DOUBLE LAYERED POROUS HOLLOW MEMBRANE AND DEVICE AND PRODUCT THEREOF 审中-公开
标题翻译：双层多孔中空膜制备方法及其制备方法
公开(公告)号：US20150136691A1
公开(公告)日：2015-05-21
申请号：US14604678
申请日：2015-01-24
申请人： MEMSTAR (Guangzhou) Co. Ltd
发明人： Xinhao YANG , Hailin GE
IPC分类号： B01D69/08 , B01D69/12
CPC分类号： B01D69/08 , B01D69/02 , B01D69/088 , B01D2325/02 , B01D2325/04 , B01D2325/24
摘要： A method for preparing a double layered porous hollow fiber membrane and the device and product thereof. The method comprises preparing uncured porous hollow fiber with larger pore diameters as the inner robust supporter of the membrane from thermoplastic polymeric resins by thermal induced phase separation (TIPS) method and then binding an ultra thin coating layer with hydrophilic microfiltration or ultrafiltration function and fine pore diameters prepared on the outer surface of the robust hollow fibers from a solution of the thermoplastic polymeric resins by a coating process using non-solvent induced phase separation (NIPS) method. The double layered porous hollow fiber membranes have such excellent mechanical strength and high water permeation as the membranes prepared by thermal induced phase separation (TIPS) method, such high accurate filtration effect, high hydrophilic effect and high fouling resistance as the membranes prepared by non-solvent induced phase separation (NIPS) method, and high binding force of the membranes between the layers by the above method.
摘要翻译：一种双层多孔中空纤维膜的制备方法及其装置及其制造方法。该方法包括通过热诱导相分离（TIPS）方法从热塑性聚合物树脂制备具有较大孔径的未固化多孔中空纤维作为膜的内部坚固支撑物，然后将超薄涂层与亲水微滤或超滤功能和细孔结合通过使用非溶剂诱导相分离（NIPS）方法的涂覆方法，从热塑性聚合物树脂的溶液在稳固的中空纤维的外表面上制备的直径。双层多孔中空纤维膜具有通过热诱导相分离（TIPS）方法制备的膜具有优异的机械强度和高的透水性，如由非线性制备的膜制备的高精度过滤效果，高亲水效果和高耐污性，溶剂诱导相分离（NIPS）方法，并通过上述方法在层之间的膜的高结合力。

82. 发明申请

US20150096934A1 Preparation method of homogeneous-reinforced PVDF hollow fiber membrane 审中-公开
标题翻译：均质增强PVDF中空纤维膜的制备方法
公开(公告)号：US20150096934A1
公开(公告)日：2015-04-09
申请号：US14381213
申请日：2013-01-24
申请人： TIANJIN POLYTECHNIC UNIVERSITY
发明人： Changfa Xiao , Xuliang Zhang , Xiaoyu Hu , Shulin An , Qinglin Huang , Guolan Huan
IPC分类号： B01D71/34 , B01D63/02 , B01D67/00 , B01D69/08 , B01D69/12
CPC分类号： B01D71/34 , B01D63/02 , B01D63/021 , B01D67/0013 , B01D67/0016 , B01D67/002 , B01D69/02 , B01D69/08 , B01D69/088 , B01D69/10 , B01D69/12 , B01D2323/00 , B01D2325/40
摘要： A preparation method of a homogeneous-reinforced PVDF hollow fiber membrane includes steps of: a) preparing a reinforced matrix membrane, wherein a PVDF hollow fiber membrane is utilized as the reinforced matrix membrane; b) preparing a PVDF casting solution, wherein mass fractions of the PVDF casting solution are: PVDF 6˜20 wt %; hydrophilic polymers or hydrophilic inorganic particles 0.6˜2 wt %; pore-forming agent 6˜10 wt %; and solvent 68˜87.4 wt %; mixing the above solutes in a water bath with a temperature of 70˜90° C., dissolving for 3˜4 h with stirring, then deaerating under vacuum for obtaining the uniform PVDF casting solution; and c) preparing the homogeneous-reinforced membrane; wherein the PVDF casting solution is uniformly coated on an outer surface of the reinforced matrix membrane through a spinning spinneret, then the reinforced matrix membrane is towed by a filament guide roller in such a manner that the hollow fiber forms a membrane, then the membrane passes through an air gap with a length of 5˜20 cm and is immersed in ultrafiltered water for coagulation, in such a manner that the homogeneous-reinforced membrane is obtained; wherein a traction speed is 5˜25 cm/(r·min).
摘要翻译：均质增强PVDF中空纤维膜的制备方法包括以下步骤：a）制备增强基质膜，其中使用PVDF中空纤维膜作为增强基质膜; b）制备PVDF浇注溶液，其中PVDF浇铸溶液的质量分数为：PVDF 6〜20wt％; 亲水性聚合物或亲水性无机颗粒0.6〜2重量％成孔剂6〜10重量％和溶剂68〜87.4wt％; 将上述溶质混合在温度为70〜90℃的水浴中，搅拌溶解3〜4h，然后真空脱气，得到均匀的PVDF浇铸溶液; 和c）制备均质增强膜; 其中通过纺丝喷丝头将PVDF铸塑溶液均匀地涂覆在增强基体膜的外表面上，然后用丝导引辊牵引加强基体膜，使得中空纤维形成膜，然后膜通过通过长度为5〜20cm的气隙，浸渍在超滤水中进行凝固，得到均质增强膜; 牵引速度为5〜25cm /（r·min）。

83. 发明申请

US20150053611A1 HYDROPHOBIC ORGANIC-INORGANIC COMPOSITE HOLLOW FIBER MEMBRANE AND METHOD OF FORMING THE SAME 审中-公开
标题翻译：疏水有机无机复合中空纤维膜及其形成方法
公开(公告)号：US20150053611A1
公开(公告)日：2015-02-26
申请号：US14467910
申请日：2014-08-25
申请人： Nanyang Technological University
发明人： Rong Wang , Yuan Zhang
IPC分类号： B01D71/64 , B01D69/08
CPC分类号： B01D71/64 , B01D61/364 , B01D67/0079 , B01D67/0093 , B01D69/02 , B01D69/088 , B01D69/125 , B01D69/148 , B01D71/025 , B01D71/027 , B01D71/34 , B01D2323/36 , B01D2325/38
摘要： The invention relates to hydrophobic hollow fiber membranes, and in particular, to hydrophobic organic-inorganic composite hollow fiber membranes. Methods for forming the hydrophobic organic-inorganic composite hollow fiber membranes are also disclosed. The hydrophobic organic-inorganic composite hollow fiber membranes may be used in membrane contactor applications such as gas-liquid (G-L) contactor and liquid-liquid (L-L) contactor processes. Applications for G-L membrane contactors include gas streams purification (gas absorption), water ozonation, and water deoxygenation. Applications for L-L membrane contactors include direct contact membrane distillation and liquid-liquid extraction.
摘要翻译：本发明涉及疏水性中空纤维膜，特别涉及疏水性有机 - 无机复合中空纤维膜。还公开了形成疏水性有机 - 无机复合中空纤维膜的方法。疏水性有机 - 无机复合中空纤维膜可用于气液（G-L）接触器和液 - 液（L-L）接触器工艺等膜接触器应用。 G-L膜接触器的应用包括气流净化（气体吸收），水臭氧化和水脱氧。 L-L膜接触器的应用包括直接接触膜蒸馏和液 - 液萃取。

84. 发明申请

US20150020685A1 HOLLOW FIBER MEMBRANES AND METHODS FOR FORMING SAME 有权
标题翻译：中空纤维膜及其形成方法
公开(公告)号：US20150020685A1
公开(公告)日：2015-01-22
申请号：US13945459
申请日：2013-07-18
申请人： GENERAL ELECTRIC COMPANY
发明人： Dhaval Ajit BHANDARI , Patrick Joseph MCCLOSKEY , Paul Edward HOWSON , Kristi Jean NARANG , William KOROS
IPC分类号： B01D71/70 , B01D69/08 , B01D67/00 , B29D23/00 , B01D53/22
CPC分类号： B01D71/70 , B01D53/228 , B01D69/088 , B01D69/12 , B01D69/148 , B01D71/024 , B01D71/027 , B01D71/16 , B01D71/44 , B01D71/68 , B01D2257/102 , B01D2257/504 , B29D23/00 , B29D23/001 , Y02C10/10
摘要： The invention provides improved hollow fiber membranes having at least two layers, and methods for forming the same. The methods include co-extruding a first composition, a second composition, and a third composition to form a dual layer hollow fiber membrane. The first composition includes a glassy polymer; the second composition includes a polysiloxane; and the third composition includes a bore fluid. The dual layer hollow fiber membranes include a first layer and a second layer, the first layer being a porous layer which includes the glassy polymer of the first composition, and the second layer being a polysiloxane layer which includes the polysiloxane of the second composition.
摘要翻译：本发明提供了具有至少两层的改进的中空纤维膜及其形成方法。所述方法包括共挤出第一组合物，第二组合物和第三组合物以形成双层中空纤维膜。第一组合物包括玻璃状聚合物; 第二组合物包括聚硅氧烷; 并且第三组合物包括孔流体。双层中空纤维膜包括第一层和第二层，第一层是包含第一组合物的玻璃状聚合物的多孔层，第二层是包含第二组合物的聚硅氧烷的聚硅氧烷层。

85. 发明授权

US08883066B2 Porous membrane, process for producing porous membrane, process for producing clarified liquid, and porous-membrane module 有权
标题翻译：多孔膜，多孔膜的制造方法，澄清液的制造方法以及多孔膜组件
公开(公告)号：US08883066B2
公开(公告)日：2014-11-11
申请号：US13936835
申请日：2013-07-08
申请人： Asahi Kasei Chemicals Corporation
发明人： Satoshi Shiki
IPC分类号： B01D69/08 , C12H1/07 , B01D71/68 , B01D69/02 , B01D61/14 , C02F1/44
CPC分类号： B01D69/02 , B01D61/145 , B01D69/087 , B01D69/088 , B01D71/68 , B01D2325/34 , B01D2325/36 , B01D2325/38 , C02F1/444 , C12H1/063
摘要： A porous membrane with the membrane wall constructed of a hydrophobic polymer and a hydrophilic polymer, wherein when the membrane wall is divided into 3 sections in the film thickness direction to form region “a” containing one wall surface A of the membrane wall, region “c” containing the other wall surface C and region “b” between region “a” and region “c”, the hydrophilic polymer content ratio Ca in region “a” is greater than the hydrophilic polymer content ratio Cc in region “c”, and the mean pore size of the wall surface C is larger than the mean pore size of the wall surface A.
摘要翻译：一种具有由疏水性聚合物和亲水性聚合物构成的膜壁的多孔膜，其中，当所述膜壁在膜厚度方向上分为3个部分以形成包含所述膜壁的一个壁面A的区域“a”时， c“，区域”a“和区域”c“之间的另一个壁表面C和区域”b“，区域”a“中的亲水性聚合物含量比Ca大于区域”c“中的亲水性聚合物含量比Cc，壁面C的平均孔径大于壁面A的平均孔径。

86. 发明授权

US08771516B2 Membranes having improved performance 有权
标题翻译：具有改进性能的膜
公开(公告)号：US08771516B2
公开(公告)日：2014-07-08
申请号：US13320699
申请日：2010-05-19
申请人： Bernd Krause , Carina Zweigart , Heinrich Behr
发明人： Bernd Krause , Carina Zweigart , Heinrich Behr
IPC分类号： A61M1/18 , A61M1/34 , B01D61/24 , B01D71/68 , B01D71/42 , B01D71/56 , B01D69/08 , B29C47/08
CPC分类号： B01D69/088 , A61M1/16 , A61M1/34 , A61M1/3403 , A61M1/341 , A61M1/3413 , A61M1/3496 , A61M2205/15 , B01D71/56 , B01D71/68
摘要： Permselective asymmetric membranes suitable e.g. for hemodialysis, hemodiafiltration and hemofiltration of blood, and having improved performance, including improved sieving characteristics, providing enhanced removal of middle molecular weight substances, e.g. inflammatory mediators having a molecular weight between 20 and 40 kDa. The improved sieving characteristics are due to a narrow pore size distribution of the membranes created in the production process. Processes for the preparation of these membranes, devices comprising these membranes, and the use of these membranes in hemodialysis, hemodiafiltration and hemofiltration of blood, as well as in bioprocessing, plasma fractionation and the preparation of protein solutions.
摘要翻译：选择性不对称膜适合于例如用于血液透析，血液透析过滤和血液的血液滤过，并且具有改善的性能，包括改善的筛分特性，提供中等分子量物质的增强的去除。具有20至40kDa分子量的炎性介质。改进的筛分特性是由于在生产过程中产生的膜的孔径分布窄。用于制备这些膜的方法，包括这些膜的装置以及这些膜在血液透析，血液透析滤过和血液血液滤过以及生物处理，血浆分离和蛋白质溶液的制备中的用途。

87. 发明申请

US20140166571A1 Hollow Fibers Having A Winding Channel 有权
标题翻译：具有绕组通道的空心纤维
公开(公告)号：US20140166571A1
公开(公告)日：2014-06-19
申请号：US13719945
申请日：2012-12-19
申请人： INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE (ITRI)
发明人： Chin-Chih Tai
IPC分类号： B01D69/08
CPC分类号： B01D69/082 , B01D69/085 , B01D69/087 , B01D69/088 , B01D69/148 , B01D2323/42 , B01D2325/12 , D01D5/24
摘要： A hollow fiber for adsorption or filtration. The hollow fiber contains a tubular matrix having a first end and a second end, and a winding channel formed through the tubular matrix and extending between the first end and the second end. The tubular matrix is porous and has a surface-area-to-volume ratio of 10 to 20000 m2/m3, a thickness of 0.05 to 9.95 mm, an outside diameter of 0.1 to 10 mm, and a length 10 to 90% that of the winding channel. Also disclosed is a method of preparing this hollow fiber.
摘要翻译：用于吸附或过滤的中空纤维。中空纤维包含具有第一端和第二端的管状基体，以及通过管状基体形成并在第一端和第二端之间延伸的缠绕通道。管状基质是多孔的，表面积体积比为10〜20000m 2 / m 3，厚度为0.05〜9.95mm，外径为0.1〜10mm，长度为10〜90％绕组通道。还公开了制备该中空纤维的方法。

88. 发明授权

US08747525B2 Composite hollow ceramic fibers, precursors for, methods of making the same, and methods of using the same 有权
标题翻译：复合中空陶瓷纤维，其前体，制造方法及其使用方法
公开(公告)号：US08747525B2
公开(公告)日：2014-06-10
申请号：US13174682
申请日：2011-06-30
申请人： Dean W. Kratzer , Tao Li , Madhava R. Kosuri
发明人： Dean W. Kratzer , Tao Li , Madhava R. Kosuri
IPC分类号： B01D69/08 , B01D53/22 , B01D71/02 , B28B3/20
CPC分类号： B01D67/0041 , B01D53/228 , B01D67/0079 , B01D69/088 , B01D69/12 , B01D71/024 , B01D2323/12 , B01D2323/20 , B82Y30/00 , C01B3/503 , C01B13/0255 , C01B2210/0046 , C04B35/2633 , C04B35/2641 , C04B35/62231 , C04B35/6264 , C04B35/62665 , C04B35/62847 , C04B35/62886 , C04B35/62897 , C04B35/63456 , C04B38/0645 , C04B2235/3213 , C04B2235/3227 , C04B2235/3275 , C04B2235/3286 , C04B2235/5264 , C04B2235/528 , C04B2235/5284 , C04B2235/5409 , C04B2235/5445 , C04B2235/5481 , C04B2235/6021 , C04B2235/6562 , C04B2235/768 , D01D5/24 , D01D5/34 , D01F9/00 , C04B38/0695
摘要： A composite hollow ceramic fiber includes a porous hollow core supporting a thin, dense sheath. The non-gas-tight core comprises a first ceramic compound and an interconnecting network of pores. The gas-tight sheath comprises a second ceramic compound. The fiber is made by extruding first and second suspensions of the first and second ceramic compounds in polymeric binders and solvent from a spinnerette and coagulating the nascent hollow fiber to effect phase inversion of the polymeric binders. The resultant green fiber is sintered in a two step process. First, the binder is burned off. Second, the sheath is densified and the second ceramic compound is sinter without fully sintering the first ceramic compound. The first ceramic compound has a melting point higher than that of the second ceramic compound.
摘要翻译：复合中空陶瓷纤维包括支撑薄而致密护套的多孔中空芯。非气密芯包括第一陶瓷化合物和孔的互连网络。气密护套包括第二陶瓷化合物。纤维通过将第一和第二陶瓷化合物的第一和第二悬浮液从纺丝板中挤出聚合物粘合剂和溶剂并凝结新生中空纤维来实现聚合物粘合剂的相转化而制成。所得绿色纤维以两步法烧结。首先，粘合剂被烧掉。其次，使皮层致密化，第二陶瓷化合物烧结而不完全烧结第一陶瓷化合物。第一陶瓷化合物的熔点高于第二陶瓷化合物。

89. 发明授权

US08741031B2 Hollow ceramic fibers, precursors for manufacture thereof utilizing pore formers, methods of making the same, and methods of using the same 有权
标题翻译：中空陶瓷纤维，使用成孔剂制造的前体，其制造方法及其使用方法
公开(公告)号：US08741031B2
公开(公告)日：2014-06-03
申请号：US13194995
申请日：2011-07-31
申请人： Madhava R. Kosuri , Dean W. Kratzer
发明人： Madhava R. Kosuri , Dean W. Kratzer
IPC分类号： B01D53/22 , B01D69/08 , B01D69/10 , B29C47/06
CPC分类号： B01D53/228 , B01D67/0041 , B01D67/0079 , B01D69/088 , B01D69/12 , B01D71/024 , B01D2323/12 , B01D2323/20 , B82Y30/00 , C01B3/503 , C01B3/505 , C01B13/0255 , C01B2203/025 , C04B35/2633 , C04B35/2641 , C04B35/62231 , C04B35/6225 , C04B35/62259 , C04B35/6263 , C04B35/62847 , C04B35/62897 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3217 , C04B2235/3224 , C04B2235/3227 , C04B2235/3229 , C04B2235/3234 , C04B2235/3255 , C04B2235/3274 , C04B2235/3275 , C04B2235/3286 , C04B2235/5264 , C04B2235/5284 , C04B2235/5436 , C04B2235/5454 , C04B2235/6021 , D01D5/24 , D01D5/34 , D01F9/10 , Y02C10/10
摘要： A composite hollow ceramic fiber includes a porous hollow core supporting a thin, dense sheath. The non-gas-tight core comprises a first ceramic material and an interconnecting network of pores. The gas-tight sheath comprises a second ceramic material. The fiber is made by extruding core and sheath suspensions from a spinnerette. The core suspension includes particles of the first ceramic material, a polymeric binder, a solvent, and a pore former material insoluble in the solvent. The sheath suspension includes particles of the second ceramic material, a polymeric binder and a solvent. The nascent hollow fiber is coagulated in a coagulant bath to effect phase inversion of the polymeric binders. The resultant green fiber is sintered in a two step process. First, the binders and pore former material are burned off. Second, the sheath is densified and the second ceramic material is sintered without fully sintering the core.
摘要翻译：复合中空陶瓷纤维包括支撑薄而致密护套的多孔中空芯。非气密芯包括第一陶瓷材料和孔的互连网络。气密护套包括第二陶瓷材料。纤维通过从纺丝板中挤出芯和护套悬浮液制成。核心悬浮液包括第一陶瓷材料的颗粒，聚合物粘合剂，溶剂和不溶于溶剂的成孔剂材料。护套悬浮液包括第二陶瓷材料的颗粒，聚合物粘合剂和溶剂。新生的中空纤维在凝结浴中凝结，以实现聚合物粘合剂的相转化。所得绿色纤维以两步法烧结。首先，粘合剂和成孔剂材料被烧掉。其次，使密封层密集，并且第二陶瓷材料在不完全烧结芯的情况下进行烧结。

90. 发明申请

US20140047976A1 Cardo-Polybenzoxazole Polymer/Copolymer Membranes For Improved Permeability And Method For Fabricating The Same 审中-公开
标题翻译：聚苯并恶唑聚合物/共聚物膜用于改善渗透性及其制造方法
公开(公告)号：US20140047976A1
公开(公告)日：2014-02-20
申请号：US14113124
申请日：2012-04-27
申请人： Yin Fong Yeong , Huan Wang , Tai-shung Neal Chung
发明人： Yin Fong Yeong , Huan Wang , Tai-shung Neal Chung
IPC分类号： B01D71/64 , B01D53/22
CPC分类号： B01D71/64 , B01D53/228 , B01D67/0009 , B01D67/0083 , B01D69/088 , B01D71/62 , B01D71/76 , B01D2323/22 , B01D2325/20 , B01D2325/22 , B01D2325/24 , C08G73/22
摘要： The present invention discloses a series of cardo-polybenzoxazole copolymer membranes, methods for preparing the cardo-polybenzoxazole copolymer membrane from thermal rearrangement of cardo-copolyimide membranes, and methods of methods for the separation of a fluid from a mixture of fluids by utilizing the cardo-polybenzoxazole copolymer membrane.
摘要翻译：本发明公开了一系列聚 - 聚苯并恶唑共聚物膜，由聚 - 聚酰亚胺膜热重排制备聚 - 聚苯并恶唑共聚物膜的方法，以及通过使用cardo从流体混合物中分离流体的方法 - 聚苯并恶唑共聚物膜。

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