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1. 发明申请

US20160023169A1 HOLLOW FIBER MEMBRANE AND METHOD FOR MANUFACTURING THEREOF 审中-公开
标题翻译：中空纤维膜及其制造方法
公开(公告)号：US20160023169A1
公开(公告)日：2016-01-28
申请号：US14850404
申请日：2015-09-10
申请人： Gambro Lundia AB
发明人： Bernd Krause , Hermann Göhl , Markus Hornung , Carina Zweigart
IPC分类号： B01D71/68 , B01D71/62 , B01D69/08
CPC分类号： B01D71/68 , A61B5/14525 , A61M1/16 , B01D63/02 , B01D69/02 , B01D69/08 , B01D69/087 , B01D71/44 , B01D71/62 , B01D2323/06 , B01D2323/08 , B01D2323/12 , B01D2323/22 , B01D2325/022
摘要： The present invention concerns a semipermeable hollow fiber membrane having an outer wall surface, an inner wall surface and an interior lumen extending along the length thereof and having the selective layer on the outer wall surface with a surface roughness below 10 nm. According to the invention the membrane has the smallest pore size on the outer wall surface, and has an outer wall surface which is smooth, continuous and homogeneous in a nanoscopic scale and four to five distinct layers of different pore size and density. Further the present invention concerns a process for manufacturing thereof and the use thereof.
摘要翻译：本发明涉及一种具有外壁表面，内壁表面和沿其长度延伸的内腔的半透性中空纤维膜，并且在外壁表面上具有表面粗糙度低于10nm的选择层。根据本发明，膜在外壁表面具有最小的孔径，并且具有在纳米尺度上光滑，连续和均匀的外壁表面，以及不同孔径和密度的四至五个不同层。此外，本发明涉及其制造方法及其用途。

2. 发明申请

US20130049246A1 PROCESS FOR PRODUCTION OF POROUS MEMBRANE 有权
标题翻译：生产多孔膜的方法
公开(公告)号：US20130049246A1
公开(公告)日：2013-02-28
申请号：US13261454
申请日：2011-04-05
申请人： Masakazu Minagawa , Masashi Teramachi
发明人： Masakazu Minagawa , Masashi Teramachi
IPC分类号： C08J9/26
CPC分类号： B01D67/0011 , B01D67/003 , B01D69/06 , B01D69/08 , B01D69/10 , B01D71/12 , B01D71/34 , B01D71/40 , B01D71/42 , B01D71/48 , B01D71/56 , B01D71/68 , B01D2323/06 , B01D2323/22 , B01D2325/20 , B01D2325/36 , C08J9/26 , C08J2201/0464 , C08J2327/16
摘要： Disclosed is a process for production of a porous membrane that includes the steps of layering a film-forming dope that contains a polymer (A) that forms a membrane base, a polyvinylpyrrolidone (B) and a solvent (C) into a single layer or two or more layers; immersing the film-forming dope in a solidifying fluid that is a non-solvent with respect to the polymer (A) and is a good solvent with respect to the polyvinylpyrrolidone (B); and removing the polyvinylpyrrolidone (B), wherein the polyvinylpyrrolidone (B) has a K value of 50 to 80, a mass ratio r of the polyvinylpyrrolidone (B) to the polymer (A) is 0.5 or more and less than 1, and the viscosity of the film-forming dope at a membrane production temperature is 100 to 500 Pa·s. Accordingly, by using an appropriate amount of a low-molecular-weight hydrophilic polymer capable of being easily removed, it is possible to produce a porous membrane of a three-dimensional network structure in which macrovoids are suppressed, having high water permeability and superior filtration performance.
摘要翻译：公开了一种生产多孔膜的方法，其包括以下步骤：将含有形成膜基的聚合物（A），聚乙烯吡咯烷酮（B）和溶剂（C））的成膜原液分层成单层或两层或多层; 将成膜原液浸渍在相对于聚合物（A）为非溶剂的凝固液中，相对于聚乙烯吡咯烷酮（B）为良好的溶剂; 除去聚乙烯吡咯烷酮（B），其中聚乙烯吡咯烷酮（B）的K值为50〜80，聚乙烯吡咯烷酮（B）与聚合物（A）的质量比r为0.5以上且小于1，膜生成温度下的成膜原液的粘度为100〜500Pa·s。因此，通过使用能够容易地除去的适量的低分子量亲水性聚合物，可以制造出抑制大孔，具有高透水性和优异过滤性的三维网状结构的多孔膜性能。

3. 发明申请

US20120055867A1 DOPING OF INORGANIC MINERALS TO HYDROPHOBIC MEMBRANE SURFACE 有权
标题翻译：无机矿物掺入到疏水膜表面
公开(公告)号：US20120055867A1
公开(公告)日：2012-03-08
申请号：US13217837
申请日：2011-08-25
申请人： Kaimin Shih , Xiao-Yan Li , Xiao-Mao Wang , Tong Zhang
发明人： Kaimin Shih , Xiao-Yan Li , Xiao-Mao Wang , Tong Zhang
IPC分类号： B01D39/00 , B05D1/12
CPC分类号： B01D67/0079 , B01D67/0016 , B01D67/0051 , B01D69/148 , B01D2323/21 , B01D2323/22
摘要： Disclosed is a membrane surface modification method. The method is applicable to a variety of hydrophobic membranes by doping selected inorganic particles. One act of the method involves the in-situ embedment of the inorganic particles onto the membrane surface by dispersing the particles in a non-solvent bath for polymer precipitation. Further membrane surface modification can be achieved by hydrothermally growing new inorganic phase on the embedded particles. The embedment of particles is for the subsequent phase growth.
摘要翻译：公开了一种膜表面改性方法。该方法通过掺杂选择的无机颗粒适用于各种疏水膜。该方法的一个举措包括通过将颗粒分散在用于聚合物沉淀的非溶剂浴中来将无机颗粒原位包埋在膜表面上。可以通过在嵌入的颗粒上水热生长新的无机相来实现进一步的膜表面改性。颗粒的嵌入是随后的相生长。

4. 发明申请

US20110240550A1 BLOCK COPOLYMER MEMBRANES AND ASSOCIATED METHODS FOR MAKING THE SAME 有权
标题翻译：嵌段共聚物膜及其制备方法
公开(公告)号：US20110240550A1
公开(公告)日：2011-10-06
申请号：US12751824
申请日：2010-03-31
申请人： David Roger Moore , Hongyi Zhou , Matthew Jeremiah Misner , Xiaohui Chen , Lifeng Zhang , Daniel Joseph Brunelle , Minglin Ma
发明人： David Roger Moore , Hongyi Zhou , Matthew Jeremiah Misner , Xiaohui Chen , Lifeng Zhang , Daniel Joseph Brunelle , Minglin Ma
IPC分类号： B01D71/80 , C08L81/06 , B01D69/10
CPC分类号： B01D71/80 , B01D67/0006 , B01D67/0011 , B01D69/10 , B01D71/68 , B01D2323/22 , B01D2325/28 , B01D2325/36 , C08L81/06
摘要： A separation matrix comprises a porous surface layer; and a bulk porous support, wherein both the porous surface layer and the bulk porous support comprising a block copolymer. The block copolymer comprises A-B or A-B-A repeating units, wherein A and B at each occurrence are two different blocks of oligomer, or polymer. A structural unit of block A is derived from one or more atom transfer radical polymerization (ATRP)-active monomer or oligomer and a structural unit of block B is derived from a thermoplastic ATRP-active macro initiator. A poly dispersity index of the block copolymer is at least about 2.
摘要翻译：分离基质包括多孔表面层; 和多孔支撑体，其中多孔表面层和本体多孔载体均包含嵌段共聚物。嵌段共聚物包含A-B或A-B-A重复单元，其中A和B每次出现时是两个不同的低聚物或聚合物嵌段。嵌段A的结构单元衍生自一种或多种原子转移自由基聚合（ATRP）活性单体或低聚物，并且嵌段B的结构单元衍生自热塑性ATRP活性的大分子引发剂。嵌段共聚物的聚分散指数为至少约2。

5. 发明申请

US20110146492A1 AIR SEPARATION MODULE FIBER MATERIAL FORMULATION 审中-公开
标题翻译：空气分离模块纤维材料配方
公开(公告)号：US20110146492A1
公开(公告)日：2011-06-23
申请号：US12641787
申请日：2009-12-18
申请人： MELISSA DOPKINS , ADAM GLEN THOMAS , CHUNQING LIU , REHAN ZAKI
发明人： MELISSA DOPKINS , ADAM GLEN THOMAS , CHUNQING LIU , REHAN ZAKI
IPC分类号： B01D53/22 , B29C47/00 , C08K5/092
CPC分类号： B01D69/087 , B01D67/0011 , B01D71/68 , B01D2323/22 , C08K5/092
摘要： Hollow fiber membranes, such as those used in air separation modules, are generally made from solution spinning. Typically, solvent is present in the bore of the fiber for the spinning process. This solvent, in addition to the solvent already present in the polymer dope solution, may cause voids in the fiber material. By adding citric acid to the polymer dope material, these voids may be reduced or eliminated.
摘要翻译：中空纤维膜，例如用于空气分离模块的那些，通常由溶液纺丝制成。通常，纤维的孔中存在溶剂用于纺丝过程。除了已经存在于聚合物掺杂溶液中的溶剂之外，该溶剂可能导致纤维材料中的空隙。通过向聚合物涂料材料中加入柠檬酸，可以减少或消除这些空隙。

6. 发明申请

US20110072965A1 CARBON MEMBRANES FROM CELLULOSE ESTERS 失效
标题翻译：来自纤维素酯的碳膜
公开(公告)号：US20110072965A1
公开(公告)日：2011-03-31
申请号：US12988709
申请日：2009-04-20
申请人： Jon Arvid Lie , Tone Borge , Edel Sheridan , May-Britt Hagg
发明人： Jon Arvid Lie , Tone Borge , Edel Sheridan , May-Britt Hagg
IPC分类号： B01D53/22 , D01F9/16
CPC分类号： B01D67/0067 , B01D65/08 , B01D69/08 , B01D71/10 , B01D2321/22 , B01D2323/22 , B01D2325/10 , C01B3/503 , C01B7/07 , C01B7/0706 , C01B13/0255 , C01B2203/0405 , C01B2203/0475 , C01B2203/048 , C01B2210/0046 , D01F2/28 , D01F9/16 , D01F11/02
摘要： A process for the production of a carbon hollow fibre membrane comprising: (i) dissolving at least one cellulose ester in a solvent to form a solution; (ii) dry/wet spinning the solution to form hollow fibres; (iii) deesterifying said hollow fibres with a base or an acid in the presence of an alcohol; (iv) if necessary, drying said fibres; (v) carbonising the fibres; (vi) assembling the carbonised fibres to form a carbon hollow fibre membrane.
摘要翻译：一种生产碳中空纤维膜的方法，包括：（i）将至少一种纤维素酯溶解在溶剂中以形成溶液; （ii）将溶液干/湿纺成中空纤维; （iii）在醇的存在下用碱或酸对所述中空纤维进行脱酯化; （iv）如果需要，干燥所述纤维; （v）将纤维碳化; （vi）组装碳化纤维以形成碳中空纤维膜。

7. 发明授权

US07819956B2 Gas transfer membrane 有权
标题翻译：气体转移膜
公开(公告)号：US07819956B2
公开(公告)日：2010-10-26
申请号：US11571100
申请日：2005-06-30
申请人： Heinz-Joachim Muller
发明人： Heinz-Joachim Muller
IPC分类号： B01D53/22 , B01D71/32
CPC分类号： B01D53/228 , B01D67/0011 , B01D67/0018 , B01D67/0027 , B01D67/003 , B01D67/0088 , B01D69/02 , B01D69/08 , B01D71/32 , B01D2323/12 , B01D2323/18 , B01D2323/22 , B01D2325/02 , B01D2325/022 , B01D2325/36 , B01D2325/38 , Y10S55/05
摘要： Porous polymeric membranes formed from a hydrophobic polymer, such as halar having membrane pores of a size sufficient to permit gas and/or vapor permeation 0.05 μm to 5 μm without permitting the flow of a hydrophilic fluid across the membrane. Pore distribution is uniform and porosity is high, in some cases up to 80%. Membranes may be in the form of a flay sheet or hollow fibre for example and can be used in a variety of applications such as stripping HF gas, degassing of caustic solution, chlorine gas/alkaline filtration, degassing tap water to remove dissolved chlorine. Processes used to make such membranes can be carried out using relatively non toxic solvents such as citric acid ethyl ester or glycerol triacetate.
摘要翻译：由疏水性聚合物形成的多孔聚合物膜，例如具有足以允许气体和/或蒸气渗透0.05μm至5μm的膜孔的Halar，而不允许亲水流体流过膜。孔分布均匀，孔隙率高，有时高达80％。膜可以是例如薄片或中空纤维的形式，并且可以用于各种应用中，例如汽提HF气体，苛性碱溶液的脱气，氯气/碱性过滤，脱气自来水以除去溶解的氯。用于制造这种膜的方法可以使用相对无毒的溶剂如柠檬酸乙酯或三乙酸甘油进行。

8. 发明授权

US07459121B2 Method for continuous fabrication of carbon nanotube networks or membrane materials 有权
标题翻译：连续制造碳纳米管网络或膜材料的方法
公开(公告)号：US07459121B2
公开(公告)日：2008-12-02
申请号：US11185513
申请日：2005-07-20
申请人： Zhiyong Liang , Ben Wang , Chun Zhang , Jonnattan T. Ugarte , Chih-Yen Lin , James Thagard
发明人： Zhiyong Liang , Ben Wang , Chun Zhang , Jonnattan T. Ugarte , Chih-Yen Lin , James Thagard
IPC分类号： B29C39/14 , B01D61/00 , D01F9/12
CPC分类号： B01D69/10 , B01D67/0046 , B01D71/021 , B01D2323/22 , B01D2323/35 , B01D2323/46 , B82Y30/00 , Y10S264/902 , Y10S977/742 , Y10S977/755
摘要： Methods and devices are provided for the continuous production of a network of nanotubes or other nanoscale fibers. The method includes making a suspension of nanoscale fibers dispersed in a liquid medium, optionally with surfactant and/or sonication, and filtering the suspension by moving a filter membrane through the suspension, such that the nanoscale fibers are deposited directly on the filter membrane as the fluid medium flows through the filter membrane, thereby forming a continuous membrane of the nanoscale fibers. The deposition of the nanoscale fibers can occur when and where the filter membrane moves into contact with a static, porous filter element or a dynamic, porous filter element. The filtering can be conducted within a magnetic field effective to align the nanoscale fibers, and/or with the aid of vacuum to pull water through the filter membrane, applied pressure to press water though the filter membrane, or a combination thereof.
摘要翻译：提供了用于连续生产纳米管或其他纳米级纤维网络的方法和装置。该方法包括制备分散在液体介质中的纳米尺度纤维的悬浮液，任选地用表面活性剂和/或超声处理，并且通过移动过滤膜通过悬浮液来过滤悬浮液，使得纳米级纤维直接沉积在过滤膜上作为流体介质流过过滤膜，从而形成纳米级纤维的连续膜。纳米尺度纤维的沉积可以在滤膜与静止的多孔过滤元件或动态多孔过滤元件接触时发生。过滤可以在有效地对准纳米级纤维的磁场中和/或借助于真空来进行，以将水通过过滤膜，施加压力以通过过滤膜压入水或其组合。

9. 发明申请

US20080241503A1 PROCESS FOR FORMING MICROPOROUS MEMBRANES 有权
标题翻译：形成微孔膜的方法
公开(公告)号：US20080241503A1
公开(公告)日：2008-10-02
申请号：US11692257
申请日：2007-03-28
申请人： Ilyess H. Romdhane , Scott L. Ciliske
发明人： Ilyess H. Romdhane , Scott L. Ciliske
IPC分类号： B32B3/26
CPC分类号： B01D67/0013 , B01D67/0016 , B01D69/12 , B01D2323/22 , B01D2323/42 , B01D2325/022 , Y10T428/24998
摘要： A method for forming a microporous membrane having a microstructure is described. Dope and coagulant formulations are simultaneously cast, where the coagulant formulation diffuses into the dope formulation through an interface effecting a phase inversion forming a microstructure.
摘要翻译：描述了一种形成具有微观结构的微孔膜的方法。掺混剂和凝结剂配方同时浇注，其中凝结剂制剂通过影响相转化形成微结构的界面扩散到涂料配方中。

10. 发明授权

US07309523B2 Hybrid material, use of said hybrid material and method for making same 失效
标题翻译：混合材料，所述混合材料的使用及其制造方法
公开(公告)号：US07309523B2
公开(公告)日：2007-12-18
申请号：US10332281
申请日：2001-07-06
申请人： Jacques Roziere , Deborah Jones , Lydie Tchicaya-Boukary , Bernd Bauer
发明人： Jacques Roziere , Deborah Jones , Lydie Tchicaya-Boukary , Bernd Bauer
IPC分类号： B32B3/26 , H01B1/12
CPC分类号： B01D67/0093 , B01D69/141 , B01D71/00 , B01D71/024 , B01D71/027 , B01D71/52 , B01D71/68 , B01D71/82 , B01D2323/08 , B01D2323/22 , C08G83/001 , C25B13/04 , H01B1/122 , H01M8/0289 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1051 , H01M8/106 , H01M8/1062 , H01M8/1074 , H01M8/1081 , H01M2300/0082 , Y02P70/56 , Y10T428/249954 , Y10T428/249955 , Y10T428/249967 , Y10T428/249969 , Y10T428/24997 , Y10T428/31663
摘要： The present invention relates to a hybrid material, its use and its production process.The hybrid material comprises a polymer with acid groups. The inorganic part of the said hybrid material is constituted by the combination of at least two metal oxide components, whereof at least one comprises a functional group permitting an interaction and a spatial relationship with the acid groups of the polymer.
摘要翻译：本发明涉及混合材料，其用途及其制造方法。杂化材料包含具有酸基团的聚合物。所述杂化材料的无机部分由至少两种金属氧化物组分的组合构成，其中至少一种包含允许与聚合物的酸基相互作用和空间关系的官能团。

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