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    • 83. 发明授权
    • Tough thermoplastic polyester compositions
    • 坚韧的热塑性聚酯组合物
    • US4172859A
    • 1979-10-30
    • US580514
    • 1975-05-23
    • Bennett N. Epstein
    • Bennett N. Epstein
    • C08J3/20C08L23/00C08L33/00C08L33/02C08L33/04C08L67/00C08L67/02C08L69/00C08L101/00D01F6/92
    • C08L67/02C08L69/00Y10T428/2982
    • Toughened multi-phase thermoplastic composition consisting essentially of one phase containing 60 to 99 percent by weight of a polyester including polycarbonate matrix resin of inherent viscosity of at least 0.35 deciliter/gram, and 1 to 40 percent by weight of at least one other phase containing particles of at least one random copolymer having a particle size in the range of 0.01 to 3.0 microns and being adhered to the polyester, the at least one random copolymer having a tensile modulus in the range of 1.0 to 20,000 p.s.i., the ratio of the tensile modulus of the polyester matrix resin to tensile modulus of said at least one polymer being greater than 10 to 1. Said at least one polymer is either a branched or straight chain polymer. The toughened compositions are useful for making molded and extruded parts. Such parts possess greater ductility, less reduction in toughness from scratches and molded in notches and reduced susceptibility to catastrophic failure when compared to known melt fabricated materials.
    • 增韧的多相热塑性组合物基本上由包含60-99重量%的包含特性粘度为至少0.35分升/克的聚碳酸酯基质树脂和1至40重量%至少一个含有 至少一种无规共聚物的颗粒,其粒径在0.01至3.0微米范围内,并且粘附在聚酯上,所述至少一种无规共聚物的拉伸模量在1.0至20,000psi的范围内,拉伸比 聚酯基质树脂的模量与所述至少一种聚合物的拉伸模量大于10:1。所述至少一种聚合物是支链或直链聚合物。 增韧的组合物可用于制造模塑和挤出部件。 与已知的熔融制造材料相比,这样的部件具有更大的延展性,更小的刮痕降低和凹陷模制并减少了对灾难性破坏的敏感性。