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1. 发明申请

US20090171037A1 POLYESTER DERIVED FROM BIOMASS RESOURCES AND METHOD FOR PRODUCTION THEREOF 有权
标题翻译：从生物质资源衍生的聚酯及其生产方法
公开(公告)号：US20090171037A1
公开(公告)日：2009-07-02
申请号：US11912212
申请日：2006-04-21
申请人： Takayuki Aoshima , Yasuaki Miki , Katsuhisa Kumazawa , Satoshi Katou , Tadashi Uyeda , Toyomasa Hoshino , Noboru Shintani , Kenji Yamagishi , Atsushi Isotani
发明人： Takayuki Aoshima , Yasuaki Miki , Katsuhisa Kumazawa , Satoshi Katou , Tadashi Uyeda , Toyomasa Hoshino , Noboru Shintani , Kenji Yamagishi , Atsushi Isotani
IPC分类号： C08L67/02 , C08G63/16
CPC分类号： C08G63/16 , C08G63/20 , C08G63/78 , C08L1/00 , C08L3/00 , C08L5/00 , C08L67/02 , C08L99/00 , C08L2201/06 , C08L2666/02
摘要： The present invention provides a resin capable of contributing greatly to solve environmental problems and problems related to exhaustion of fossil fuel resources and having physical properties suited for practical use.The polyester according to the present invention has a diol and a dicarboxylic acid as constituent components and has an amount of terminal acid of 50 equivalents/metric ton or less.
摘要翻译：本发明提供能够大大有助于解决与化石燃料资源耗尽有关的环境问题和具有适用于实际应用的物理特性的树脂。本发明的聚酯具有二醇和二羧酸作为构成成分，其末端酸的量为50当量/吨以下。

2. 发明申请

US20180171071A1 BIOMASS-RESOURCE-DERIVED POLYESTER AND PRODUCTION PROCESS THEREOF 审中-公开
公开(公告)号：US20180171071A1
公开(公告)日：2018-06-21
申请号：US15693646
申请日：2017-09-01
申请人： Takayuki AOSHIMA , Yasuaki Miki , Katsuhisa Kumazawa , Satoshi Katou , Tadashi Uyeda , Toyomasa Hoshino , Noboru Shintani , Kenji Yamagishi , Atsushi Isotani
发明人： Takayuki AOSHIMA , Yasuaki Miki , Katsuhisa Kumazawa , Satoshi Katou , Tadashi Uyeda , Toyomasa Hoshino , Noboru Shintani , Kenji Yamagishi , Atsushi Isotani
IPC分类号： C08G63/16 , C08G63/78 , C08G63/20 , C08L67/02 , C08L1/00 , C08L3/00 , C08L99/00 , C08L5/00
CPC分类号： C08G63/16 , C08G63/20 , C08G63/78 , C08L1/00 , C08L3/00 , C08L5/00 , C08L67/02 , C08L99/00 , C08L2201/06 , C08L2666/02
摘要： An aliphatic dicarboxylic acid, an aliphatic diol or a derivatives thereof and/or as succinic acid, a butane diol, or a both-hydroxy-terminated polyether having the number of carbon atoms of 4 to 1000, each of which is derived from a biomass resource and has nitrogen atoms in an amount of 0.01 to 100 ppm. Products and methods using these materials are also provided.

3. 发明申请

US20090137843A1 METHOD FOR PRODUCING ORGANIC ACID 审中-公开
标题翻译：生产有机酸的方法
公开(公告)号：US20090137843A1
公开(公告)日：2009-05-28
申请号：US12272523
申请日：2008-11-17
申请人： Atsushi ISOTANI
发明人： Atsushi ISOTANI
IPC分类号： C07C51/64 , C07C231/00
CPC分类号： C07C51/50 , C07C51/02 , C07C51/412 , C07C51/43 , C07C51/48 , C07C55/14 , C07C55/02 , C07C55/10 , C07C55/20 , C07C53/122 , C07C53/10 , C07C53/124
摘要： A novel method is provided whereby a free organic acid can be produced particularly from an ammonium salt of an organic acid having a high melting point obtainable by bioconversion of a carbon source in the presence of a neutralizing agent, efficiently at a low cost, and the used material for reaction and a byproduct can be recycled for reuse without being disposed.An ammonium salt of organic acid A such as a dicarboxylic acid, a tricarboxylic acid or an amino acid is subjected to reactive crystallization by means of acid B such as a monocarboxylic acid satisfying the following formula (1), to separate free organic acid A in solid form: pKa(A)≦pKa(B) (1) where pKa(A) and pKa(B) represent ionization indices of organic acid A and acid B, respectively, provided that when they have plural values, they represent the minimum pKa among them.The crystallization mother liquor after precipitating and separating organic acid A is, after separating acid B and then an ammonium salt of acid B, recycled for use in the reactive crystallization step. The ammonium salt of acid B is decomposed into acid B and ammonia, which are recycled for use in the reactive crystallization step and as a neutralizing agent in the bioconversion step, respectively.
摘要翻译：提供了一种新颖的方法，其中可以有效地以低成本有效地生产游离的有机酸，特别是可以通过在中和剂的存在下通过碳源的生物转化而获得的具有高熔点的有机酸的铵盐，用于反应的所用材料和副产物可以被再循环以便重新使用而不被处置。将二羧酸，三羧酸或氨基酸等有机酸铵的铵盐通过酸性B如满足下式（1）的一元羧酸进行反应结晶，从而分离游离有机酸A 固体形式：<？in-line-formula description =“In-line Formulas”end =“lead”？> pKa（A）<= pKa（B）（1）<？in-line-formula description = 其中pKa（A）和pKa（B）分别表示有机酸A和酸B的电离指数，条件是当它们具有多个值时，它们代表其中的最小pKa。沉淀分离有机酸A后的结晶母液在分离出酸B，然后分离出酸B的铵盐后再循环用于反应结晶步骤。酸B的铵盐分解成酸B和氨，分别在生物转化步骤中再循环用于反应结晶步骤和中和剂。

4. 发明申请

US20130030145A1 BIOMASS-RESOURCE-DERIVED POLYESTER AND PRODUCTION PROCESS THEREOF 审中-公开
标题翻译：生物质资源衍生的聚酯及其生产工艺
公开(公告)号：US20130030145A1
公开(公告)日：2013-01-31
申请号：US13586916
申请日：2012-08-16
申请人： Takayuki AOSHIMA , Yasuaki Miki , Katsuhisa Kumazawa , Satoshi Katou , Tadashi Uyeda , Toyomasa Hoshino , Noboru Shintani , Kenji Yamagishi , Atsushi Isotani
发明人： Takayuki AOSHIMA , Yasuaki Miki , Katsuhisa Kumazawa , Satoshi Katou , Tadashi Uyeda , Toyomasa Hoshino , Noboru Shintani , Kenji Yamagishi , Atsushi Isotani
IPC分类号： C08G63/685 , C07C215/10
CPC分类号： C08G63/16 , C08G63/20 , C08G63/78 , C08L1/00 , C08L3/00 , C08L5/00 , C08L67/02 , C08L99/00 , C08L2201/06 , C08L2666/02
摘要： The present invention provides a resin capable of contributing greatly to solve environmental problems and problems related to exhaustion of fossil fuel resources and having physical properties suited for practical use.The polyester according to the present invention has a diol and a dicarboxylic acid as constituent components and has an amount of terminal acid of 50 equivalents/metric ton or less.
摘要翻译：本发明提供能够大大有助于解决与化石燃料资源耗尽有关的环境问题和具有适用于实际应用的物理特性的树脂。本发明的聚酯具有二醇和二羧酸作为构成成分，其末端酸的量为50当量/吨以下。

5. 发明授权

US07985566B2 Biomass-resource-derived polyester and production process thereof 有权
标题翻译：生物质源资源聚酯及其生产工艺
公开(公告)号：US07985566B2
公开(公告)日：2011-07-26
申请号：US11912212
申请日：2006-04-21
申请人： Takayuki Aoshima , Yasuaki Miki , Katsuhisa Kumazawa , Satoshi Katou , Tadashi Uyeda , Toyomasa Hoshino , Noboru Shintani , Kenji Yamagishi , Atsushi Isotani
发明人： Takayuki Aoshima , Yasuaki Miki , Katsuhisa Kumazawa , Satoshi Katou , Tadashi Uyeda , Toyomasa Hoshino , Noboru Shintani , Kenji Yamagishi , Atsushi Isotani
IPC分类号： C12P7/48
CPC分类号： C08G63/16 , C08G63/20 , C08G63/78 , C08L1/00 , C08L3/00 , C08L5/00 , C08L67/02 , C08L99/00 , C08L2201/06 , C08L2666/02
摘要： The present invention provides a resin capable of contributing greatly to solve environmental problems and problems related to exhaustion of fossil fuel resources and having physical properties suited for practical use.The polyester according to the present invention has a diol and a dicarboxylic acid as constituent components and has an amount of terminal acid of 50 equivalents/metric ton or less.
摘要翻译：本发明提供能够大大有助于解决与化石燃料资源耗尽有关的环境问题和具有适用于实际应用的物理特性的树脂。本发明的聚酯具有二醇和二羧酸作为构成成分，其末端酸的量为50当量/吨以下。

6. 发明授权

US07217837B2 Method for producing organic acid 有权
标题翻译：生产有机酸的方法
公开(公告)号：US07217837B2
公开(公告)日：2007-05-15
申请号：US10976822
申请日：2004-11-01
申请人： Atsushi Isotani
发明人： Atsushi Isotani
IPC分类号： C07C51/42
CPC分类号： C07C51/50 , C07C51/02 , C07C51/412 , C07C51/43 , C07C51/48 , C07C55/14 , C07C55/02 , C07C55/10 , C07C55/20 , C07C53/122 , C07C53/10 , C07C53/124
摘要： A free organic acid can be produced efficiently at a low cost, by subjecting an ammonium salt of organic acid A such as a dicarboxylic acid, a tricarboxylic acid or an amino acid, to reactive crystallization with an acid B, such as a monocarboxylic acid, wherein organic acid A and acid B satisfy the following formula (1): pKa(A)≦pKa(B) (1) where pKa(A) and pKa(B) represent ionization indices of organic acid A and acid B, respectively, provided that when they have plural values, they represent the minimum pKa among them, to separate free organic acid A in solid form.
摘要翻译：通过使诸如二羧酸，三羧酸或氨基酸的有机酸A的铵盐与单体羧酸等酸B进行反应性结晶，可以以低成本有效地制备游离的有机酸，其中有机酸A和酸B满足下列公式（1）：<？in-line-formula description =“In-line formula”end =“lead”？> pKa（A）<= pKa（B）（1）其中pKa（A）和pKa（B）分别表示有机酸A和酸B的电离指数，条件是当它们具有有机酸A和酸B时，复数值，它们代表其中最小的pKa，以分离固体形式的游离有机酸A.

7. 发明申请

US20190185615A1 BIOMASS-RESOURCE-DERIVED POLYESTER AND PRODUCTION PROCESS THEREOF 审中-公开
公开(公告)号：US20190185615A1
公开(公告)日：2019-06-20
申请号：US16290140
申请日：2019-03-01
申请人： Takayuki AOSHIMA , Yasuaki Miki , Katsuhisa Kumazawa , Satoshi Katou , Tadashi Uyeda , Toyomasa Hoshino , Noboru Shintani , Kenji Yamagishi , Atsushi Isotani
发明人： Takayuki AOSHIMA , Yasuaki Miki , Katsuhisa Kumazawa , Satoshi Katou , Tadashi Uyeda , Toyomasa Hoshino , Noboru Shintani , Kenji Yamagishi , Atsushi Isotani
IPC分类号： C08G63/16 , C08G63/78 , C08G63/20 , C08L67/02
CPC分类号： C08G63/16 , C08G63/20 , C08G63/78 , C08L1/00 , C08L3/00 , C08L5/00 , C08L67/02 , C08L99/00 , C08L2201/06 , C08L2666/02
摘要： An aliphatic dicarboxylic acid, an aliphatic diol or a derivatives thereof and/or as succinic acid, a butane diol, or a both-hydroxy-terminated polyether having the number of carbon atoms of 4 to 1000, each of which is derived from a biomass resource and has nitrogen atoms in an amount of 0.01 to 100 ppm. Products and methods using these materials are also provided.

8. 发明授权

US09080009B2 Biomass-resource-derived polyester and production process thereof 有权
标题翻译：生物质源资源聚酯及其生产工艺
公开(公告)号：US09080009B2
公开(公告)日：2015-07-14
申请号：US13168513
申请日：2011-06-24
申请人： Takayuki Aoshima , Yasuaki Miki , Katsuhisa Kumazawa , Satoshi Katou , Tadashi Uyeda , Toyomasa Hoshino , Noboru Shintani , Kenji Yamagishi , Atsushi Isotani
发明人： Takayuki Aoshima , Yasuaki Miki , Katsuhisa Kumazawa , Satoshi Katou , Tadashi Uyeda , Toyomasa Hoshino , Noboru Shintani , Kenji Yamagishi , Atsushi Isotani
IPC分类号： C07C55/00 , C08G63/16 , C08G63/20 , C08G63/78 , C08L67/02 , C08L1/00 , C08L3/00 , C08L5/00 , C08L99/00
CPC分类号： C08G63/16 , C08G63/20 , C08G63/78 , C08L1/00 , C08L3/00 , C08L5/00 , C08L67/02 , C08L99/00 , C08L2201/06 , C08L2666/02
摘要： The present invention provides a resin capable of contributing greatly to solve environmental problems and problems related to exhaustion of fossil fuel resources and having physical properties suited for practical use.The polyester according to the present invention has a diol and a dicarboxylic acid as constituent components and has an amount of terminal acid of 50 equivalents/metric ton or less.
摘要翻译：本发明提供能够大大有助于解决与化石燃料资源耗尽有关的环境问题和具有适用于实际应用的物理特性的树脂。本发明的聚酯具有二醇和二羧酸作为构成成分，其末端酸的量为50当量/吨以下。

9. 发明申请

US20110288207A1 BIOMASS-RESOURCE-DERIVED POLYESTER AND PRODUCTION PROCESS THEREOF 有权
标题翻译：生物质资源衍生的聚酯及其生产工艺
公开(公告)号：US20110288207A1
公开(公告)日：2011-11-24
申请号：US13168513
申请日：2011-06-24
申请人： Takayuki AOSHIMA , Yasuaki Miki , Katsuhisa Kumazawa , Satoshi Katou , Tadashi Uyeda , Toyomasa Hoshino , Noboru Shintani , Kenji Yamagishi , Atsushi Isotani
发明人： Takayuki AOSHIMA , Yasuaki Miki , Katsuhisa Kumazawa , Satoshi Katou , Tadashi Uyeda , Toyomasa Hoshino , Noboru Shintani , Kenji Yamagishi , Atsushi Isotani
IPC分类号： C08L67/02 , C08L93/00 , C08L5/00 , C08G63/16 , C08G63/20
CPC分类号： C08G63/16 , C08G63/20 , C08G63/78 , C08L1/00 , C08L3/00 , C08L5/00 , C08L67/02 , C08L99/00 , C08L2201/06 , C08L2666/02
摘要： The present invention provides a resin capable of contributing greatly to solve environmental problems and problems related to exhaustion of fossil fuel resources and having physical properties suited for practical use.The polyester according to the present invention has a diol and a dicarboxylic acid as constituent components and has an amount of terminal acid of 50 equivalents/metric ton or less.
摘要翻译：本发明提供能够大大有助于解决与化石燃料资源耗尽有关的环境问题和具有适用于实际应用的物理特性的树脂。本发明的聚酯具有二醇和二羧酸作为构成成分，其末端酸的量为50当量/吨以下。

10. 发明授权

US08021864B2 Biomass-resource-derived polyester and production process thereof 有权
公开(公告)号：US08021864B2
公开(公告)日：2011-09-20
申请号：US12858046
申请日：2010-08-17
申请人： Takayuki Aoshima , Yasuaki Miki , Katsuhisa Kumazawa , Satoshi Katou , Tadashi Uyeda , Toyomasa Hoshino , Noboru Shintani , Kenji Yamagishi , Atsushi Isotani
发明人： Takayuki Aoshima , Yasuaki Miki , Katsuhisa Kumazawa , Satoshi Katou , Tadashi Uyeda , Toyomasa Hoshino , Noboru Shintani , Kenji Yamagishi , Atsushi Isotani
IPC分类号： C12P7/48
CPC分类号： C08G63/16 , C08G63/20 , C08G63/78 , C08L1/00 , C08L3/00 , C08L5/00 , C08L67/02 , C08L99/00 , C08L2201/06 , C08L2666/02
摘要： The present invention provides a resin capable of contributing greatly to solve environmental problems and problems related to exhaustion of fossil fuel resources and having physical properties suited for practical use.The polyester according to the present invention has a diol and a dicarboxylic acid as constituent components and has an amount of terminal acid of 50 equivalents/metric ton or less.

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