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    • 6. 发明授权
    • Diblock copolymers prepared by cross metathesis
    • 通过交叉复分解制备的二嵌段共聚物
    • US08940839B2
    • 2015-01-27
    • US13072383
    • 2011-03-25
    • John R. HagadornCharles J. RuffRenuka N. GaneshPatrick Brant
    • John R. HagadornCharles J. RuffRenuka N. GaneshPatrick Brant
    • C08G61/04C08L65/00
    • C08G61/04C08G2261/419C08L65/00
    • This invention relates to a composition comprising a multiblock polyolefin represented by the formula: PO—C(R11)(R12)—C(R13)═C(R14)—C(R15)(R16)—PO*, or isomers thereof, wherein R11, R12, R13, R14, R15, and R16, are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; PO and PO* are polyolefins; PO and PO* are each independently a substituted or unsubstituted hydrocarbyl group having 9 to 4000 carbon atoms, provided that at least one of PO and PO* are C20 or greater, said polyolefin having: 1) an internal unsaturation as shown by the 13C NMR peak at between about 128 and about 132 ppm; 2) an Mn ratio “Z”=0.1 to 10 where Z is the Mn (as determined by 13C NMR) divided by Mn (as determined according to Gel Permeation Chromotography using polystyrene standards); and 3) optionally, from 0.3(J) and 0.75(J) internal unsaturations per 1000 carbons as determined by 1H NMR spectroscopy, where J is the number of reactive groups per 1000 carbons for the mixture of vinyl terminated polyolefins that become PO and PO*, before they are coupled by an alkene metathesis catalyst.
    • 本发明涉及一种组合物,其包含由式:PO-C(R 11)(R 12)-C(R 13)= C(R 14)-C(R 15)(R 16)-PO *表示的多嵌段聚烯烃或其异构体, 其中R11,R12,R13,R14,R15和R16各自独立地为取代或未取代的C1至C4烃基或氢; PO和PO *是聚烯烃; PO和PO *各自独立地为具有9至4000个碳原子的取代或未取代的烃基,条件是PO和PO *中的至少一个为C20或更大,所述聚烯烃具有:1)如13 C NMR所示的内部不饱和度 在约128至约132ppm之间的峰; 2)Mn比“Z”= 0.1〜10,其中Z为Mn(通过13 C NMR测定)除以Mn(根据使用聚苯乙烯标准品的凝胶渗透色谱法测定); 和3)任选地,通过1 H NMR光谱确定的每1000个碳的0.3(J)和0.75(J)内部不饱和度,其中J是成为PO和PO的乙烯基封端的聚烯烃的混合物的每1000个碳的反应性数 *,在它们通过烯烃复分解催化剂偶合之前。