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1. 发明申请

US20090258221A1 Light-Reflective Articles and Methods for Making Same 审中-公开
标题翻译：反光制品及其制作方法
公开(公告)号：US20090258221A1
公开(公告)日：2009-10-15
申请号：US12102959
申请日：2008-04-15
申请人： David A. Diehl , Nicholas J. Mullins , Max L. Howells , Jeanne D. Housman
发明人： David A. Diehl , Nicholas J. Mullins , Max L. Howells , Jeanne D. Housman
IPC分类号： B32B27/00 , B32B9/00
CPC分类号： G02B5/0866 , Y10T428/26 , Y10T428/31663
摘要： Light-reflective article including polymeric substrate; tie layer disposed on polymeric substrate and having composition including metal element; support layer including diamond-like carbon disposed on tie layer; and light-reflective layer disposed on support layer and having composition including metal element. Light-reflective article further including lubricious, optically-transparent protective layer disposed on light-reflective layer and including diamond-like carbon, silicon, and oxygen. Method for fabricating article.
摘要翻译：包括聚合物基材的光反射制品; 粘合层设置在聚合物基材上并具有包含金属元素的组合物; 支撑层，包括设置在连接层上的类金刚石碳; 以及设置在支撑层上并具有包含金属元素的成分的光反射层。光反射制品还包括设置在光反射层上并且包括类金刚石碳，硅和氧的光滑透光保护层。制造方法。

2. 发明授权

US5095069A Internally-curable water-based polyurethanes 失效
标题翻译：内部可固化水基聚氨酯
公开(公告)号：US5095069A
公开(公告)日：1992-03-10
申请号：US575024
申请日：1990-08-30
申请人： Ronald R. Ambrose , David A. Diehl , Leon A. Perez
发明人： Ronald R. Ambrose , David A. Diehl , Leon A. Perez
IPC分类号： C08F299/06 , C08G18/67
CPC分类号： C08G18/67 , C08F299/06 , C08G18/6715 , C08G18/675
摘要： There is provided herein a stable water-based internally-crosslinkable unsaturated polyurethane composition containing unsaturated groups comprising an allyl group and another ethylenically unsaturated group that can react with the allyl group to form a solvent resistant coating.

3. 发明授权

US08133324B2 Methods for removal of polymeric coating layers from coated substrates 有权
标题翻译：从涂覆的基材上去除聚合物涂层的方法
公开(公告)号：US08133324B2
公开(公告)日：2012-03-13
申请号：US11154924
申请日：2005-06-16
申请人： James A. Claar , Jerome J. Cuomo , David A. Diehl , Christopher J. Oldham , Roger C. Sanwald , Truman F. Wilt , Peter J. Yancey
发明人： James A. Claar , Jerome J. Cuomo , David A. Diehl , Christopher J. Oldham , Roger C. Sanwald , Truman F. Wilt , Peter J. Yancey
IPC分类号： B08B7/00
CPC分类号： B08B7/0035 , B44D3/16
摘要： The invention provides a method for the at least partial removal of one or more polymeric coating layers from a coated substrate having at least one coated surface. The method includes generating at least one reactive species in an ionized gas stream discharged at atmospheric pressure; and placing the coated surface in the ionized gas stream. The at least one reactive species reacts with the one or more polymeric coating layers such that one or more coating layers is at least partially removed from the coated surface of the substrate at atmospheric pressure.
摘要翻译：本发明提供了一种用于从具有至少一个涂覆表面的涂覆基材至少部分去除一个或多个聚合物涂层的方法。该方法包括在大气压下排出的电离气流产生至少一种反应性物质; 并将涂覆的表面放置在电离气流中。至少一种反应性物质与一种或多种聚合物涂层反应，使得一个或多个涂层在大气压力下至少部分地从基底的涂覆表面除去。

4. 发明申请

US20080113103A1 HALOGEN TREATMENT OF POLYMER FILMS USING ATMOSPHERIC PLASMA 审中-公开
标题翻译：使用大气等离子体处理聚合物薄膜
公开(公告)号：US20080113103A1
公开(公告)日：2008-05-15
申请号：US11689063
申请日：2007-03-21
申请人： James A. Claar , Truman F. Wilt , Edward R. Millero , Kaliappa G. Ragunathan , David A. Diehl
发明人： James A. Claar , Truman F. Wilt , Edward R. Millero , Kaliappa G. Ragunathan , David A. Diehl
IPC分类号： B05D3/04
CPC分类号： B29C59/14 , B05D3/107 , B05D3/145 , B05D5/083 , B05D7/14 , B05D2202/25 , B29C2059/145
摘要： A method of treating a surface coating with a halogen-containing plasma generated at atmospheric pressure is disclosed.
摘要翻译：公开了一种在大气压下产生的含卤素等离子体处理表面涂层的方法。

5. 发明授权

US07001667B2 Alkyd-based free radical wood coating compositions 有权
标题翻译：基于醇酸的自由基木质涂料组合物
公开(公告)号：US07001667B2
公开(公告)日：2006-02-21
申请号：US10196804
申请日：2002-07-17
申请人： Roy E. Dean , David A. Diehl , Truman F. Wilt , Ronald R. Ambrose , Michael J. Ziegler , William H. Retsch, Jr.
发明人： Roy E. Dean , David A. Diehl , Truman F. Wilt , Ronald R. Ambrose , Michael J. Ziegler , William H. Retsch, Jr.
IPC分类号： B32B21/04 , B32B21/08 , B32B27/18 , B32B27/26 , B32B27/36
CPC分类号： C09D167/08 , Y10T428/31786 , Y10T428/3179 , Y10T428/31794 , Y10T428/31855 , Y10T428/31906 , Y10T428/31909 , Y10T428/31935 , Y10T428/31938 , Y10T428/31989
摘要： Coating compositions comprising a polymer and an initiator are disclosed. The polymer comprises an alkyd, portion and a free radical curable portion that is pendant from the alkyd portion; the alkyd portion includes one or more fatty acid moieties that can be derived from one or more drying, semi-drying or nondrying oils. When drying or semi-drying oils are used, the molecules of the present invention exhibit a dual cure, both oxidative and free radical. The compositions are particularly suitable for coating substrates comprising wood. Methods for using the present compositions are also disclosed.
摘要翻译：公开了包含聚合物和引发剂的涂料组合物。该聚合物包含醇酸部分和可自由基固化的部分，其部分是从醇酸部分悬挂出来的; 醇酸部分包括可以衍生自一种或多种干燥，半干燥或不干燥的油的一种或多种脂肪酸部分。当使用干燥或半干性油时，本发明的分子表现出双重固化，包括氧化和自由基。所述组合物特别适用于涂覆包含木材的基材。还公开了使用本发明组合物的方法。

6. 发明授权

US5942556A Stabilized radiation curable compositions based on unsaturated ester and vinyl ether compounds 失效
标题翻译：基于不饱和酯和乙烯基醚化合物的稳定的可辐射固化组合物
公开(公告)号：US5942556A
公开(公告)日：1999-08-24
申请号：US757271
申请日：1996-11-27
申请人： Charles B. Friedlander , Ronald R. Ambrose , David A. Diehl , Alan B. Weissberg , Carolyn A. Novak
发明人： Charles B. Friedlander , Ronald R. Ambrose , David A. Diehl , Alan B. Weissberg , Carolyn A. Novak
IPC分类号： C08F2/50 , C08K5/06 , C08L67/06 , C09D175/06 , C08K5/524 , C08L67/07
CPC分类号： C08L67/06 , C08K5/06 , C09D175/06
摘要： Disclosed is a radiation curable composition which includes: (a) an unsaturated ester compound, and (b) a pulverizable vinyl ether compound. The unsaturated ester compound is characterized as having a plurality of unsaturated ester groups per molecule. The pulverizable vinyl ether compound is characterized as including at least one of the following: (a) a compound having an average of greater than 1.0 reactive vinyl ether groups per molecule, and (b) a vinyl ether-containing group bonded to the unsaturated ester compound such that there is an average of at least 1.0 reactive vinyl ether group per molecule. The unsaturated ester compound, the vinyl ether compound and/or a mixture thereof is treated with a reducing agent so as to decompose destabilizing agents present therein that would initiate premature polymerization of the vinyl ether compound. Accordingly, in the stabilized radiation curable coating compositions of this invention, polymerization of the vinyl ether compound is substantially avoided until blended with the unsaturated ester compound and exposed to radiation.
摘要翻译：公开了一种可辐射固化组合物，其包括：（a）不饱和酯化合物和（b）可粉化的乙烯基醚化合物。不饱和酯化合物的特征在于每分子具有多个不饱和酯基。可粉碎的乙烯基醚化合物的特征在于包括以下至少一种：（a）每分子平均具有大于1.0个反应性乙烯基醚基团的化合物，和（b）与不饱和酯键合的含乙烯基醚基团化合物，使得每个分子平均具有至少1.0个反应性乙烯基醚基团。用还原剂处理不饱和酯化合物，乙烯基醚化合物和/或它们的混合物，以分解其中存在乙烯基醚化合物过早聚合的不稳定剂。因此，在本发明的稳定的可辐射固化涂料组合物中，基本上避免了乙烯基醚化合物的聚合，直到与不饱和酯化合物共混并暴露于辐射。

7. 发明授权

US5536760A Radiation curable compositions based on unsaturated polyesters and compounds having at least two vinyl ether groups 失效
标题翻译：基于不饱和聚酯和具有至少两个乙烯基醚基团的化合物的可辐射固化组合物
公开(公告)号：US5536760A
公开(公告)日：1996-07-16
申请号：US166665
申请日：1993-12-10
申请人： Charles B. Friedlander , David A. Diehl
发明人： Charles B. Friedlander , David A. Diehl
IPC分类号： C08F283/01 , C08F2/46 , C08F2/48 , C08F2/50 , C08F2/54 , C08F290/00 , C08F299/02 , C08F299/04 , C09D4/00 , C09D4/06 , C09D155/00 , C09D167/06
CPC分类号： C08F299/0478 , C09D4/06
摘要： Disclosed is a liquid, radiation curable composition comprising: (A) an unsaturated polyester component containing an unsaturated polyester polymer, an unsaturated polyester oligomer or a mixture thereof; and (B) a non-polymerized, cocurable vinyl ether component which may be separate from or structurally incorporated in the unsaturated polyester component, provided that the vinyl ether component contains an average of at least two vinyl ether groups per molecule of the vinyl ether component.Also disclosed is a method of coating comprising: applying to a substrate a film of a liquid, radiation curable composition of the invention, and curing the composition through its thickness to a tack-free state by exposing the film to ionizing radiation and/or ultraviolet light.
摘要翻译：本发明公开了一种液体可辐射固化组合物，其包含：（A）含有不饱和聚酯聚合物，不饱和聚酯低聚物或其混合物的不饱和聚酯组分; 和（B）未聚合的可共凝胶的乙烯基醚组分，其可以与不饱和聚酯组分分开或结构上并入不饱和聚酯组分中，条件是乙烯基醚组分每分子含有至少两个乙烯基醚基团的平均乙烯基醚组分。还公开了一种涂覆方法，其包括：向基材施加本发明的液体，可辐射固化组合物的膜，并通过将该膜暴露于电离辐射和/或紫外线而将组合物通过其厚度固化至无粘性状态光。

8. 发明授权

US07387843B2 Alkyd-based free radical wood coating compositions 失效
标题翻译：基于醇酸的自由基木质涂料组合物
公开(公告)号：US07387843B2
公开(公告)日：2008-06-17
申请号：US11252380
申请日：2005-10-18
申请人： Roy E. Dean , David A. Diehl , Truman F. Wilt , Ronald R. Ambrose , Michael J. Ziegler , William H. Retsch, Jr.
发明人： Roy E. Dean , David A. Diehl , Truman F. Wilt , Ronald R. Ambrose , Michael J. Ziegler , William H. Retsch, Jr.
IPC分类号： B32B21/04 , B32B21/08 , B32B27/26 , B32B27/36 , B32B27/30
CPC分类号： C09D167/08 , Y10T428/31786 , Y10T428/3179 , Y10T428/31794 , Y10T428/31855 , Y10T428/31906 , Y10T428/31909 , Y10T428/31935 , Y10T428/31938 , Y10T428/31989
摘要： Coating compositions comprising a polymer and an initiator are disclosed. The polymer comprises an alkyd portion and a free radical curable portion that is pendant from the alkyd portion; the alkyd portion includes one or more fatty acid moieties that can be derived from one or more drying, semi-drying or nondrying oils. When drying or semi-drying oils are used, the molecules of the present invention exhibit a dual cure, both oxidative and free radical. The compositions are particularly suitable for coating substrates comprising wood. Methods for using the present compositions are also disclosed.
摘要翻译：公开了包含聚合物和引发剂的涂料组合物。聚合物包含醇酸部分和从醇酸部分悬挂的自由基可固化部分; 醇酸部分包括可以衍生自一种或多种干燥，半干燥或不干燥的油的一种或多种脂肪酸部分。当使用干燥或半干性油时，本发明的分子表现出双重固化，包括氧化和自由基。所述组合物特别适用于涂覆包含木材的基材。还公开了使用本发明组合物的方法。

9. 发明授权

US5585415A Pigmented compositions and methods for producing radiation curable coatings of very low gloss 失效
标题翻译：用于生产非常低光泽的可辐射固化涂料的着色组合物和方法
公开(公告)号：US5585415A
公开(公告)日：1996-12-17
申请号：US338077
申请日：1994-11-14
申请人： Peter J. Gorzalski , David A. Diehl
发明人： Peter J. Gorzalski , David A. Diehl
IPC分类号： C08F2/50 , C09D4/00 , C08J3/28 , C08K3/22 , C08K5/00
CPC分类号： C09D4/00
摘要： Very low gloss finishes are attained in pigmented, radiation curable coatings by inclusion of a combination of photoinitiators having an acylphosphine oxide photoinitiator and a second photoinitiator such as an acetophenone derivative. In the method of producing the low gloss finishes, the coating is first exposed to ionizing radiation (e.g., electron beam) in air, then exposed to actinic radiation (ultraviolet light) in an essentially inert atmosphere. The low gloss is achieved by a fine, uniform surface wrinkling effect.
摘要翻译：通过包含具有酰基氧化膦光引发剂和第二光引发剂如苯乙酮衍生物的光引发剂的组合，在着色的可辐射固化涂层中获得非常低的光泽度。在制造低光泽饰面的方法中，首先在空气中暴露于电离辐射（例如电子束），然后在基本上惰性的气氛中暴露于光化辐射（紫外光）。低光泽度通过细微均匀的表面起皱效果实现。

10. 发明授权

US4314923A Coating compositions formulated from polyols modified by reaction with glycidyl ether 失效
标题翻译：由通过与缩水甘油醚反应改性的多元醇配制的涂料组合物
公开(公告)号：US4314923A
公开(公告)日：1982-02-09
申请号：US156529
申请日：1980-06-04
申请人： Wen-Hsuan Chang , Robert Piccirilli , David A. Diehl
发明人： Wen-Hsuan Chang , Robert Piccirilli , David A. Diehl
IPC分类号： C09D161/20 , C08L61/28 , C08L61/24
CPC分类号： C09D161/20
摘要： Coating compositions are formulated using a polyol with a hydroxyl functionality of at least three modified by reaction with a glycidyl ether in proportion of about 0.1 to about 4, preferably from about 0.2 to about 2 moles of glycidyl ether per mole of polyol, with which is combined, as curing agent, a compatible aminoplast resin. When the polyol is trimethylol ethane, for example, and is so modified with allyl or butyl glycidyl ether, for example, and is so modified with allyl or butyl glycidyl ether, for example, and the compositions contain a methylated melamine formaldehyde condensate as curing agent, they are especially suitable for clear top coating surfaces of wood or flat woodstock containing printing inks to simulate woodgrain, to provide a durable coating highly adherent to the inks as well as the cellulosic materials. The compositions may contain high solids content yet they are stable on storage without development of crystallization and are reducible or thinnable with water.
摘要翻译：涂料组合物使用具有至少三个羟基官能度的多元醇配制，所述多元醇通过与缩水甘油醚反应而改性，其比例为每摩尔多元醇约0.1至约4，优选约0.2至约2摩尔缩水甘油醚，组合，作为固化剂，相容的氨基塑料树脂。例如，当多元醇为三羟甲基乙烷并用烯丙基或丁基缩水甘油醚进行改性时，例如用烯丙基或丁基缩水甘油醚进行改性，组合物含有甲基化三聚氰胺甲醛缩合物作为固化剂，它们特别适用于含有印刷油墨的木材或扁平木材的透明顶部涂层表面以模拟木纹，以提供高度贴附于油墨以及纤维素材料的耐用涂层。组合物可以含有高固体含量，但它们在储存时稳定而不发展结晶，并且可用水还原或稀释。

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