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1. 发明授权

US5936099A Process for preparing BIS(ether anhydrides) using alkylamine derived bisimides having low melting temperature 失效
标题翻译：使用具有低熔融温度的烷基胺衍生双酰亚胺制备BIS（醚酐）的方法
公开(公告)号：US5936099A
公开(公告)日：1999-08-10
申请号：US964032
申请日：1997-11-04
申请人： Brent Dellacoletta , Roy Ray Odle , Thomas L. Guggenheim , Ronald A. Greenberg , James P. Barren , Joseph A. King , Sunita Singh Baghel , Deborah A. Haitko , David G. Hawron
发明人： Brent Dellacoletta , Roy Ray Odle , Thomas L. Guggenheim , Ronald A. Greenberg , James P. Barren , Joseph A. King , Sunita Singh Baghel , Deborah A. Haitko , David G. Hawron
IPC分类号： C07D209/48 , C07D307/89 , C07D209/12
CPC分类号： C07D209/48 , C07D307/89
摘要： A process for making bis(ether anhydrides) employs alkylamines having low melting temperatures thus allowing for novel intermediate process steps for preparing bis(ether anhydrides). The alkylamines have alkyl groups which contain at least three carbon atoms and have boiling temperatures in the range of 48 to 250.degree. C. at atmospheric pressure. As a result of using these amines, liquid alkylamines now can be employed in the imidization process step. The N-alkyl nitrophthalimides prepared from the recovered imidization product according to this invention can now be purified using liquid/liquid extraction or vacuum distillation. The alkyl nitrophthalimides prepared according to this invention provide for displacement reactions which now can be run at a high solids level. Likewise, the exchange reaction can be run at a higher solids level, and thus achieves an efficiency level which is higher than conventional processes.
摘要翻译：制备双（醚酐）的方法使用具有低熔融温度的烷基胺，从而允许制备双（醚酐）的新的中间方法步骤。烷基胺具有含有至少三个碳原子的烷基，并且在大气压下具有在48至250℃范围内的沸点温度。作为使用这些胺的结果，液体烷基胺现在可用于酰亚胺化工艺步骤。从本发明回收的酰亚胺化产物制备的N-烷基硝基邻苯二酰亚胺现在可以使用液/液萃取或真空蒸馏来纯化。根据本发明制备的烷基硝基邻苯二酰亚胺提供了现在可以以高固体含量运行的置换反应。同样，交换反应可以在更高的固体含量下进行，从而达到高于常规方法的效率水平。

2. 发明授权

US5575926A Dechlorination of chlorinated hydrocarbons by soluble iron citrate 失效
标题翻译：用可溶性柠檬酸铁脱氯氯化烃
公开(公告)号：US5575926A
公开(公告)日：1996-11-19
申请号：US218396
申请日：1994-03-28
申请人： Deborah A. Haitko , Gerald R. Eykholt
发明人： Deborah A. Haitko , Gerald R. Eykholt
IPC分类号： B09C1/00 , C02F1/70
CPC分类号： C02F1/705 , B09C1/002 , C02F2101/36 , C02F2103/06 , Y10S210/908 , Y10S210/909
摘要： A method for significantly improving the dechlorination of chlorinated hydrocarbon compounds is disclosed. The method involves admixing preformed ferrous citrate with chlorinated hydrocarbon contaminated aqueous compositions both in situ and ex situ. The use of ferrous citrate decreases the oxidation potential of the Fe.sup.+2 /Fe.sup.+3 redox couple to cause oxidation by the chlorinated hydrocarbon with its concomitant reduction, thereby generating chloride ion.
摘要翻译：公开了一种显着改善氯化烃化合物脱氯的方法。该方法包括原位和非原位混合预先形成的柠檬酸亚铁与氯化烃污染的水性组合物。使用柠檬酸亚铁降低Fe + 2 / Fe + 3氧化还原对的氧化电位，使氯化烃伴随着还原而氧化，从而产生氯离子。

3. 发明授权

US5068352A Bisimidodiphenol derivatives 失效
标题翻译：二亚氨基二苯酚衍生物
公开(公告)号：US5068352A
公开(公告)日：1991-11-26
申请号：US606417
申请日：1990-10-31
申请人： David N. Schissel , Deborah A. Haitko
发明人： David N. Schissel , Deborah A. Haitko
IPC分类号： C08G73/16 , C09K19/38 , C07D403/10
CPC分类号： C09K19/3823 , C08G73/16
摘要： Liquid crystalline polyesteretherimides are prepared by a transesterification reaction involving terephthalic acid and acylated derivatives of 4-hydroxybenzoic acid and of certain bisimidodiphenols, or from the free bisimidodiphenol and aryl esters of the acids. In addition to being liquid crystalline, the polyesterethermides are crystalline in the solid state and have relatively high glass transition temperatures.
摘要翻译：液晶聚对苯二甲酰亚胺通过涉及对苯二甲酸和4-羟基苯甲酸和某些双亚氨基二酚的酰化衍生物或来自游离双亚氨基二苯酚和酸的芳基酯的酯交换反应制备。除了是液晶之外，聚醚醚醚醚是固态的结晶，并具有较高的玻璃化转变温度。

4. 发明授权

US4482697A Process, complex and catalyst for preparation of polyphenylene oxide 失效
标题翻译：制备聚苯醚的工艺，复合物和催化剂
公开(公告)号：US4482697A
公开(公告)日：1984-11-13
申请号：US494835
申请日：1983-05-16
申请人： Deborah A. Haitko
发明人： Deborah A. Haitko
IPC分类号： C07F1/08 , B01J31/18 , C08G65/44
CPC分类号： C08G65/44 , B01J31/1805 , B01J2531/16
摘要： Polyphenylene oxides are prepared by the oxidative coupling of monohydroxy aromatic compounds such as 2,6-xylenol in the presence of copper-halide-amine catalysts in which at least part of the amine component is an aromatic diamine such as N,N'-diphenylethylenediamine, N,N'-diphenyl-N,N'-dimethylethylenediamine, N,N'-diphenylpiperazine or N,N,N',N'-tetramethyl-o-phenylenediamine. Other amines preferably present in the catalyst are a tertiary monoamine such as dimethyl-n-butylamine and a secondary monoamine such as di-n-butylamine. These diamines are characterized by a low rate of consumption during polymerization, and the catalysts prepared therefrom are hydrolytically stable.
摘要翻译：聚苯醚通过在卤化铜 - 胺催化剂的存在下，通过氧化偶合单羟基芳族化合物如2,6-二甲苯酚来制备，其中至少部分胺组分是芳族二胺，例如N，N'-二苯基乙二胺 N，N'-二苯基-N，N'-二甲基乙二胺，N，N'-二苯基哌嗪或N，N，N'，N'-四甲基邻苯二胺。优选存在于催化剂中的其它胺是叔胺如二正丁胺和仲正丁胺如二正丁胺。这些二胺的特征在于聚合期间的低消耗速率，由其制备的催化剂具有水解稳定性。

5. 发明授权

US5362402A Enhanced remediation of aqueous compositions contaminated with halogenated hydrocarbons 失效
标题翻译：增强对被卤代烃污染的含水组合物的补救
公开(公告)号：US5362402A
公开(公告)日：1994-11-08
申请号：US217832
申请日：1994-03-25
申请人： Deborah A. Haitko , Sunita S. Baghel , Patricia D. Mackenzie
发明人： Deborah A. Haitko , Sunita S. Baghel , Patricia D. Mackenzie
IPC分类号： A62D3/00 , A62D3/34 , A62D3/36 , A62D101/22 , C02F1/70
CPC分类号： A62D3/34 , C02F1/70 , Y10S210/908 , Y10S210/909
摘要： A process for significantly improving the rate of dehalogenation of aqueous compositions contaminated with halogenated hydrocarbon compounds is disclosed. The process involves admixing the contaminated aqueous composition with metallic iron in the presence of citric acid both in-situ and ex-situ. The use of citric acid as an additive in the reaction substantially increases the rate of iron-induced dechlorination of chlorinated hydrocarbons, such as trichloroethylene.
摘要翻译：公开了一种显着提高被卤代烃化合物污染的含水组合物脱卤速率的方法。该方法包括在原位和非原位的柠檬酸存在下将污染的含水组合物与金属铁混合。在反应中使用柠檬酸作为添加剂大大增加氯化烃如三氯乙烯的铁诱导脱氯的速率。

6. 发明授权

US4814466A Method for making thianthrene dianhydride and polyimides obtained therefrom 失效
公开(公告)号：US4814466A
公开(公告)日：1989-03-21
申请号：US179370
申请日：1988-04-08
申请人： James A. Cella , Deborah A. Haitko
发明人： James A. Cella , Deborah A. Haitko
IPC分类号： C08G73/10 , C07D495/14 , C08G73/06 , C07D339/08
CPC分类号： C07D495/14 , C08G73/1064 , C08G73/1085
摘要： A method is provided for making 9,10-dithiaanthracene-2,3,6,7-tetracarboxylic acid dianhydride. Polyimides having improved oxidative stability also are provided which can be made intercondensing organic diamine and the aforementioned dianhydride or a dianhydride mixture.

7. 发明授权

US4594405A Copper (I) complexes useful as catalysts for polyphenylene oxide preparation 失效
标题翻译：铜（I）络合物可用作聚苯醚制备的催化剂
公开(公告)号：US4594405A
公开(公告)日：1986-06-10
申请号：US572036
申请日：1984-01-19
申请人： Deborah A. Haitko
发明人： Deborah A. Haitko
IPC分类号： C07F1/00 , C08G65/44 , C07F1/08 , C08G65/38
CPC分类号： C07F1/005 , C08G65/44
摘要： Copper(I)-diamine-chloride complexes are prepared by the reaction of cuprous chloride with a diamine such as N,N'-di-t-butylethylenediamine. Said complexes are reacted with phenoxides such as potassium 2,6-xylenoxide to produce the corresponding copper(I)-diamine-phenoxide complexes, which are useful for the preparation of polyphenylene oxides by oxidative coupling of various phenols such as 2,6-xylenol.
摘要翻译：通过氯化亚铜与二胺如N，N'-二叔丁基乙二胺的反应制备铜（I） - 二胺氯化物配合物。所述配合物与苯氧化物例如2,6-二甲苯胺钾反应生成相应的铜（I） - 二胺 - 苯酚络合物，它们可用于通过各种酚如2,6-二甲苯酚的氧化偶联制备聚苯醚。

8. 发明授权

US4471068A Process and catalyst for preparation of polyphenylene oxide 失效
标题翻译：制备聚苯醚的方法和催化剂
公开(公告)号：US4471068A
公开(公告)日：1984-09-11
申请号：US474604
申请日：1983-03-11
申请人： Deborah A. Haitko
发明人： Deborah A. Haitko
IPC分类号： C08G65/00 , C08G65/38 , C08G65/44 , B01J27/24 , B01J23/72
CPC分类号： C08G65/44
摘要： Polyphenylene oxides are prepared by the oxidative coupling of monohydroxy aromatic compounds such as 2,6-xylenol in the presence of copper-bromide-amine catalysts in which at least part of the amine component is a diamine such as N,N'diphenylethylendiamine, N,N'-diphenyl-N,N'-dimethylethylene diamine or N,N'-diphenylpiperazine. Other amines preferably present in the catalyst are a tertiary monoamine such as dimethyl-n-butylamine and a secondary monoamine such as di-n-butylamine. The diamines are characterized by a low rate of consumption during polymerization, and the catalysts prepared therefrom are hydrolytically stable.
摘要翻译：聚苯醚通过在溴化铜 - 胺催化剂存在下，通过氧化偶合一羟基芳族化合物如2,6-二甲苯酚制备，其中至少部分胺组分是二胺如N，N'-二苯基乙二胺，N ，N'-二苯基-N，N'-二甲基乙二胺或N，N'-二苯基哌嗪。优选存在于催化剂中的其它胺是叔胺如二正丁胺和仲正丁胺如二正丁胺。二胺的特征在于聚合期间的低消耗速率，由其制备的催化剂具有水解稳定性。

9. 发明授权

US5719295A Process for preparing bis(ether anhydrides) using alkylamine derived bisimides having low melting temperatures 失效
公开(公告)号：US5719295A
公开(公告)日：1998-02-17
申请号：US652067
申请日：1996-05-23
申请人： Brent Dellacoletta , Roy Ray Odle , Thomas L. Guggenheim , Ronald A. Greenberg , James P. Barren , Joseph A. King , Sunita Singh Baghel , Deborah A. Haitko , David G. Hawron
发明人： Brent Dellacoletta , Roy Ray Odle , Thomas L. Guggenheim , Ronald A. Greenberg , James P. Barren , Joseph A. King , Sunita Singh Baghel , Deborah A. Haitko , David G. Hawron
IPC分类号： C07D209/48 , C07D307/89 , C07D209/12
CPC分类号： C07D209/48 , C07D307/89
摘要： A process for making bis(ether anhydrides) employs alkylamines having low melting temperatures thus allowing for novel intermediate process steps for preparing bis(ether anhydrides). The alkylamines have alkyl groups which contain at least three carbon atoms and have boiling temperatures in the range of 48.degree. to 250.degree. C. at atmospheric pressure. As a result of using these amines, liquid alkylamines now can be employed in the imidization process step. The N-alkyl nitrophthalimides prepared from the recovered imidization product according to this invention can now be purified using liquid/liquid extraction or vacuum distillation. The alkyl nitrophthalimides prepared according to this invention provide for displacement reactions which now can be run at a high solids level. Likewise, the exchange reaction can be run at a higher solids level, and thus achieves an efficiency level which is higher than conventional processes.

10. 发明授权

US5034540A Liquid crystalline polyesteretherimides 失效
标题翻译：液晶聚醚酰亚胺
公开(公告)号：US5034540A
公开(公告)日：1991-07-23
申请号：US583743
申请日：1990-09-17
申请人： Deborah A. Haitko , David N. Schissel
发明人： Deborah A. Haitko , David N. Schissel
IPC分类号： C08G73/16
CPC分类号： C08G73/16
摘要： Liquid crystalline polyesteretherimides are prepared by a transesterification reaction involving hydroquinone, 4,4'-biphenol or 2,6-dihydroxynaphthalene and esters of certain bisimidodicarboxylic acids, or from the free bisimidodicarboxylic acids and esters of the dihydroxyaromatic compounds. In addition to being liquid crystalline, the polyesteretherimides are crystalline in the solid state and have relatively high glass transition temperatures.
摘要翻译：通过含有氢醌，4,4'-联苯酚或2,6-二羟基萘的酯交换反应或某些双亚氨基二羧酸的酯，或者游离的双亚氨基二羧酸和二羟基芳族化合物的酯来制备液晶聚对苯二酰亚胺。除了是液晶之外，聚异噻吩酰亚胺是固态的结晶并且具有相当高的玻璃化转变温度。

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