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1. 发明授权

US06924382B2 Rumen bypass calcium salts of C18:1 and C18:2 fatty acids 有权
标题翻译：瘤胃旁路C18：1和C18：2脂肪酸钙盐
公开(公告)号：US06924382B2
公开(公告)日：2005-08-02
申请号：US10431318
申请日：2003-05-06
申请人： George K. Strohmaier , Eiler D. Frederiksen , Nestor D. Luchini
发明人： George K. Strohmaier , Eiler D. Frederiksen , Nestor D. Luchini
IPC分类号： A23K1/16 , A23K1/175 , A23K1/18 , C07C51/00
CPC分类号： A23K50/40 , A23K20/158 , A23K20/24 , A23K50/10 , Y10S426/807
摘要： Free-flowing unsaturated fatty acid calcium salts containing from about 0.1 to about 1.5 equivalents of calcium hydroxide relative to the fatty acid content, with the fatty acid content consisting essentially of (a) from about 40 to about 95% percent by weight of unsaturated C:16-C:22 fatty acids; (b) from about 5 to about 60% by weight of saturated C:14-C:22 fatty acids; and (c) no more than about 6% by weight of moisture, insolubles and unsaponifiables; with no more than about 20% by weight being in for form of glycerides; wherein from about 40 to about 65% by weight of the total product weight consists of trans-C18:1 and C18:2 fatty acids; provided that when less than 0.75 equivalents of calcium hydroxide is present, the fatty acid content is at least 25% by weight saturated fatty acids.
摘要翻译：含有约0.1至约1.5当量氢氧化钙相对于脂肪酸含量的自由流动的不饱和脂肪酸钙盐，脂肪酸含量基本上由（a）组成，约40至约95重量％的不饱和C ：16-C：22脂肪酸; （b）约5至约60重量％的饱和C：14-C：22脂肪酸; 和（c）不超过约6重量％的水分，不溶物和不皂化物; 不超过约20重量％的甘油酯形式; 其中总产物重量的约40至约65重量％由反式C18：1和C18：2脂肪酸组成; 条件是当存在小于0.75当量的氢氧化钙时，脂肪酸含量为至少25重量％饱和脂肪酸。

2. 发明授权

US06774252B2 Method for manufacturing fatty acid calcium salts from high glyceride content oils 有权
标题翻译：从高甘油酯含量油制造脂肪酸钙盐的方法
公开(公告)号：US06774252B2
公开(公告)日：2004-08-10
申请号：US10316486
申请日：2002-12-11
申请人： George K. Strohmaier , Eiler D. Frederiksen , Nestor Daniel Luchini
发明人： George K. Strohmaier , Eiler D. Frederiksen , Nestor Daniel Luchini
IPC分类号： C07C5100
CPC分类号： C11C1/045 , A23K10/14 , A23K10/22 , A23K20/158 , A23K20/24 , A23K40/10 , A23K50/10 , C11C1/025
摘要： A method for the preparation of fatty acid calcium salts, which includes the steps of: (a) providing a fatty acid feedstock having a glyceride content between about 30 and about 60% by weight; (b) adding to the feedstock from about 2 to about 3 equivalents of calcium oxide relative to the feedstock, so that a reactive admixture is formed; and (c) adding to the reactive admixture from about 2 to about 5 equivalents of water relative to the calcium oxide so that the calcium oxide hydrates and neutralizes the fatty acids to form calcium salts. Fatty acid calcium salts containing eicosapentaenoic acid and decosahexaenoic acid are also disclosed, as well as methods for enhancing ruminant fertility.
摘要翻译：一种制备脂肪酸钙盐的方法，其包括以下步骤：（a）提供具有约30至约60重量％之间的甘油酯含量的脂肪酸原料;（b）将原料从约2至约3当量的氧化钙，从而形成反应性混合物; 和（c）相对于氧化钙加入约2至约5当量水的活性混合物，使得氧化钙水合并中和脂肪酸形成钙盐。还公开了含有二十碳五烯酸和十二碳六烯酸的脂肪酸钙盐以及增强反刍动物生育力的方法。

3. 发明授权

US06576667B2 Method for manufacturing fatty acid calcium salts from high glyceride content oils 有权
标题翻译：从高甘油酯含量油制造脂肪酸钙盐的方法
公开(公告)号：US06576667B2
公开(公告)日：2003-06-10
申请号：US09990784
申请日：2001-11-14
申请人： George K. Strohmaier , Eiler D. Frederiksen , Nestor Daniel Luchini
发明人： George K. Strohmaier , Eiler D. Frederiksen , Nestor Daniel Luchini
IPC分类号： A01N3700
CPC分类号： C11C1/045 , A23K10/14 , A23K10/22 , A23K20/158 , A23K20/24 , A23K40/10 , A23K50/10 , C11C1/025
摘要： A method for the preparation of fatty acid calcium salts, which includes the steps of: (a) providing a fatty acid feedstock having a glyceride content between about 30 and about 60% by weight; (b) adding to the feedstock from about 2 to about 3 equivalents of calcium oxide relative to the feedstock, so that a reactive admixture is formed; and (c) adding to the reactive admixture from about 2 to about 5 equivalents of water relative to the calcium oxide so that the calcium oxide hydrates and neutralizes the fatty acids to form calcium salts. Fatty acid calcium salts containing eicosapentaenoic acid and docosahexaenoic acid are also disclosed, as well as methods for enhancing ruminant fertility.
摘要翻译：一种制备脂肪酸钙盐的方法，其包括以下步骤：（a）提供具有约30至约60重量％之间的甘油酯含量的脂肪酸原料;（b）将原料从约2至约3当量的氧化钙，从而形成反应性混合物; 和（c）相对于氧化钙加入约2至约5当量水的活性混合物，使得氧化钙水合并中和脂肪酸形成钙盐。还公开了含有二十碳五烯酸和二十二碳六烯酸的脂肪酸钙盐以及增强反刍动物生育力的方法。

4. 发明授权

US5709903A Reduced fat confectionery products and process 失效
公开(公告)号：US5709903A
公开(公告)日：1998-01-20
申请号：US509529
申请日：1995-07-31
申请人： James F. St. John , John G. Fetterhoff , John R. Carpenter , B. Douglas Brown , C. Daniel Azzara , Stanley M. Tarka, Jr. , Craig Rank , George K. Strohmaier
发明人： James F. St. John , John G. Fetterhoff , John R. Carpenter , B. Douglas Brown , C. Daniel Azzara , Stanley M. Tarka, Jr. , Craig Rank , George K. Strohmaier
IPC分类号： A23G1/30 , A23D9/00 , A23G1/00 , A23G1/04 , A23G1/36 , A23G1/40 , A23L33/20 , A23G3/00
CPC分类号： A23G1/40 , A23G1/047 , A23G1/36 , Y10S426/804
摘要： The present invention relates to a lowfat confection comprising a chocolate of full fat texture, said chocolate comprising a fat or fat substitute present in 20.0-24.5% (w/w), and nonfat solids comprising nutritive carbohydrate sweetener, nonfat cocoa solids and an edible emulsifier. The present invention further relates to a process for producing a lowfat chocolate and more specifically, to the process of preparing and formulating said product compositions.

5. 发明申请

US20110039932A1 POLYUNSATURATED FATTY ACID MONOVALENT AND DIVALENT METAL SALT SYNTHESIS 失效
标题翻译：聚脂肪酸单一和多金属盐合成
公开(公告)号：US20110039932A1
公开(公告)日：2011-02-17
申请号：US12912668
申请日：2010-10-26
申请人： Daniel Nestor Luchini , George K. Strohmaier , Eiler D. Frederiksen , James G. Hawkes , Bob J. Dull
发明人： Daniel Nestor Luchini , George K. Strohmaier , Eiler D. Frederiksen , James G. Hawkes , Bob J. Dull
IPC分类号： A61K31/202 , C07F1/08 , C07F3/06 , C07C27/02 , C07C57/03 , A61P15/08
CPC分类号： C11C1/00 , A23D9/00 , A23K20/158 , A23K20/24 , A23K50/40 , A23L33/12 , Y10S426/807
摘要： Methods for the preparation of a free-flowing, storage-stable fatty acid metal salt product by forming a reactive admixture of (a) an unsaturated fatty acid glyceride feedstock; and (b) from about 1 mol to about 3 mol of at least one monovalent metal hydroxide or at least one divalent metal hydroxide; and heating the admixture to a temperature at which said fatty acid glycerides saponify to form fatty acid metals salts; wherein said monovalent metal is potassium; and wherein said divalent metal is selected from the group consisting of calcium, copper, magnesium and zinc. The fatty acid glycerides are saponified in an atmosphere in which the partial pressure of oxygen has been reduced by an amount effective to provide an improvement in storage stability until a free-flowing, storage-stage product is obtained. Storage stable metal salts of unsaturated fatty acids prepared by the inventive methods are also disclosed.
摘要翻译：通过形成（a）不饱和脂肪酸甘油酯原料的反应性混合物来制备自由流动的储存稳定的脂肪酸金属盐产物的方法; 和（b）约1mol至约3mol的至少一种一价金属氢氧化物或至少一种二价金属氢氧化物; 并将所述混合物加热至所述脂肪酸甘油酯皂化以形成脂肪酸金属盐的温度; 其中所述一价金属是钾; 并且其中所述二价金属选自钙，铜，镁和锌。脂肪酸甘油酯在氧气分压降低的气氛中皂化，从而提供储存稳定性的有效量，直到得到自由流动的储存阶段产物。还公开了通过本发明方法制备的不稳定的不饱和脂肪酸的储存稳定金属盐。

6. 发明授权

US08278354B2 Method for increasing ruminant fertility 失效
标题翻译：增加反刍动物生殖力的方法
公开(公告)号：US08278354B2
公开(公告)日：2012-10-02
申请号：US10915644
申请日：2004-08-10
申请人： George K. Strohmaier , Eiler D. Frederiksen , Nestor Daniel Luchini
发明人： George K. Strohmaier , Eiler D. Frederiksen , Nestor Daniel Luchini
IPC分类号： A61K31/202 , A01N37/00
CPC分类号： C11C1/045 , A23K10/14 , A23K10/22 , A23K20/158 , A23K20/24 , A23K40/10 , A23K50/10 , C11C1/025
摘要： Methods for reducing the likelihood of embryonic death in a female ruminant by feeding the ruminant for at least 30 days after conception an effective amount of free-flowing fatty acid calcium salt product comprising from about 1 to 10% by weight of eicosapentaenoic acid (EPA) and from about 1 to about 10% by weight of decosahexaenoic acid (DHA).
摘要翻译：通过在受孕后至少30天喂食反刍动物来降低雌性反刍动物胚胎死亡的可能性的方法，包含约1-10重量％的二十碳五烯酸（EPA）的有效量的自由流动的脂肪酸钙盐产品，和约1至约10重量％的十二碳六烯酸（DHA）。

7. 发明授权

US07098352B2 Calcium salt saponification of polyunsaturated oils 失效
标题翻译：多不饱和油的钙盐皂化
公开(公告)号：US07098352B2
公开(公告)日：2006-08-29
申请号：US10716292
申请日：2003-11-18
申请人： George K. Strohmaier , Nestor D. Luchini , Michael A. Varcho , Eiler D. Frederiksen
发明人： George K. Strohmaier , Nestor D. Luchini , Michael A. Varcho , Eiler D. Frederiksen
IPC分类号： C07C51/00
CPC分类号： C07C57/03 , C07C53/126 , Y10S426/807
摘要： Methods for the preparation of storage-stable fatty acid calcium salt products by forming a reactive admixture of (a) an unsaturated fatty acid glyceride feedstock; and (b) from about 10% to about 30% of the total admixture weight of calcium hydroxide; and heating the admixture to a temperature at which the fatty acid glycerides saponify to form fatty acid calcium salts in an atmosphere in which the partial pressure of oxygen has been reduced by an amount effective to provide an improvement in storage stability. Storage stable calcium salts of unsaturated fatty acids prepared by the inventive method are also disclosed.
摘要翻译：通过形成（a）不饱和脂肪酸甘油酯原料的反应性混合物来制备储存稳定的脂肪酸钙盐产物的方法; 和（b）氢氧化钙的总混合物重量的约10％至约30％; 并将该混合物加热到在氧气分压降低了有效提高储存稳定性的量的气氛中皂化脂肪酸甘油酯以形成脂肪酸钙盐的温度。还公开了通过本发明方法制备的不稳定的不饱和脂肪酸钙盐。

8. 发明授权

US07820842B2 Polyunsaturated fatty acid monovalent and divalent metal salt synthesis 有权
标题翻译：多不饱和脂肪酸一价和二价金属盐合成
公开(公告)号：US07820842B2
公开(公告)日：2010-10-26
申请号：US10598681
申请日：2005-04-29
申请人： Daniel Nestor Luchini , George K. Strohmaier , Eiler D. Frederiksen , James G. Hawkes , Bob J. Dull
发明人： Daniel Nestor Luchini , George K. Strohmaier , Eiler D. Frederiksen , James G. Hawkes , Bob J. Dull
IPC分类号： C07C51/00
CPC分类号： C11C1/00 , A23D9/00 , A23K20/158 , A23K20/24 , A23K50/40 , A23L33/12 , Y10S426/807
摘要： Disclosed herein are methods for the preparation of a free-flowing, storage-stable fatty acid metal salt product by forming a reactive admixture comprising (a) an unsaturated fatty acid glyceride feedstock; and (b) from about 1 mol to about 3 mol of at least one monovalent metal hydroxide or at least one divalent metal hydroxide; and heating the admixture to a temperature at which said fatty acid glycerides saponify to form fatty acid metals salts; wherein said monovalent metal is potassium; and wherein said divalent metal is selected from the group consisting of calcium, copper, magnesium and zinc. The fatty acid glycerides may be saponified in an atmosphere in which the partial pressure of oxygen has been reduced by an amount effective to provide an improvement in storage stability until a free-flowing, storage-stage product is obtained, or prior to saponification, the fatty acid glycerides may blended with a stabilizing oil that promotes storage stability, or both. Storage stable metal salts of unsaturated fatty acids prepared by the inventive methods are also disclosed.
摘要翻译：本文公开了通过形成包含（a）不饱和脂肪酸甘油酯原料的反应性混合物来制备自由流动的储存稳定的脂肪酸金属盐产物的方法; 和（b）约1mol至约3mol的至少一种一价金属氢氧化物或至少一种二价金属氢氧化物; 并将所述混合物加热至所述脂肪酸甘油酯皂化以形成脂肪酸金属盐的温度; 其中所述一价金属是钾; 并且其中所述二价金属选自钙，铜，镁和锌。脂肪酸甘油酯可以在氧气分压降低的气氛中被皂化，以有效提高储存稳定性，直到获得自由流动的储存阶段产物，或在皂化之前，脂肪酸甘油酯可以与促进保存稳定性的稳定油或两者混合。还公开了通过本发明方法制备的不稳定的不饱和脂肪酸的储存稳定金属盐。

9. 发明授权

US06392075B1 Method for manufacturing calcium salts of highly unsaturated fatty acids 有权
标题翻译：高度不饱和脂肪酸钙盐的制造方法
公开(公告)号：US06392075B1
公开(公告)日：2002-05-21
申请号：US09675745
申请日：2000-09-29
申请人： George K. Strohmaier , Eiler D. Fredericksen
发明人： George K. Strohmaier , Eiler D. Fredericksen
IPC分类号： C07C5100
CPC分类号： C07C51/412 , Y10S426/807 , C07C53/126 , C07C57/12 , C07C57/03
摘要： A method for the preparation of free-flowing calcium salts of highly unsaturated fatty acids, which includes the steps of: (a) providing a fatty acid feedstock consisting essentially of: (i) from about 50 to about 95% by weight of unsaturated C:16-C:22 fatty acids; (ii) from about 5 to about 40% by weight of saturated C:14-C:22 fatty acids; and (iii) no more than about 6% by weight of moisture, insolubles and unsaponifiables, with no more than about 20% by weight of the unsaturated feedstock being in the form of glycerides; (b) adding to the unsaturated feedstock from about 1.0 to about 2.5 equivalents of calcium oxide relative to the unsaturated feedstock, so that a reactive admixture is formed; and (c) adding to the reactive admixture from about 2 to about 5 equivalents of water relative to the calcium oxide, so that the calcium oxide hydrates and neutralizes the fatty acids to form the calcium salts; provided that when less than 1.75 equivalents of calcium oxide is added, the unsaturated feedstock comprises at least 25% by weight of the saturated fatty acids and is heated to a temperature above its melting point before the step of adding the calcium oxide. Highly unsaturated fatty acid calcium salts prepared by this method are also disclosed.
摘要翻译：一种用于制备高度不饱和脂肪酸的自由流动钙盐的方法，其包括以下步骤：（a）提供脂肪酸原料，其基本上由以下组成：（i）约50至约95重量％的不饱和C ：16-C：22脂肪酸;（ii）约5至约40重量％的饱和C：14-C：22脂肪酸; 和（iii）不超过约6重量％的水分，不溶物和不皂化物，不超过约20重量％的不饱和原料为甘油酯形式;（b）将不饱和原料从约1.0 至约2.5当量的氧化钙，从而形成反应性混合物; 和（c）相对于氧化钙将约2至约5当量的水相加到活性混合物中，使得氧化钙水合并中和脂肪酸以形成钙盐;条件是当小于1.75当量的钙氧化物，不饱和原料包含至少25重量％的饱和脂肪酸，并在加入氧化钙步骤之前加热至高于其熔点的温度。还公开了通过该方法制备的高度不饱和脂肪酸钙盐。

10. 发明授权

US06229031B1 Method for manufacturing rumen bypass feed supplements 有权
标题翻译：制造瘤胃旁路饲料补充剂的方法
公开(公告)号：US06229031B1
公开(公告)日：2001-05-08
申请号：US09349662
申请日：1999-07-08
申请人： George K Strohmaier , Eiler D. Frederiksen
发明人： George K Strohmaier , Eiler D. Frederiksen
IPC分类号： C07C5100
CPC分类号： C07C51/09 , A23K20/142 , A23K20/158 , A23K40/35 , A23K50/10 , C07C53/126 , C07C57/12
摘要： A method for the preparation of fatty acid calcium salt products in which an admixture is formed of reactive ingredients consisting of (a) a C10-C22 fatty acid mixture having greater than about 45 weight% of the C10-C22 fatty acid content in the form of fatty acid glycerides, and (b) from about 10 to about 30% of the total admixture weight of calcium oxide. Water is then added to the admixture in an amount between about 10% and about 100% by weight relative to the amount of calcium oxide; and the admixture is then heated to a temperature at which the fatty acid glycerides saponify to form fatty acid calcium salts. Rumen bypass feed supplements are also disclosed, as well as ruminant feeds containing the feed supplements and processes for supplying the feed supplements to ruminant animals.
摘要翻译：一种制备脂肪酸钙盐产品的方法，其中混合物由以下组成的反应成分形成：（a）具有大于约45重量％的C 10 -C 22脂肪酸含量的C 10 -C 22脂肪酸混合物，其形式为的脂肪酸甘油酯，和（b）占氧化钙总混合物重量的约10至约30％。然后将水相对于氧化钙的量以约10重量％至约100重量％的量加入混合物中; 然后将混合物加热至脂肪酸甘油酯皂化形成脂肪酸钙盐的温度。还公开了瘤胃旁路饲料补充剂，以及含有饲料补充剂的反刍动物饲料和向反刍动物供应饲料补充剂的方法。

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