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    • 2. 发明授权
    • Polyunsaturated fatty acid monovalent and divalent metal salt synthesis
    • 多不饱和脂肪酸一价和二价金属盐合成
    • US07820842B2
    • 2010-10-26
    • US10598681
    • 2005-04-29
    • Daniel Nestor LuchiniGeorge K. StrohmaierEiler D. FrederiksenJames G. HawkesBob J. Dull
    • Daniel Nestor LuchiniGeorge K. StrohmaierEiler D. FrederiksenJames G. HawkesBob J. Dull
    • C07C51/00
    • C11C1/00A23D9/00A23K20/158A23K20/24A23K50/40A23L33/12Y10S426/807
    • Disclosed herein are methods for the preparation of a free-flowing, storage-stable fatty acid metal salt product by forming a reactive admixture comprising (a) an unsaturated fatty acid glyceride feedstock; and (b) from about 1 mol to about 3 mol of at least one monovalent metal hydroxide or at least one divalent metal hydroxide; and heating the admixture to a temperature at which said fatty acid glycerides saponify to form fatty acid metals salts; wherein said monovalent metal is potassium; and wherein said divalent metal is selected from the group consisting of calcium, copper, magnesium and zinc. The fatty acid glycerides may be saponified in an atmosphere in which the partial pressure of oxygen has been reduced by an amount effective to provide an improvement in storage stability until a free-flowing, storage-stage product is obtained, or prior to saponification, the fatty acid glycerides may blended with a stabilizing oil that promotes storage stability, or both. Storage stable metal salts of unsaturated fatty acids prepared by the inventive methods are also disclosed.
    • 本文公开了通过形成包含(a)不饱和脂肪酸甘油酯原料的反应性混合物来制备自由流动的储存稳定的脂肪酸金属盐产物的方法; 和(b)约1mol至约3mol的至少一种一价金属氢氧化物或至少一种二价金属氢氧化物; 并将所述混合物加热至所述脂肪酸甘油酯皂化以形成脂肪酸金属盐的温度; 其中所述一价金属是钾; 并且其中所述二价金属选自钙,铜,镁和锌。 脂肪酸甘油酯可以在氧气分压降低的气氛中被皂化,以有效提高储存稳定性,直到获得自由流动的储存阶段产物,或在皂化之前, 脂肪酸甘油酯可以与促进保存稳定性的稳定油或两者混合。 还公开了通过本发明方法制备的不稳定的不饱和脂肪酸的储存稳定金属盐。
    • 10. 发明授权
    • Method for manufacturing rumen bypass feed supplements
    • 制造瘤胃旁路饲料补充剂的方法
    • US06229031B1
    • 2001-05-08
    • US09349662
    • 1999-07-08
    • George K StrohmaierEiler D. Frederiksen
    • George K StrohmaierEiler D. Frederiksen
    • C07C5100
    • C07C51/09A23K20/142A23K20/158A23K40/35A23K50/10C07C53/126C07C57/12
    • A method for the preparation of fatty acid calcium salt products in which an admixture is formed of reactive ingredients consisting of (a) a C10-C22 fatty acid mixture having greater than about 45 weight% of the C10-C22 fatty acid content in the form of fatty acid glycerides, and (b) from about 10 to about 30% of the total admixture weight of calcium oxide. Water is then added to the admixture in an amount between about 10% and about 100% by weight relative to the amount of calcium oxide; and the admixture is then heated to a temperature at which the fatty acid glycerides saponify to form fatty acid calcium salts. Rumen bypass feed supplements are also disclosed, as well as ruminant feeds containing the feed supplements and processes for supplying the feed supplements to ruminant animals.
    • 一种制备脂肪酸钙盐产品的方法,其中混合物由以下组成的反应成分形成:(a)具有大于约45重量%的C 10 -C 22脂肪酸含量的C 10 -C 22脂肪酸混合物,其形式为 的脂肪酸甘油酯,和(b)占氧化钙总混合物重量的约10至约30%。 然后将水相对于氧化钙的量以约10重量%至约100重量%的量加入混合物中; 然后将混合物加热至脂肪酸甘油酯皂化形成脂肪酸钙盐的温度。 还公开了瘤胃旁路饲料补充剂,以及含有饲料补充剂的反刍动物饲料和向反刍动物供应饲料补充剂的方法。