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1. 发明授权

US09556384B2 Method for extracting biochemical products obtained from a process of hydrothermal carbonization of biomass 有权
标题翻译：从生物质热水碳化过程中提取生化产物的方法
公开(公告)号：US09556384B2
公开(公告)日：2017-01-31
申请号：US14114818
申请日：2011-12-22
申请人： Martin Hitzl , Michael Renz , Avelino Corma Canos
发明人： Martin Hitzl , Michael Renz , Avelino Corma Canos
IPC分类号： C10G1/00 , C10G1/02 , C10L9/08
CPC分类号： C10G1/002 , C10G1/008 , C10G1/02 , C10G2300/1011 , C10L9/086 , C10L2290/54 , Y02E50/13 , Y02P30/20
摘要： The invention relates to a method for extracting biochemical products obtained from a process of hydrothermal carbonization of biomass, which includes feeding an aqueous mixture of biomass from a preheating tube for the aqueous mixture of biomass to a vertical reactor with a predetermined level of floatation and an area for accumulation of steam and gases in the upper part thereof, wherein said method for extracting biochemical products is characterized in that it includes (a) heating the aqueous mixture of biomass to, or above, evaporation temperature in said vertical reactor and/or in a previous stage of preheating the aqueous mixture of biomass, increasing the generation of stream and/or gases at the predetermined flotation level of the vertical reactor, (b) extracting the steam and/or gases generated in the previous stage and accumulated in the upper part of the vertical reactor, and (c) cooling the gases and/or condensing the steam extracted in the previous stage at different levels of temperature and pressure. The invention likewise relates to the biochemical product obtainable from said method, as well as to a system for implementing said method.
摘要翻译：本发明涉及一种从生物质水热碳化过程中提取生物化学产品的方法，其包括将生物质的水混合物从用于生物质的含水混合物的预热管中提供至具有预定水平浮选的垂直反应器，其中所述用于提取生物化学产物的方法的特征在于其包括（a）将所述生物质的水混合物加热至或高于所述垂直反应器中的蒸发温度和/或在预热生物质水混合物的先前阶段，在垂直反应器的预定浮选水平增加流和/或气体的产生，（b）提取先前阶段产生的并积聚在上层的蒸汽和/或气体垂直反应器的一部分，和（c）在不同的水平下冷却气体和/或冷凝在前一阶段提取的蒸汽 ls的温度和压力。本发明同样涉及可从所述方法获得的生物化学产品，以及用于实施所述方法的系统。

2. 发明授权

US08633338B2 Production of myrtanal from beta-pinene epoxide 有权
标题翻译：从β-蒎烯环氧化物生产米尔那那
公开(公告)号：US08633338B2
公开(公告)日：2014-01-21
申请号：US13517403
申请日：2010-12-17
申请人： Avelino Corma Canós , Michael Renz , Olalla De La Torre Alfaro
发明人： Avelino Corma Canós , Michael Renz , Olalla De La Torre Alfaro
IPC分类号： C07C45/58
CPC分类号： B01J29/7615 , B01J29/7057 , B01J29/7815 , B01J35/002 , C01B39/02 , C07C45/58 , C07C47/347
摘要： The present invention refers to a process for the production of myrtanal from β-pinene epoxide that comprises at least of putting this epoxide in contact with a microporous and crystalline catalyst with pores of a diameter of at least 0.52 nm with an empirical formula for the calcinated and dehydrated form of Hw(MwTixSnyZrzSi1-w-x-y-z)O2 where M is at least a metal with valence+3 selected from Al, B, Ga, Fe, Cr and combinations of these; w is a molar fraction of M with a value of between 0 and 2(x+y+z); x is a molar fraction of titanium and has a value of between 0 and 0.06; y is a molar fraction of tin and has a value of between 0 and 0.06; z is a molar fraction of zirconium and has a value of between 0 and 0.06; and where at least one of the three values “x”, “y” or “z” is different from zero. In the present invention, the microporous and crystalline catalyst preferably has pores of at least 0.52 nm and has a crystalline structure with an X-ray diffractogram of a zeolite beta.
摘要翻译：本发明涉及一种由β-蒎烯环氧化物制备米糠醛的方法，该方法至少包括使该环氧化物与具有至少0.52nm直径的孔的微孔和结晶催化剂接触，其煅烧的经验式和Hw（MwTixSnyZrzSi1-wxyz）O2的脱水形式，其中M至少为选自Al，B，Ga，Fe，Cr的价数+3的金属及其组合; w是0至2（x + y + z）之间的M的摩尔分数; x是钛的摩尔分数，其值在0和0.06之间; y是锡的摩尔分数，其值在0和0.06之间; z是锆的摩尔分数，其值在0和0.06之间; 并且三个值“x”，“y”或“z”中的至少一个与零不同。在本发明中，微孔和结晶催化剂优选具有至少0.52nm的孔，并具有具有β沸石的X射线衍射图的晶体结构。

3. 发明申请

US20080234510A1 Method of Obtaining Polyoxygenated Organic Compounds 审中-公开
标题翻译：获得多氧化有机化合物的方法
公开(公告)号：US20080234510A1
公开(公告)日：2008-09-25
申请号：US11628953
申请日：2005-06-09
申请人： Avelino Corma Canos , Marcelo Eduardo Domine , Michael Renz
发明人： Avelino Corma Canos , Marcelo Eduardo Domine , Michael Renz
IPC分类号： C07C69/66 , C07C43/30
CPC分类号： C07C68/00 , C07C69/96
摘要： The invention relates to a method of obtaining polyoxygenated organic compounds. The inventive method is characterized in that it comprises the oxidation reaction of a diether, preferably an acetal, with an oxygen source, in the presence of: one or more radical initiating agents, one or more additives that generate a basic reaction medium, and one or more catalysts.
摘要翻译：本发明涉及获得聚氧化有机化合物的方法。本发明的方法的特征在于，它包括二醚，优选缩醛与氧源的氧化反应，存在下：一种或多种自由基引发剂，一种或多种产生碱性反应介质的添加剂和一种或更多的催化剂。

4. 发明授权

US06617299B1 Composition and method for bleaching a substrate 失效
标题翻译：用于漂白基材的组合物和方法
公开(公告)号：US06617299B1
公开(公告)日：2003-09-09
申请号：US09539756
申请日：2000-03-31
申请人： Riccardo Filippo Carina , Bernard Lucas Feringa , Ronald Hage , Catherine Hemmert , Jean Hypolites Koek , Rene Marcel LaCrois , Bernard Meunier , Michael Renz , Johannes Gerhardus Roelfes , Ebe Pieter Schudde , Rob Thijssen , Robin Stefan Twisker , Charon Zondervan
发明人： Riccardo Filippo Carina , Bernard Lucas Feringa , Ronald Hage , Catherine Hemmert , Jean Hypolites Koek , Rene Marcel LaCrois , Bernard Meunier , Michael Renz , Johannes Gerhardus Roelfes , Ebe Pieter Schudde , Rob Thijssen , Robin Stefan Twisker , Charon Zondervan
IPC分类号： C11D3395
CPC分类号： C07D401/14 , C07D213/38 , C07D213/55 , C11D3/3932 , D06L4/12 , D06L4/13 , D06L4/15
摘要： The invention relates to catalytically bleaching substrates, especially laundry fabrics, with atmospheric oxygen or air. A method of bleaching a substrate is provided that comprises applying to the substrate, in an aqueous medium, a specified ligand from a selected class which forms a complex with a transition metal, the complex catalysing bleaching of the substrate by atmospheric oxygen. Also provided is an aqueous bleaching composition substantially devoid of peroxygen bleach or a peroxy-based or -generating bleach system. Also provided is a method of treating a textile such as a laundry fabric whereby a complex catalyses bleaching of the textile by atmospheric oxygen after the treatment. The catalyst may be used in dry form, or in a liquor that is then dried, such as an aqueous spray-on fabric treatment fluid or a wash liquor for laundry cleaning, or a non-aqueous dry cleaning fluid or spray-on aerosol fluid. The method can confer cleaning benefits to the textile after the treatment. Also provided is a dry textile having a catalyst applied or deposited thereon, whereby bleaching by atmospheric oxygen is catalysed on the textile.
摘要翻译：本发明涉及用大气中的氧气或空气催化漂洗底物，特别是洗衣织物。提供了一种漂白底物的方法，其包括在水性介质中向所述底物施加与过渡金属形成络合物的所选类别的特定配体，所述复合物通过大气氧催化底物的漂白。还提供了基本上不含过氧漂白剂或过氧基或生成漂白体系的水性漂白组合物。还提供了一种处理织物如洗衣布的方法，由此复合物在处理后通过大气氧催化织物的漂白。催化剂可以以干式形式使用，也可以在随后干燥的液体中使用，例如水性喷涂织物处理流体或用于衣物清洗的洗涤液，或非水性干洗液或喷雾气溶胶流体。该方法可以在处理后赋予纺织品清洁效果。还提供了具有施加或沉积在其上的催化剂的干织物，由此通过大气氧气漂白在织物上被催化。

5. 发明授权

US09199955B2 Production of liquid fuels (sylvan-liquid-fuels) from 2-methylfuran 有权
标题翻译：从2-甲基呋喃生产液体燃料（乙醇 - 液体燃料）
公开(公告)号：US09199955B2
公开(公告)日：2015-12-01
申请号：US13491910
申请日：2012-06-08
申请人： Avelino Corma Canós , Michael Renz , Olalla De La Torre Alfaro
发明人： Avelino Corma Canós , Michael Renz , Olalla De La Torre Alfaro
IPC分类号： C10G1/00 , C07C27/00 , C10L1/00 , C07D307/38 , C10G3/00
CPC分类号： C07D307/38 , C10G3/42 , C10G3/45 , C10G3/47 , C10G3/50 , Y02P30/20
摘要： The present invention describes a procedure for the production of liquid fuel having a content high in alkanes and low in oxygenated compounds, comprising as a minimum: a first step of alkylation of 2-methylfuran (commonly denominated Sylvan) with a furan alcohol 2 having the formula: (2), wherein R1 is H or an aliphatic or aromatic or heteroaromatic moiety, R2 is H or an aliphatic or aromatic or heteroaromatic moiety, and R3 is H, hydroxymethyl or an aliphatic or aromatic or heteroaromatic moiety, in the presence of a catalyst, a second step of hydrogenation and dehydration of the compound obtained in step 1 in the presence of hydrogen, utilizing suitable hydrogenation and dehydration catalysts.
摘要翻译：本发明描述了生产具有高烷烃含量和低氧化合物含量低的液体燃料的方法，该方法至少包括：将呋喃醇2与2-甲基呋喃（通常称为Sylvan）烷基化的第一步骤式（2）其中R 1为H或脂族或芳族或杂芳族部分，R 2为H或脂族或芳族或杂芳族部分，且R 3为H，羟甲基或脂族或芳族或杂芳族部分，催化剂，在氢存在下，使用合适的氢化和脱水催化剂氢化和脱水步骤1中获得的化合物的第二步骤。

6. 发明申请

US20140142353A1 METHOD FOR EXTRACTING BIOCHEMICAL PRODUCTS OBTAINED FROM A PROCESS OF HYDROTHERMAL CARBONIZATION OF BIOMASS 有权
标题翻译：从生物质热水碳酸化过程中提取生物化学产品的方法
公开(公告)号：US20140142353A1
公开(公告)日：2014-05-22
申请号：US14114818
申请日：2011-12-22
申请人： Martin Hitzl , Michael Renz , Avelino Corma Canos
发明人： Martin Hitzl , Michael Renz , Avelino Corma Canos
IPC分类号： C10G1/00
CPC分类号： C10G1/002 , C10G1/008 , C10G1/02 , C10G2300/1011 , C10L9/086 , C10L2290/54 , Y02E50/13 , Y02P30/20
摘要： The invention relates to a method for extracting biochemical products obtained from a process of hydrothermal carbonization of biomass, which includes feeding an aqueous mixture of biomass from a preheating tube for the aqueous mixture of biomass to a vertical reactor with a predetermined level of floatation and an area for accumulation of steam and gases in the upper part thereof, wherein said method for extracting biochemical products is characterized in that it includes (a) heating the aqueous mixture of biomass to, or above, evaporation temperature in said vertical reactor and/or in a previous stage of preheating the aqueous mixture of biomass, increasing the generation of stream and/or gases at the predetermined flotation level of the vertical reactor, (b) extracting the steam and/or gases generated in the previous stage and accumulated in the upper part of the vertical reactor, and (c) cooling the gases and/or condensing the steam extracted in the previous stage at different levels of temperature and pressure. The invention likewise relates to the biochemical product obtainable from said method, as well as to a system for implementing said method.
摘要翻译：本发明涉及一种从生物质水热碳化过程中提取生物化学产品的方法，其包括将生物质的水混合物从用于生物质的含水混合物的预热管中提供至具有预定水平浮选的垂直反应器，其中所述用于提取生物化学产物的方法的特征在于其包括（a）将所述生物质的水混合物加热至或高于所述垂直反应器中的蒸发温度和/或在预热生物质水混合物的先前阶段，在垂直反应器的预定浮选水平增加流和/或气体的产生，（b）提取先前阶段产生的并积聚在上层的蒸汽和/或气体垂直反应器的一部分，和（c）在不同的水平下冷却气体和/或冷凝在前一阶段提取的蒸汽 ls的温度和压力。本发明同样涉及可从所述方法获得的生物化学产品，以及用于实施所述方法的系统。

7. 发明申请

US20120316372A1 PRODUCTION OF LIQUID FUELS (SYLVAN-LIQUID-FUELS) FROM 2-METHYLFURAN 有权
标题翻译：二甲苯的液体燃料（SYLVAN-LIQUID-FUELS）的生产
公开(公告)号：US20120316372A1
公开(公告)日：2012-12-13
申请号：US13491910
申请日：2012-06-08
申请人： Avelino CORMA CANÓS , Michael RENZ , Olalla DE LA TORRE ALFARO
发明人： Avelino CORMA CANÓS , Michael RENZ , Olalla DE LA TORRE ALFARO
IPC分类号： C07C1/247
CPC分类号： C07D307/38 , C10G3/42 , C10G3/45 , C10G3/47 , C10G3/50 , Y02P30/20
摘要： The present invention describes a procedure for the production of liquid fuel having a content high in alkanes and low in oxygenated compounds, comprising as a minimum: —a first step of alkylation of 2-methylfuran (commonly denominated Sylvan) with a furan alcohol 2 having the formula: (2), wherein R1 is H or an aliphatic or aromatic or heteroaromatic moiety, R2 is H or an aliphatic or aromatic or heteroaromatic moiety, and R3 is H, hydroxymethyl or an aliphatic or aromatic or heteroaromatic moiety, in the presence of a catalyst, —a second step of hydrogenation and dehydration of the compound obtained in step 1 in the presence of hydrogen, utilising suitable hydrogenation and dehydration catalysts.
摘要翻译：本发明描述了一种制备具有高烷烃含量和低氧化合物含量低的液体燃料的方法，其至少包括： - 第一步是将2-甲基呋喃（通常称为Sylvan）烷基化，其中呋喃醇2具有式（2）其中R 1为H或脂族或芳族或杂芳族部分，R 2为H或脂族或芳族或杂芳族部分，R 3为H，羟甲基或脂族或芳族或杂芳族部分，的催化剂， - 在氢的存在下，利用合适的氢化和脱水催化剂，在步骤1中获得的化合物氢化和脱水的第二步骤。

8. 发明授权

US07087779B2 Aldehyde conversion method using a molecular sieve and the use of the molecular sieve as a catalyst in said method 失效
标题翻译：使用分子筛的醛转化方法和在所述方法中使用分子筛作为催化剂
公开(公告)号：US07087779B2
公开(公告)日：2006-08-08
申请号：US10932564
申请日：2004-09-02
申请人： Avelino Corma Canos , María Mifsud Grau , Sara Iborra Chornet , Michael Renz
发明人： Avelino Corma Canos , María Mifsud Grau , Sara Iborra Chornet , Michael Renz
IPC分类号： C07D331/02 , C07D301/12 , C07C69/76
CPC分类号： C07C51/285 , B01J29/0308 , B01J29/035 , B01J29/04 , B01J29/7057 , C01B37/005 , C01B39/085 , C07C51/235 , C07C67/39 , C07C63/04 , C07C65/21 , C07C69/017 , C07C69/08 , C07C69/10
摘要： The invention relates to an aldehyde conversion method comprising putting an aldehyde into contact with oxygenated water and with a catalyst, under oxidation conditions, wherein the catalyst is a molecular sieve with pores of a diameter of at least 0.52 nm and has an empirical formula in a calcined and dehydrated form of (SnxTiySi1-x-y-zGez)O2 wherein x is a molar fraction of the tin and has a value between 0.001 and 0.1; y is a molar fraction of titanium and has a value from zero to 0.1; and z is the molar fraction molar of the germanium and has a value from zero to 0.08.
摘要翻译：本发明涉及醛转化方法，其包括在氧化条件下将醛与含氧水和催化剂接触，其中催化剂是直径为至少0.52nm的孔的分子筛，并且具有经验式煅烧和脱水形式的<？in-line-formula description =“In-line Formulas”end =“lead”？（Sn x x Ti x Si x Si α-in-line-formula description =“In-line Formulas”end =“tail”？>其中x（x，y）是锡的摩尔分数，其值在0.001和0.1之间; y是钛的摩尔分数，其值为0至0.1; z是锗的摩尔分数摩尔，其值为零至0.08。

9. 发明授权

US06344583B1 Oxidation of ketones to esters using a tin substituted zeolite beta 有权
标题翻译：使用锡取代沸石β将酮氧化成酯
公开(公告)号：US06344583B1
公开(公告)日：2002-02-05
申请号：US09557302
申请日：2000-04-25
申请人： Avelino Corma Canos , Laszlo T. Nemeth , Michael Renz , Jaime G. Moscoso
发明人： Avelino Corma Canos , Laszlo T. Nemeth , Michael Renz , Jaime G. Moscoso
IPC分类号： C07C6902
CPC分类号： C07D315/00 , C07D309/30
摘要： Applicants have developed a process for the oxidation of ketones to esters. The process involves contacting the ketone with hydrogen peroxide and a catalyst at oxidation conditions. The catalyst is a molecular sieve represented by the empirical formula: (MwSnxTiySi1−x−y−zGez)O2 where M is a trivalent metal such as aluminum or boron. These molecular sieves have a microporous three dimensional framework structure of at least SiO2 and SnO2 tetrahedral units, a crystallographically regular pore system and the characteristic x-ray diffraction pattern of zeolite beta.
摘要翻译：申请人已经开发了将酮氧化成酯的方法。该方法包括在氧化条件下使酮与过氧化氢和催化剂接触。催化剂是由经验式表示的分子筛：其中M是三价金属如铝或硼。这些分子筛具有至少SiO 2和SnO 2四面体单元的微孔三维骨架结构，晶体学规则孔系统和β沸石的特征X射线衍射图。

10. 发明授权

US08573323B2 Hand-held power tool 有权
标题翻译：手持电动工具
公开(公告)号：US08573323B2
公开(公告)日：2013-11-05
申请号：US13074079
申请日：2011-03-29
申请人： Matthias Müller , Heiko Roβkamp , Gernot Liebhard , Michael Renz
发明人： Matthias Müller , Heiko Roβkamp , Gernot Liebhard , Michael Renz
IPC分类号： H02K7/14
CPC分类号： A01D34/902 , A01G3/06 , B25F5/008 , B25F5/02
摘要： A hand-held power tool has a tool member and a motor drivingly connected to the tool member, wherein the motor is arranged in a motor housing. A battery for driving the tool member is provided. A guide shaft has arranged on its first end the battery and on its second end the motor housing and the tool member. A rotatably power output part arranged on the motor housing is drivingly connected to the motor. The power output part supports the tool member. Cooling air is sucked through the guide shaft into the motor housing. Between the power output part and the motor housing an annular air exit gap is formed through which the cooling air exits the motor housing. At least one guide vane that projects into the annular air exit gap is provided.
摘要翻译：手持电动工具具有工具构件和驱动地连接到工具构件的电动机，其中电动机布置在电动机壳体中。提供用于驱动工具构件的电池。引导轴在其第一端上布置有电池，并且在其第二端上布置有电动机壳体和工具构件。布置在马达壳体上的可旋转动力输出部分驱动地连接到马达。电源输出部分支持工具部件。冷却空气通过导向轴吸入电动机壳体。在动力输出部分和马达壳体之间形成环形空气出口间隙，冷却空气通过该空气出口间隙离开马达壳体。提供突出到环形空气出口间隙中的至少一个导向叶片。

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