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1. 发明申请

US20120330065A1 PRODUCTION OF MYRTANAL FROM BETA-PINENE EPOXIDE 有权
标题翻译：由环戊二烯环氧化物生产木质素
公开(公告)号：US20120330065A1
公开(公告)日：2012-12-27
申请号：US13517403
申请日：2010-12-17
申请人： Avelino Corma Canós , Michael Renz , Olalla De La Torre Alfaro
发明人： Avelino Corma Canós , Michael Renz , Olalla De La Torre Alfaro
IPC分类号： C07C45/58
CPC分类号： B01J29/7615 , B01J29/7057 , B01J29/7815 , B01J35/002 , C01B39/02 , C07C45/58 , C07C47/347
摘要： The present invention refers to a process for the production of myrtanal from β-pinene epoxide that comprises at least of putting this epoxide in contact with a microporous and crystalline catalyst with pores of a diameter of at least 0.52 nm with an empirical formula for the calcinated and dehydrated form of Hw(MwTixSnyZrzSi1-w-x-y-z)O2 where M is at least a metal with valence+3 selected from Al, B, Ga, Fe, Cr and combinations of these; w is a molar fraction of M with a value of between 0 and 2(x+y+z); x is a molar fraction of titanium and has a value of between 0 and 0.06; y is a molar fraction of tin and has a value of between 0 and 0.06; z is a molar fraction of zirconium and has a value of between 0 and 0.06; and where at least one of the three values “x”, “y” or “z” is different from zero. In the present invention, the microporous and crystalline catalyst preferably has pores of at least 0.52 nm and has a crystalline structure with an X-ray diffractogram of a zeolite beta.
摘要翻译：本发明涉及一种从环氧丙烷生产木药的方法，该方法至少包括使该环氧化物与直径为至少0.52nm的孔的微孔和结晶催化剂接触，其经验公式为煅烧和脱水形式的Hw（MwTixSnyZrzSi1-wxyz）O2，其中M至少为选自Al，B，Ga，Fe，Cr的价数+3的金属及其组合; w是0至2（x + y + z）之间的M的摩尔分数; x是钛的摩尔分数，其值在0和0.06之间; y是锡的摩尔分数，其值在0和0.06之间; z是锆的摩尔分数，其值在0和0.06之间; 并且其中三个值x，y或z中的至少一个不同于零。在本发明中，微孔和结晶催化剂优选具有至少0.52nm的孔，并具有具有β沸石的X射线衍射图的晶体结构。

2. 发明授权

US08633338B2 Production of myrtanal from beta-pinene epoxide 有权
标题翻译：从β-蒎烯环氧化物生产米尔那那
公开(公告)号：US08633338B2
公开(公告)日：2014-01-21
申请号：US13517403
申请日：2010-12-17
申请人： Avelino Corma Canós , Michael Renz , Olalla De La Torre Alfaro
发明人： Avelino Corma Canós , Michael Renz , Olalla De La Torre Alfaro
IPC分类号： C07C45/58
CPC分类号： B01J29/7615 , B01J29/7057 , B01J29/7815 , B01J35/002 , C01B39/02 , C07C45/58 , C07C47/347
摘要： The present invention refers to a process for the production of myrtanal from β-pinene epoxide that comprises at least of putting this epoxide in contact with a microporous and crystalline catalyst with pores of a diameter of at least 0.52 nm with an empirical formula for the calcinated and dehydrated form of Hw(MwTixSnyZrzSi1-w-x-y-z)O2 where M is at least a metal with valence+3 selected from Al, B, Ga, Fe, Cr and combinations of these; w is a molar fraction of M with a value of between 0 and 2(x+y+z); x is a molar fraction of titanium and has a value of between 0 and 0.06; y is a molar fraction of tin and has a value of between 0 and 0.06; z is a molar fraction of zirconium and has a value of between 0 and 0.06; and where at least one of the three values “x”, “y” or “z” is different from zero. In the present invention, the microporous and crystalline catalyst preferably has pores of at least 0.52 nm and has a crystalline structure with an X-ray diffractogram of a zeolite beta.
摘要翻译：本发明涉及一种由β-蒎烯环氧化物制备米糠醛的方法，该方法至少包括使该环氧化物与具有至少0.52nm直径的孔的微孔和结晶催化剂接触，其煅烧的经验式和Hw（MwTixSnyZrzSi1-wxyz）O2的脱水形式，其中M至少为选自Al，B，Ga，Fe，Cr的价数+3的金属及其组合; w是0至2（x + y + z）之间的M的摩尔分数; x是钛的摩尔分数，其值在0和0.06之间; y是锡的摩尔分数，其值在0和0.06之间; z是锆的摩尔分数，其值在0和0.06之间; 并且三个值“x”，“y”或“z”中的至少一个与零不同。在本发明中，微孔和结晶催化剂优选具有至少0.52nm的孔，并具有具有β沸石的X射线衍射图的晶体结构。

3. 发明授权

US09199955B2 Production of liquid fuels (sylvan-liquid-fuels) from 2-methylfuran 有权
标题翻译：从2-甲基呋喃生产液体燃料（乙醇 - 液体燃料）
公开(公告)号：US09199955B2
公开(公告)日：2015-12-01
申请号：US13491910
申请日：2012-06-08
申请人： Avelino Corma Canós , Michael Renz , Olalla De La Torre Alfaro
发明人： Avelino Corma Canós , Michael Renz , Olalla De La Torre Alfaro
IPC分类号： C10G1/00 , C07C27/00 , C10L1/00 , C07D307/38 , C10G3/00
CPC分类号： C07D307/38 , C10G3/42 , C10G3/45 , C10G3/47 , C10G3/50 , Y02P30/20
摘要： The present invention describes a procedure for the production of liquid fuel having a content high in alkanes and low in oxygenated compounds, comprising as a minimum: a first step of alkylation of 2-methylfuran (commonly denominated Sylvan) with a furan alcohol 2 having the formula: (2), wherein R1 is H or an aliphatic or aromatic or heteroaromatic moiety, R2 is H or an aliphatic or aromatic or heteroaromatic moiety, and R3 is H, hydroxymethyl or an aliphatic or aromatic or heteroaromatic moiety, in the presence of a catalyst, a second step of hydrogenation and dehydration of the compound obtained in step 1 in the presence of hydrogen, utilizing suitable hydrogenation and dehydration catalysts.
摘要翻译：本发明描述了生产具有高烷烃含量和低氧化合物含量低的液体燃料的方法，该方法至少包括：将呋喃醇2与2-甲基呋喃（通常称为Sylvan）烷基化的第一步骤式（2）其中R 1为H或脂族或芳族或杂芳族部分，R 2为H或脂族或芳族或杂芳族部分，且R 3为H，羟甲基或脂族或芳族或杂芳族部分，催化剂，在氢存在下，使用合适的氢化和脱水催化剂氢化和脱水步骤1中获得的化合物的第二步骤。

4. 发明授权

US09561498B2 Process for the direct synthesis of Cu-SAPO-34 有权
标题翻译：直接合成Cu-SAPO-34的方法
公开(公告)号：US09561498B2
公开(公告)日：2017-02-07
申请号：US14395872
申请日：2012-04-27
申请人： Raquel Martinez Franco , Manuel Moliner Marin , Avelino Corma Canós , Arkady Kustov , Joakim Reimer Thøgersen
发明人： Raquel Martinez Franco , Manuel Moliner Marin , Avelino Corma Canós , Arkady Kustov , Joakim Reimer Thøgersen
IPC分类号： C01B39/54 , B01J29/85 , C01B37/08 , B01D53/86 , B01J37/08
CPC分类号： B01J29/85 , B01D53/8628 , B01D2255/50 , B01D2257/404 , B01J37/08 , B01J2229/183 , C01B37/08 , C01B39/54
摘要： A process for the direct synthesis of Cu-SAPO-34 comprising at least the steps: preparation of a mixture of water, at least one silicon source, at least one Al source, at least one P source, at least one Cu source, at least one 0SDA1 (any polyamine), and at least one OSDA2 source (where OSDA2 is any organic molecule capable of directing the synthesis of SAPO 34); and where the final synthesis mixture has the molar composition: a Si:0.5 Al:c Cu:d OSDA1:e OSDA2:f H2O wherein a is in the range from 0.01 to 0.3; b is in the range from 0.2 to 0.49; c is in the range from 0.001 to 0.6; d is in the range from 0.001 to 0.6; e is in the range from 0.001 to 2; f is in the range 1 to 200; hydrothermal treatment of the mixture at 80−200° C. until formation of the crystalline material, and recovery of the crystalline material.
摘要翻译：一种用于直接合成Cu-SAPO-34的方法，至少包括以下步骤：制备水，至少一种硅源，至少一种Al源，至少一种P源，至少一种Cu源，至少一个0SDA1（任何多胺）和至少一个OSDA2源（其中OSDA2是能够指导SAPO 34的合成的任何有机分子）; 并且其中最终合成混合物具有以下摩尔组成：Si：0.5 Al：c Cu：d OSDA1：e OSDA2：fH2O，其中a在0.01至0.3的范围内; b在0.2〜0.49的范围内; c在0.001至0.6的范围内; d在0.001至0.6的范围内; e在0.001至2的范围内; f在1到200的范围内; 在80-200℃下对混合物进行水热处理，直到形成结晶材料，并回收结晶材料。

5. 发明授权

US08765993B2 One-pot production of carbamates using solid catalysts 失效
标题翻译：使用固体催化剂单罐生产氨基甲酸酯
公开(公告)号：US08765993B2
公开(公告)日：2014-07-01
申请号：US13228815
申请日：2011-09-09
申请人： Avelino Corma Canós , Hermenegildo GarcíGómez , Raquel Juarez Marín
发明人： Avelino Corma Canós , Hermenegildo GarcíGómez , Raquel Juarez Marín
IPC分类号： C07C271/06
CPC分类号： C07C269/00 , B01J23/63 , B01J23/66 , B01J23/83 , B01J35/006 , C07C271/20 , C07C271/28
摘要： The invention relates to the production of carbamates in a single reactor (one-pot) using solid catalysts, involving the reaction between at least one nitro compound, an organic carbonate of formula (OR)(OR′)C═O, a gas selected from hydrogen gas and a mixture of gases containing hydrogen and hydrogen precursor compounds, and a catalyst that has at least one metallic oxide and can also contain an element of groups 8, 9, 10 and 11 of the periodical table. The carbonates obtained can be transformed into their corresponding isocyanates.
摘要翻译：本发明涉及使用固体催化剂在单个反应器（一锅）中生产氨基甲酸酯，涉及至少一种硝基化合物，式（OR）（OR'）C = O的有机碳酸酯，选择的气体来自氢气和含有氢和氢前体化合物的气体混合物，以及具有至少一种金属氧化物并且还可以含有周期表第8,9,10和11族元素的催化剂。得到的碳酸酯可以转化成它们相应的异氰酸酯。

6. 发明授权

US07371318B2 Method and catalysts for the elimination of sulphur compounds from the diesel fraction 失效
$Method and catalysts for the elimination of sulphur compounds from the diesel fraction$
标题翻译：从柴油馏分中消除硫化合物的方法和催化剂
公开(公告)号：US07371318B2
公开(公告)日：2008-05-13
申请号：US10683557
申请日：2003-10-10
申请人： Avelino Corma Canós , Marcelo Eduardo Domine , Cristina Martinez Sánchez
发明人： Avelino Corma Canós , Marcelo Eduardo Domine , Cristina Martinez Sánchez
IPC分类号： C10G27/04 , C10G27/10
CPC分类号： B01J21/063 , B01J21/06 , B01J21/08 , B01J29/89 , B01J37/0209 , B01J2229/32 , C10G27/04 , C10G2400/04
摘要： The invention relates to a process for the elimination of sulphur compounds from the diesel fraction, which is characterized in that an oxidising reaction of said sulphur compound is carried out by using at least an organic-inorganic composite as catalyst, said composite comprising Si, Ti; and silicon bonded to carbon, and organic and inorganic hydroperoxides as oxidizing agents. According to the inventive process, said organic-inorganic composite can be obtained by a method comprising a post-synthesis silylation step.
摘要翻译：本发明涉及一种从柴油馏分中除去硫化合物的方法，其特征在于，使用至少一种有机 - 无机复合物作为催化剂进行所述硫化合物的氧化反应，所述复合物包括Si，Ti ; 和与碳结合的硅，以及有机和无机氢过氧化物作为氧化剂。根据本发明的方法，所述有机 - 无机复合物可以通过包括后合成甲硅烷基化步骤的方法获得。

7. 发明授权

US07344696B2 Porous crystalline material (zeolite ITQ-24), preparation method thereof and use of same in the catalytic conversion of organic compounds 有权
标题翻译：多孔结晶材料（沸石ITQ-24），其制备方法及其在有机化合物的催化转化中的应用
公开(公告)号：US07344696B2
公开(公告)日：2008-03-18
申请号：US11200534
申请日：2005-08-09
申请人： Avelino Corma Canós , Rafael Castañeda Sánchez , Vicente Fornés Seguí , Fernando Rey García
发明人： Avelino Corma Canós , Rafael Castañeda Sánchez , Vicente Fornés Seguí , Fernando Rey García
IPC分类号： C01B39/46 , C01B39/48 , B01J29/06 , B01J29/064 , B01J29/068 , B01J29/70 , B01J29/72 , B01J29/74 , B01J29/76
CPC分类号： C01B39/085 , C01B39/06 , C01B39/12 , C10G11/05 , C10G2300/1088 , C10G2300/1096 , C10G2400/30
摘要： The invention relates to a porous crystalline material (ITQ-24), the preparation method thereof and the use of same in the catalytic conversion of organic compounds. More specifically, the invention relates to a synthetic porous crystalline material which is characterised in that it is formed by tetrahedrally coordinated atoms which are interconnected by means of oxygens. Said material, which comprises a unit cell containing 56 tetrahedrally coordinated atoms, is known as ITQ-24. Moreover, in the calcined anhydrous state, the material has chemical formula nM1/pXO2: YO2, wherein: X is at least one trivalent element, Y is at least one tetravalent element, n is between 0 and 0.2 and M is at least one charge compensation cation in oxidation state p.
摘要翻译：本发明涉及多孔结晶材料（ITQ-24），其制备方法及其在有机化合物的催化转化中的用途。更具体地说，本发明涉及一种合成多孔结晶材料，其特征在于它由四面体配位的原子形成，这些原子通过氧相互连接。所述材料包括含有56个四面体配位原子的晶胞，称为ITQ-24。此外，在煅烧无水状态下，该材料具有化学式nM 1 / p XO 2：YO 2 N，其中：X至少为一个三价元素，Y是至少一种四价元素，n在0和0.2之间，M是氧化态p中的至少一种电荷补偿阳离子。

8. 发明授权

US07014836B2 Synthesis of ITQ-17 in the absence of fluoride ions 失效
标题翻译：在没有氟离子的情况下合成ITQ-17
公开(公告)号：US07014836B2
公开(公告)日：2006-03-21
申请号：US10750329
申请日：2003-12-31
申请人： Avelino Corma Canós , Fernando Rey García , María Teresa Navarro Villalba , Susana Valencia Valencia
发明人： Avelino Corma Canós , Fernando Rey García , María Teresa Navarro Villalba , Susana Valencia Valencia
IPC分类号： C01B39/48
CPC分类号： B01J29/70 , B01J29/035 , B01J29/04 , C01B37/005 , C01B39/06 , Y10S423/27
摘要： The present invention refers to a crystalline material that does not contain fluorides, with a composition in a roasted state corresponding to that of the material called ITQ-17 and that has a composition on an anhydrous base and in terms of oxide moles upon being synthesized, unroasted, represented by: xX2O3:(1−z)YO2:zGeO2:r/nRnO wherein: X is at least one trivalent element, Y is one or more tetravalent elements other than germanium, R is an organic structure directing compound, preferably the cation 1-methyl-4-aza,1-azoniumbicyclo[2.2.2]octane (DABMe+) or the cation 1,4-bis[N-(4-aza,1-azoniumbicyclo[2.2.2]octane)methyl]benzene (d-DABBz)+2 x varies between 0 and 0.02, z is comprised between 0.02 and 0.67, r varies between 0.01 and 0.5, and n is 1 or 2. It also refers to a process for synthesizing said material, as well as to the material obtained by said process and subjected to a step of post-synthesis to eliminate the organic component from its structure.
摘要翻译：本发明涉及不含氟化物的结晶材料，其组成为与称为ITQ-17的材料相当的焙烧状态，其组成为无水碱和合成后的氧化物摩尔数，未加工的，由以下代表：<？in-line-formula description =“In-line Formulas”end =“lead”？> xX 2 3（1-z ）YO 2：zGeO 2：r / n R n +2X在0和0.02之间变化，z在0.02和0.67之间，r在0.01和0.5之间变化，n是1或2.它也是指sy 使所述材料固化，以及通过所述方法获得的材料，并进行后合成步骤以从其结构中除去有机组分。

9. 发明授权

US06716784B2 Catalytic cracking materials based on ITQ-7 zeolites and their use in hydrocarbons cracking processes 失效
标题翻译：基于ITQ-7沸石的催化裂化材料及其在烃裂解过程中的应用
公开(公告)号：US06716784B2
公开(公告)日：2004-04-06
申请号：US10252955
申请日：2002-09-23
申请人： Avelino Corma Canós , María Diaz Caba{overscore (n)}as , Joaquín Martinez Triguero
发明人： Avelino Corma Canós , María Diaz Caba{overscore (n)}as , Joaquín Martinez Triguero
IPC分类号： B01J2906
CPC分类号： B01J29/80 , B01J29/084 , B01J29/70 , C10G11/05
摘要： Catalytic compositions are described for hydrocarbons cracking containing at least two zeolitic components of which at least one zeolitic component containing aluminium in its structure is selected from among ITQ-7 zeolites, intergrowths of ITQ-7 zeolites, ITQ-7 zeolites exchanged with rare earths, intergrowths of ITQ-7 zeolites exchanged with rare earths, and combinations of them. These combinations are of utility as catalysts for cracking in FCC units and permit C3 and C4 olefins to be efficiently obtained along with high yields of gasoline. Also described is the use of a zeolitic material containing aluminium in its structure and selected from among ITQ-7 zeolites, intergrowths of ITQ-7 zeolites, ITQ-7 zeolites exchanged with rare earths, intergrowths of ITQ-7 zeolites exchanged with rare earths, and combinations of them, as a catalytic material in hydrocarbon catalytic cracking processes.
摘要翻译：描述了含有至少两种沸石组分的催化组合物，其中至少一种在其结构中含有铝的沸石组分选自ITQ-7沸石，ITQ-7沸石的共生体，与稀土交换的ITQ-7沸石，与稀土交换的ITQ-7沸石的共同生长，以及它们的组合。这些组合可用作FCC单元中的裂化催化剂，并允许有效地获得C3和C4烯烃以及高产率的汽油。还描述了在其结构中使用含有铝的沸石材料，并且选自ITQ-7沸石，ITQ-7沸石的共生体，与稀土交换的ITQ-7沸石，与稀土交换的ITQ-7沸石的共生体，以及它们的组合，作为烃催化裂化过程中的催化材料。

10. 发明授权

US06696033B2 Microporous acidic oxide with catalytic properties ITQ-18 有权
标题翻译：具有催化性能的ITQ-18微孔酸性氧化物
公开(公告)号：US06696033B2
公开(公告)日：2004-02-24
申请号：US10047938
申请日：2002-01-15
申请人： Avelino Corma Canós , Vicente Fornes Segui , Urbano Díaz Morales
发明人： Avelino Corma Canós , Vicente Fornes Segui , Urbano Díaz Morales
IPC分类号： C01B3326
CPC分类号： C01B39/48 , B01J29/04 , B01J29/049 , B01J29/70 , C01B33/38
摘要： The invention concerns a microporous crystalline material, with a characteristic X-ray diffractogram, made up by oxygen tetrahedra and one metal (T+4 and T+3) with the possibility of introducing surface acidity produced by the substitution in the network of some T+4 cations (normally Si+4) by T+3 cations (normally Al+3), which gives rise to a structural charge deficiency which can be offset by protons, Brönsted acidity, and/or cations with a high charge-radium ratio, Lewis acidity. The method of preparation is based on the modification of the laminar structure of a mixed oxide (normally SiO2, Al2O3) synthesized from a gel treated under controlled hydrothermal conditions, intercalating organic molecules with a proton-acceptor group and a long hydrocarbonic chain between its laminae. The intercalated material has laminae with a significant separation between them due to the presence between them of the organic chains. The swollen material is then treated in order to separate and disperse the laminae. The final washing and subsequent calcination gives rise to a microporous material with a high external surface, the object of this invention.
摘要翻译：本发明涉及一种微孔结晶材料，具有由氧四面体和一种金属（T +4和T +3）组成的特征X射线衍射图，其可能性是引入由该取代产生的表面酸度一些T +4阳离子（通常为Si +4）的网络由T +3阳离子（通常为Al +3）引起，这导致结构电荷缺陷，这可被质子抵消，布朗斯台德酸度，和/或具有高电荷 - 镭比的阳离子，路易斯酸度。制备方法是基于在受控的水热条件下处理的凝胶合成的混合氧化物（通常为SiO 2，Al 2 O 3）的层状结构的修改，在有机分子与质子受体基团之间插入长的烃链。插层材料由于它们之间的有机链的存在而具有它们之间显着分离的层。然后处理膨胀的材料以分离和分散薄片。本发明的目的是最后的洗涤和随后的煅烧产生具有高外表面的微孔材料。

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