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    • 2. 发明申请
    • Method for producing 1-butene
    • 1-丁烯的制备方法
    • US20070055088A1
    • 2007-03-08
    • US10595551
    • 2004-10-27
    • Götz-Peter SchindlerAndreas BrodhagenThorsten JohanThomas HillMarcus SiglRegina Benfer
    • Götz-Peter SchindlerAndreas BrodhagenThorsten JohanThomas HillMarcus SiglRegina Benfer
    • C07C4/00
    • C07C5/333C07C5/05C07C5/2506C07C7/08C07C11/08
    • A) Provision of an n-butane-containing feed gas stream a; B) introduction of the n-butane-containing feed gas stream a into at least one dehydrogenation zone and nonoxidative catalytic dehydrogenation of n-butane to give a product gas stream b comprising n-butane, 1-butene, 2-butene, butadiene, hydrogen, low-boiling secondary constituents and possibly water vapor; C) removal of hydrogen, the low-boiling secondary constituents and, if appropriate, water vapor to give a C4 product gas stream c consisting essentially of n-butane, 1-butene, 2-butene and butadiene; D) separation of the C4 product gas stream c into a recycle stream d1 consisting essentially of n-butane and a stream d2 comprising 1-butene, 2-butene and butadiene by extractive distillation and recirculation of the recycle stream d1 consisting essentially of n-butane to the dehydrogenation zone; E) introduction of the stream d2 comprising 1-butene, 2-butene and butadiene into a selective hydrogenation zone and selective hydrogenation of butadiene to 1-butene and/or 2-butene to give a stream e comprising 1-butene and 2-butene; F) introduction of the stream e comprising 1-butene and 2-butene and a circulating stream g comprising 1-butene and 2-butene into a distillation zone and isolation of a desired product stream f1 consisting essentially of 1-butene to leave a 2-butene-containing stream f2; G) introduction of the 2-butene-containing stream f2, if appropriate after a purge gas stream has been separated off, into an isomerization zone and isomerization of 2-butene to 1-butene so as to give a circulating stream g comprising 1-butene and 2-butene and recirculation, if appropriate after a purge gas stream has been separated off from the circulating gas stream g, of the circulating gas stream g to the distillation zone.
    • A)提供含正丁烷的进料气流a; B)将含正丁烷的原料气流a引入至少一个脱氢区和正丁烷的非氧化催化脱氢,得到包含正丁烷,1-丁烯,2-丁烯,丁二烯, 氢,低沸点二级成分和可能的水蒸气; C)除去氢气,低沸点二级成分,如果合适的话,除去水蒸气,得到基本上由正丁烷,1-丁烯,2-丁烯组成的C 4 H 4产物气流c, 丁二烯 D)将C 4 H 4产物气流c分离成基本上由正丁烷组成的再循环料流d1和包含1-丁烯,2-丁烯和丁二烯的料流d2,通过萃取蒸馏和再循环 基本上由正丁烷组成的再循环流d1到脱氢区; E)将包含1-丁烯,2-丁烯和丁二烯的料流d2引入选择性氢化区并将丁二烯选择性氢化为1-丁烯和/或2-丁烯,得到包含1-丁烯和2-丁烯的料流e ; F)将包含1-丁烯和2-丁烯的流e和包含1-丁烯和2-丁烯的循环流g引入蒸馏区并分离基本上由1-丁烯组成的所需产物流f1以留下2 含丁烯的流f2; G)引入含有2-丁烯的料流f2,如果在吹扫气体流已经分离出之后适当,将其引入异构化区域并将2-丁烯异构化成1-丁烯,从而得到包含1-丁烯的循环流g, 丁烯和2-丁烯,并且如果适当,在将循环气流g从循环气流g分离出吹扫气流之后再循环到蒸馏区。
    • 5. 发明申请
    • Method for producing alkylaryl compounds
    • 烷基芳基化合物的制备方法
    • US20070142258A1
    • 2007-06-21
    • US10583140
    • 2004-12-17
    • Ulrich SteinbrennerThomas HeidemannMichael RoperJurgen StephanThomas NarbeshuberJurgen TropschNils BottkeRegina Benfer
    • Ulrich SteinbrennerThomas HeidemannMichael RoperJurgen StephanThomas NarbeshuberJurgen TropschNils BottkeRegina Benfer
    • C09D9/00
    • C07C6/04C07C2/08C07C2/66C07C5/2506C07C303/06C11D1/22C11D11/04C07C309/31C07C11/02C07C11/10C07C15/107
    • The preparation of alkylaryl compounds takes place by a) reaction of a C4/C5-olefin mixture over a metathesis catalyst to prepare a C4-8-olefin mixture comprising 2-pentene, and optional removal of the C4-8-olefin mixture, b) removal of from 5 to 100% of the 2-pentene present in stage a) and subsequent reaction over an isomerization catalyst to give a mixture of 2-pentene and 1-pentene which is returned to stage a), c) dimerization of the C4-8-olefin mixture obtained in stage b) following removal in the presence of a dimerization catalyst to give a mixture containing C8-16-olefins, removal of these C8-16-olefins and optional removal of a partial stream thereof, d) reaction of the c8-16-olefin mixtures obtained in stage c) or of the partial stream with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds where, prior to the reaction, 0 to 60% by weight, based on the c8-16-olefin mixtures obtained in stage c), of linear olefins may additionally be added, e) optional sulfonation of the alkyl aromatic compounds obtained in stage d) and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, 0 to 60% by weight, based on the alkyl aromatic compounds obtained in stage d), of linear alkylbenzenes may additionally be added if no admixing has taken place in stage d), f) optional mixing of the alkylarylsulfonates obtained in stage e) with 0 to 60% by weight, based on the alkylarylsulfonates obtained in stage e), of linear alkylarylsulfonate, if no admixing has taken place in stages d) and e).
    • 烷基芳基化合物的制备通过以下步骤进行:a)在复分解催化剂上使C 4-14 C 5 -C 5 - 烯烃混合物反应以制备C 4-8 - 其包含2-戊烯,任选地除去C 4-18α-烯烃混合物,b)除去在步骤a)中存在的5-100%的2-戊烯, 并随后在异构化催化剂上反应,得到2-戊烯和1-戊烯的混合物,将其返回到a)步骤,c)在步骤b中获得的C 4-18α-烯烃混合物的二聚反应 ),在二聚催化剂存在下除去,得到含有C 8-16 - 烯烃的混合物,除去这些C 8-16 - 烯烃并任选地除去 其部分流,d)在烷基化催化剂存在下,将阶段c)或部分流中获得的C 8-16 - α-烯烃混合物与芳族烃反应,形成烷基芳族化合物,其中 在反应之前,0至60重量%,b 在阶段c)中得到的C 8-16α-烯烃混合物中,可以另外加入线性烯烃,e)任选的在步骤d)中获得的烷基芳族化合物磺化,中和得到烷基芳基磺酸盐 ,其中在磺化之前,如果在步骤d)中没有混合,则可以另外加入基于直链烷基苯中得到的直链烷基苯0至60重量%,f)任选混合 如果在阶段d)和e)中没有混合,则在阶段e)中获得的烷基芳基磺酸盐以0至60重量%的量计,基于阶段e)中得到的烷基芳基磺酸盐,为直链烷基芳基磺酸盐。