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1. 发明授权

US07060852B2 Method for producing alkyl aryl sulphonates 失效
标题翻译：烷基芳基磺酸盐的制备方法
公开(公告)号：US07060852B2
公开(公告)日：2006-06-13
申请号：US10343835
申请日：2001-08-10
申请人： Heiko Maas , Thomas Narbeshuber , Michael Roeper
发明人： Heiko Maas , Thomas Narbeshuber , Michael Roeper
IPC分类号： C07C309/31
CPC分类号： C07C303/32 , C07C2/08 , C07C2/66 , C07C6/04 , C07C303/06 , C11D1/22 , C11D11/04 , C07C309/31 , C07C11/02 , C07C11/10 , C07C11/107 , C07C15/107
摘要： The invention relates to a process for the preparation of alkylarylsulfonates by a) reaction of a C4-olefin mixture over a metathesis catalyst for the preparation of an olefin mixture comprising 2-pentene and/or 3-hexene, and optional removal of 2-pentene and/or 3-hexene, b) dimerization of the 2-pentene and/or 3-hexene obtained in stage a) over a dimerization catalyst to give a mixture containing C10-12-olefins, and optional removal of the C10-12-olefins, c) reaction of the C10-12-olefin mixtures obtained in stage b) with an aromatic hydrocarbon in the presence of an alkylating catalyst to form alkylaromatic compounds, where, prior to the reaction, additional linear olefins may be added, d) sulfonation of the alkylaromatic compounds obtained in stage c), and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, linear alkylbenzenes may additionally be added, e) optional mixing of the alkylarylsulfonates obtained in stage d) with linear alkylarylsulfonates.
摘要翻译：本发明涉及一种通过以下方法制备烷基芳基磺酸盐的方法：a）C 4 - 4α-烯烃混合物在复分解催化剂上的反应，用于制备包含2-戊烯和/或3-己烯的烯烃混合物并且任选地除去2-戊烯和/或3-己烯，b）在二级催化剂中在阶段a）中获得的2-戊烯和/或3-己烯的二聚化，得到含有C 10-12 并且任选地除去C 10-12 - 烯烃，c）在步骤b）中获得的C 10-12α-烯烃混合物的反应，在烷基化催化剂存在下用芳族烃形成烷基芳族化合物，其中在反应之前可以加入另外的直链烯烃，d）在步骤c）中获得的烷基芳族化合物的磺化，并中和得到烷基芳基磺酸盐，其中在磺化之前，可以另外加入直链烷基苯，e）任选地将在sta中获得的烷基芳基磺酸盐 ge d）与直链烷基芳基磺酸盐。

2. 发明授权

US06262325B1 Basic catalyst based on titanates, zirconates and hafnates 失效
标题翻译：基于钛酸盐，锆酸盐和铪的基本催化剂
公开(公告)号：US06262325B1
公开(公告)日：2001-07-17
申请号：US09412604
申请日：1999-10-06
申请人： Thomas Narbeshuber , Ulrich Steinbrenner
发明人： Thomas Narbeshuber , Ulrich Steinbrenner
IPC分类号： C07C266
CPC分类号： B01J21/06 , B01J21/063 , B01J21/066 , B01J23/002 , B01J23/02 , B01J23/04 , B01J2523/00 , C07C2/72 , C07C2521/06 , C07C2521/10 , C07C2523/02 , C07C2523/04 , C07C2523/06 , C07C2523/14 , C07C2523/745 , C07C2523/75 , C07C2523/755 , Y10S502/525 , C07C15/00 , B01J2523/23 , B01J2523/48 , B01J2523/47 , B01J2523/22 , B01J2523/25
摘要： The catalyst comprises at least one alkali metal on a support which has the general formula (I) An′Tim′Zrp′Hfq′On′+2(m′+p′+q′) (I) where A is a divalent metal, 20·(m′+p′+q′)>n′>0.05·(m′+p′+q′), and which may be doped with at least one compound of an alkali metal and/or alkaline earth metal, where the alkali metal/support ratio by weight is 0.01-5:1 and, when a dopant is present, the dopant/support ratio by weight is 0.01-5:1, and where the proportion of support phase corresponding to the ZrO2 structure or an alkaline earth metal oxide structure or consisting of ZrO2 or alkaline earth metal oxide is less than 10% by weight. The catalyst is used for the side-chain alkylation or alkenylation of alkylaromatic compounds with olefins or diolefins, for the double-bond isomerization of olefins, for the dimerization of olefins, for the coupling of aromatic nuclei and for the amination of olefins and conjugated diolefins.
摘要翻译：催化剂包含至少一种碱金属，其具有通式（I），其中A是二价金属，20（m'+ p'+ q'）> n'> 0.05（m'+ p'+ q'），并且其可以掺杂有至少一种碱金属和/或碱土金属的化合物，其中碱金属/载体重量比为0.01-5:1，并且当存在掺杂剂时，掺杂剂 /载体重量比为0.01-5:1，其中对应于ZrO 2结构或碱土金属氧化物结构或由ZrO 2或碱土金属氧化物组成的支撑相的比例小于10重量％。催化剂用于烷基芳基化合物与烯烃或二烯烃的侧链烷基化或链烯基化，用于烯烃的双键异构化，用于烯烃的二聚，芳族核的偶联和用于烯烃和共轭二烯烃的胺化。

3. 发明申请

US20070078075A1 Method for producing alkylaryl compounds and alklaryl sulphonates 失效
标题翻译：烷基芳基化合物和烷芳基磺酸盐的制备方法
公开(公告)号：US20070078075A1
公开(公告)日：2007-04-05
申请号：US10577321
申请日：2004-10-29
申请人： Nils Bottke , Regina Benfer , Marco Bosch , Thomas Narbeshuber , Ulrich Steinbrenner , Jurgen Stephan
发明人： Nils Bottke , Regina Benfer , Marco Bosch , Thomas Narbeshuber , Ulrich Steinbrenner , Jurgen Stephan
IPC分类号： C11D17/08 , C07C309/24
CPC分类号： C11D1/22 , C07C2/66 , C07C2529/18 , C07C2529/70 , C07C15/107
摘要： In a process for preparing alkylaryl compounds by reacting a C10-14-monoolefin mixture with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds and if appropriate subsequently sulfonating and neutralizing the resulting alkylaryl compounds, in the C10-14-monoolefins, on average, more than 0% and up to 100% of methyl branches are present in the longest carbon chain and fewer than 50% of the methyl branches are in the 2-, 3- and 4-position, calculated starting from the chain ends of the longest carbon chain.
摘要翻译：在烷基芳基化合物的存在下通过使C 10-14 - 单烯烃混合物与芳族烃反应制备烷基芳基化合物的方法，以形成烷基芳族化合物，并且如果合适，则随后磺化和中和所得的烷基芳基在最长的碳链中存在C 10-14 - 单烯烃中的平均超过0％和高达100％的甲基支链的化合物，少于50％的甲基支链是在2-，3-和4-位，从最长碳链的链端开始计算。

4. 发明申请

US20060241328A1 Method for producing alkyl aromatic compounds 失效
标题翻译：烷基芳族化合物的制备方法
公开(公告)号：US20060241328A1
公开(公告)日：2006-10-26
申请号：US10552434
申请日：2004-04-14
申请人： Ulrich Steinbrenner , Thomas Narbeshuber , Jörg Unger , Peter Zehner , Soeren Zimdahl , Regina Benfer
发明人： Ulrich Steinbrenner , Thomas Narbeshuber , Jörg Unger , Peter Zehner , Soeren Zimdahl , Regina Benfer
IPC分类号： C07C2/64
CPC分类号： C07C303/08 , C07C2/66 , C07C15/107 , C07C303/06 , C07C309/31
摘要： In a process for the preparation of alkylaromatic compounds by reacting C3-30-olefins, or alcohols from which C3-30-olefins are formed under the reaction conditions, with an aromatic hydrocarbon in the presence of an alkylation catalyst, the reaction is carried out in a reactor cascade of at least two reactors, where each of the reactors comprises the alkylation catalyst, at least 80% of the aromatic hydrocarbon are fed into the first reactor of the reactor cascade, and at least 40% of the olefins are intermediately fed in after the first reactor.
摘要翻译：在制备烷基芳族化合物的方法中，通过使C 3-30 - 烯烃或在反应条件下形成C 3-30 - α-烯烃的醇与式在烷基化催化剂存在下的芳族烃，反应在至少两个反应器的反应器级联中进行，其中每个反应器包含烷基化催化剂，将至少80％的芳烃加入第一反应器的反应器级联，并且至少40％的烯烃在第一反应器之后中间进料。

5. 发明授权

US6046130A Catalyst and side-chain alkylation therewith 失效
标题翻译：催化剂和侧链烷基化
公开(公告)号：US6046130A
公开(公告)日：2000-04-04
申请号：US55673
申请日：1998-04-07
申请人： Thomas Narbeshuber , Georg Heinrich Grosch , Michael Trefzer , Eugen Gehrer , Michael Baier
发明人： Thomas Narbeshuber , Georg Heinrich Grosch , Michael Trefzer , Eugen Gehrer , Michael Baier
IPC分类号： B01J23/04 , B01J23/00 , B01J23/02 , B01J23/78 , B01J23/80 , B01J23/835 , B01J23/86 , B01J27/045 , B01J27/051 , B01J27/08 , C07B61/00 , C07C2/66 , C07C2/72 , C07C15/02 , B01J23/40 , B01J23/58 , B01J23/72
CPC分类号： B01J23/02 , B01J23/005 , C07C2/72 , C07C2523/04 , C07C2527/02 , C07C2527/057 , C07C2527/06 , Y10S502/524
摘要： The catalyst comprising at least one alkali metal on a spinel or inverse spinel as carrier may be doped with at least one compound of an alkali metal and/or alkaline earth metal, where the alkali metal/carrier ratio by weight is from 0.01 to 5 and, when a dopant is present, the dopant/carrier ratio by weight is from 0.01 to 5.The spinel therein has formula (I) and the inverse spinel has formula (II)AB.sub.2 X.sub.4 (I)B(AB)X.sub.4 (II)whereA is divalent metal,B is tri- or tetravalent metal,X is O, S, Se, halogen, pseudohalogen,the charges being balanced, and A preferably being selected from Mg, Cr, Fe, Zn, Mn, Co, Ni, Cu, Cd, Sn and mixtures thereof, and B being selected from Al, Ga, In, Fe, V, Cr, Ti, Pb, Mn, Co, Rh, Ni, Si and mixtures thereof, and X being O.
摘要翻译：包含在尖晶石或反尖晶石上的至少一种碱金属作为载体的催化剂可以掺杂有至少一种碱金属和/或碱土金属的化合物，其中碱金属/载体的重量比为0.01-5，和当掺杂剂存在时，掺杂剂/载体的重量比为0.01至5.其中尖晶石具有式（I），并且反尖晶石具有式（II）AB2X4（I）B（AB）X4（II）其中 A是二价金属，B是三价或四价金属，X是O，S，Se，卤素，假卤素，电荷平衡，A优选选自Mg，Cr，Fe，Zn，Mn，Co，Ni， Cu，Cd，Sn及其混合物，B选自Al，Ga，In，Fe，V，Cr，Ti，Pb，Mn，Co，Rh，Ni，Si及其混合物，X为O.

6. 发明授权

US06870014B2 Catalyst and method for producing polytetrahydrofurane 失效
标题翻译：催化剂和生产聚四氢呋喃的方法
公开(公告)号：US06870014B2
公开(公告)日：2005-03-22
申请号：US10312860
申请日：2001-07-02
申请人： Ulrich Steinbrenner , Thomas Narbeshuber , Martin Haubner , Christoph Sigwart , Gerd Linden , Gerhard Cox , Rolf-Hartmuth Fischer , Michael Hesse , Gerd Bohner , Hartmut Hibst , Ekkehard Schwab , Andreas Tenten
发明人： Ulrich Steinbrenner , Thomas Narbeshuber , Martin Haubner , Christoph Sigwart , Gerd Linden , Gerhard Cox , Rolf-Hartmuth Fischer , Michael Hesse , Gerd Bohner , Hartmut Hibst , Ekkehard Schwab , Andreas Tenten
IPC分类号： C08G65/10 , B01J21/06 , B01J23/28 , B01J23/30 , B01J27/188 , B01J35/00 , B01J35/10 , B01J37/00 , C08G65/20 , C08G65/26 , C08F4/06 , B01J23/00 , C08F4/40 , C08F4/42 , C08F124/00
CPC分类号： B01J37/0018 , B01J21/063 , B01J21/066 , B01J23/28 , B01J23/30 , B01J27/188 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , C08G65/20 , C08G65/266 , C08G65/2666 , C08G65/2693
摘要： The invention relates to a catalyst which contains a catalytically active quantity of at least one oxygen-containing molybdenum and/or wolfram compound on an oxidic support material and which has been calcinated at temperatures of 400 to 900° C. after the precursor compound of the catalytically active compounds have been applied to the support material or to a support material precursor. The transport pores for this catalyst each have a diameter of >25 nm and a volume of at least 50 mm3/g. The catalyst contains x μmol (wolfram and/or molybdenum)/m2 molybdenum and/or wolfram, with 10.1
摘要翻译：本发明涉及一种催化剂，其在氧化载体材料上含有至少一种含氧钼和/或钨化合物的催化活性量，并且在400-900℃的温度下煅烧之后，催化活性化合物已经施加到载体材料或载体材料前体上。该催化剂的输送孔各自具有> 25nm的直径和至少50mm 3 / g的体积。该催化剂含有xmumol（钨和/或钼）/ m 2钼和/或钨，相对于成品催化剂为10.1

7. 发明授权

US06384154B1 Preparation of halogen-free, reactive polyisobutene 失效
标题翻译：无卤素，反应性聚异丁烯的制备
公开(公告)号：US06384154B1
公开(公告)日：2002-05-07
申请号：US09744256
申请日：2001-01-31
申请人： Christoph Sigwart , Thomas Narbeshuber , Eugen Gehrer , Rolf Fischer , Ulrich Steinbrenner , Shelue Liang
发明人： Christoph Sigwart , Thomas Narbeshuber , Eugen Gehrer , Rolf Fischer , Ulrich Steinbrenner , Shelue Liang
IPC分类号： C08F11010
CPC分类号： C08F110/10 , C08F2/00 , C08F4/10 , C08F4/26 , C08F4/24 , C08F4/12 , C08F4/06 , C08F4/18 , C08F4/22
摘要： A process for preparing halogen-free, reactive polyisobutene having a terminal double bond content of more than 60 mol % and an average molecular weight Mn of 800-3000 dalton by cationic polymerization in the liquid phase of isobutene over an acidic, essentially halogen-free heterogeneous catalyst, where a) a hydrocarbon mixture of essentially C4-hydrocarbons comprising isobutene in an amount of from 10 to 80% by weight is used as the starting material and b) polymerization is carried out continuously at from −30 to 0° C. with average starting material residence times of one hour or less, where the temperature and the residence time are selected such that the isobutene conversion is less than 60% and, after separation from the resulting polyisobutene, the isobutene is either enriched in the partially converted hydrocarbon mixture and returned to the polymerization or passed to another isobutene reaction coupled with the polymerization.
摘要翻译：一种通过阳离子聚合在异丁烯液相中酸性，基本上不含卤素的方式制备末端双键含量大于60mol％，平均分子量Mn为800-3000道尔顿的无卤素的活性聚异丁烯的方法非均相催化剂，其中将基本上含有10-80重量％异丁烯的C 4烃的烃混合物用作原料，和b）在-30℃至0℃下连续进行聚合，平均起始材料停留时间为1小时或更短，其中选择温度和停留时间使得异丁烯转化率小于60％，并且在从所得聚异丁烯分离后，异丁烯富含部分转化的烃混合物，返回聚合反应或通过与聚合偶联的另一异丁烯反应。

8. 发明授权

US5994562A Preparation of N-alkenylcarboxamides 失效
标题翻译： N-链烯基酰胺的制备
公开(公告)号：US5994562A
公开(公告)日：1999-11-30
申请号：US229996
申请日：1999-01-14
申请人： Klaus Ebel , Matthias Eiermann , Thomas Narbeshuber , Eugen Gehrer
发明人： Klaus Ebel , Matthias Eiermann , Thomas Narbeshuber , Eugen Gehrer
IPC分类号： B01J29/06 , B01J29/08 , B01J29/40 , B01J29/86 , C07B61/00 , C07C231/12 , C07C233/02 , C07D207/26 , C07D207/267 , C07D207/12 , C07C233/18 , C07C235/08
CPC分类号： C07D207/267 , B01J29/061
摘要： In a process for preparing N-alkenylcarboxamides by dehydration of N-(2-hydroxyalkyl)carboxamides and/or diethers thereof in the presence of a catalyst, molecular sieves, in particular zeolites, are used as catalyst.
摘要翻译：在催化剂存在下，通过N-（2-羟基烷基）甲酰胺和/或其醚脱水制备N-链烯基酰胺的方法中，使用分子筛，特别是沸石作为催化剂。

9. 发明授权

US07652183B2 Method for producing alkyl aromatic compounds 失效
标题翻译：烷基芳族化合物的制备方法
公开(公告)号：US07652183B2
公开(公告)日：2010-01-26
申请号：US10552434
申请日：2004-04-14
申请人： Ulrich Steinbrenner , Thomas Narbeshuber , Joerg Unger , Peter Zehner , Soeren Zimdahl , Regina Benfer
发明人： Ulrich Steinbrenner , Thomas Narbeshuber , Joerg Unger , Peter Zehner , Soeren Zimdahl , Regina Benfer
IPC分类号： C07C2/66
CPC分类号： C07C303/08 , C07C2/66 , C07C15/107 , C07C303/06 , C07C309/31
摘要： In a process for the preparation of alkylaromatic compounds by reacting C3-30-olefins, or alcohols from which C3-30-olefins are formed under the reaction conditions, with an aromatic hydrocarbon in the presence of an alkylation catalyst, the reaction is carried out in a reactor cascade of at least two reactors, where each of the reactors comprises the alkylation catalyst, at least 80% of the aromatic hydrocarbon are fed into the first reactor of the reactor cascade, and at least 40% of the olefins are intermediately fed in after the first reactor.
摘要翻译：在烷基芳族化合物的制备方法中，在烷基化催化剂的存在下，使C3-30-烯烃或在反应条件下由C 3-30-烯烃形成的醇与芳烃反应，进行反应在至少两个反应器的反应器级联中，其中每个反应器包含烷基化催化剂，至少80％的芳族烃进料到反应器级联的第一反应器中，并且至少40％的烯烃被中间进料在第一反应堆之后。

10. 发明申请

US20070142258A1 Method for producing alkylaryl compounds 审中-公开
标题翻译：烷基芳基化合物的制备方法
公开(公告)号：US20070142258A1
公开(公告)日：2007-06-21
申请号：US10583140
申请日：2004-12-17
申请人： Ulrich Steinbrenner , Thomas Heidemann , Michael Roper , Jurgen Stephan , Thomas Narbeshuber , Jurgen Tropsch , Nils Bottke , Regina Benfer
发明人： Ulrich Steinbrenner , Thomas Heidemann , Michael Roper , Jurgen Stephan , Thomas Narbeshuber , Jurgen Tropsch , Nils Bottke , Regina Benfer
IPC分类号： C09D9/00
CPC分类号： C07C6/04 , C07C2/08 , C07C2/66 , C07C5/2506 , C07C303/06 , C11D1/22 , C11D11/04 , C07C309/31 , C07C11/02 , C07C11/10 , C07C15/107
摘要： The preparation of alkylaryl compounds takes place by a) reaction of a C4/C5-olefin mixture over a metathesis catalyst to prepare a C4-8-olefin mixture comprising 2-pentene, and optional removal of the C4-8-olefin mixture, b) removal of from 5 to 100% of the 2-pentene present in stage a) and subsequent reaction over an isomerization catalyst to give a mixture of 2-pentene and 1-pentene which is returned to stage a), c) dimerization of the C4-8-olefin mixture obtained in stage b) following removal in the presence of a dimerization catalyst to give a mixture containing C8-16-olefins, removal of these C8-16-olefins and optional removal of a partial stream thereof, d) reaction of the c8-16-olefin mixtures obtained in stage c) or of the partial stream with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds where, prior to the reaction, 0 to 60% by weight, based on the c8-16-olefin mixtures obtained in stage c), of linear olefins may additionally be added, e) optional sulfonation of the alkyl aromatic compounds obtained in stage d) and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, 0 to 60% by weight, based on the alkyl aromatic compounds obtained in stage d), of linear alkylbenzenes may additionally be added if no admixing has taken place in stage d), f) optional mixing of the alkylarylsulfonates obtained in stage e) with 0 to 60% by weight, based on the alkylarylsulfonates obtained in stage e), of linear alkylarylsulfonate, if no admixing has taken place in stages d) and e).
摘要翻译：烷基芳基化合物的制备通过以下步骤进行：a）在复分解催化剂上使C 4-14 C 5 -C 5 - 烯烃混合物反应以制备C 4-8 - 其包含2-戊烯，任选地除去C 4-18α-烯烃混合物，b）除去在步骤a）中存在的5-100％的2-戊烯，并随后在异构化催化剂上反应，得到2-戊烯和1-戊烯的混合物，将其返回到a）步骤，c）在步骤b中获得的C 4-18α-烯烃混合物的二聚反应），在二聚催化剂存在下除去，得到含有C 8-16 - 烯烃的混合物，除去这些C 8-16 - 烯烃并任选地除去其部分流，d）在烷基化催化剂存在下，将阶段c）或部分流中获得的C 8-16 - α-烯烃混合物与芳族烃反应，形成烷基芳族化合物，其中在反应之前，0至60重量％，b 在阶段c）中得到的C 8-16α-烯烃混合物中，可以另外加入线性烯烃，e）任选的在步骤d）中获得的烷基芳族化合物磺化，中和得到烷基芳基磺酸盐，其中在磺化之前，如果在步骤d）中没有混合，则可以另外加入基于直链烷基苯中得到的直链烷基苯0至60重量％，f）任选混合如果在阶段d）和e）中没有混合，则在阶段e）中获得的烷基芳基磺酸盐以0至60重量％的量计，基于阶段e）中得到的烷基芳基磺酸盐，为直链烷基芳基磺酸盐。

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