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1. 发明授权

US10857527B2 Polyoxometalates comprising noble metals and corresponding metal clusters 有权
公开(公告)号：US10857527B2
公开(公告)日：2020-12-08
申请号：US16071049
申请日：2017-01-19
申请人： Ulrich Kortz , Yixian Xiang , Zhengguo Lin , Peng Yang , Helge Jaensch , Wassim W. Ayass
发明人： Ulrich Kortz , Yixian Xiang , Zhengguo Lin , Peng Yang , Helge Jaensch , Wassim W. Ayass
IPC分类号： B01J27/185 , B01J35/10 , C07C5/10 , B01J23/00 , B01J29/03 , C01G55/00 , B01J37/03 , B01J21/08 , B01J35/02 , B01J37/02 , C01B25/45 , B01J35/00
摘要： The invention relates to poly oxometalates represented by the formula (An)m+{M′s[M″M15X10OyRzHq]}m− or solvates thereof, corresponding supported polyoxometalates, and processes for their preparation, as well as corresponding metal-clusters, optionally in the form of a dispersion in a liquid carrier medium or immobilized on a solid support, and processes for their preparation, as well as their use in reductive conversion of organic substrate.

2. 发明授权

US07906686B2 Process for oxidizing alkylaromatic compounds 失效
标题翻译：氧化烷基芳族化合物的方法
公开(公告)号：US07906686B2
公开(公告)日：2011-03-15
申请号：US12532388
申请日：2008-04-07
申请人： Helge Jaensch , Jihad M. Dakka , Francisco M. Benitez , Ulrich Kortz , Ryan Matthew Richards
发明人： Helge Jaensch , Jihad M. Dakka , Francisco M. Benitez , Ulrich Kortz , Ryan Matthew Richards
IPC分类号： C07C45/53 , C07C409/00 , C07C37/00
CPC分类号： C07C409/08 , B01J27/1817 , B01J27/188 , C07C37/06 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/10 , C07C409/14 , C07C2601/14 , Y02P20/52 , C07C49/403 , C07C39/04
摘要： In a process for producing hydroperoxides, an alkylaromatic compound of general formula (I): in which R1 and R2 each independently represents hydrogen or an alkyl group having from 1 to 4 carbon atoms, provided that R1 and R2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, said cyclic group being optionally substituted, and R3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group, is contacted with oxygen in the presence of a catalyst comprising a polyoxometalate to produce a hydroperoxide of general formula (II): in which R1, R2 and R3 have the same meaning as in formula (I) and wherein the polyoxometalate comprises a polyoxotungstate substituted with at least one further transition metal.
摘要翻译：在制备氢过氧化物的方法中，通式（I）的烷基芳族化合物：其中R 1和R 2各自独立地表示氢或具有1至4个碳原子的烷基，条件是R 1和R 2可以连接形成环状具有4至10个碳原子的基团，所述环状基团任选被取代，并且R 3表示氢，具有1至4个碳原子的一个或多个烷基或环己基与氧在催化剂的存在下与产生通式（II）的氢过氧化物：其中R 1，R 2和R 3具有与式（I）中相同的含义，并且其中多金属氧酸盐包括被至少一个其它过渡金属取代的聚氧钨酸酯。

3. 发明授权

US07820868B2 Transition metal substituted polyoxometalates and process for their preparation 失效
标题翻译：过渡金属取代的多金属氧酸盐及其制备方法
公开(公告)号：US07820868B2
公开(公告)日：2010-10-26
申请号：US11655593
申请日：2007-01-19
申请人： Ulrich Kortz , Sib Sankar Mal
发明人： Ulrich Kortz , Sib Sankar Mal
IPC分类号： C07C15/02
CPC分类号： B01J23/002 , B01J23/30 , B01J23/6527 , B01J23/888 , B01J27/188 , B01J2523/00 , C01G41/006 , C01G55/002 , C01P2002/76 , C01P2002/77 , C01P2002/82 , B01J2523/12 , B01J2523/17 , B01J2523/53 , B01J2523/69 , B01J2523/70 , B01J2523/54 , B01J2523/52
摘要： This invention relates to polyoxometalates represented by the formula (An)m+[My(H2O)pXzZ2W18O66]m−1 or solvates thereof, wherein A represents a cation acting as counterion of the polyanion, n is the number of the cations A, m is the charge of the polyoxoanion, M represents a transition metal selected from Cu, Zn, Pd, Pt and mixtures thereof, y is the number of transition metals M and is a number from greater than 4 to less than 6, p is a number of water molecules and is a number from 0 to 10, X is a halide selected from F, Cl, Br, I and mixtures thereof, z is a number of halides and is a number from 0 to 6 and Z represents a heteroatom selected from SbIII, BiIII, AsIII, SeIV and TeIV.
摘要翻译：本发明涉及由式（An）m + [My（H 2 O）p X z Z 2 W 18 O 66] m-1或其溶剂化物表示的多金属氧酸盐，其中A表示作为聚阴离子的抗衡离子的阳离子，n为阳离子A的数量，m为多氧阴离子的电荷，M表示选自Cu，Zn，Pd，Pt及其混合物的过渡金属，y是过渡金属M的数量，并且是大于4至小于6的数，p是水分子，为0〜10的数，X为选自F，Cl，Br，I及其混合物的卤化物，z为数量的卤化物，为0〜6的数，Z为选自SbIII ，BiIII，AsIII，SeIV和TeIV。

4. 发明申请

US20100185016A1 Process for Oxidizing Alkylaromatic Compounds 失效
标题翻译：氧化烷基芳族化合物的方法
公开(公告)号：US20100185016A1
公开(公告)日：2010-07-22
申请号：US12532388
申请日：2008-04-07
申请人： Helge Jaensch , Jihad M. Dakka , Francisco M. Benitez , Ulrich Kortz , Ryan Matthew Richards
发明人： Helge Jaensch , Jihad M. Dakka , Francisco M. Benitez , Ulrich Kortz , Ryan Matthew Richards
IPC分类号： C07C45/00 , C07C409/08
CPC分类号： C07C409/08 , B01J27/1817 , B01J27/188 , C07C37/06 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/10 , C07C409/14 , C07C2601/14 , Y02P20/52 , C07C49/403 , C07C39/04
摘要： In a process for producing hydroperoxides, an alkylaromatic compound of general formula (I): in which R1 and R2 each independently represents hydrogen or an alkyl group having from 1 to 4 carbon atoms, provided that R1 and R2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, said cyclic group being optionally substituted, and R3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group, is contacted with oxygen in the presence of a catalyst comprising a polyoxometalate to produce a hydroperoxide of general formula (II): in which R1, R2 and R3 have the same meaning as in formula (I) and wherein the polyoxometalate comprises a polyoxotungstate substituted with at least one further transition metal.
摘要翻译：在制备氢过氧化物的方法中，通式（I）的烷基芳族化合物：其中R 1和R 2各自独立地表示氢或具有1至4个碳原子的烷基，条件是R 1和R 2可以连接形成环状具有4至10个碳原子的基团，所述环状基团任选被取代，并且R 3表示氢，具有1至4个碳原子的一个或多个烷基或环己基与氧在催化剂的存在下与产生通式（II）的氢过氧化物：其中R 1，R 2和R 3具有与式（I）中相同的含义，并且其中多金属氧酸盐包括被至少一个其它过渡金属取代的聚氧钨酸酯。

5. 发明授权

US07514577B2 Pd- and Pt-substituted polyoxometalates and process for their preparation 失效
标题翻译： Pd-和Pt-取代的多金属氧酸盐及其制备方法
公开(公告)号：US07514577B2
公开(公告)日：2009-04-07
申请号：US11445073
申请日：2006-05-31
申请人： Ulrich Kortz , Lihua Bi
发明人： Ulrich Kortz , Lihua Bi
IPC分类号： C07F17/02 , C01G41/02 , C07C27/00 , B01J23/00
CPC分类号： B01J27/188 , B01J23/42 , B01J23/44 , B01J23/6527 , C01G41/006 , C01G55/002 , C01P2002/76 , C01P2002/77 , C01P2002/82 , C01P2006/10
摘要： The invention relates to polyoxometalates represented by the formula (An)m+ [My(H2O)(p.y)X2W22O74(OH)2]m− or solvates or mixtures thereof, wherein A represents a cation, n is the number of the cations, m is the charge of the polyoxoanion, M represents a transition metal selected from Pd, Pt and mixtures thereof, y is 1, 2, 3 or 4, p is the number of water molecules bound to one M and varies from 3 to 5, and X represents a heteroatom selected from SbIII, BiIII, AsIII, SeIV and TeIV, a process for their preparation and their use for the catalytic oxidation of organic molecules.
摘要翻译：本发明涉及由式（An）m + [My（H 2 O）（py）X2W22O74（OH）2] m - 或溶剂化物或其混合物表示的多金属氧酸盐，其中A表示阳离子，n表示阳离子数，m 是多氧阴离子的电荷，M表示选自Pd，Pt及其混合物的过渡金属，y是1,2,3或4，p是结合到一个M并且从3到5变化的水分子的数量，并且 X表示选自SbIII，BiIII，AsIII，SeIV和TeIV的杂原子，其制备方法及其用于有机分子的催化氧化。

6. 发明申请

US20080177118A1 Novel transition metal substituted polyoxometalates and process for their preparation 失效
标题翻译：新型过渡金属取代多金属氧酸盐及其制备方法
公开(公告)号：US20080177118A1
公开(公告)日：2008-07-24
申请号：US11655593
申请日：2007-01-19
申请人： Ulrich Kortz , Sib Sankar Mal
发明人： Ulrich Kortz , Sib Sankar Mal
IPC分类号： C01G1/02
CPC分类号： B01J23/002 , B01J23/30 , B01J23/6527 , B01J23/888 , B01J27/188 , B01J2523/00 , C01G41/006 , C01G55/002 , C01P2002/76 , C01P2002/77 , C01P2002/82 , B01J2523/12 , B01J2523/17 , B01J2523/53 , B01J2523/69 , B01J2523/70 , B01J2523/54 , B01J2523/52
摘要： This invention relates to polyoxometalates represented by the formula (An)m+[My(H2O)pXzZ2W18O66]m− or solvates thereof, wherein A represents a cation acting as counterion of the polyanion, n is the number of the cations A, m is the charge of the polyoxoanion, M represents a transition metal selected from Cu, Zn, Pd, Pt and mixtures thereof, y is the number of transition metals M and is a number from greater than 4 to less than 6, p is a number of water molecules and is a number from 0 to 10, X is a halide selected from F, Cl, Br, I and mixtures thereof, z is a number of halides and is a number from 0 to 6 and Z represents a heteroatom selected from SbIII, BiIII, AsIII, SeIV and TeIV. This invention also relates to a method to make polyoxometalates represented by the formula (II): (An)m+[My(H2O)pXzZ2W18O66]m− or solvates thereof, where y is the number of transition metals M and is a number from greater than 4 to less than or equal to 6, and A, n, m, M p, X, z, Z, are as defined for formula (I). This invention further relates to a method of oxidizing an organic substrate comprising contacting the organic substrate with polyoxometallates represented by formula (II).
摘要翻译：本发明涉及式（Ⅳ）m ates ates）））））））））））））））））））））））））））））））））））））））））））））））））其中，m为1至5的整数，m为1至5的整数，其中A表示作为聚阴离子的抗衡离子的阳离子，n是阳离子A的数量，m是多氧阴离子的电荷，M表示选自Cu，Zn，Pd， Pt及其混合物，y为过渡金属M的数量，为大于4至小于6的数，p为水分子数，为0〜10的数，X为选自F， Cl，Br，I及其混合物，z是卤化物的数量，为0至6的数，Z表示选自Sb，III，III，作为第III，第四和第四IV。本发明还涉及一种制备由式（II）表示的多金属氧酸盐的方法：（Ⅳ）m + [[M（/）其中，O 2为低级烷基或低级烷基，其中y是过渡金属M的数量，并且是大于4至小于或等于6的数，A，n，m，M p，X，z，Z如式（I）所定义。本发明还涉及氧化有机基质的方法，包括使有机底物与由式（II）表示的多金属氧酸盐接触。

7. 发明申请

US20230044129A1 Polyoxometalates Comprising Noble Metals and Metal Cluster Units Thereof 有权
公开(公告)号：US20230044129A1
公开(公告)日：2023-02-09
申请号：US17778404
申请日：2020-11-06
申请人： Ali S. Mougharbel , Helge Jaensch , Ananthu Rajan , Saurav Bhattacharya , Ulrich Kortz
发明人： Ali S. Mougharbel , Helge Jaensch , Ananthu Rajan , Saurav Bhattacharya , Ulrich Kortz
IPC分类号： C07F17/02 , C01G55/00 , C01G5/00 , C01G41/00
摘要： The invention relates to polyoxometalates represented by the formula (An)m+[(MR′t)sOyHqRz(X8W48+rO184+4r)]m− or solvates thereof, corresponding supported polyoxometalates, and processes for their preparation, as well as corresponding metal cluster units, optionally in the form of a dispersion in a liquid carrier medium or immobilized on a solid support, and processes for their preparation, as well as their use in conversion of organic substrate.

8. 发明授权

US08080493B2 Heteropolyanions with late transition metal addenda atoms and process for their preparation 失效
标题翻译：具有晚期过渡金属附加原子的杂多角及其制备方法
公开(公告)号：US08080493B2
公开(公告)日：2011-12-20
申请号：US12037647
申请日：2008-02-26
申请人： Elena Vladimirovna Chubarova , Ulrich Kortz
发明人： Elena Vladimirovna Chubarova , Ulrich Kortz
IPC分类号： B01J23/40 , B01J23/02 , C07C51/16
CPC分类号： C07B41/00 , C01G55/002 , C01P2002/77 , C01P2002/88
摘要： The invention relates to polyoxometalates represented by the formula (An)m+ [M13X8RqOy]m− or solvates thereof, wherein A represents a cation, n is the number of the cations, m is the charge of the polyanion, M represents a transition metal selected from Pd, Pt, Au, Rh, Ir and mixtures thereof, X represents a heteroatom selected from As, Sb, Bi, P, Si, Ge, B, Al, Ga, S, Se, Te and mixtures thereof, and y is the number of oxygen atoms ranging from 32 to 40, a process for their preparation and their use for the catalytic oxidation of organic molecules.
摘要翻译：本发明涉及由式（An）m + [M13X8RqOy] m-或其溶剂化物表示的多金属氧酸盐，其中A表示阳离子，n表示阳离子数，m表示聚阴离子的电荷，M表示选定的过渡金属来自Pd，Pt，Au，Rh，Ir及其混合物，X表示选自As，Sb，Bi，P，Si，Ge，B，Al，Ga，S，Se，Te及其混合物的杂原子，y为氧原子数为32〜40，其制备方法及其用于有机分子的催化氧化。

9. 发明授权

US07645907B2 Transition metal substituted polyoxometalates and process for their preparation 失效
标题翻译：过渡金属取代的多金属氧酸盐及其制备方法
公开(公告)号：US07645907B2
公开(公告)日：2010-01-12
申请号：US11728142
申请日：2007-03-23
申请人： Ulrich Kortz , Sib Sankar Mal
发明人： Ulrich Kortz , Sib Sankar Mal
IPC分类号： C07C45/27 , C07C45/32 , C07C45/33 , C07C45/34 , C01B25/45 , C01G28/00
CPC分类号： B01J27/188 , B01J27/285 , B01J38/48 , C01G1/00 , C01G41/006 , C01P2002/76 , C01P2002/77 , Y02P20/584
摘要： This invention relates to a Polyoxometalate (POM) represented by the formula: (An)m+[HqM16X8W48O184(OH)32]m− or solvates thereof, wherein: A represents a cation, n is the number of the cations A, m is the charge of the polyoxoanion, q is the number of protons and varies from 0 to 12, M represents a transition metal, and X represents a heteroatom selected from P, As and mixtures thereof. This invention also relates to a process to produce such POMs and to a process for the homogeneous or heterogeneous oxidation of organic substrates comprising contacting the organic substrate with such POMs.
摘要翻译：本发明涉及由下式表示的多金属氧酸盐（POM）：（An）m + [HqM16X8W48O184（OH）32] m-或其溶剂化物，其中：A表示阳离子，n表示阳离子A的数目，m表示多氧阴离子的电荷，q是质子的数量，从0变化到12，M表示过渡金属，X表示选自P，As的杂原子及其混合物。本发明还涉及产生这种POM的方法以及有机基质的均相或非均相氧化的方法，包括使有机底物与这种POM接触。

10. 发明申请

US20070282139A1 Novel Pd- and Pt-substituted polyoxometalates and process for their preparation 失效
标题翻译：新型Pd-和Pt-取代的多金属氧酸盐及其制备方法
公开(公告)号：US20070282139A1
公开(公告)日：2007-12-06
申请号：US11445073
申请日：2006-05-31
申请人： Ulrich Kortz , Lihua Bi
发明人： Ulrich Kortz , Lihua Bi
IPC分类号： C07C27/00 , B01J23/00
CPC分类号： B01J27/188 , B01J23/42 , B01J23/44 , B01J23/6527 , C01G41/006 , C01G55/002 , C01P2002/76 , C01P2002/77 , C01P2002/82 , C01P2006/10
摘要： The invention relates to polyoxometalates represented by the formula (An)m+ [My(H2O)(p.y)X2W22O74(OH)2]m− or solvates or mixtures thereof, wherein A represents a cation, n is the number of the cations, m is the charge of the polyoxoanion, M represents a transition metal selected from Pd, Pt and mixtures thereof, y is 1, 2, 3 or 4, p is the number of water molecules bound to one M and varies from 3 to 5, and X represents a heteroatom selected from SbIII, BiIII, AsIII, SeIV and TeIV, a process for their preparation and their use for the catalytic oxidation of organic molecules.
摘要翻译：本发明涉及由式（Ⅳ）m ates ates））））））））））））））））））））））））））））））））））））））））））））））（py）X 2 2 W 22 N 2（OH）2 N 2 其中A表示阳离子，n表示阳离子数，m表示多氧阴离子的电荷，M表示选自Pd，Pt及其混合物的过渡金属， y是1,2,3或4，p是结合到一个M并且从3到5变化的水分子的数量，X代表选自Sb III，Bi III 其中，作为其制备方法和它们用于有机分子的催化氧化的方法，作为其中的第三种，第四种和第四种，。

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