专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明申请

US20190030517A1 Polyoxometalates Comprising Noble Metals and Corresponding Metal Clusters 审中-公开
公开(公告)号：US20190030517A1
公开(公告)日：2019-01-31
申请号：US16071049
申请日：2017-01-19
申请人： Ulrich Kortz , Yixian Xiang , Zhengguo Lin , Peng Yang , Helge Jaensch , Wassim W. Ayass
发明人： Ulrich Kortz , Yixian Xiang , Zhengguo Lin , Peng Yang , Helge Jaensch , Wassim W. Ayass
IPC分类号： B01J27/185 , C01B25/45 , B01J21/08 , B01J35/02 , B01J37/03 , B01J37/02 , C07C5/10
摘要： The invention relates to poly oxometalates represented by the formula (An)m+{M′s[M″M15X10OyRzHq]}m− or solvates thereof, corresponding supported poly-oxometalates, and processes for their preparation, as well as corresponding metal-clusters, optionally in the form of a dispersion in a liquid carrier medium or immobilized on a solid support, and processes for their preparation, as well as their use in reductive conversion of organic substrate.

2. 发明授权

US10857527B2 Polyoxometalates comprising noble metals and corresponding metal clusters 有权
公开(公告)号：US10857527B2
公开(公告)日：2020-12-08
申请号：US16071049
申请日：2017-01-19
申请人： Ulrich Kortz , Yixian Xiang , Zhengguo Lin , Peng Yang , Helge Jaensch , Wassim W. Ayass
发明人： Ulrich Kortz , Yixian Xiang , Zhengguo Lin , Peng Yang , Helge Jaensch , Wassim W. Ayass
IPC分类号： B01J27/185 , B01J35/10 , C07C5/10 , B01J23/00 , B01J29/03 , C01G55/00 , B01J37/03 , B01J21/08 , B01J35/02 , B01J37/02 , C01B25/45 , B01J35/00
摘要： The invention relates to poly oxometalates represented by the formula (An)m+{M′s[M″M15X10OyRzHq]}m− or solvates thereof, corresponding supported polyoxometalates, and processes for their preparation, as well as corresponding metal-clusters, optionally in the form of a dispersion in a liquid carrier medium or immobilized on a solid support, and processes for their preparation, as well as their use in reductive conversion of organic substrate.

3. 发明申请

US20220144663A1 Polyoxometalates Comprising Transition Metals 有权
公开(公告)号：US20220144663A1
公开(公告)日：2022-05-12
申请号：US17430982
申请日：2020-02-27
申请人： Ulrich Kortz , Hafiz M. Qasim , Ali S. Mougharbel , Bassem S. Bassil , Wassim W. Ayass
发明人： Ulrich Kortz , Hafiz M. Qasim , Ali S. Mougharbel , Bassem S. Bassil , Wassim W. Ayass
IPC分类号： C01G41/00 , B01J23/30 , B01J37/03 , C07C315/00 , B01J38/44
摘要： The invention relates to polyoxometalates represented by the formula (An)m+{[M6(O2)9][(XM′10O37)3]}m− or solvates thereof, corresponding supported polyoxometalates, and processes for their preparation, as well as their use in oxidative conversion of organic substrate.

4. 发明申请

US20230044129A1 Polyoxometalates Comprising Noble Metals and Metal Cluster Units Thereof 有权
公开(公告)号：US20230044129A1
公开(公告)日：2023-02-09
申请号：US17778404
申请日：2020-11-06
申请人： Ali S. Mougharbel , Helge Jaensch , Ananthu Rajan , Saurav Bhattacharya , Ulrich Kortz
发明人： Ali S. Mougharbel , Helge Jaensch , Ananthu Rajan , Saurav Bhattacharya , Ulrich Kortz
IPC分类号： C07F17/02 , C01G55/00 , C01G5/00 , C01G41/00
摘要： The invention relates to polyoxometalates represented by the formula (An)m+[(MR′t)sOyHqRz(X8W48+rO184+4r)]m− or solvates thereof, corresponding supported polyoxometalates, and processes for their preparation, as well as corresponding metal cluster units, optionally in the form of a dispersion in a liquid carrier medium or immobilized on a solid support, and processes for their preparation, as well as their use in conversion of organic substrate.

5. 发明授权

US07906686B2 Process for oxidizing alkylaromatic compounds 失效
标题翻译：氧化烷基芳族化合物的方法
公开(公告)号：US07906686B2
公开(公告)日：2011-03-15
申请号：US12532388
申请日：2008-04-07
申请人： Helge Jaensch , Jihad M. Dakka , Francisco M. Benitez , Ulrich Kortz , Ryan Matthew Richards
发明人： Helge Jaensch , Jihad M. Dakka , Francisco M. Benitez , Ulrich Kortz , Ryan Matthew Richards
IPC分类号： C07C45/53 , C07C409/00 , C07C37/00
CPC分类号： C07C409/08 , B01J27/1817 , B01J27/188 , C07C37/06 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/10 , C07C409/14 , C07C2601/14 , Y02P20/52 , C07C49/403 , C07C39/04
摘要： In a process for producing hydroperoxides, an alkylaromatic compound of general formula (I): in which R1 and R2 each independently represents hydrogen or an alkyl group having from 1 to 4 carbon atoms, provided that R1 and R2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, said cyclic group being optionally substituted, and R3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group, is contacted with oxygen in the presence of a catalyst comprising a polyoxometalate to produce a hydroperoxide of general formula (II): in which R1, R2 and R3 have the same meaning as in formula (I) and wherein the polyoxometalate comprises a polyoxotungstate substituted with at least one further transition metal.
摘要翻译：在制备氢过氧化物的方法中，通式（I）的烷基芳族化合物：其中R 1和R 2各自独立地表示氢或具有1至4个碳原子的烷基，条件是R 1和R 2可以连接形成环状具有4至10个碳原子的基团，所述环状基团任选被取代，并且R 3表示氢，具有1至4个碳原子的一个或多个烷基或环己基与氧在催化剂的存在下与产生通式（II）的氢过氧化物：其中R 1，R 2和R 3具有与式（I）中相同的含义，并且其中多金属氧酸盐包括被至少一个其它过渡金属取代的聚氧钨酸酯。

6. 发明申请

US20100185016A1 Process for Oxidizing Alkylaromatic Compounds 失效
标题翻译：氧化烷基芳族化合物的方法
公开(公告)号：US20100185016A1
公开(公告)日：2010-07-22
申请号：US12532388
申请日：2008-04-07
申请人： Helge Jaensch , Jihad M. Dakka , Francisco M. Benitez , Ulrich Kortz , Ryan Matthew Richards
发明人： Helge Jaensch , Jihad M. Dakka , Francisco M. Benitez , Ulrich Kortz , Ryan Matthew Richards
IPC分类号： C07C45/00 , C07C409/08
CPC分类号： C07C409/08 , B01J27/1817 , B01J27/188 , C07C37/06 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/10 , C07C409/14 , C07C2601/14 , Y02P20/52 , C07C49/403 , C07C39/04
摘要： In a process for producing hydroperoxides, an alkylaromatic compound of general formula (I): in which R1 and R2 each independently represents hydrogen or an alkyl group having from 1 to 4 carbon atoms, provided that R1 and R2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, said cyclic group being optionally substituted, and R3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group, is contacted with oxygen in the presence of a catalyst comprising a polyoxometalate to produce a hydroperoxide of general formula (II): in which R1, R2 and R3 have the same meaning as in formula (I) and wherein the polyoxometalate comprises a polyoxotungstate substituted with at least one further transition metal.
摘要翻译：在制备氢过氧化物的方法中，通式（I）的烷基芳族化合物：其中R 1和R 2各自独立地表示氢或具有1至4个碳原子的烷基，条件是R 1和R 2可以连接形成环状具有4至10个碳原子的基团，所述环状基团任选被取代，并且R 3表示氢，具有1至4个碳原子的一个或多个烷基或环己基与氧在催化剂的存在下与产生通式（II）的氢过氧化物：其中R 1，R 2和R 3具有与式（I）中相同的含义，并且其中多金属氧酸盐包括被至少一个其它过渡金属取代的聚氧钨酸酯。

7. 发明申请

US20090318723A1 Novel Ru-Containing Polyoxotungstates and Process for Their Preparation 失效
标题翻译：新型含钌多元钨酸盐及其制备方法
公开(公告)号：US20090318723A1
公开(公告)日：2009-12-24
申请号：US12143628
申请日：2008-06-20
申请人： Ulrich Kortz , Elena Vladimirovna Chubarova , Nadeen Hassan Nsouli
发明人： Ulrich Kortz , Elena Vladimirovna Chubarova , Nadeen Hassan Nsouli
IPC分类号： C07F7/02 , C07F7/30 , C07C27/10
CPC分类号： C07F15/0053 , B01J23/002 , B01J23/6527 , B01J27/188 , B01J31/2295 , B01J2523/00 , B01J2531/821 , B01J2523/13 , B01J2523/42 , B01J2523/69 , B01J2523/821
摘要： The invention relates to polyoxometalates represented by the formula (An)m+ [Ru2L2(XW11O39)2WO2]m− or solvates thereof, wherein A is a cation, n is the number of the cations, m is the charge of the polyanion, L is a ligand bound to ruthenium and is independently selected from group consisting of water, unsubstituted or substituted arenes, unsubstituted or substituted heteroarenes, unsaturated hydrocarbons, ethers, unsubstituted or substituted allyl, unsubstituted or substituted alkanes, nitriles, carboxylates, peroxides, peracids, phosphines, phosphanes, CO, OH−, peroxo, carbonate, NO3−, NO2−, NO−, NH3, amines, F−, Cl−, Br−, I−, SCN−, NCS−, NCO− and mixtures thereof and X is a heteroatom selected from Si, Ge, B and mixtures thereof, a process for their preparation and their use for the catalytic oxidation of organic molecules.
摘要翻译：本发明涉及由式（An）m + [Ru 2 L 2（XW 11 O 39）2 WO 2] m - 或其溶剂合物表示的多金属氧酸盐，其中A为阳离子，n为阳离子数，m为聚阴离子的电荷，L为与钌结合并且独立地选自水，未取代或取代的芳烃，未取代或取代的杂芳烃，不饱和烃，醚，未取代或取代的烯丙基，未取代或取代的烷烃，腈，羧酸盐，过氧化物，过酸，膦，膦，CO，OH-，过氧，碳酸根，NO 3 - ，NO 2 - ，NO-，NH 3，胺，F-，Cl-，Br-，I-，SCN-，NCS-，NCO-及其混合物，X是选自Si，Ge，B及其混合物的杂原子，其制备方法及其用于有机分子的催化氧化。

8. 发明申请

US20090216052A1 Novel Heteropolyanions With Late Transition Metal Addenda Atoms And Process For Their Preparation 失效
标题翻译：具有后期过渡金属添加剂原子的新型杂多糖及其制备方法
公开(公告)号：US20090216052A1
公开(公告)日：2009-08-27
申请号：US12037647
申请日：2008-02-26
申请人： Elena Vladimirovna Chubarova , Ulrich Kortz
发明人： Elena Vladimirovna Chubarova , Ulrich Kortz
IPC分类号： C07B41/00 , C01G28/00
CPC分类号： C07B41/00 , C01G55/002 , C01P2002/77 , C01P2002/88
摘要： The invention relates to polyoxometalates represented by the formula (An)m+ [M13X8RqOy]m− or solvates thereof, wherein A represents a cation, n is the number of the cations, m is the charge of the polyanion, M represents a transition metal selected from Pd, Pt, Au, Rh, Ir and mixtures thereof, X represents a heteroatom selected from As, Sb, Bi, P, Si, Ge, B, Al, Ga, S, Se, Te and mixtures thereof, and y is the number of oxygen atoms ranging from 32 to 40, a process for their preparation and their use for the catalytic oxidation of organic molecules.
摘要翻译：本发明涉及由式（An）m + [M13X8RqOy] m-或其溶剂化物表示的多金属氧酸盐，其中A表示阳离子，n表示阳离子数，m表示聚阴离子的电荷，M表示选定的过渡金属来自Pd，Pt，Au，Rh，Ir及其混合物，X表示选自As，Sb，Bi，P，Si，Ge，B，Al，Ga，S，Se，Te及其混合物的杂原子，y为氧原子数为32〜40，其制备方法及其用于有机分子的催化氧化。

9. 发明授权

US07858814B2 Ru-containing polyoxotungstates and process for their preparation 失效
标题翻译：含Ru多聚钨酸盐及其制备方法
公开(公告)号：US07858814B2
公开(公告)日：2010-12-28
申请号：US12143628
申请日：2008-06-20
申请人： Ulrich Kortz , Elena Vladimirovna Chubarova , Nadeen Hassan Nsouli
发明人： Ulrich Kortz , Elena Vladimirovna Chubarova , Nadeen Hassan Nsouli
IPC分类号： C07F19/00 , B01J23/00 , C07C27/10
CPC分类号： C07F15/0053 , B01J23/002 , B01J23/6527 , B01J27/188 , B01J31/2295 , B01J2523/00 , B01J2531/821 , B01J2523/13 , B01J2523/42 , B01J2523/69 , B01J2523/821
摘要： The invention relates to polyoxometalates represented by the formula (An)m+ [Ru2L2(XW11O39)2WO2]m− or solvates thereof, wherein A is a cation, n is the number of the cations, m is the charge of the polyanion, L is a ligand bound to ruthenium and is independently selected from group consisting of water, unsubstituted or substituted arenes, unsubstituted or substituted heteroarenes, unsaturated hydrocarbons, ethers, unsubstituted or substituted allyl, unsubstituted or substituted alkanes, nitriles, carboxylates, peroxides, peracids, phosphines, phosphanes, CO, OH−, peroxo, carbonate, NO3−, NO2−, NO−, NH3, amines, F−, Cl−, Br−, I−, SCN−, NCS−, NCO− and mixtures thereof and X is a heteroatom selected from Si, Ge, B and mixtures thereof, a process for their preparation and their use for the catalytic oxidation of organic molecules.
摘要翻译：本发明涉及由式（An）m + [Ru 2 L 2（XW 11 O 39）2 WO 2] m - 或其溶剂合物表示的多金属氧酸盐，其中A为阳离子，n为阳离子数，m为聚阴离子的电荷，L为与钌结合并且独立地选自水，未取代或取代的芳烃，未取代或取代的杂芳烃，不饱和烃，醚，未取代或取代的烯丙基，未取代或取代的烷烃，腈，羧酸盐，过氧化物，过酸，膦，膦，CO，OH-，过氧，碳酸根，NO 3 - ，NO 2 - ，NO-，NH 3，胺，F-，Cl-，Br-，I-，SCN-，NCS-，NCO-及其混合物，X是选自Si，Ge，B及其混合物的杂原子，其制备方法及其用于有机分子的催化氧化。

10. 发明授权

US07417008B2 Supported polyoxometalates and process for their preparation 失效
标题翻译：负载型多金属氧酸盐及其制备方法
公开(公告)号：US07417008B2
公开(公告)日：2008-08-26
申请号：US11443683
申请日：2006-05-31
申请人： Ryan M. Richards , Ulrich Kortz , Lihua Bi , Kake Zhu
发明人： Ryan M. Richards , Ulrich Kortz , Lihua Bi , Kake Zhu
IPC分类号： B01J23/00 , C01G41/02 , C07C45/00 , C07C27/00
CPC分类号： B01J27/188 , B01J23/6527 , B01J23/888 , C01G1/00 , C01G41/006 , C01G49/009 , C01G53/006 , C01P2002/52
摘要： The invention relates to supported polyoxometalates represented by the formula (An)m+ [M4(H2O)10(XW9O33)2]m− or solvates thereof, wherein A represents a cation, n is the number of cations, m is the charge of the polyoxoanion, M is a transition metal, and X is an element selected from the group consisting of As, Sb, Bi, Se and Te, characterized in that the polyoxometalate is supported on a solid support selected from the group consisting of Al2O3, MgO, TiO2, ZrO2, SiO2, mesoporous silica, active carbon, diatomite, clays, zeolites, polyoxometalate salts and mixtures thereof, with the proviso that the polyoxometalate salt supports are different from the supported polyoxometalates defined by the above formula, a process for their preparation and their use for the catalytic oxidation of organic molecules.
摘要翻译：本发明涉及由式（Ⅳ）表示的负载型多金属氧酸盐：[M n O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O ）10 （XW 9 O 33）其中m - 或其溶剂化物其中A表示阳离子，n为阳离子数，m为多氧阴离子的电荷，M为过渡金属，X为选自As，Sb，Bi，Se和Te的元素，其特征在于其中所述多金属氧酸盐负载在选自由Al 2 O 3，MgO，TiO 2，ZrO 2，Na 2 O 3， > 2，SiO 2，介孔二氧化硅，活性炭，硅藻土，粘土，沸石，多金属氧酸盐及其混合物，条件是多金属氧酸盐载体不同于负载的多金属氧酸盐定义通过上式，其制备方法及其用于有机分子的催化氧化。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式