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1. 发明授权

US07132476B2 Thermosetting compositions containing alternating copolymers of isobutylene type monomers 失效
公开(公告)号：US07132476B2
公开(公告)日：2006-11-07
申请号：US10887682
申请日：2004-07-09
申请人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
发明人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
IPC分类号： C08F8/00
CPC分类号： B05D7/57 , B05D1/007 , B05D3/0209 , B05D3/067 , B05D7/53 , C08F8/00 , C08F210/10 , C08F220/10 , C08F290/046 , C08G18/6229 , C08G18/792 , C08G18/798 , C08G18/8025 , C08G18/807 , C08G18/8074 , C08G2150/20 , C08L33/068 , C09D123/22 , C09D133/062 , C09D133/08 , Y10T428/31504 , Y10T428/31511 , C08F220/00 , C08F220/12 , C08F210/00 , C08L2666/28 , C08L2666/02 , C08F214/18 , C08F2500/03 , C08F2500/02 , C08F212/00 , C08F222/00 , C08F2500/26 , C08L2666/04
摘要： A thermosetting composition that includes an ungelled copolymer composition and a crosslinking agent. The ungelled copolymer composition includes a functional group-containing copolymer that includes segments of alternating residues derived from a donor monomer composition comprising an acceptor monomer composition. The donor monomer composition includes one or both of isobutylene and diisobutylene, and the acceptor monomer composition includes acrylic monomers and monomers containing functional groups. The ungelled copolymer composition is substantially free of transition metals and Lewis acids, and the copolymer is substantially free of maleate-type monomer residues and fumarate-type monomer residues. The crosslinking agent has at least two functional groups that are reactive with the functional groups of the copolymer. The thermosetting composition may be in liquid, powder, or dispersed form and may be applied by traditional or electrocoating methods.

2. 发明授权

US06686432B2 Alternating copolymers of isobutylene type monomers 失效
公开(公告)号：US06686432B2
公开(公告)日：2004-02-03
申请号：US10076984
申请日：2002-02-15
申请人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
发明人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
IPC分类号： C08F1000
CPC分类号： C09D201/02 , C08F8/00 , C08F10/00 , C08F20/00
摘要： A copolymer composition that includes a copolymer comprised of at least 30 mol % of residues having the following alternating residues from a donor monomer and from an acceptor monomer. The copolymer contains at least 15 mol % of an isobutylene type donor monomer and at least 15 mol % of an acrylic monomer as an acceptor monomer. The copolymer is substantially free of maleate or fumarate monomer segments and the copolymer composition is substantially free of Lewis acids and transition metals. Also disclosed is a thermosetting composition that includes a reactant comprising functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups first reactant, and a copolymer flow control agent that includes the copolymer composition as well as substrates coated with the thermosetting composition.

3. 发明授权

US06180181B2 Methods for forming composite coatings on substrates 有权
标题翻译：在基材上形成复合涂层的方法
公开(公告)号：US06180181B2
公开(公告)日：2001-01-30
申请号：US09211127
申请日：1998-12-14
申请人： Christopher A. Verardi , Dennis L. Faler , Marvis E. Hartman , Nicholas J. Crano , Rodger G. Temple , Victoria A. Trettel
发明人： Christopher A. Verardi , Dennis L. Faler , Marvis E. Hartman , Nicholas J. Crano , Rodger G. Temple , Victoria A. Trettel
IPC分类号： B05D136
CPC分类号： B05D7/572
摘要： The present invention provides methods for forming composite coatings on substrates including the steps of: (A) applying an aqueous primary coating composition to at least a portion of a surface of a substrate, the primary coating composition including: (1) at least one thermosettable dispersion including polymeric microparticles having functionality adapted to react with a crosslinking material, the microparticles including: (a) at least one acid functional reaction product of ethylenically unsaturated monomers; and (b) at least one hydrophobic polymer having a number average molecular weight of at least about 500; and (2) at least one crosslinking material, to form a substantially uncured primary coating thereon; (B) applying a secondary coating composition to at least a portion of the primary coating formed in step (A) without substantially curing the primary coating to form a substantially uncured secondary coating thereon; and (C) applying a clear coating composition to at least a portion of the secondary coating formed in step (B) without substantially curing the secondary coating to form a substantially uncured composite coating thereon.
摘要翻译：本发明提供了在基材上形成复合涂层的方法，包括以下步骤：（A）将水性初级涂料组合物施用至基材表面的至少一部分，所述主要涂料组合物包括：（1）至少一种可热固化包括具有适于与交联材料反应的官能团的聚合物微粒的分散体，所述微粒包括：（a）至少一种烯属不饱和单体的酸官能反应产物; 和（b）数均分子量为至少约500的至少一种疏水性聚合物; 和（2）至少一种交联材料，以在其上形成基本上未固化的初级涂层; （B）将第二涂料组合物施加到步骤（A）中形成的初级涂层的至少一部分，而基本上不固化初级涂层，以在其上形成基本上未固化的二次涂层; 和（C）将透明涂料组合物施加到步骤（B）中形成的二次涂层的至少一部分，而基本上不固化二次涂层，以在其上形成基本上未固化的复合涂层。

4. 发明授权

US07776959B2 Coatings comprising terpene 失效
标题翻译：包含萜烯的涂料
公开(公告)号：US07776959B2
公开(公告)日：2010-08-17
申请号：US11564570
申请日：2006-11-29
申请人： Simion Coca , James O'Dwyer , Richard F. Karabin , Stephen J. Thomas , Victoria A. Trettel , Davina Schwartzmiller , Jane N. Valenta , Gregory J. McCollum , Richard J. Sadvary
发明人： Simion Coca , James O'Dwyer , Richard F. Karabin , Stephen J. Thomas , Victoria A. Trettel , Davina Schwartzmiller , Jane N. Valenta , Gregory J. McCollum , Richard J. Sadvary
IPC分类号： C08L33/04 , C08L99/00 , C08G65/34
CPC分类号： C09D4/00 , C08F289/00 , C08F291/00 , C09D151/003 , C09D151/08 , C08L2666/02
摘要： Coatings comprising a polymer comprising a terpene and a monomer polymerized with terpene by free radical polymerization are disclosed. Coatings comprising terpene in greater than 30 wt % are also disclosed as are coatings comprising a terpene and a urea. Copolymers with terpene are also disclosed.
摘要翻译：公开了包含由萜烯和通过自由基聚合与萜烯聚合的单体的聚合物的涂料。包含大于30wt％的萜烯的涂层也被公开为包含萜烯和脲的涂层。还公开了与萜烯的共聚物。

5. 发明授权

US07438972B2 Nanoparticle coatings for flexible and/or drawable substrates 有权
标题翻译：用于柔性和/或可拉伸基材的纳米颗粒涂层
公开(公告)号：US07438972B2
公开(公告)日：2008-10-21
申请号：US10876315
申请日：2004-06-24
申请人： Dennis L. Faler , Anthony D. Kulfan , Victoria A. Trettel
发明人： Dennis L. Faler , Anthony D. Kulfan , Victoria A. Trettel
IPC分类号： B32B5/16 , B32B18/00 , B32B27/36 , B32B27/00
CPC分类号： B32B5/18 , B32B3/26 , B32B7/12 , B32B37/12 , B32B2255/26 , B32B2266/025 , C01P2004/64 , C08J7/047 , C08K3/013 , C08K9/08 , C09C1/3072 , C09C3/10 , C09D7/41 , C09D7/62 , Y10T428/249953 , Y10T428/249978 , Y10T428/25 , Y10T428/252 , Y10T428/259 , Y10T428/265 , Y10T428/31507 , Y10T428/31551 , Y10T428/31663 , Y10T428/31721 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855
摘要： Flexible and/or drawable substrates having coatings comprising a dispersion of resin coated nanoparticles are disclosed, as are laminated articles comprising such flexible and/or drawable substrates.
摘要翻译：公开了具有包含树脂涂覆的纳米颗粒的分散体的涂层的柔性和/或可拉伸基材，以及包括这种柔性和/或可拉伸基材的层合制品。

6. 发明授权

US06784248B2 Thermosetting compositions containing alternating copolymers of isobutylene type monomers 失效
标题翻译：含有异丁烯型单体交替共聚物的热固性组合物
公开(公告)号：US06784248B2
公开(公告)日：2004-08-31
申请号：US10077645
申请日：2002-02-15
申请人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
发明人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
IPC分类号： C08F832
CPC分类号： B05D7/57 , B05D1/007 , B05D3/0209 , B05D3/067 , B05D7/53 , C08F8/00 , C08F210/10 , C08F220/10 , C08F290/046 , C08G18/6229 , C08G18/792 , C08G18/798 , C08G18/8025 , C08G18/807 , C08G18/8074 , C08G2150/20 , C08L33/068 , C09D123/22 , C09D133/062 , C09D133/08 , Y10T428/31504 , Y10T428/31511 , C08F220/00 , C08F220/12 , C08F210/00 , C08L2666/28 , C08L2666/02 , C08F214/18 , C08F2500/03 , C08F2500/02 , C08F212/00 , C08F222/00 , C08F2500/26 , C08L2666/04
摘要： A thermosetting composition that includes an ungelled copolymer composition and a crosslinking agent. The ungelled copolymer composition includes a functional group-containing copolymer that includes segments of alternating residues derived from a donor monomer composition comprising an acceptor monomer composition. The donor monomer composition includes one or both of isobutylene and diisobutylene, and the acceptor monomer composition includes acrylic monomers and monomers containing functional groups. The ungelled copolymer composition is substantially free of transition metals and Lewis acids, and the copolymer is substantially free of maleate-type monomer residues and fumarate-type monomer residues. The crosslinking agent has at least two functional groups that are reactive with the functional groups of the copolymer. The thermosetting composition may be in liquid, powder, or dispersed form and may be applied by traditional or electrocoating methods.
摘要翻译：包含未凝胶化共聚物组合物和交联剂的热固性组合物。非凝胶共聚物组合物包括含官能团的共聚物，其包含衍生自包含受体单体组合物的供体单体组合物的交替残基的片段。供体单体组合物包括异丁烯和二异丁烯中的一种或两种，并且受体单体组合物包括丙烯酸单体和含有官能团的单体。未凝胶化的共聚物组合物基本上不含过渡金属和路易斯酸，共聚物基本上不含马来酸盐型单体残基和富马酸盐型单体残基。交联剂具有与共聚物的官能团反应的至少两个官能团。热固性组合物可以是液体，粉末或分散形式，并且可以通过传统或电泳方法施加。

7. 发明申请

US20080145638A1 Transparent Composite Articles 有权
标题翻译：透明复合制品
公开(公告)号：US20080145638A1
公开(公告)日：2008-06-19
申请号：US11610755
申请日：2006-12-14
申请人： Stuart D. Hellring , Kaliappa G. Ragunathan , Thomas G. Rukavina , Victoria A. Trettel
发明人： Stuart D. Hellring , Kaliappa G. Ragunathan , Thomas G. Rukavina , Victoria A. Trettel
IPC分类号： B32B27/04 , C08L75/04
CPC分类号： C08J5/005 , B82Y30/00 , C08G18/3206 , C08G18/758 , C08J5/046 , C08J5/24 , C08J2375/04 , C08L43/04 , C08L75/04 , Y10T428/24994 , C08L2666/04
摘要： A transparent composite article comprising a polyurethane matrix and incorporated within the matrix nanofibers having a diameter up to 5000 nanometers.
摘要翻译：一种透明复合制品，其包含聚氨酯基质并且结合到具有高达5000纳米直径的基质纳米纤维内。

8. 发明申请

US20080121139A1 COATINGS COMPRISING TERPENE 失效
标题翻译：包括TERPENE的涂料
公开(公告)号：US20080121139A1
公开(公告)日：2008-05-29
申请号：US11564570
申请日：2006-11-29
申请人： SIMION COCA , JAMES O'DWYER , RICHARD F. KARABIN , STEPHEN J. THOMAS , VICTORIA A. TRETTEL , DAVINA SCHWARTZMILLER , JANE N. VALENTA , GREGORY J. McCOLLUM , RICHARD J. SADVARY
发明人： SIMION COCA , JAMES O'DWYER , RICHARD F. KARABIN , STEPHEN J. THOMAS , VICTORIA A. TRETTEL , DAVINA SCHWARTZMILLER , JANE N. VALENTA , GREGORY J. McCOLLUM , RICHARD J. SADVARY
IPC分类号： C09D193/00 , C08L93/00
CPC分类号： C09D4/00 , C08F289/00 , C08F291/00 , C09D151/003 , C09D151/08 , C08L2666/02
摘要： Coatings comprising a polymer comprising a terpene and a monomer polymerized with terpene by free radical polymerization are disclosed. Coatings comprising terpene in greater than 30 wt % are also disclosed as are coatings comprising a terpene and a urea. Copolymers with terpene are also disclosed.
摘要翻译：公开了包含由萜烯和通过自由基聚合与萜烯聚合的单体的聚合物的涂料。包含大于30wt％的萜烯的涂层也被公开为包含萜烯和脲的涂层。还公开了与萜烯的共聚物。

9. 发明授权

US07125931B2 Thermosetting compositions containing alternating copolymers of isobutylene type monomers 失效
公开(公告)号：US07125931B2
公开(公告)日：2006-10-24
申请号：US10887733
申请日：2004-07-09
申请人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
发明人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
IPC分类号： C08F8/00
CPC分类号： B05D7/57 , B05D1/007 , B05D3/0209 , B05D3/067 , B05D7/53 , C08F8/00 , C08F210/10 , C08F220/10 , C08F290/046 , C08G18/6229 , C08G18/792 , C08G18/798 , C08G18/8025 , C08G18/807 , C08G18/8074 , C08G2150/20 , C08L33/068 , C09D123/22 , C09D133/062 , C09D133/08 , Y10T428/31504 , Y10T428/31511 , C08F220/00 , C08F220/12 , C08F210/00 , C08L2666/28 , C08L2666/02 , C08F214/18 , C08F2500/03 , C08F2500/02 , C08F212/00 , C08F222/00 , C08F2500/26 , C08L2666/04
摘要： A thermosetting composition that includes an ungelled copolymer composition and a crosslinking agent. The ungelled copolymer composition includes a functional group-containing copolymer that includes segments of alternating residues derived from a donor monomer composition comprising an acceptor monomer composition. The donor monomer composition includes one or both of isobutylene and diisobutylene, and the acceptor monomer composition includes acrylic monomers and monomers containing functional groups. The ungelled copolymer composition is substantially free of transition metals and Lewis acids, and the copolymer is substantially free of maleate-type monomer residues and fumarate-type monomer residues. The crosslinking agent has at least two functional groups that are reactive with the functional groups of the copolymer. The thermosetting composition may be in liquid, powder, or dispersed form and may be applied by traditional or electrocoating methods.

10. 发明授权

US06992137B2 Alternating copolymers of isobutylene type monomers 失效
公开(公告)号：US06992137B2
公开(公告)日：2006-01-31
申请号：US10697413
申请日：2003-10-30
申请人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
发明人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
IPC分类号： C08F8/00
CPC分类号： C09D201/02 , C08F8/00 , C08F10/00 , C08F20/00
摘要： A copolymer composition that includes a copolymer comprised of at least 30 mol % of residues having the following alternating residues from a donor monomer and from an acceptor monomer. The copolymer contains at least 15 mol % of an isobutylene type donor monomer and at least 15 mol % of an acrylic monomer as an acceptor monomer. The copolymer is substantially free of maleate or fumarate monomer segments and the copolymer composition is substantially free of Lewis acids and transition metals. Also disclosed is a thermosetting composition that includes a reactant comprising functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups first reactant, and a copolymer flow control agent that includes the copolymer composition as well as substrates coated with the thermosetting composition.

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