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    • 1. 发明申请
    • POSITIVE RESIST COMPOSITION AND METHOD FOR FORMING RESIST PATTERN
    • 积极抗性组合物和形成耐药模式的方法
    • US20090098483A1
    • 2009-04-16
    • US11913308
    • 2006-04-07
    • Yohei KinoshitaMakiko IrieWaki OhkuboYusuke NakagawaShinichi Hidesaka
    • Yohei KinoshitaMakiko IrieWaki OhkuboYusuke NakagawaShinichi Hidesaka
    • G03F7/028G03F7/20
    • G03F7/0397C08F220/28G03F7/0046Y10S430/111Y10S430/12Y10S430/121Y10S430/122Y10S430/123Y10S430/126
    • A positive resist composition and method for forming a resist pattern are provided which enable a resist pattern with excellent shape to be obtained. The resist composition includes a resin component (A) which exhibits increased alkali solubility under action of acid, an acid-generator component (B) which generates acid upon irradiation and an organic solvent (S) in which the components (A) and (B) are dissolved, the resin component (A) including a copolymer (A1) containing: a structural unit (a1) having an acetal-type protected group, a structural unit (a2) derived from an acrylate ester having a lactone-containing polycyclic group, which is represented by general formula (a2-1) shown below; and a structural unit (a3) derived from an acrylate ester having a polar group-containing aliphatic hydrocarbon group: wherein R represents a hydrogen atom, a fluorine atom, a lower alkyl group or a fluorinated lower alkyl group; R′ represents a hydrogen atom, a lower alkyl group or an alkoxy group of 1 to 5 carbon atoms; and m represents 0 or 1.
    • 提供了一种形成抗蚀剂图案的正型抗蚀剂组合物和方法,其能够获得具有优异形状的抗蚀剂图案。 抗蚀剂组合物包括在酸作用下表现出增加的碱溶性的树脂组分(A),在照射时产生酸的酸产生剂组分(B)和其中组分(A)和(B)的有机溶剂 )的树脂组分(A)包含共聚物(A1),其包含:具有缩醛型保护基的结构单元(a1),源自具有含内酯多环基团的丙烯酸酯的结构单元(a2) ,由下述通式(a2-1)表示; 和衍生自具有极性基团的脂族烃基的丙烯酸酯的结构单元(a3):其中R表示氢原子,氟原子,低级烷基或氟化低级烷基; R'表示氢原子,低级烷基或碳原子数1〜5的烷氧基。 m表示0或1。
    • 2. 发明授权
    • Positive resist composition and method of forming resist pattern using same
    • 正型抗蚀剂组合物和使用其形成抗蚀剂图案的方法
    • US07192687B2
    • 2007-03-20
    • US10931958
    • 2004-09-01
    • Kazuyuki NittaWaki OhkuboSatoshi Shimatani
    • Kazuyuki NittaWaki OhkuboSatoshi Shimatani
    • G03F7/40G03F7/004
    • G03F7/0392G03F7/0045
    • A positive resist composition capable of realizing an improvement in resolution, a reduction in LER, and a reduction in the level of defects, as well as a method of forming a resist pattern. This composition and method provide: a positive resist composition comprising a resin component (A) containing a structural unit (a1) derived from an (α-methyl)hydroxystyrene, represented by a general formula (1) shown below, and a structural unit (a2) represented by a general formula (2) shown below, wherein the solubility rate of the component (A) in a 2.38% by weight aqueous solution of TMAH (tetramethylammonium hydroxide) is within a range from 100 to 1000 Å/second, as well as a method of forming a resist pattern that uses such a composition; (wherein in the general formulas (1) and (2), R represents a hydrogen atom or a methyl group).
    • 能够实现分辨率提高,LER降低和缺陷水平降低的正型抗蚀剂组合物以及形成抗蚀剂图案的方法。 该组合物和方法提供:包含含有由(α-甲基)羟基苯乙烯衍生的结构单元(a1)的树脂组分(A)的正性抗蚀剂组合物,由下述通式(1)表示,和结构单元( a2),其中组分(A)在2.38重量%的TMAH(氢氧化四甲铵)水溶液中的溶解度在100至1000埃/秒的范围内,如 以及形成使用这种组合物的抗蚀剂图案的方法; (其中在通式(1)和(2)中,R表示氢原子或甲基)。
    • 5. 发明授权
    • Positive resist composition and method for forming resist pattern
    • 正型抗蚀剂组合物和形成抗蚀剂图案的方法
    • US07858286B2
    • 2010-12-28
    • US11913308
    • 2006-04-07
    • Yohei KinoshitaMakiko IrieWaki OhkuboYusuke NakagawaShinichi Hidesaka
    • Yohei KinoshitaMakiko IrieWaki OhkuboYusuke NakagawaShinichi Hidesaka
    • G03F7/039G03F7/20G03F7/30
    • G03F7/0397C08F220/28G03F7/0046Y10S430/111Y10S430/12Y10S430/121Y10S430/122Y10S430/123Y10S430/126
    • A positive resist composition and method for forming a resist pattern are provided which enable a resist pattern with excellent shape to be obtained. The resist composition includes a resin component (A) which exhibits increased alkali solubility under action of acid, an acid-generator component (B) which generates acid upon irradiation and an organic solvent (S) in which the components (A) and (B) are dissolved, the resin component (A) including a copolymer (A1) containing: a structural unit (a1) having an acetal-type protected group, a structural unit (a2) derived from an acrylate ester having a lactone-containing polycyclic group, which is represented by general formula (a2-1) shown below; and a structural unit (a3) derived from an acrylate ester having a polar group-containing aliphatic hydrocarbon group: wherein R represents a hydrogen atom, a fluorine atom, a lower alkyl group or a fluorinated lower alkyl group; R′ represents a hydrogen atom, a lower alkyl group or an alkoxy group of 1 to 5 carbon atoms; and m represents 0 or 1.
    • 提供了一种形成抗蚀剂图案的正型抗蚀剂组合物和方法,其能够获得具有优异形状的抗蚀剂图案。 抗蚀剂组合物包括在酸作用下表现出增加的碱溶性的树脂组分(A),在照射时产生酸的酸产生剂组分(B)和其中组分(A)和(B)的有机溶剂 )的树脂组分(A)包含共聚物(A1),其包含:具有缩醛型保护基的结构单元(a1),源自具有含内酯多环基团的丙烯酸酯的结构单元(a2) ,由下述通式(a2-1)表示; 和衍生自具有极性基团的脂族烃基的丙烯酸酯的结构单元(a3):其中R表示氢原子,氟原子,低级烷基或氟化低级烷基; R'表示氢原子,低级烷基或碳原子数1〜5的烷氧基; m表示0或1。