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    • 1. 发明申请
    • POSITIVE RESIST COMPOSITION AND METHOD FOR FORMING RESIST PATTERN
    • 积极抗性组合物和形成耐药模式的方法
    • US20090098483A1
    • 2009-04-16
    • US11913308
    • 2006-04-07
    • Yohei KinoshitaMakiko IrieWaki OhkuboYusuke NakagawaShinichi Hidesaka
    • Yohei KinoshitaMakiko IrieWaki OhkuboYusuke NakagawaShinichi Hidesaka
    • G03F7/028G03F7/20
    • G03F7/0397C08F220/28G03F7/0046Y10S430/111Y10S430/12Y10S430/121Y10S430/122Y10S430/123Y10S430/126
    • A positive resist composition and method for forming a resist pattern are provided which enable a resist pattern with excellent shape to be obtained. The resist composition includes a resin component (A) which exhibits increased alkali solubility under action of acid, an acid-generator component (B) which generates acid upon irradiation and an organic solvent (S) in which the components (A) and (B) are dissolved, the resin component (A) including a copolymer (A1) containing: a structural unit (a1) having an acetal-type protected group, a structural unit (a2) derived from an acrylate ester having a lactone-containing polycyclic group, which is represented by general formula (a2-1) shown below; and a structural unit (a3) derived from an acrylate ester having a polar group-containing aliphatic hydrocarbon group: wherein R represents a hydrogen atom, a fluorine atom, a lower alkyl group or a fluorinated lower alkyl group; R′ represents a hydrogen atom, a lower alkyl group or an alkoxy group of 1 to 5 carbon atoms; and m represents 0 or 1.
    • 提供了一种形成抗蚀剂图案的正型抗蚀剂组合物和方法,其能够获得具有优异形状的抗蚀剂图案。 抗蚀剂组合物包括在酸作用下表现出增加的碱溶性的树脂组分(A),在照射时产生酸的酸产生剂组分(B)和其中组分(A)和(B)的有机溶剂 )的树脂组分(A)包含共聚物(A1),其包含:具有缩醛型保护基的结构单元(a1),源自具有含内酯多环基团的丙烯酸酯的结构单元(a2) ,由下述通式(a2-1)表示; 和衍生自具有极性基团的脂族烃基的丙烯酸酯的结构单元(a3):其中R表示氢原子,氟原子,低级烷基或氟化低级烷基; R'表示氢原子,低级烷基或碳原子数1〜5的烷氧基。 m表示0或1。
    • 2. 发明授权
    • Positive resist composition and method for forming resist pattern
    • 正型抗蚀剂组合物和形成抗蚀剂图案的方法
    • US07858286B2
    • 2010-12-28
    • US11913308
    • 2006-04-07
    • Yohei KinoshitaMakiko IrieWaki OhkuboYusuke NakagawaShinichi Hidesaka
    • Yohei KinoshitaMakiko IrieWaki OhkuboYusuke NakagawaShinichi Hidesaka
    • G03F7/039G03F7/20G03F7/30
    • G03F7/0397C08F220/28G03F7/0046Y10S430/111Y10S430/12Y10S430/121Y10S430/122Y10S430/123Y10S430/126
    • A positive resist composition and method for forming a resist pattern are provided which enable a resist pattern with excellent shape to be obtained. The resist composition includes a resin component (A) which exhibits increased alkali solubility under action of acid, an acid-generator component (B) which generates acid upon irradiation and an organic solvent (S) in which the components (A) and (B) are dissolved, the resin component (A) including a copolymer (A1) containing: a structural unit (a1) having an acetal-type protected group, a structural unit (a2) derived from an acrylate ester having a lactone-containing polycyclic group, which is represented by general formula (a2-1) shown below; and a structural unit (a3) derived from an acrylate ester having a polar group-containing aliphatic hydrocarbon group: wherein R represents a hydrogen atom, a fluorine atom, a lower alkyl group or a fluorinated lower alkyl group; R′ represents a hydrogen atom, a lower alkyl group or an alkoxy group of 1 to 5 carbon atoms; and m represents 0 or 1.
    • 提供了一种形成抗蚀剂图案的正型抗蚀剂组合物和方法,其能够获得具有优异形状的抗蚀剂图案。 抗蚀剂组合物包括在酸作用下表现出增加的碱溶性的树脂组分(A),在照射时产生酸的酸产生剂组分(B)和其中组分(A)和(B)的有机溶剂 )的树脂组分(A)包含共聚物(A1),其包含:具有缩醛型保护基的结构单元(a1),源自具有含内酯多环基团的丙烯酸酯的结构单元(a2) ,由下述通式(a2-1)表示; 和衍生自具有极性基团的脂族烃基的丙烯酸酯的结构单元(a3):其中R表示氢原子,氟原子,低级烷基或氟化低级烷基; R'表示氢原子,低级烷基或碳原子数1〜5的烷氧基; m表示0或1。
    • 5. 发明申请
    • OZONE GENERATOR
    • 臭氧发生器
    • US20120134890A1
    • 2012-05-31
    • US13380752
    • 2010-06-24
    • Yohei KinoshitaTakashi SakugawaHidenori Akiyama
    • Yohei KinoshitaTakashi SakugawaHidenori Akiyama
    • B01J19/08
    • C01B13/115C01B2201/90
    • An ozone generator is provided with a pulse generator (110) that at least includes pulse generation means for generating a pulse voltage and a magnetic switch (SI2) adjusting pulse width of the generated pulse voltage, and a discharge reactor that is provided with a plurality of electrodes to which the pulse voltage for which the pulse width has been adjusted is applied, and that generates a discharge between the plurality of electrodes as a result of the pulse voltage, for which the pulse width has been adjusted, being applied thereto, and also generates ozone as a result of a raw material gas containing oxygen being supplied from the outside to between the electrodes where the discharge has been generated.
    • 臭氧发生器设置有脉冲发生器(110),脉冲发生器(110)至少包括用于产生脉冲电压的脉冲发生装置和调整产生的脉冲电压的脉冲宽度的磁性开关(S12),以及设置有多个 施加脉冲宽度已被调整的脉冲电压的电极,由于施加了脉冲宽度的脉冲电压而在多个电极之间产生放电,并且 也由于从外部向生成了放电的电极之间供给氧的原料气体而产生臭氧。
    • 6. 发明申请
    • POSITIVE RESIST COMPOSITION AND METHOD OF FORMING RESIST PATTERN
    • 正电阻组合物和形成电阻图案的方法
    • US20090068588A1
    • 2009-03-12
    • US11816272
    • 2005-12-13
    • Yohei KinoshitaIsao Hirano
    • Yohei KinoshitaIsao Hirano
    • G03F7/004G03F7/20
    • G03F7/0397G03F7/0045G03F7/0046Y10S430/111Y10S430/122Y10S430/123
    • A positive resist composition that includes a resin component (A) that exhibits increased alkali solubility under the action of acid, and an acid generator component (B) that generates acid on exposure to radiation, wherein the component (A) includes a structural unit (a1) represented by a general formula (a1-2) or (a1-4), a structural unit (a2) derived from an acrylate ester that contains a lactone-containing monocyclic or polycyclic group, and a structural unit (a3), which is different from the structural unit (a1) and the structural unit (a2), and is derived from an acrylate ester that contains an aliphatic cyclic group-containing non-acid-dissociable, dissolution-inhibiting group and contains no polar groups, and the component (B) includes an onium salt (B1) having an anion portion represented by a formula: R41—SO3−.
    • 包含在酸作用下表现出增加的碱溶性的树脂组分(A)的阳性抗蚀剂组合物和在暴露于辐射时产生酸的酸产生剂组分(B),其中组分(A)包括结构单元( a1)由(a1-2)或(a1-4)表示的结构单元(a2),由含有内酯单环或多环基团的丙烯酸酯衍生的结构单元(a2)和结构单元(a3) 与结构单元(a1)和结构单元(a2)不同,并且衍生自含有脂族环状基团的非酸解离性,溶解抑制基团且不含极性基团的丙烯酸酯,并且 组分(B)包括具有由式R 41 -SO 3 - 表示的阴离子部分的鎓盐(B1)。