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1. 发明授权

US09346952B2 Stain-resistant article and use thereof 有权
标题翻译：耐污渍制品及其用途
公开(公告)号：US09346952B2
公开(公告)日：2016-05-24
申请号：US13861529
申请日：2013-04-12
申请人： Etienne Aepli , Mark Pfleghar , Botho Hoffmann , Heinz Hoff
发明人： Etienne Aepli , Mark Pfleghar , Botho Hoffmann , Heinz Hoff
IPC分类号： C08L77/06 , C08K3/30 , C08G69/14 , C08G69/26 , C08K7/14 , C08K3/22
CPC分类号： C08L77/06 , C08G69/14 , C08G69/26 , C08K3/22 , C08K3/30 , C08K7/14 , C08K2003/2241 , C08K2003/3036 , C08L2205/02
摘要： What is described is the use of a polyamide moulding composition for the production of a stain-resistant article, the staining tendency (ST) of the article being at least 2. Here, the composition contains 30-100% by weight of a polyamide or a polyamide mixture, consisting of 50-100% by weight of at least one amorphous and/or microcrystalline polyamide having a glass transition temperature of at least 100° C., based on: 20-100 mol % of at least one cycloaliphatic diamine; and 0-80 mol % of at least one other aliphatic and/or aromatic diamine; and also aromatic and/or aliphatic dicarboxylic acids comprising at least 6 carbon atoms, and 0-50% by weight of at least one semi-aromatic polyamide. In addition, 0-70% by weight of fibrous fillers (B1) and/or particulate fillers (B2), 0-30% by weight of impact toughness modifier and/or polymers different from (A), 0-25% by weight of a flame retardant, and 0-3% by weight of additives may also be contained.
摘要翻译：描述的是使用聚酰胺模塑组合物来生产耐污渍制品，制品的染色趋势（ST）至少为2.这里，组合物含有30-100重量％的聚酰胺或至少一种玻璃化转变温度至少为100℃的至少一种无定形和/或微晶聚酰胺组成的聚酰胺混合物，基于：20-100摩尔％的至少一种脂环族二胺; 和0-80摩尔％的至少一种其它脂族和/或芳族二胺; 以及包含至少6个碳原子的芳族和/或脂族二羧酸和0-50重量％的至少一种半芳族聚酰胺。此外，0-70重量％的纤维填料（B1）和/或颗粒填料（B2），0-30重量％的冲击韧性改性剂和/或不同于（A）的聚合物，0-25重量％的阻燃剂，并且还可以含有0-3重量％的添加剂。

2. 发明申请

US20100203275A1 TRANSPARENT POLYAMIDE ELASTOMERS 审中-公开
标题翻译：透明聚酰胺弹性体
公开(公告)号：US20100203275A1
公开(公告)日：2010-08-12
申请号：US12670306
申请日：2008-07-17
申请人： Botho Hoffmann , Heinz Hoff
发明人： Botho Hoffmann , Heinz Hoff
IPC分类号： C08G69/08 , B32B1/08 , B29C45/00
CPC分类号： C08G69/26 , B29C39/006 , B29C45/0001 , B29C48/022 , C08G69/08 , C08G69/265 , C08G69/36 , C08G69/40 , C08G69/44 , Y10T428/139 , Y10T428/1397
摘要： A description is given, together with preferred applications, of a transparent polyamide elastomer of the general structure (I), where R1 is a polyamide segment formed from (a) 10-100 mol % of alkyl-substituted bis(aminocyclohexyl)methane and/or bis(aminocyclohexyl)propane and 0-90 mol % of other cycloaliphatic C6-C36 diamines and/or aliphatic C2-C36 diamines and/or aromatic C6-C36 diamines, the concentration figures being based on the total amount of diamine in the polyamide segment, and (b) aliphatic C4-C36 dicarboxylic acids and/or cycloaliphatic C8-C36 dicarboxylic acids and/or aromatic C8-C36 dicarboxylic acids, and (c) optionally lactams and/or aminocarboxylic acids C6-C12, R2 being selected from the group of the divalent radicals: linear or branched C2-C5 polyoxyalkylene, polyolefin, polysiloxane with a number-average molar mass in the range of 200-3000 g/mol, linear or branched, substituted or unsubstituted C2-C36 alkylene, C6-C36 cycloalkylene, C6-C20 aryl, polycaprolactone, polyesters based on aliphatic or cycloaliphatic dicarboxylic acids and diols, aliphatic polycarbonate, and also copolymers of or mixtures of these elements, and X1 and X2 independently of one another being amide (CONH) or ester (COO) bonds.
摘要翻译：连同一般结构（I）的透明聚酰胺弹性体一起被描述，其中R1是由（a）10-100摩尔％的烷基取代的双（氨基环己基）甲烷形成的聚酰胺链段和/ 或二（氨基环己基）丙烷和0-90摩尔％的其它脂环族C 6 -C 36二胺和/或脂肪族C 2 -C 36二胺和/或芳族C 6 -C 36二胺，其浓度图基于聚酰胺中二胺的总量和（b）脂族C 4 -C 36二羧酸和/或脂环族C 8 -C 36二羧酸和/或芳族C 8 -C 36二羧酸，和（c）任选的内酰胺和/或氨基羧酸C6-C12，R2选自二价基团：直链或支链C 2 -C 5聚氧化烯，聚烯烃，数均摩尔质量在200-3000g / mol范围内的聚硅氧烷，直链或支链的取代或未取代的C 2 -C 36亚烷基， C36亚环烷基，C6-C20芳基，聚己内酯，p 基于脂族或脂环族二羧酸和二醇的脂肪族聚酯，脂肪族聚碳酸酯，以及这些元素的共聚物或这些元素的混合物，X 1和X 2彼此独立地为酰胺（CONH）或酯（COO）键。

3. 发明授权

US07282551B2 Thermoplastic block copolymers consisting of polyalkyl(meth)acrylate and polyamide segments and the use thereof 有权
标题翻译：由（甲基）丙烯酸烷基酯和聚酰胺链段组成的热塑性嵌段共聚物及其用途
公开(公告)号：US07282551B2
公开(公告)日：2007-10-16
申请号：US10467994
申请日：2002-02-21
申请人： Heinz Hoff , Botho Hoffmann
发明人： Heinz Hoff , Botho Hoffmann
IPC分类号： C08F20/00 , C08F118/02 , C08L53/00
CPC分类号： B32B27/08
摘要： Polyamide polyalkyl(meth)acrylate block copolymers which are built from polyamide generating monomers in addition to 15-70 weight percent polyalkyl(meth)acrylates as well as products produced from same. The block copolymers are produced by producing polyamide or copolyamide blocks with an average molar mass in the range between 500 and 5,000 g/Mol with an amino end group in a first polymerization or polycondensation step and degassing in order to reduce the water content; adding, in a second step, α,ω-functionalized polyalkyl(meth)acrylate diols; and fully condensing the reaction mixture into high-molecular block copolymer (A) at a reduce pressure in a further polycondensation step; discharging it, or further processing it into molding bodies.
摘要翻译：聚酰胺聚（甲基）丙烯酸烷基酯嵌段共聚物，除了由15-70重量％的聚（甲基）丙烯酸烷基酯组成的聚酰胺产生单体以及由其制备的产品外还制成。嵌段共聚物通过在第一聚合或缩聚步骤中制备平均摩尔质量在500-5,000g / mol之间的氨基端基的聚酰胺或共聚酰胺嵌段来制备，并且为了降低水分含量进行脱气; 在第二步中加入α，ω官能化的（甲基）丙烯酸烷基酯二醇; 并在进一步缩聚步骤中以降低的压力将反应混合物充分冷凝成高分子嵌段共聚物（A）; 将其排出，或进一步将其加工成成型体。

4. 发明授权

US08022170B2 Copolyamides 有权
标题翻译：共聚酰胺
公开(公告)号：US08022170B2
公开(公告)日：2011-09-20
申请号：US10536494
申请日：2003-12-17
申请人： Botho Hoffmann , Heinz Hoff , Hanns-Jörg Liedloff , Ralph Kettl
发明人： Botho Hoffmann , Heinz Hoff , Hanns-Jörg Liedloff , Ralph Kettl
IPC分类号： C08G69/08
CPC分类号： C08G69/34
摘要： The invention relates to semi crystalline, melt processible, partially aromatic copolyamides, producible by condensation of at least the following monomers or the precondensates thereof: a) terephthalic acid b) at least one dimerised fatty acid with up to 44 carbon atoms and c) at least one aliphatic diamine of the formula H2N—(CH2)x—NH2, wherein x means a whole number from 4-18.
摘要翻译：本发明涉及半结晶，可熔融加工的部分芳族共聚酰胺，其可通过至少以下单体或其预缩合物的缩合产生：a）对苯二甲酸b）至少一种具有多达44个碳原子的二聚脂肪酸和c）至少一个式H2N-（CH2）x-NH2的脂族二胺，其中x表示4-18的整数。

5. 发明申请

US20060235190A1 Copolyamides 有权
标题翻译：共聚酰胺
公开(公告)号：US20060235190A1
公开(公告)日：2006-10-19
申请号：US10536494
申请日：2003-12-17
申请人： Botho Hoffmann , Heinz Hoff , Hanns-Jörg Liedloff , Ralph Kettl
发明人： Botho Hoffmann , Heinz Hoff , Hanns-Jörg Liedloff , Ralph Kettl
IPC分类号： C08G69/08
CPC分类号： C08G69/34
摘要： The invention relates to semi crystalline, melt processible, partially aromatic copolyamides, producible by condensation of at least the following monomers or the precondensates thereof: a) terephthalic acid b) at least one dimerised fatty acid with up to 44 carbon atoms and c) at least one aliphatic diamine of the formula H2N—(CH2)x—NH2, wherein x means a whole number from 4-18.
摘要翻译：本发明涉及半结晶，可熔融加工的部分芳族共聚酰胺，其可通过至少以下单体或其预缩合物的缩合产生：a）对苯二甲酸b）至少一种具有多达44个碳原子的二聚脂肪酸和c）至少一种式H 2 N-（CH 2）2 -NH 2的脂族二胺，其中x 指从4-18起的整数。

6. 发明授权

US08859662B2 Polyamide moulding material and use thereof for production of LED housing components 有权
标题翻译：聚酰胺成型材料及其用于生产LED外壳部件的用途
公开(公告)号：US08859662B2
公开(公告)日：2014-10-14
申请号：US13096374
申请日：2011-04-28
申请人： Nikolai Lamberts , Andreas Bayer , Manfred Hewel , Heinz Hoff
发明人： Nikolai Lamberts , Andreas Bayer , Manfred Hewel , Heinz Hoff
IPC分类号： C08K3/26 , C08K3/22 , C08K7/14
CPC分类号： C08K3/26 , C08K3/22 , C08K7/14 , C08L77/06
摘要： What is described is a polyamide molding material based on semicrystalline polyamides for production of LED housings or housing components with high strength, high long-term reflectivity and low blistering tendency. The polyamide moulding material proposed consists of the following components (A) 40 to 80% by weight of at least one semiaromatic polyamide based on at least 70 mol % of aromatic dicarboxylic acids and at least 70 mol % of aliphatic diamines having 4 to 18 carbon atoms and having a melting temperature in the range from 270° C. to 340° C. (B) 10 to 30% by weight of titanium dioxide particles (C) 5 to 20% by weight of glass fibres (D) 5-30% by weight of calcium carbonate. The percentages by weight of components (A) to (D) together add up to 100%, with the proviso that components (B), (C) and (D) meet the following conditions: (B)+(C)+(D)=20 to 60% by weight; weight ratio of (C)/(D) in the range from 0.25 to 1.5, where the polyamide molding material may optionally comprise customary additives (E) in addition to components (A) to (D), and where the amount thereof is in addition to the sum of components (A) to (D).
摘要翻译：描述的是用于生产具有高强度，高长期反射率和低起泡倾向的LED壳体或壳体部件的半结晶聚酰胺的聚酰胺模塑材料。提出的聚酰胺成型材料由以下组分（A）40至80重量％的至少一种基于至少70摩尔％的芳族二羧酸和至少70摩尔％的具有4至18个碳原子的脂族二胺的半芳族聚酰胺原子并且具有在270℃至340℃范围内的熔融温度。（B）10至30重量％的二氧化钛颗粒（C）5至20重量％的玻璃纤维（D）5-30 重量％的碳酸钙。组分（A）至（D）的重量百分比一起加起来为100％，条件是组分（B），（C）和（D）满足以下条件：（B）+（C）+（ D）= 20〜60重量％（C）/（D）的重量比在0.25至1.5的范围内，其中除了组分（A）至（D）之外，聚酰胺模塑材料可任选地包含常规添加剂（E），并且其量在（A）至（D）的总和除外。

7. 发明授权

US07135428B2 Catalyst solution for implementing anionic lactam polymerization, method for production thereof and polyamide moulding compound 失效
标题翻译：用于实施阴离子内酰胺聚合的催化剂溶液，其制备方法和聚酰胺模塑料
公开(公告)号：US07135428B2
公开(公告)日：2006-11-14
申请号：US10937721
申请日：2004-09-09
申请人： Eduard Schmid , Heinz Hoff , Ornulf Rexin
发明人： Eduard Schmid , Heinz Hoff , Ornulf Rexin
IPC分类号： B01J31/00
CPC分类号： C08G69/20 , C08G63/823
摘要： A catalyst solution for the anionic polymerization of lactones and/or lactams comprises a salt of at least one compound of the general formula I In this formula (I), R1 is H or an aliphatic, cycloaliphatic or aromatic radical with 1 to 12 C atoms which can also have heteroatoms or hetero groups, the radical R2, which is the same or different, is H, halogen, C1–C5-alkyl, ethoxy or wherein said solvation agent S comprises N-methylpyrrolidone, N-octylpyrrolidone, N-cyclohexylpyrrolidone, N-octylcaprolactam, tetrabutyl urea or mixtures thereof methoxy, and n=1, 2 or 3, and wherein the salt is dissolved in an aprotic solvation agent S.
摘要翻译：用于内酯和/或内酰胺阴离子聚合的催化剂溶液包含至少一种通式I化合物的盐。在该式（I）中，R 1是H或脂族，脂环族或具有1至12个C原子的芳族基团，其也可以具有杂原子或杂基团，相同或不同的基团R 2是H，卤素，C 1 H 3， -C 5 - 烷基，乙氧基或其中所述溶剂化物S包括N-甲基吡咯烷酮，N-辛基吡咯烷酮，N-环己基吡咯烷酮，N-辛基己内酰胺，四丁基脲或其混合物甲氧基，n = 1,2 或3，并且其中所述盐溶解在非质子溶剂化剂S中。

8. 发明申请

US20050090382A1 Catalyst solution for implementing anionic lactam polymerisation, method for production thereof and polyamide moulding compound 失效
标题翻译：用于实施阴离子内酰胺聚合的催化剂溶液，其制备方法和聚酰胺模塑料
公开(公告)号：US20050090382A1
公开(公告)日：2005-04-28
申请号：US10937721
申请日：2004-09-09
申请人： Eduard Schmid , Heinz Hoff , Ornulf Rexin
发明人： Eduard Schmid , Heinz Hoff , Ornulf Rexin
IPC分类号： C08G69/20 , C08G63/82 , B01J31/00 , C07F1/00
CPC分类号： C08G69/20 , C08G63/823
摘要： The invention relates to a solution of an alkali salt, which is strongly basic, clear, stable in storage and liquid at room temperature, of aniline, amidated with a monocarboxylic acid, or its derivatives in an aprotic solvation agent, a method for production thereof and the polyamides produced using this solution.
摘要翻译：本发明涉及在非质子传递溶剂化剂中，在碱存在下和液体中稳定的碱金属盐，苯胺与单羧酸或其衍生物酰胺化的方法，其生产方法和使用该溶液制备的聚酰胺。

9. 发明授权

US4327551A Multi-cylinder hot-gas engine with automatic air and gas supply 失效
标题翻译：具有自动空气和气体供应的多缸热气发动机
公开(公告)号：US4327551A
公开(公告)日：1982-05-04
申请号：US151883
申请日：1980-05-21
申请人： Joachim Grossmann , Heinz Hoff
发明人： Joachim Grossmann , Heinz Hoff
IPC分类号： F02G1/043 , F02G1/044 , F02G1/047 , F02G1/04
CPC分类号： F02G1/047 , F02G1/044
摘要： The temperature of the working gas in the heating chamber of each of a number of cylinders is continuously measured. An electronic selection circuit selects the lowest measured temperature as a control parameter by which the speed of a blower in the common air supply is controlled for providing an air flow proportional to blower speed. A pressure-detecting device measures the air flow through a pressure converter provides an electrical signal that normally controls the valves of the respective fuel supplies for the combustion chambers of the cylinders, but a monitoring device for each cylinder compares the measured working gas temperature with a pre-set maximum value so that when the maximum value is exceeded, the fuel supply valve is changed over to control by the output of the monitoring device, to reduce the fuel supply until the maximum temperature is no longer exceeded in that cylinder. For still a higher temperature of the working gas in any cylinder, determined by another sensor, a general shutdown valve reduces the common fuel supply. An auxiliary air supply provides atomizing air for fuel injection.
摘要翻译：连续地测量多个气缸中的每一个的加热室中的工作气体的温度。电子选择电路选择最低测量温度作为控制参数，通过该参数控制共用空气供应中的鼓风机的速度以提供与鼓风机速度成比例的空气流。压力检测装置测量通过压力转换器的气流提供通常控制用于气缸的燃烧室的相应燃料供应的阀的电信号，但是每个气缸的监测装置将测得的工作气体温度与预设最大值，使得当超过最大值时，通过监视装置的输出改变燃料供给阀以进行控制，以减少燃料供应，直到该气缸中不再超过最大温度。对于由另一个传感器确定的任何气缸中的工作气体的较高温度，一般关闭阀减少了常见的燃料供应。辅助空气源提供用于燃料喷射的雾化空气。

10. 发明授权

US5703177A Partially crystalline block copolyester-polyamides 失效
标题翻译：部分结晶嵌段共聚酯 - 聚酰胺
公开(公告)号：US5703177A
公开(公告)日：1997-12-30
申请号：US573058
申请日：1995-12-15
申请人： Heinz Hoff
发明人： Heinz Hoff
IPC分类号： C08G69/44 , C08G81/00
CPC分类号： C08G69/44
摘要： This invention relates to biologically degradable, partially crystalline block copolyester-polyamides comprising at least two chemically differently structured segments of which at least one is a polyester (PES) block or a copolyester (coPES) block, preferably with a number average molecular mass of 340 to 10,000 g/mole, and at least one is a polyamide (PA) block or a copolyamide (coPA) block, preferably with a number average molecular mass of 400 to 3,000 g/mole. In addition, copolyester-amide (coPEA) blocks can be employed, preferably with a number average molecular mass of 500 to 5,000 g/mole. The invention also relates to a polycondensation process for the manufacture of these partially crystalline block copolyester-polyamides. The block copolymers described are useful for the manufacture of fibers, foils, molded articles and hot melt-type adhesives. Molded components manufactured from the copolymers in accordance with the invention are biologically degradable and are capable of being composted.
摘要翻译：本发明涉及生物可降解的部分结晶的嵌段共聚酯 - 聚酰胺，其包含至少两个化学上不同的结构化部分，其中至少一个是聚酯（PES）嵌段或共聚酯（coPES）嵌段，优选数均分子量为340 至10,000g / mol，并且至少一种是聚酰胺（PA）嵌段或共聚酰胺（coPA）嵌段，优选数均分子量为400至3,000g / mol。此外，可以使用共聚酯 - 酰胺（coPEA）嵌段，优选数均分子量为500-5,000g / mol。本发明还涉及用于制造这些部分结晶嵌段共聚酯 - 聚酰胺的缩聚方法。所述的嵌段共聚物可用于制造纤维，箔，模塑制品和热熔型粘合剂。由本发明的共聚物制成的成型部件是生物可降解的并且能够被堆肥。

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