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1. 发明申请

US20120225278A1 METHOD FOR PRODUCING A FOAM COMPOSITE ELEMENT 有权
标题翻译：生产泡沫复合材料元素的方法
公开(公告)号：US20120225278A1
公开(公告)日：2012-09-06
申请号：US13388409
申请日：2010-07-23
申请人： Johannes Van De Braak , Rolf Roers , Peter Haas
发明人： Johannes Van De Braak , Rolf Roers , Peter Haas
IPC分类号： B32B5/18 , B32B37/06 , B32B5/32 , B32B37/12
CPC分类号： C08G18/0876 , B32B5/022 , B32B5/18 , B32B5/22 , B32B5/245 , B32B7/12 , B32B11/046 , B32B11/048 , B32B15/046 , B32B15/08 , B32B15/18 , B32B15/20 , B32B21/047 , B32B21/08 , B32B27/065 , B32B27/08 , B32B27/10 , B32B27/12 , B32B27/285 , B32B27/36 , B32B27/40 , B32B29/007 , B32B2262/02 , B32B2262/108 , B32B2266/0278 , B32B2307/304 , B32B2307/50 , C08G18/1808 , C08G18/1816 , C08G18/225 , C08G18/4018 , C08G18/4202 , C08G18/4211 , C08G18/4216 , C08G18/4261 , C08G18/4833 , C08G18/4837 , C08G18/6685 , C08G2101/00 , C08G2105/02 , C08J5/02 , C08J5/12 , C08J9/141 , C08J2375/06 , C09J5/02 , Y10T428/249981 , Y10T428/249985
摘要： The invention relates to a process for the production of a foam composite element, comprising the steps of providing a facing, applying adhesion promoter, and applying a foam layer comprising polyurethane and/or polyisocyanurate to the adhesion promoter, characterised in that the adhesion promoter consists of at least one compound selected from the group consisting of polyether polyol (B.1), polymer polyol (B.2), polyurea dispersion (B.3), polyester polyol (B.4) and PIPA polyol (B.5). The invention relates further to the use of at least one compound selected from the group consisting of polyether polyol, polymer polyol and polyurea dispersion as adhesion promoter in the production of foam composite elements, as well as to foam composite elements produced by the process according to the invention.
摘要翻译：本发明涉及一种生产泡沫复合材料的方法，包括以下步骤：提供面对的，施加的粘合促进剂，以及将包含聚氨酯和/或聚异氰脲酸酯的泡沫层施加到粘合促进剂上，其特征在于粘合促进剂组成的选自聚醚多元醇（B.1），聚合物多元醇（B.2），聚脲分散体（B.3），聚酯多元醇（B.4）和PIPA多元醇（B.5））中的至少一种化合物，。本发明进一步涉及至少一种选自聚醚多元醇，聚合物多元醇和聚脲分散体的化合物在生产泡沫复合材料中作为粘合促进剂的用途，以及通过根据本发明的方法生产的泡沫复合材料本发明。

2. 发明申请

US20120121887A1 METHOD FOR PREPARING A FOAM COMPOSITE ELEMENT 审中-公开
标题翻译：制备泡沫复合材料元素的方法
公开(公告)号：US20120121887A1
公开(公告)日：2012-05-17
申请号：US13322172
申请日：2010-05-14
申请人： Johannes Van De Braak , Rene Abels , Rolf Roers , Peter Haas
发明人： Johannes Van De Braak , Rene Abels , Rolf Roers , Peter Haas
IPC分类号： B05D3/10 , B32B27/10 , B32B27/06
CPC分类号： C08G18/4812 , B32B5/18 , B32B5/245 , B32B7/12 , B32B15/046 , B32B15/18 , B32B15/20 , B32B21/047 , B32B27/065 , B32B29/007 , B32B2262/02 , B32B2262/10 , B32B2266/0278 , B32B2266/08 , B32B2307/304 , B32B2307/3065 , B32B2307/50 , B32B2307/72 , C08G18/10 , C08G18/4018 , C08G18/4211 , C08G18/4845 , C08G2101/0008 , C08J9/141 , C08J2375/04 , C09J5/02 , Y10T428/249985
摘要： The invention relates to a method for preparing a foam composite element, including the steps of preparing a top layer, applying an adhesion promoter layer to the top layer, wherein the adhesion promoter layer includes a modified isocyanate, and applying a foam layer including polyurethane and/or polyisocyanurate to the adhesion promoter layer. On application, the modified isocyanate in the adhesion promoter layer has a content of free isocyanate groups of from ≧10% to ≦29%. The invention further relates to the use of a modified isocyanate having a content of free isocyanate groups of ≧10% to ≦29% as an adhesion promoter in the preparation of foam composite elements and foam composite elements obtained by the method according to the invention.
摘要翻译：本发明涉及一种制备泡沫复合材料的方法，包括制备顶层，向顶层施加粘合促进剂层的步骤，其中粘合促进剂层包括改性的异氰酸酯，并施加包括聚氨酯的泡沫层和 /或聚异氰脲酸酯转移至粘附促进剂层。应用时，粘合促进剂层中的改性异氰酸酯的游离异氰酸酯基的含量为≥10％至≥NE; 29％。本发明还涉及在通过本发明的方法获得的泡沫复合材料和泡沫复合材料的制备中，作为粘合促进剂，使用游离异氰酸酯基含量为≥10％至≥100; 29％的改性异氰酸酯。

3. 发明授权

US09382371B2 Method for producing a foam composite element 有权
标题翻译：泡沫复合材料的制造方法
公开(公告)号：US09382371B2
公开(公告)日：2016-07-05
申请号：US13388409
申请日：2010-07-23
申请人： Johannes Van De Braak , Rolf Roers , Peter Haas
发明人： Johannes Van De Braak , Rolf Roers , Peter Haas
IPC分类号： C04B37/00 , C08G18/08 , B32B5/18 , B32B7/12 , B32B27/40 , C08G18/18 , C08G18/22 , C08G18/40 , C08G18/42 , C08G18/48 , C08G18/66 , C08J5/12 , C08J9/14 , C08J5/02 , C08G101/00
CPC分类号： C08G18/0876 , B32B5/022 , B32B5/18 , B32B5/22 , B32B5/245 , B32B7/12 , B32B11/046 , B32B11/048 , B32B15/046 , B32B15/08 , B32B15/18 , B32B15/20 , B32B21/047 , B32B21/08 , B32B27/065 , B32B27/08 , B32B27/10 , B32B27/12 , B32B27/285 , B32B27/36 , B32B27/40 , B32B29/007 , B32B2262/02 , B32B2262/108 , B32B2266/0278 , B32B2307/304 , B32B2307/50 , C08G18/1808 , C08G18/1816 , C08G18/225 , C08G18/4018 , C08G18/4202 , C08G18/4211 , C08G18/4216 , C08G18/4261 , C08G18/4833 , C08G18/4837 , C08G18/6685 , C08G2101/00 , C08G2105/02 , C08J5/02 , C08J5/12 , C08J9/141 , C08J2375/06 , C09J5/02 , Y10T428/249981 , Y10T428/249985
摘要： The invention relates to a process for the production of a foam composite element, comprising the steps of providing a facing, applying adhesion promoter, and applying a foam layer comprising polyurethane and/or polyisocyanurate to the adhesion promoter, characterized in that the adhesion promoter consists of at least one compound selected from the group consisting of polyether polyol (B.1), polymer polyol (B.2), polyurea dispersion (B.3), polyester polyol (B.4) and PIPA polyol (B.5). The invention relates further to the use of at least one compound selected from the group consisting of polyether polyol, polymer polyol and polyurea dispersion as adhesion promoter in the production of foam composite elements, as well as to foam composite elements produced by the process according to the invention.
摘要翻译：本发明涉及一种生产泡沫复合材料的方法，包括以下步骤：提供面对的，施加的粘合促进剂，以及将包含聚氨酯和/或聚异氰脲酸酯的泡沫层施加到粘合促进剂上，其特征在于粘合促进剂组成的选自聚醚多元醇（B.1），聚合物多元醇（B.2），聚脲分散体（B.3），聚酯多元醇（B.4）和PIPA多元醇（B.5））中的至少一种化合物，。本发明进一步涉及至少一种选自聚醚多元醇，聚合物多元醇和聚脲分散体的化合物在生产泡沫复合材料中作为粘合促进剂的用途，以及通过根据本发明的方法生产的泡沫复合材料本发明。

4. 发明授权

US08592623B2 Method for producing polyester polyols having low amounts of dioxane waste 有权
标题翻译：制备少量二恶烷废物的聚酯多元醇的方法
公开(公告)号：US08592623B2
公开(公告)日：2013-11-26
申请号：US13127300
申请日：2009-11-03
申请人： Rolf Roers , Hartmut Nefzger , Erika Bauer , Johannes Van De Braak , Torsten Heinemann , Jürgen Schloβmacher
发明人： Rolf Roers , Hartmut Nefzger , Erika Bauer , Johannes Van De Braak , Torsten Heinemann , Jürgen Schloβmacher
IPC分类号： C08G63/20 , C07C69/54
CPC分类号： C08G18/425 , C08G18/4018 , C08G18/7664 , C08G18/794 , C08G63/672 , C08G63/78 , C08G2101/0025 , C08G2101/005 , C08G2350/00 , Y10T428/24999
摘要： Polyester polyols are produced from at least one carboxylic acid hydride and diethylene glycol by a process in which the formation of 1,4-dioxane is suppressed. These polyester polyols are useful for producing polyurethane (PUR) and polyisocyanurate (PIR) foams and metal composite elements containing these PUR or PIR foams.
摘要翻译：通过抑制1,4-二恶烷的形成的方法由至少一种羧酸氢化物和二甘醇制备聚酯多元醇。这些聚酯多元醇可用于制备含有这些PUR或PIR泡沫的聚氨酯（PUR）和聚异氰脲酸酯（PIR）泡沫和金属复合元素。

5. 发明申请

US20110236671A1 METHOD FOR PRODUCING POLYESTER POLYOLS HAVING LOW AMOUNTS OF DIOXANE WASTE 有权
标题翻译：用于生产具有二氧化碳废物含量低的聚酯多元醇的方法
公开(公告)号：US20110236671A1
公开(公告)日：2011-09-29
申请号：US13127300
申请日：2009-11-03
申请人： Rolf Roers , Hartmut Nefzger , Erika Bauer , Johannes Van De Braak , Torsten Heinemann , Jürgen Schlossmacher
发明人： Rolf Roers , Hartmut Nefzger , Erika Bauer , Johannes Van De Braak , Torsten Heinemann , Jürgen Schlossmacher
IPC分类号： B32B3/26 , C08L75/06 , C07C69/34
CPC分类号： C08G18/425 , C08G18/4018 , C08G18/7664 , C08G18/794 , C08G63/672 , C08G63/78 , C08G2101/0025 , C08G2101/005 , C08G2350/00 , Y10T428/24999
摘要： Polyester polyols are produced from at least one carboxylic acid hydride and diethylene glycol by a process in which the formation of 1,4-dioxane is suppressed. These polyester polyols are useful for producing polyurethane (PUR) and polyisocyanurate (PIR) foams and metal composite elements containing these PUR or PIR foams.
摘要翻译：通过抑制1,4-二恶烷的形成的方法由至少一种羧酸氢化物和二甘醇制备聚酯多元醇。这些聚酯多元醇可用于制备含有这些PUR或PIR泡沫的聚氨酯（PUR）和聚异氰脲酸酯（PIR）泡沫和金属复合元素。

6. 发明申请

US20120123009A1 POLYESTER POLYOLS MADE OF ISOPHTHALIC ACID AND/OR TEREPHTHALIC ACID AND OLIGOALKYL OXIDES 有权
标题翻译：异辛酸和/或正十二酸和低聚乙烯氧化物的聚酯多元醇
公开(公告)号：US20120123009A1
公开(公告)日：2012-05-17
申请号：US13322989
申请日：2010-05-18
申请人： Hartmut Nefzger , Erika Bauer , Johannes Van De Braak , Jürgen Schlossmacher , Silvia Kasperek
发明人： Hartmut Nefzger , Erika Bauer , Johannes Van De Braak , Jürgen Schlossmacher , Silvia Kasperek
IPC分类号： C08L75/06 , C08J9/00 , C07C69/82
CPC分类号： C08G18/4252 , C08G18/4211 , C08G63/672 , C08G63/85 , C08G2101/0025 , C08G2101/005 , C08G2105/02
摘要： The present invention relates to a method for producing a polyester polyol having a concentration of ether groups in the range from 9.0 mol/kg of polyester polyol to 22 mol/kg polyester polyol, characterized in that (i) in a first step (A) isophthalic acid, optionally in the form of a C1-C4 alkyl ester, and/or terephthalic acid, optionally in the form of a C1-C4 alkyl ester, is reacted with (B) oligoethylene glycol of the formula H—(OCH2CH2)n—OH having a numerical average number of oxyethylene groups n in the range from 3.0 to 9.0, in the presence of at least one catalyst selected from the group made up of tin(II) salts, bismuth(II) salts, and titanium tetraalkoxylates, at a temperature in the range from 160° C. to 240° C., and at a pressure in the range from 1 to 1013 mbar, for a duration in the range from 7 to 100 hours, and (ii) in a second step the reaction mixture resulting from step (i) is reacted with (C) phthalic acid and/or phthalic acid hydride, the polyester polyols obtained according to said method, and to the use thereof for producing PUR/PIR hard foam materials
摘要翻译：本发明涉及一种聚酯多元醇的制造方法，所述聚酯多元醇的浓度为9.0摩尔/千克聚酯多元醇至22摩尔/千克聚酯多元醇，其特征在于，（i）在第一步骤（A）任选呈C1-C4烷基酯形式的间苯二甲酸和/或对苯二甲酸，任选呈C1-C4烷基酯形式，与式（B）的低聚乙二醇（H 2 OCH 2 CH 2）n -OH在数均平均数为3.0至9.0的范围内，在至少一种选自锡（II）盐，铋（II）盐和四烷氧基钛酸盐的催化剂存在下，在160℃至240℃的温度范围内和在1至1013毫巴的压力下持续7至100小时的持续时间，和（ii）在第二步骤中由步骤（i）得到的反应混合物与（C）邻苯二甲酸和/或邻苯二甲酸氢化物反应，聚酯多元醇根据所述方法染色，以及其用于生产PUR / PIR硬泡沫材料的用途

7. 发明申请

US20050257893A1 Apparatus and process for the production of sandwich composite elements 有权
标题翻译：用于生产夹心复合材料的装置和方法
公开(公告)号：US20050257893A1
公开(公告)日：2005-11-24
申请号：US11120453
申请日：2005-05-03
申请人： Thomas Rub , Johannes Van De Braak
发明人： Thomas Rub , Johannes Van De Braak
IPC分类号： B05B3/10 , B05C3/10 , B32B5/00 , B32B31/00 , B32B31/18
CPC分类号： B05B3/1021 , B05B3/001 , B29C44/129 , B29C44/321 , B29C44/326 , B32B37/1284 , B32B2038/0084 , B32B2305/022 , B32B2311/00 , Y10T156/1052 , Y10T156/12 , Y10T156/1317 , Y10T156/1343 , Y10T156/1352 , Y10T156/1361 , Y10T156/1702
摘要： An apparatus for the production of sandwich composite elements which includes at least two feed apparatus for facings, to which an application apparatus for an adhesion promoter, an application apparatus for a core layer, a conveying apparatus and a cutting apparatus are connected one after the other. The application apparatus for the adhesion promoter includes at least one feed line for the adhesion promoter, a rotary table with at least one lateral outlet orifice and a drive for the rotary table.
摘要翻译：一种用于生产夹层复合元件的装置，其包括至少两个面板供给装置，用于粘合促进剂的施加装置，用于芯层的施加装置，输送装置和切割装置一个接一个地连接到该装置。用于粘合促进剂的施加装置包括至少一个用于粘合促进剂的进料管线，具有至少一个侧向出口孔口的旋转工作台和用于旋转工作台的驱动装置。

8. 发明授权

US09605106B2 Polyester polyols made of isophthalic acid and/or terephthalic acid and oligoalkyl oxides 有权
公开(公告)号：US09605106B2
公开(公告)日：2017-03-28
申请号：US13322989
申请日：2010-05-18
申请人： Hartmut Nefzger , Erika Bauer , Johannes Van De Braak , Jürgen Schlossmacher , Silvia Kasperek
发明人： Hartmut Nefzger , Erika Bauer , Johannes Van De Braak , Jürgen Schlossmacher , Silvia Kasperek
IPC分类号： C08L75/06 , C08J9/00 , C07C69/82 , C08G18/42 , C08G63/672 , C08G63/85 , C08G101/00
CPC分类号： C08G18/4252 , C08G18/4211 , C08G63/672 , C08G63/85 , C08G2101/0025 , C08G2101/005 , C08G2105/02
摘要： The present invention relates to a method for producing a polyester polyol having a concentration of ether groups in the range from 9.0 mol/kg of polyester polyol to 22 mol/kg polyester polyol, characterized in that (i) in a first step (A) isophthalic acid, optionally in the form of a C1-C4 alkyl ester, and/or terephthalic acid, optionally in the form of a C1-C4 alkyl ester, is reacted with (B) oligoethylene glycol of the formula H—(OCH2CH2)n—OH having a numerical average number of oxyethylene groups n in the range from 3.0 to 9.0, in the presence of at least one catalyst selected from the group made up of tin(II) salts, bismuth(II) salts, and titanium tetraalkoxylates, at a temperature in the range from 160° C. to 240° C., and at a pressure in the range from 1 to 1013 mbar, for a duration in the range from 7 to 100 hours, and (ii) in a second step the reaction mixture resulting from step (i) is reacted with (C) phthalic acid and/or phthalic acid hydride, the polyester polyols obtained according to said method, and to the use thereof for producing PUR/PIR hard foam materials.

9. 发明申请

US20120129966A1 PROCESS FOR PRODUCING POLYESTER POLYOLS WITH LOW QUANTITIES OF DIOXANE WASTE 审中-公开
标题翻译：用于生产低浓度二氧化硫废物的聚酯多元醇的方法
公开(公告)号：US20120129966A1
公开(公告)日：2012-05-24
申请号：US13376450
申请日：2010-06-02
申请人： Hartmut Nefzger , Erika Bauer , Johannes Van De Braak , Silvia Kasperek
发明人： Hartmut Nefzger , Erika Bauer , Johannes Van De Braak , Silvia Kasperek
IPC分类号： C08G18/42 , C07C69/82 , C07C67/08
CPC分类号： C08G18/4252 , C08G18/4018 , C08G63/181 , C08G2101/0025 , C08G2101/005 , C08K5/0066 , C08L75/06
摘要： The present invention relates to the production and use of polyester polyols produced from at least one aromatic dicarboxylic acid or an alkyl ester of an aromatic dicarboxylic acid or the anhydride of an aromatic dicarboxylic acid and at least one α,ω-diol, wherein the formation of 1,4-dioxane from diethylene glycol is largely suppressed by means of specific reaction management.
摘要翻译：本发明涉及由至少一种芳族二羧酸或芳族二羧酸的烷基酯或芳族二羧酸的酸酐和至少一种α，ω-二醇制备的聚酯多元醇的制造和使用，其中形成的二甘醇的1,4-二恶烷通过特定的反应管理被大大抑制。

10. 发明授权

US07540932B2 Apparatus and process for the production of sandwich composite elements 有权
标题翻译：用于生产夹心复合材料的装置和方法
公开(公告)号：US07540932B2
公开(公告)日：2009-06-02
申请号：US11120453
申请日：2005-05-03
申请人： Thomas Rüb , Johannes Van De Braak
发明人： Thomas Rüb , Johannes Van De Braak
IPC分类号： B32B37/00 , B32B38/04 , B32B38/10 , B29C65/00 , C08J5/00 , C09J5/02 , B05C5/00 , B05D1/26
CPC分类号： B05B3/1021 , B05B3/001 , B29C44/129 , B29C44/321 , B29C44/326 , B32B37/1284 , B32B2038/0084 , B32B2305/022 , B32B2311/00 , Y10T156/1052 , Y10T156/12 , Y10T156/1317 , Y10T156/1343 , Y10T156/1352 , Y10T156/1361 , Y10T156/1702
摘要： An apparatus for the production of sandwich composite elements which includes at least two feed apparatus for facings, to which an application apparatus for an adhesion promoter, an application apparatus for a core layer, a conveying apparatus and a cutting apparatus are connected one after the other. The application apparatus for the adhesion promoter includes at least one feed line for the adhesion promoter, a rotary table with at least one lateral outlet orifice and a drive for the rotary table.
摘要翻译：一种用于生产夹层复合元件的装置，其包括至少两个面板供给装置，用于粘合促进剂的施加装置，用于芯层的施加装置，输送装置和切割装置一个接一个地连接到该装置。用于粘合促进剂的施加装置包括至少一个用于粘合促进剂的进料管线，具有至少一个侧向出口孔口的旋转工作台和用于旋转工作台的驱动装置。

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