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1. 发明申请

US20100113700A1 CURABLE FLUORINE-CONTAINING POLYMER COMPOSITION 有权
标题翻译：可固化含氟聚合物组合物
公开(公告)号：US20100113700A1
公开(公告)日：2010-05-06
申请号：US12445354
申请日：2007-10-12
申请人： Katsuhiko Imoto , Tetsuo Shimizu , Tatsuya Morikawa , Masayuki Hayashi , Tomohiro Iimura , Peter Cheshire Hupfield
发明人： Katsuhiko Imoto , Tetsuo Shimizu , Tatsuya Morikawa , Masayuki Hayashi , Tomohiro Iimura , Peter Cheshire Hupfield
IPC分类号： C08F8/00 , C08F14/00
CPC分类号： C08G18/8108 , C08G18/6279 , C08G77/045 , C08G77/12 , C08G77/442 , C08K5/5419 , C08L27/12 , C08L31/02 , C08L83/04 , C09D127/12 , C09D127/18 , C09D127/20 , C09D131/02 , C08L2666/04 , C08L2666/14
摘要： There is provided a curable fluorine-containing polymer composition which is quickly cured at relatively low temperatures by hydrosilylation reaction and provides a coating film which has high hardness, excellent solvent resistance and flexibility. The curable fluorine-containing polymer composition comprises a fluorine-containing polymer comprising a fluorinated ethylenic monomer unit and a non-fluorinated ethylenic monomer unit, in which a part or the whole of the non-fluorinated ethylenic monomer units is a unit represented by the formula: wherein R1 is hydrogen or methyl; R2 is a hydrocarbon group having ethylenic C═C; X is —C(O)NH— or —C(O)—; R3 is —O—, —O[CH(R4)]mO—, —(CH2)mO—, —OC(O)—(CH2)mO— or —(CH2)mOC(O)—(CH2)nO—, where R4 is —H, —OH, —CH2OH or —O—X—R2, a siloxane compound having hydrogen atom bonded to silicon atom, and a catalyst for hydrosilylation reaction.
摘要翻译：提供一种通过氢化硅烷化反应在相对低的温度下快速固化的可固化含氟聚合物组合物，并提供具有高硬度，优异的耐溶剂性和柔性的涂膜。可固化含氟聚合物组合物包含含有氟化乙烯性单体单元和非氟化乙烯性单体单元的含氟聚合物，其中一部分或全部未氟化烯属单体单元为式其中R1是氢或甲基; R2是具有烯属C = C的烃基; X是-C（O）NH-或-C（O） - ; R 3是-O-，-O [CH（R 4）] m O - ， - （CH 2）m O - ， - OC（O） - （CH 2）m O-或 - （CH 2）mOC（O） - （CH 2）其中R4是-H，-OH，-CH2OH或-O-X-R2，具有与硅原子键合的氢原子的硅氧烷化合物和氢化硅烷化反应的催化剂。

2. 发明授权

US09127114B2 Curable fluorine-containing polymer composition 有权
标题翻译：可固化含氟聚合物组合物
公开(公告)号：US09127114B2
公开(公告)日：2015-09-08
申请号：US12445354
申请日：2007-10-12
申请人： Katsuhiko Imoto , Tetsuo Shimizu , Tatsuya Morikawa , Masayuki Hayashi , Tomohiro Iimura , Peter Cheshire Hupfield
发明人： Katsuhiko Imoto , Tetsuo Shimizu , Tatsuya Morikawa , Masayuki Hayashi , Tomohiro Iimura , Peter Cheshire Hupfield
IPC分类号： C08G18/81 , C09D127/18 , C09D127/12 , C09D127/20 , C08G18/62 , C08G77/442 , C08L83/04 , C09D131/02 , C08G77/04 , C08G77/12 , C08K5/5419 , C08L27/12 , C08L31/02
CPC分类号： C08G18/8108 , C08G18/6279 , C08G77/045 , C08G77/12 , C08G77/442 , C08K5/5419 , C08L27/12 , C08L31/02 , C08L83/04 , C09D127/12 , C09D127/18 , C09D127/20 , C09D131/02 , C08L2666/04 , C08L2666/14
摘要： There is provided a curable fluorine-containing polymer composition which is quickly cured at relatively low temperatures by hydrosilylation reaction and provides a coating film which has high hardness, excellent solvent resistance and flexibility. The curable fluorine-containing polymer composition comprises a fluorine-containing polymer comprising a fluorinated ethylenic monomer unit and a non-fluorinated ethylenic monomer unit, in which a part or the whole of the non-fluorinated ethylenic monomer units is a unit represented by the formula: wherein R1 is hydrogen or methyl; R2 is a hydrocarbon group having ethylenic C═C; X is —C(O)NH— or —C(O)—; R3 is —O—, —O[CH(R4)]mO—, —(CH2)mO—, —OC(O)—(CH2)mO— or —(CH2)mOC(O)—(CH2)nO—, where R4 is —H, —OH, —CH2OH or —O—X—R2, a siloxane compound having hydrogen atom bonded to silicon atom, and a catalyst for hydrosilylation reaction.
摘要翻译：提供一种通过氢化硅烷化反应在相对低的温度下快速固化的可固化含氟聚合物组合物，并提供具有高硬度，优异的耐溶剂性和柔性的涂膜。可固化含氟聚合物组合物包含含有氟化乙烯性单体单元和非氟化乙烯性单体单元的含氟聚合物，其中一部分或全部未氟化烯属单体单元为式其中R1是氢或甲基; R2是具有烯属C = C的烃基; X是-C（O）NH-或-C（O） - ; R 3是-O-，-O [CH（R 4）] m O - ， - （CH 2）m O - ， - OC（O） - （CH 2）m O-或 - （CH 2）mOC（O） - （CH 2）其中R4是-H，-OH，-CH2OH或-O-X-R2，具有与硅原子键合的氢原子的硅氧烷化合物和氢化硅烷化反应的催化剂。

3. 发明授权

US08026313B2 Curable polymer composition 有权
标题翻译：可固化的聚合物组成
公开(公告)号：US08026313B2
公开(公告)日：2011-09-27
申请号：US12514935
申请日：2007-12-06
申请人： Katsuhiko Imoto , Tetsuo Shimizu , Masayuki Hayashi , Tomohiro Iimura , Eiji Kitaura , Peter Cheshire Hupfield
发明人： Katsuhiko Imoto , Tetsuo Shimizu , Masayuki Hayashi , Tomohiro Iimura , Eiji Kitaura , Peter Cheshire Hupfield
IPC分类号： C08L9/00 , C08L27/12 , C08L29/00 , C08L31/00 , C08L33/02 , C08L33/04 , C08L35/02 , C08L45/00
CPC分类号： C08L27/16 , C08L27/14 , C08L33/04 , C08L2666/04
摘要： A curable polymer composition that is quickly curable to form a cured article having excellent adhesion and followability to a substrate and at least including (A) an acrylic copolymer having a hydrogen atom bonded to a silicon atom, (B) a compound having at least two aliphatic unsaturated bonds in one molecule thereof, (C) a fluoroolefin copolymer including vinylidene fluoride as main component, and (D) a catalyst for hydrosilylation reaction.
摘要翻译：一种可固化的聚合物组合物，其可快速固化以形成具有优异的粘合性和对基材的追随性的固化制品，并且至少包括（A）具有与硅原子键合的氢原子的丙烯酸共聚物，（B）具有至少两个一个分子中的脂族不饱和键，（C）以偏氟乙烯为主成分的氟烯烃共聚物，（D）氢化硅烷化反应用催化剂。

4. 发明申请

US20100076158A1 CURABLE POLYMER COMPOSITION 有权
标题翻译：可固化聚合物组合物
公开(公告)号：US20100076158A1
公开(公告)日：2010-03-25
申请号：US12514935
申请日：2007-12-06
申请人： Katsuhiko Imoto , Tetsuo Shimizu , Masayuki Hayashi , Tomohiro Iimura , Eiji Kitaura , Peter Cheshire Hupfield
发明人： Katsuhiko Imoto , Tetsuo Shimizu , Masayuki Hayashi , Tomohiro Iimura , Eiji Kitaura , Peter Cheshire Hupfield
IPC分类号： C08L27/16
CPC分类号： C08L27/16 , C08L27/14 , C08L33/04 , C08L2666/04
摘要： There is provided a curable polymer composition being curable quickly to form a cured article having excellent adhesion and followability to a substrate and at least comprising (A) an acrylic copolymer having a hydrogen atom bonded to a silicon atom, (B) a compound having at least two aliphatic unsaturated bonds in one molecule thereof, (C) a fluoroolefin copolymer comprising vinylidene fluoride as main component, and (D) a catalyst for hydrosilylation reaction.
摘要翻译：提供了可固化的聚合物组合物，其可快速固化以形成具有优异的粘附性和对基材的追随性的固化制品，并且至少包含（A）具有与硅原子键合的氢原子的丙烯酸共聚物，（B）其一分子中含有至少两个脂族不饱和键，（C）以偏氟乙烯为主要成分的氟代烯烃共聚物，（D）氢化硅烷化反应催化剂。

5. 发明授权

US09018306B2 Curable fluorine-containing polymer composition 有权
标题翻译：可固化含氟聚合物组合物
公开(公告)号：US09018306B2
公开(公告)日：2015-04-28
申请号：US12664535
申请日：2008-06-09
申请人： Masayuki Hayashi , Eiji Kitaura , Peter Cheshire Hupfield , Katsuhiko Imoto , Masaru Nagato
发明人： Masayuki Hayashi , Eiji Kitaura , Peter Cheshire Hupfield , Katsuhiko Imoto , Masaru Nagato
IPC分类号： C09D5/16 , C08F8/42 , C08G18/62 , C08G18/81 , C08G18/83 , C08K5/5415 , C08L33/16 , C09D127/16 , C09D131/02 , C09D133/16 , C09D183/10 , C08F214/28 , C08F216/14 , C08F218/10 , C08L83/04 , C08L83/10
CPC分类号： C09D5/1675 , C08F8/42 , C08F214/28 , C08F216/1416 , C08F218/10 , C08G18/6279 , C08G18/8108 , C08G18/837 , C08K5/5415 , C08L33/16 , C08L83/04 , C08L83/10 , C09D127/16 , C09D131/02 , C09D133/16 , C09D183/10 , C08F214/267 , C08L27/12 , C08L27/16 , C08L83/00 , C08L2666/14
摘要： There is provided a curable fluorine-containing polymer composition which is rapidly cured at relatively low temperature by hydrosilylation reaction to form a coating film having not only high hardness and flexibility but also water- and oil-repellency, thereby giving stain-proofing effect for a long period of time, especially maintaining property of removing and wiping-off stain. The curable fluorine-containing polymer composition comprises a fluorine-containing polymer comprising a fluorinated ethylenic monomer unit and an un-fluorinated ethylenic monomer unit, in which a part or the whole of the un-fluorinated ethylenic monomer units are units represented by the formula: where R1 is hydrogen atom or methyl group; R2 is a hydrocarbon group having ethylenic C═C; X is —C(O)NH— or —C(O)—; R3 is —O—, —O[CH(R4)]mO—, —(CH2)mO—, —OC(O)—(CH2)nO— or —(CH2)mOC(O)—(CH2)nO—, where R4 is —H, —OH, —CH2OH or —O—X—R2, a siloxane compound having hydrogen atom bonded to silicon atom, a catalyst for hydrosilylation reaction, and a siloxane compound having no hydrogen atom bonded to silicon atom.
摘要翻译：提供了一种可固化的含氟聚合物组合物，其通过氢化硅烷化反应在相对低的温度下快速固化以形成不仅具有高硬度和柔韧性，而且具有防水拒油性的涂膜，从而赋予防污效果长时间，特别是保持去除和擦拭污渍的性能。可固化含氟聚合物组合物包含含有氟化乙烯性单体单元和未氟化的乙烯性单体单元的含氟聚合物，其中一部分或全部未氟化的烯属单体单元是由下式表示的单元：其中R1是氢原子或甲基; R2是具有烯属C = C的烃基; X是-C（O）NH-或-C（O） - ; R 3是-O-，-O [CH（R 4）] m O - ， - （CH 2）m O - ， - OC（O） - （CH 2）n O-或 - （CH 2）mOC（O） - （CH 2）其中R 4为-H，-OH，-CH 2 OH或-O-X-R 2，具有与硅原子键合的氢原子的硅氧烷化合物，氢化硅烷化反应的催化剂和与硅原子键合的无氢原子的硅氧烷化合物。

6. 发明申请

US20100210769A1 CURABLE FLUORINE-CONTAINING POLYMER COMPOSITION 有权
标题翻译：可固化含氟聚合物组合物
公开(公告)号：US20100210769A1
公开(公告)日：2010-08-19
申请号：US12664535
申请日：2008-06-09
申请人： Masayuki Hayashi , Eiji Kitaura , Peter Cheshire Hupfield , Katsuhiko Imoto , Masaru Nagato
发明人： Masayuki Hayashi , Eiji Kitaura , Peter Cheshire Hupfield , Katsuhiko Imoto , Masaru Nagato
IPC分类号： C08K5/5415
CPC分类号： C09D5/1675 , C08F8/42 , C08F214/28 , C08F216/1416 , C08F218/10 , C08G18/6279 , C08G18/8108 , C08G18/837 , C08K5/5415 , C08L33/16 , C08L83/04 , C08L83/10 , C09D127/16 , C09D131/02 , C09D133/16 , C09D183/10 , C08F214/267 , C08L27/12 , C08L27/16 , C08L83/00 , C08L2666/14
摘要： There is provided a curable fluorine-containing polymer composition which is rapidly cured at relatively low temperature by hydrosilylation reaction to form a coating film having not only high hardness and flexibility but also water- and oil-repellency, thereby giving stain-proofing effect for a long period of time, especially maintaining property of removing and wiping-off stain. The curable fluorine-containing polymer composition comprises a fluorine-containing polymer comprising a fluorinated ethylenic monomer unit and an un-fluorinated ethylenic monomer unit, in which a part or the whole of the un-fluorinated ethylenic monomer units are units represented by the formula: where R1 is hydrogen atom or methyl group; R2 is a hydrocarbon group having ethylenic C═C; X is —C(O)NH— or —C(O)—; R3 is —O—, —O[CH(R4)]mO—, —(CH2)mO—, —OC(O)—(CH2)nO— or —(CH2)mOC(O)—(CH2)nO—, where R4 is —H, —OH, —CH2OH or —O—X—R2, a siloxane compound having hydrogen atom bonded to silicon atom, a catalyst for hydrosilylation reaction, and a siloxane compound having no hydrogen atom bonded to silicon atom.
摘要翻译：提供了一种可固化的含氟聚合物组合物，其通过氢化硅烷化反应在相对低的温度下快速固化以形成不仅具有高硬度和柔韧性，而且具有防水拒油性的涂膜，从而赋予防污效果长时间，特别是保持去除和擦拭污渍的性能。可固化含氟聚合物组合物包含含有氟化乙烯性单体单元和未氟化的乙烯性单体单元的含氟聚合物，其中一部分或全部未氟化的烯属单体单元是由下式表示的单元：其中R1是氢原子或甲基; R2是具有烯属C = C的烃基; X是-C（O）NH-或-C（O） - ; R 3是-O-，-O [CH（R 4）] m O - ， - （CH 2）m O - ， - OC（O） - （CH 2）n O-或 - （CH 2）mOC（O） - （CH 2）其中R 4为-H，-OH，-CH 2 OH或-O-X-R 2，具有与硅原子键合的氢原子的硅氧烷化合物，氢化硅烷化反应的催化剂和与硅原子键合的无氢原子的硅氧烷化合物。

7. 发明申请

US20140221556A1 AQUEOUS DISPERSION AND METHOD FOR PRODUCING SAME 有权
标题翻译：水性分散体及其生产方法
公开(公告)号：US20140221556A1
公开(公告)日：2014-08-07
申请号：US14347516
申请日：2012-09-14
申请人： Shumi Yoshida , Katsuhiko Imoto
发明人： Shumi Yoshida , Katsuhiko Imoto
IPC分类号： C09D127/16 , C08L27/16
CPC分类号： C09D127/16 , C08F2/22 , C08F14/22 , C08F214/222 , C08F220/06 , C08F220/18 , C08F259/08 , C08L27/16 , C09D133/02 , C09D133/16 , C08L33/12 , C08F220/02
摘要： The present invention aims to provide an aqueous dispersion capable of forming a coating film that has excellent adhesion to a substrate and excellent water resistance. The aqueous dispersion of the present invention includes fluorine-containing composite polymer particles of a polymer (A) with a repeating unit of vinylidene fluoride and a polymer (B) with a repeating unit of at least one acrylic monomer selected from the group consisting of acrylic acid, acrylic acid esters, methacrylic acid, and methacrylic acid esters, the dispersion having an acid value of at least 3 mgKOH/g.
摘要翻译：本发明旨在提供一种能够形成对基材具有优异粘合性和优异的耐水性的涂膜的水性分散体。本发明的水性分散体包括具有偏二氟乙烯重复单元的聚合物（A）和聚合物（B）的含氟复合聚合物颗粒，所述聚合物（B）具有选自丙烯酸类的至少一种丙烯酸类单体的重复单元酸，丙烯酸酯，甲基丙烯酸和甲基丙烯酸酯，该分散体的酸值至少为3mgKOH / g。

8. 发明授权

US06359030B1 Aqueous resin dispersion composition 失效
标题翻译：水性树脂分散组合物
公开(公告)号：US06359030B1
公开(公告)日：2002-03-19
申请号：US09529984
申请日：2000-04-24
申请人： Nobuhiko Tsuda , Katsuhiko Imoto , Nobuo Mitsuhata , Masaru Nagato
发明人： Nobuhiko Tsuda , Katsuhiko Imoto , Nobuo Mitsuhata , Masaru Nagato
IPC分类号： C08L8300
CPC分类号： C09D127/16 , C08L33/12 , C08L2666/04
摘要： An aqueous-dispersing composition of synthetic resin (A) having an intrinsic viscosity “&eegr;” of from 0.3 to 2.0 measured at 35° C. in a methyl ethyl ketone solvent or a mixture of that aqueous dispersion and an aqueous dispersion of synthetic resin (B) having an intrinsic viscosity “&eegr;” of not less than 0.6 which is larger by 0.3 or more than the intrinsic viscosity “&eegr;” of the synthetic resin (A) when the intrinsic viscosity is measured at 35° C. in a methyl ethyl ketone solvent. The aqueous-dispersing composition and the mixture have improved film forming property and can give a coating film being excellent in chemical resistance, water resistance, mechanical properties and further hot water resistance.
摘要翻译：在甲基乙基酮溶剂或该水性分散体与合成树脂的水分散体的混合物中，在35℃下测定的特性粘度“η”为0.3〜2.0的合成树脂（A）的水分散组合物（ B），特性粘度“η”不小于0.6，当特性粘度在35℃下在甲基乙基中测定时，该特性粘度“η”大于合成树脂（A）的特性粘度“eta” 酮溶剂。水性分散组合物和混合物具有改进的成膜性，并且可以得到耐化学性，耐水性，机械性能和耐热水性更好的涂膜。

9. 发明授权

US06350806B1 Aqueous fluoropolymer dispersion composition 失效
标题翻译：水性含氟聚合物分散体组合物
公开(公告)号：US06350806B1
公开(公告)日：2002-02-26
申请号：US09529977
申请日：2000-04-24
申请人： Nobuhiko Tsuda , Katsuhiko Imoto , Nobuo Mitsuhata , Masaru Nagato
发明人： Nobuhiko Tsuda , Katsuhiko Imoto , Nobuo Mitsuhata , Masaru Nagato
IPC分类号： C08K334
CPC分类号： C09D127/12 , C08K3/36 , C09D127/16 , C08L27/12 , C08L2666/54 , C08L2666/28
摘要： An aqueous-dispersing composition which gives a coating being excellent in storage stability and forming a coating film being excellent in stain-proofing property and stain removable property and having sufficient gloss and hardness, and the composition contains said colloidal silica, in solid content, in an amount of more than 50 parts by weight up to 300 parts by weight and said organoalkoxysilane in an amount of 0.1 to 20 parts by weight on the basis of 100 parts by weight in solid content of an aqueous dispersion of fluorine-containing polymer particles.
摘要翻译：一种水分散性组合物，其具有保存稳定性优异且形成涂膜的防污性和污渍除去性优异，光泽度和硬度好的涂膜，该组合物含有固体含量的所述胶体二氧化硅基于100重量份固体含量的含氟聚合物颗粒的水分散体，其量大于50重量份，至多300重量份，所述有机烷氧基硅烷的量为0.1至20重量份。

10. 发明授权

US06288160B1 Aqueous dispersion and waterproofing material 有权
标题翻译：水性分散体和防水材料
公开(公告)号：US06288160B1
公开(公告)日：2001-09-11
申请号：US09308844
申请日：1999-07-21
申请人： Susumu Wada , Katsuhiko Imoto , Kayoko Honda
发明人： Susumu Wada , Katsuhiko Imoto , Kayoko Honda
IPC分类号： C08L8306
CPC分类号： C08K5/5419 , C08L27/12
摘要： It is an object of the present invention to provide an aqueous dispersion and a waterproofing agent, which are of the aqueous one-component type and easy and simple to apply and have both a decorative effect and enough waterproofing effect. The aqueous dispersion of the present invention comprises an organosilicon compound (1) represented by the general formula (I): and a fluorine-containing resin (2) comprising an aqueous fluororesin dispersion, and the weight ratio, on the solid basis, between said organosilicon compound (1) and said fluorine-containing resin (2) is (organosilicon compound (1)):(fluorine-containing resin (2))=60:40 to 97:3.
摘要翻译：本发明的目的是提供一种水性分散体和防水剂，其为单组分型水溶性且易于使用且具有装饰效果和足够的防水效果。本发明的水分散体本发明包括由通式（I）表示的有机硅化合物（1）和含氟树脂分散体的含氟树脂（2），所述有机硅化合物（1）和所述含氟树脂（2）为（有机硅化合物（1））:(含氟树脂（2））= 60:40〜97:3。

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