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1. 发明授权

US5049220A Method for applying an applique on the sidewall of a cured tire 失效
标题翻译：将贴花施加在硫化轮胎的侧壁上的方法
公开(公告)号：US5049220A
公开(公告)日：1991-09-17
申请号：US498504
申请日：1990-03-26
申请人： Robert J. Gartland , Anthony F. Finelli , Anthony J. Bell
发明人： Robert J. Gartland , Anthony F. Finelli , Anthony J. Bell
IPC分类号： B29D30/72 , B29K9/00 , B60C13/00 , B60C13/04 , C08L9/00
CPC分类号： B60C13/001 , C08L9/00 , B29D2030/728 , C08L23/16 , C08L23/283 , C08L7/00 , Y10S152/12
摘要： Tires having white sidewalls are very popular in the United States and Canada. This invention discloses a process for preparing such tires having decorative appliques thereon. By practicing the process of this invention, tires having better uniformity can be built at lower costs than when standard tire building techniques are utilized. This invention specifically relates to a method of preparing a pneumatic rubber tire having a decorative applique on the sidewall thereof which comprises (a) applying the decorative applique to the sidewall of a cured tire and (b) binding the decorative applique to the sidewall by the application of heat and pressure; wherein the decorative applique is comprised of from about 25 weight percent to about 75 weight percent syndiotactic 1,2-polybutadiene or blends of SPBD having melting points which are within the range of about 70.degree. C. to about 160.degree. C. and from about 25 weight percent to about 75 weight percent of at least one polydiene rubber which is blended with said syndiotactic 1,2-polybutadiene, sulfur, zinc oxide and at least one pigment or colorant.

2. 发明授权

US4967818A Tire having decorative applique on sidewall and method for preparing same 失效
标题翻译：具有侧壁装饰贴花的轮胎及其制备方法
公开(公告)号：US4967818A
公开(公告)日：1990-11-06
申请号：US255699
申请日：1988-10-11
申请人： Robert J. Gartland , Anthony F. Finelli , Anthony J. Bell
发明人： Robert J. Gartland , Anthony F. Finelli , Anthony J. Bell
IPC分类号： B29D30/72 , B60C13/04
CPC分类号： B60C13/04 , B29D30/72 , B29D2030/726 , Y10S152/12
摘要： Tires having white sidewalls are very popular in the United States and Canada. Tires having white lettering thereon are also very popular. This invention discloses a process for preparing such tires having decorative appliques thereon. By practicing the process of this invention, tires having better uniformity can be built at lower costs than when standard tire building techniques are utilized. This invention specifically relates to a method of preparing a pneumatic rubber tire having a decorative design on the sidewall thereof which comprises (a) applying the decorative design to the sidewall of an uncured tire and (b) curing the tire; wherein the decorative design is comprised of from about 25 weight percent to about 75 weight percent syndiotactic 1,2-polybutadiene having a melting point which is within the range of about 100.degree. C. to about 160.degree. C. and from about 25 weight percent to about 75 weight perecent of at least one polydiene rubber which is cocurable with said sydiotactic 1,2-polybutadiene, at least one pigment or colorant, sulfur, and zinc oxide.

3. 发明授权

US5058647A Tire having decorative applique on sidewall and method for preparing same 失效
标题翻译：具有侧壁装饰贴花的轮胎及其制备方法
公开(公告)号：US5058647A
公开(公告)日：1991-10-22
申请号：US568119
申请日：1990-08-16
申请人： Robert J. Gartland , Anthony F. Finelli , Anthony J. Bell
发明人： Robert J. Gartland , Anthony F. Finelli , Anthony J. Bell
IPC分类号： B29D30/72 , B60C13/04
CPC分类号： B60C13/04 , B29D30/72 , B29D2030/726 , Y10S152/12
摘要： Tires having white sidewalls are very popular in the United States and Canada. Tires having white lettering thereon are also very popular. This invention discloses a process for preparing such tires having decorative appliques thereon. By practicing the process of this invention, tires having better uniformity can be built at lower costs than when standard tire building techniques are utilized. This invention specifically relates to a method of preparing a pneumatic rubber tire having a decorative design on the sidewall thereof which comprises (a) applying the decorative applique to the sidewall of an uncured tire and (b) curing the tire; wherein the decorative applique is comprised of from about 25 weight percent to about 75 weight percent syndiotactic 1,2-polybutadiene having a melting point which is within the range of about 70.degree. C. to about 160.degree. C. and from about 25 weight percent to about 75 weight percent of at least one polydiene rubber which is cocurable with said syndiotactic 1,2-polybutadiene, sulfur, zinc oxide and at least one pigment or colorant.
摘要翻译：具有白色侧壁的轮胎在美国和加拿大非常受欢迎。具有白色刻字的轮胎也非常受欢迎。本发明公开了一种在其上制备具有装饰贴花的轮胎的方法。通过实践本发明的方法，可以以比使用标准轮胎成型技术更低的成本来建造具有更好的均匀性的轮胎。本发明具体涉及一种制造在其侧壁上具有装饰设计的气动橡胶轮胎的方法，其包括（a）将装饰贴花施加到未硫化轮胎的侧壁上，以及（b）固化轮胎; 其中装饰贴花由约25重量％至约75重量％的间同立构1,2-聚丁二烯组成，间同立构1,2-聚丁二烯的熔点在约70℃至约160℃的范围内，约25重量％至约75重量％的至少一种可与所述间同立构1,2-聚丁二烯，硫，氧化锌和至少一种颜料或着色剂共聚的聚二烯橡胶。

4. 发明授权

US4572852A Thermoforming partially crystalline polyester articles 失效
标题翻译：热成型部分结晶聚酯制品
公开(公告)号：US4572852A
公开(公告)日：1986-02-25
申请号：US668061
申请日：1984-11-05
申请人： Robert J. Gartland , Joseph N. Feil
发明人： Robert J. Gartland , Joseph N. Feil
IPC分类号： C08L67/02 , B65D1/00 , B32B27/36 , C08K5/09
CPC分类号： C08L67/02 , Y10T428/1397 , Y10T428/31786
摘要： Thin walled thermoformed articles of partially crystallized polyethylene terephthalate containing a minor component of a polyolefin which exhibit improved impact resistance and high temperature dimensional stability are disclosed herein. A method for thermoforming such articles using polyethylene terephthalate/polyolefin blends which provides improved mold release is also revealed.
摘要翻译：本文公开了包含显示出改善的耐冲击性和高温尺寸稳定性的聚烯烃的次要组分的部分结晶的聚对苯二甲酸乙二醇酯的薄壁热成型制品。还揭示了使用提供改进的脱模剂的聚对苯二甲酸乙二醇酯/聚烯烃共混物热成型这种制品的方法。

5. 发明授权

US5279695A Process for manufacturing a cable for reinforcing rubber articles 失效
标题翻译：制造用于增强橡胶制品的电缆的方法
公开(公告)号：US5279695A
公开(公告)日：1994-01-18
申请号：US914127
申请日：1992-07-17
申请人： Thomas W. Starinshak , Robert M. Shemenski , John W. Price, Jr. , Robert J. Gartland
发明人： Thomas W. Starinshak , Robert M. Shemenski , John W. Price, Jr. , Robert J. Gartland
IPC分类号： B29K105/06 , B60C9/00 , C08J5/06 , C08K9/00 , C08L21/02 , C08L75/04 , C23C30/00 , D07B1/06 , B29C65/02
CPC分类号： D07B1/0626 , B60C9/0007 , D07B1/167 , D07B2201/2023 , D07B2201/2024 , D07B2201/2039 , D07B2201/2046 , D07B2201/2061 , D07B2201/2062 , D07B2201/2081 , D07B2201/2082 , D07B2205/2082 , D07B2205/3089 , D07B2207/4059 , Y10T428/2933 , Y10T428/2944 , Y10T428/2958 , Y10T428/2971
摘要： Steel cables are utilized for reinforcing a wide variety of rubber articles. For instance, pneumatic tires are normally reinforced with steel tire cords. It is important for such reinforcing cables to exhibit good fatigue and corrosion resistance. It has been unexpectedly found that the fatigue and corrosion resistance of such cables can be improved by incorporating syndiotactic-1,2-polybutadiene into the interstices between the steel filaments in such cables. This invention more specifically relates to a cable for reinforcing rubber articles having improved fatigue and corrosion resistance which is comprised of a plurality of steel filaments and syndiotactic-1,2-polybutadiene, wherein the syndiotactic-1,2-polybutadiene is dispersed within interstices between said steel filaments.
摘要翻译：钢丝绳用于加强各种橡胶制品。例如，充气轮胎通常用钢轮胎帘线加固。对于这种增强电缆来说重要的是表现出良好的疲劳和耐腐蚀性。意外地发现，通过将间同立构1,2-聚丁二烯引入到这种电缆中的钢丝之间的间隙中，可以改善这种电缆的疲劳和耐腐蚀性。本发明更具体地涉及一种用于增强耐疲劳和耐腐蚀性的橡胶制品的电缆，其由多根钢丝和间同立构1,2-聚丁二烯组成，其中间规-1,2-聚丁二烯分散在说钢丝。

6. 发明授权

US5036113A Tire having radiation cured air barrier coating 失效
标题翻译：轮胎具有辐射固化的空气阻隔涂层
公开(公告)号：US5036113A
公开(公告)日：1991-07-30
申请号：US407806
申请日：1989-09-14
申请人： Wyndham H. Boon , Robert J. Gartland , Patrick J. Pesata, Jr.
发明人： Wyndham H. Boon , Robert J. Gartland , Patrick J. Pesata, Jr.
IPC分类号： B32B25/00 , B60C1/00
CPC分类号： B60C1/0008 , B32B25/00
摘要： A tire has on its inner surface on elastomeric air barrier coating, which is formed by photocuring a composition comprising: (a) an end capped prepolymer (MW 2500-10,000) formed by reacting a polyester diol (MW750-1500) with a diisocyanate, and reacting the resulting diisocyanate terminated prepolymer with an end group forming compound; (b) one or more monofunctional addition polymerizable monomers; and (c) a photoinitiator or mixture thereof. In preferred embodiments, the polyester diol is hydroxyl terminated ethylene adipate, the diisocyanate is TDI, and the end group forming compound is 2-hydroxyethyl methacrylate (HEMA). The monofunctional monomer may be or include N-vinyl-pyrrolidone (NVP). The air barrier coating has high elongation, low modulus, good heat aging resistance and good adhesion to the tire in addition to low oxygen permeability.
摘要翻译：轮胎在其内表面上具有弹性体空气阻隔涂层，其通过光固化组合物而形成，所述组合物包含：（a）通过聚酯二醇（MW750-1500）与二异氰酸酯反应形成的封端预聚物（MW 2500-10,000）并使得到的二异氰酸酯封端的预聚物与端基形成化合物反应; （b）一种或多种单官能加成聚合单体; 和（c）光引发剂或其混合物。在优选的实施方案中，聚酯二醇是羟基封端的己二酸乙二醇酯，二异氰酸酯是TDI，端基形成化合物是甲基丙烯酸2-羟乙酯（HEMA）。单官能单体可以是或包括N-乙烯基吡咯烷酮（NVP）。空气阻隔涂层除了低透氧性之外，还具有高延伸率，低模量，良好的耐热老化性和对轮胎的良好粘合性。

7. 发明授权

US4374800A Method for making an article of partially crystalline organic resin 失效
标题翻译：制备部分结晶有机树脂制品的方法
公开(公告)号：US4374800A
公开(公告)日：1983-02-22
申请号：US244836
申请日：1981-03-18
申请人： Robert J. Gartland
发明人： Robert J. Gartland
IPC分类号： B29C51/00 , B29C51/42 , B29C17/04
CPC分类号： B29C51/426 , B29C51/002
摘要： A shaped article such as a container of polyalkylene terephthalate resin is described. The shaped article includes a body portion in which the resin has an average crystallinity of at least about 20 percent. The shaped article is provided with the flange which adjoins the body portion of the article. At least part of the flange has an average crystallinity less than that of the body portion and preferably of not more than about 10 percent. Process and apparatus which may be employed in the manufacture of such an article are also described.
摘要翻译：描述了诸如聚对苯二甲酸亚烷基酯树脂的容器的成型制品。成形制品包括主体部分，其中树脂的平均结晶度至少为约20％。成形制品设有与制品主体部分相邻的凸缘。凸缘的至少一部分具有小于主体部分的平均结晶度，优选不大于约10％。还描述了可用于制造这种制品的方法和装置。

8. 发明授权

US4874670A Tire having cured photopolymer air barrier coating 失效
标题翻译：轮胎具有固化的光聚合物空气阻隔涂层
公开(公告)号：US4874670A
公开(公告)日：1989-10-17
申请号：US126989
申请日：1987-11-30
申请人： Wyndham Boon , Robert J. Gartland , Patrick J. Pesata, Jr.
发明人： Wyndham Boon , Robert J. Gartland , Patrick J. Pesata, Jr.
IPC分类号： B32B25/00 , B60C1/00
CPC分类号： B32B25/00 , B60C1/0008 , Y10T428/31569 , Y10T428/31587 , Y10T428/31837 , Y10T428/31931
摘要： A tire has on its inner surface an elastomeric air barrier coating, which is formed by photocuring a compositioin comprising: (a) an end capped prepolymer (MW 2500-10,000) formed by reacting a polyester diol (MW750-1500) with a diisocyanate, and reacting the resulting diisocyanate terminated prepolymer with an end group forming compound; (b) one or more monofunctional addition polymerizable monomers; and (c) a photoinitiator or mixture thereof. In preferred embodiments, the polyester diol is hydroxyl terminated ethylene adipate, the diisocyanate is TDI, and the end group forming compound is 2-hydroxyethyl methacrylane (HEMA). The monofunctional monomer may be or include N-vinyl-pyrrolidone (NVP). The air barrier coating has high elongation, low modulus, good heat aging resistance and good adhesion to the tire in addition to low oxygen permeability.
摘要翻译：轮胎在其内表面上具有弹性体空气阻隔涂层，其通过光固化组合物形成，所述组合物包含：（a）通过聚酯二醇（MW750-1500）与二异氰酸酯反应形成的封端预聚物（MW 2500-10,000）并使得到的二异氰酸酯封端的预聚物与端基形成化合物反应; （b）一种或多种单官能加成聚合单体; 和（c）光引发剂或其混合物。在优选的实施方案中，聚酯二醇是羟基封端的己二酸乙二醇酯，二异氰酸酯是TDI，端基形成化合物是2-羟乙基甲基丙烯酸酯（HEMA）。单官能单体可以是或包括N-乙烯基吡咯烷酮（NVP）。空气阻隔涂层除了低透氧性之外，还具有高延伸率，低模量，良好的耐热老化性和对轮胎的良好粘合性。

9. 发明授权

US4463121A Thermoforming partially crystalline polyester articles 失效
标题翻译：热成型部分结晶聚酯制品
公开(公告)号：US4463121A
公开(公告)日：1984-07-31
申请号：US409219
申请日：1982-08-18
申请人： Robert J. Gartland , Joseph N. Feil
发明人： Robert J. Gartland , Joseph N. Feil
IPC分类号： C08L67/00 , B29C51/00 , B29K23/00 , B29K67/00 , C08K5/13 , C08L7/00 , C08L21/00 , C08L23/00 , C08L67/02 , C08L101/00 , C08K5/09
CPC分类号： B29C51/002 , C08L67/02 , B29K2023/00 , B29K2067/00 , Y10T428/1397
摘要： Thin walled thermoformed articles of partially crystallized polyethylene terephthalate containing a minor component of a polyolefin which exhibit improved impact resistance and high temperature dimensional stability. Method for thermoforming such articles using polyethylene terephthalate/polyolefin blends which give improved mold release.
摘要翻译：包含部分结晶的聚对苯二甲酸乙二醇酯的薄壁热成型制品，其包含改善的耐冲击性和高温尺寸稳定性的聚烯烃的次要成分。使用聚对苯二甲酸乙二醇酯/聚烯烃共混物热成型这种制品的方法，其提供改进的脱模剂。

10. 发明授权

US5527407A Apparatus and method for marking a rubber article with a message readable by a light scanning device 失效
标题翻译：用于通过光扫描装置读取的信息来标记橡胶制品的装置和方法
公开(公告)号：US5527407A
公开(公告)日：1996-06-18
申请号：US998290
申请日：1992-12-30
申请人： Robert J. Gartland , Gary T. Belski
发明人： Robert J. Gartland , Gary T. Belski
IPC分类号： B41M1/32 , B29C37/00 , B60C13/00 , G06K1/12 , B32B31/00 , B32B31/26 , B32B35/00
CPC分类号： B60C13/001 , B29C37/0025 , G06K1/126 , B29C2037/0046 , B29D2030/726 , B29D2030/728 , B29L2031/744 , Y10T156/1062 , Y10T156/12 , Y10T156/1705
摘要： An apparatus and method for supplying a graphic label that is readable with a light scanning device with such label placed on a rubber article. The graphic bar code label is optically interpreted with a bar code reader.Thus, the cured substrate with the label with the graphic message is produced by using thermal transfer techniques. For this purpose, the ribbon in contact with the substrate passes by a print head and the ink can be selectively heated with this operation being synchronized by computer operation. When the ribbon is stripped away, the ink is left where heating occurred on the substrate material. The printed substrate exits and is cut to produce labels of desired length. The label is placed on a curable article and the label and substrate are subjected to curing conditions to effect transfer of the label to the cured substrate which may now contain the message in solely, alphanumeric, bar codes, human readable characters, and logos or mixtures of them. The bar code message is normally printed as a series of vertical bars and spaces of varying widths to supply the message in readable form with the light reflected from the series of varying width bars and spaces.
摘要翻译：一种用于将具有这样的标签的光扫描装置可读取的图形标签提供在橡胶制品上的装置和方法。图形条形码标签用条形码读取器进行光学解释。因此，具有带有图形信息的标签的固化基板通过使用热转印技术产生。为此，与基板接触的带通过打印头，并且可以选择性地加热油墨，这种操作通过计算机操作同步。当色带被剥离时，墨水留在基板材料上发生加热的地方。印刷的基板离开并被切割以产生所需长度的标签。将标签放置在可固化的制品上，标签和基材经受固化条件，以使标签转移到固化的基材上，固化的基材现在可以单独包含消息，字母数字，条形码，人类可读字符，标识或混合物的他们。条形码消息通常被打印为一系列具有不同宽度的垂直条和空格，以便从可变宽度条和间隔的系列反射的光提供可读形式的消息。

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