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    • 1. 发明申请
    • Barrier film
    • 屏障电影
    • US20090110942A1
    • 2009-04-30
    • US11665477
    • 2005-10-18
    • Rulande Henderson-RutgersMark FinkNicholas Roy Oakley
    • Rulande Henderson-RutgersMark FinkNicholas Roy Oakley
    • B32B27/08C08L3/02C08L3/04C08L29/04
    • B32B9/02B32B1/02B32B9/045B32B27/08B32B27/18B32B27/22B32B27/24B32B27/306B32B27/36B32B2250/24B32B2270/00B32B2307/308B32B2307/71B32B2307/7166B32B2307/7242B32B2307/7244B32B2439/60B32B2439/70B32B2553/023C08J3/18C08J2303/00C08K5/053C08K5/09C08K2201/008C08L3/02C08L3/04C08L3/06C08L3/08C08L23/0853C08L23/0861C08L29/04C08L31/04C08L71/02C08L2205/02C08L2205/03Y10T428/31786Y10T428/31797Y10T428/31913Y10T428/31971C08L2666/04C08L2666/02
    • A barrier composition which is injection mouldable and able to be made into a transparent film or incorporated (by co-extrusion and/or lamination) into multi-layer film products, the composition on dry basis: a) from 45 to 90% by weight of a starch and/or a modified starch selected from starches modified by reaction with a hydroxyl alkyl group, an acetate or a dicarboxylic acid anhydride or a grafting polymer; b) from 4 to 12% by weight of a water soluble polymer selected from polyvinyl alcohol, polyvinylacetate, and copolymers of ethylene and vinylalcohol which have a melting point compatible with the molten state of the starch components c) from 5 to 45% by weight of a non-crystallising mixture of sorbitol and at least one other plasticizer selected from glycerol, maltitol, xylitol, mannitol, glycerol trioleate, epoxidised linseed or soybean oil, tributyl citrate, acetyl tri-ethyl citrate, glyceryl triacetate, 2,2,4-trimethyl-1,3-pentanediol diisobutyrate; polyethylene oxide or polyethylene glycol; d) from 0.3 to 2.5 % by weight of a C12-22 fatty acid or salt; e) from 0.25% to 3% of an emulsifier system having a hydrophilic lipophilic balance value between 2 and 10. The barrier film may be co-injection moulded with polyethylene terephthalate (PET) or polylactic acid (PLA) for blow moulding into beverage bottles, with polyethylene (PE) or polypropylene (PP) or biodegradable polymers for high gas-barrier containers or closures, or may be co-extruded with polyethylene, polypropylene or polylactic acid for thin film packaging applications or for blow-moulded containers.
    • 一种阻隔组合物,其是可注射成型且能够制成透明膜或通过共挤出和/或层压结合到多层膜产品中的组合物,所述组合物以干基计:a)45至90重量% 的淀粉和/或选自通过与羟基烷基,乙酸酯或二羧酸酐或接​​枝聚合物反应改性的淀粉的改性淀粉; b)4至12重量%的选自聚乙烯醇,聚乙酸乙烯酯的水溶性聚合物和乙烯和乙烯醇的共聚物,其具有与淀粉组分的熔融状态相容的熔点c)5至45重量% 的山梨糖醇和至少一种选自甘油,麦芽糖醇,木糖醇,甘露糖醇,甘油三油酸甘油酯,环氧化亚麻籽油或大豆油的其它增塑剂的非结晶混合物,柠檬酸三丁酯,柠檬酸乙酰基三乙酯,柠檬酸甘油酯,2,2,4 - 三甲基-1,3-戊二醇二异丁酸酯; 聚环氧乙烷或聚乙二醇; d)0.3至2.5重量%的C 12-22脂肪酸或盐; e)0.25%至3%的亲水亲油平衡值在2至10之间的乳化剂体系。阻挡膜可以与聚对苯二甲酸乙二醇酯(PET)或聚乳酸(PLA)共注塑成型,用于吹塑成饮料瓶 ,聚乙烯(PE)或聚丙烯(PP)或可生物降解聚合物,用于高阻隔性容器或封闭物,或与聚乙烯,聚丙烯或聚乳酸共挤出用于薄膜包装应用或吹塑容器。
    • 2. 发明授权
    • Barrier film
    • 屏障电影
    • US07854994B2
    • 2010-12-21
    • US11665477
    • 2005-10-18
    • Rulande Henderson-RutgersMark FinkNicholas Roy Oakley
    • Rulande Henderson-RutgersMark FinkNicholas Roy Oakley
    • C08L3/00B32B27/18B32B27/22B32B27/30B32B27/36
    • B32B9/02B32B1/02B32B9/045B32B27/08B32B27/18B32B27/22B32B27/24B32B27/306B32B27/36B32B2250/24B32B2270/00B32B2307/308B32B2307/71B32B2307/7166B32B2307/7242B32B2307/7244B32B2439/60B32B2439/70B32B2553/023C08J3/18C08J2303/00C08K5/053C08K5/09C08K2201/008C08L3/02C08L3/04C08L3/06C08L3/08C08L23/0853C08L23/0861C08L29/04C08L31/04C08L71/02C08L2205/02C08L2205/03Y10T428/31786Y10T428/31797Y10T428/31913Y10T428/31971C08L2666/04C08L2666/02
    • A barrier composition which is injection mouldable and able to be made into a transparent film or incorporated (by co-extrusion and/or lamination) into multi-layer film products, the composition on dry basis: a) from 45 to 90% by weight of a starch and/or a modified starch selected from starches modified by reaction with a hydroxyl alkyl group, an acetate or a dicarboxylic acid anhydride or a grafting polymer; b) from 4 to 12% by weight of a water soluble polymer selected from polyvinyl alcohol, polyvinylacetate, and copolymers of ethylene and vinylalcohol which have a melting point compatible with the molten state of the starch components c) from 5 to 45% by weight of a non-crystallising mixture of sorbitol and at least one other plasticizer selected from glycerol, maltitol, xylitol, mannitol, glycerol trioleate, epoxidised linseed or soybean oil, tributyl citrate, acetyl tri-ethyl citrate, glyceryl triacetate, 2,2,4-trimethyl-1,3-pentanediol diisobutyrate; polyethylene oxide or polyethylene glycol; d) from 0.3 to 2.5% by weight of a C12-22 fatty acid or salt; e) from 0.25% to 3% of an emulsifier system having a hydrophilic lipophilic balance value between 2 and 10. The barrier film may be co-injection moulded with polyethylene terephthalate (PET) or polylactic acid (PLA) for blow moulding into beverage bottles, with polyethylene (PE) or polypropylene (PP) or biodegradable polymers for high gas-barrier containers or closures, or may be co-extruded with polyethylene, polypropylene or polylactic acid for thin film packaging applications or for blow-moulded containers.
    • 一种阻隔组合物,其是可注射成型且能够制成透明膜或通过共挤出和/或层压结合到多层膜产品中的组合物,所述组合物以干基计:a)45至90重量% 的淀粉和/或选自通过与羟基烷基,乙酸酯或二羧酸酐或接​​枝聚合物反应改性的淀粉的改性淀粉; b)4至12重量%的选自聚乙烯醇,聚乙酸乙烯酯的水溶性聚合物和乙烯和乙烯醇的共聚物,其具有与淀粉组分的熔融状态相容的熔点c)5至45重量% 的山梨糖醇和至少一种选自甘油,麦芽糖醇,木糖醇,甘露糖醇,甘油三油酸甘油酯,环氧化亚麻籽油或大豆油的其它增塑剂的非结晶混合物,柠檬酸三丁酯,柠檬酸乙酰基三乙酯,柠檬酸甘油酯,2,2,4 - 三甲基-1,3-戊二醇二异丁酸酯; 聚环氧乙烷或聚乙二醇; d)0.3至2.5重量%的C 12-22脂肪酸或盐; e)0.25%至3%的亲水亲油平衡值在2至10之间的乳化剂体系。阻挡膜可以与聚对苯二甲酸乙二醇酯(PET)或聚乳酸(PLA)共注塑成型,用于吹塑成饮料瓶 ,聚乙烯(PE)或聚丙烯(PP)或可生物降解聚合物,用于高阻隔性容器或封闭物,或与聚乙烯,聚丙烯或聚乳酸共挤出用于薄膜包装应用或吹塑容器。