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1. 发明申请

US20150266745A1 Metal Cyanometallate Synthesis Method 审中-公开
标题翻译：金属氰酸金属盐合成方法
公开(公告)号：US20150266745A1
公开(公告)日：2015-09-24
申请号：US14731165
申请日：2015-06-04
申请人： Sharp Laboratories of America, Inc. , Board of Regents, The University of Texas System
发明人： Jie Song , Yuhao Lu , Long Wang
IPC分类号： C01C3/12
CPC分类号： C01C3/12 , H01M4/5825 , H01M10/054
摘要： A method is provided for synthesizing metal cyanometallate (MCM). The method provides a solution of AXM1Y(CN)Z; where “A” is selected from a first group of metals and M1 is selected from a second group of metals. The method adds a material including M2 to the solution to form a liquid phase material that may be either a suspension or a solution. M2 is selected from the second group of metals. The method adds acid to the liquid phase material. The addition of acid to the liquid phase material decomposes the M2 material into M2-ions. Simultaneous with the addition of the acid, a precipitate of ANM1PM2Q(CN)R.FH2O is formed, where N is in a range of 1 to 2. A variation of the above-described synthesis method is also provided.
摘要翻译：提供了合成氰基金属金属（MCM）的方法。该方法提供AXM1Y（CN）Z的溶液; 其中“A”选自第一组金属，M1选自第二组金属。该方法将包括M2的材料添加到溶液中以形成可以是悬浮液或溶液的液相材料。 M2选自第二组金属。该方法向液相材料中加入酸。将酸添加到液相材料中将M2材料分解成M2-离子。加入酸同时形成ANM1PM2Q（CN）R.FH2O的沉淀物，其中N在1〜2的范围内。还提供了上述合成方法的变化。

2. 发明授权

US09745202B2 Metal cyanometallate synthesis method 有权
公开(公告)号：US09745202B2
公开(公告)日：2017-08-29
申请号：US14731607
申请日：2015-06-05
申请人： Board of Regents, The University of Texas System , Sharp Laboratories of America, Inc.
发明人： Jie Song , Yuhao Lu , Long Wang
IPC分类号： H01M4/52 , C01C3/12 , H01M4/58 , H01M10/054
CPC分类号： C01C3/12 , H01M4/58 , H01M10/054 , Y10T29/49108
摘要： A method is provided for synthesizing metal cyanometallate (MCM). The method provides a solution of AXM1Y(CN)Z; where “A” is selected from a first group of metals and M1 is selected from a second group of metals. The method adds a material including M2 to the solution to form a liquid phase material that may be either a suspension or a solution. M2 is selected from the second group of metals. The method adds acid to the liquid phase material. The addition of acid to the liquid phase material decomposes the M2 material into M2-ions. Simultaneous with the addition of the acid, a precipitate of ANM1PM2Q(CN)R.FH2O is formed, where N is in a range of 1 to 2. A variation of the above-described synthesis method is also provided.

3. 发明申请

US20150266746A1 Metal Cyanometallate Synthesis Method 有权
标题翻译：金属氰酸金属盐合成方法
公开(公告)号：US20150266746A1
公开(公告)日：2015-09-24
申请号：US14731607
申请日：2015-06-05
申请人： Board of Regents, The University of Texas System , Sharp Laboratories of America, Inc.
发明人： Jie Song , Yuhao Lu , Long Wang
IPC分类号： C01C3/12
CPC分类号： C01C3/12 , H01M4/58 , H01M10/054 , Y10T29/49108
摘要： A method is provided for synthesizing metal cyanometallate (MCM). The method provides a solution of AXM1Y(CN)Z; where “A” is selected from a first group of metals and M1 is selected from a second group of metals. The method adds a material including M2 to the solution to form a liquid phase material that may be either a suspension or a solution. M2 is selected from the second group of metals. The method adds acid to the liquid phase material. The addition of acid to the liquid phase material decomposes the M2 material into M2-ions. Simultaneous with the addition of the acid, a precipitate of ANM1PM2Q(CN)R. FH2O is formed, where N is in a range of 1 to 2. A variation of the above-described synthesis method is also provided.
摘要翻译：提供了合成氰基金属金属（MCM）的方法。该方法提供AXM1Y（CN）Z的溶液; 其中“A”选自第一组金属，M1选自第二组金属。该方法将包括M2的材料添加到溶液中以形成可以是悬浮液或溶液的液相材料。 M2选自第二组金属。该方法向液相材料中加入酸。将酸添加到液相材料中将M2材料分解成M2-离子。加入酸同时加入ANM1PM2Q（CN）R的沉淀物。形成FH 2 O，其中N在1至2的范围内。还提供了上述合成方法的变化。

4. 发明授权

US10411286B2 Alkali/oxidant battery 有权
公开(公告)号：US10411286B2
公开(公告)日：2019-09-10
申请号：US15146071
申请日：2016-05-04
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Hidayat Kisdarjono , Jong-Jan Lee , David R. Evans
IPC分类号： H01M8/18 , H01M4/52 , H01M10/44 , H01M8/20 , H01M10/05 , H01M12/08 , H01M4/24 , H01M4/32 , H01M4/38 , H01M4/50 , H01M10/26 , H01M10/30 , H01M10/052 , H01M10/0525 , H01M10/0568 , H01M2/14 , H01M4/02
摘要： An alkali/oxidant battery is provided with an associated method of creating battery capacity. The battery is made from an anode including a reduced first alkali metal such as lithium (Li), sodium (Na), and potassium (K), when the battery is charged. The battery's catholyte includes an element, in the battery charged state, such as nickel oxyhydroxide (NiOOH), manganese(IV) (oxide Mn(4+)O2), or iron(III) oxyhydroxide Fe(3+)(OH)3), with the alkali metal hydroxide. An alkali metal ion permeable separator is interposed between the anolyte and the catholyte. For example, if the catholyte includes nickel(II) hydroxide (Ni(OH)2) in a battery discharged state, then it includes NiOOH in a battery charged state. To continue the example, the anolyte may include dissolved lithium ions (Li+) in a discharged state, with solid phase reduced Li formed on the anode in the battery charged state.

5. 发明授权

US09847527B2 Non-metal anode alkali and alkaline-earth ion batteries with hexacyanometallate cathode 有权
公开(公告)号：US09847527B2
公开(公告)日：2017-12-19
申请号：US14699918
申请日：2015-04-29
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Jong-Jan Lee , Motoaki Nishijima , Seizoh Kakimoto
IPC分类号： H01M4/1399 , H01M4/58 , H01M4/04 , H01M4/139 , H01M10/054 , H01M10/36 , H01M4/136 , H01M4/587 , H01M4/02
CPC分类号： H01M4/58 , H01M4/0404 , H01M4/0438 , H01M4/0445 , H01M4/0459 , H01M4/136 , H01M4/139 , H01M4/587 , H01M10/054 , H01M10/36 , H01M2004/028 , Y02E60/122
摘要： A battery structure is provided for making alkali ion and alkaline-earth ion batteries. The battery has a hexacyanometallate cathode, a non-metal anode, and non-aqueous electrolyte. A method is provided for forming the hexacyanometallate battery cathode and non-metal battery anode prior to the battery assembly. The cathode includes hexacyanometallate particles overlying a current collector. The hexacyanometallate particles have the chemical formula A′n′AmM1xM2y(CN)6, and have a Prussian Blue hexacyanometallate crystal structure.

6. 发明授权

US09680152B2 Transition metal hexacyanoferrate battery with carbonaceous anode 有权
公开(公告)号：US09680152B2
公开(公告)日：2017-06-13
申请号：US15173866
申请日：2016-06-06
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Hidayat Kisdarjono , Jong-Jan Lee , David Evans
IPC分类号： H01M4/58 , H01M4/136 , H02J7/00 , H01M10/054 , H01M10/0568 , H01M10/44 , H01M4/62 , H01M4/02
CPC分类号： H01M4/5825 , H01M4/136 , H01M4/58 , H01M4/625 , H01M10/054 , H01M10/0568 , H01M10/446 , H01M2004/028 , H02J7/0063 , H02J7/0068 , Y02E60/122
摘要： A transition metal hexacyanoferrate (TMH) cathode battery is provided. The battery has a AxMn[Fe(CN)6]y.zH2O cathode, where the A cations are either alkali or alkaline-earth cations, such as sodium or potassium, where x is in the range of 1 to 2, where y is in the range of 0.5 to 1, and where z is in the range of 0 to 3.5. The AxMn[Fe(CN)6]y.zH2O has a rhombohedral crystal structure with Mn2+/3+ and Fe2+/3+ having the same reduction/oxidation potential. The battery also has an electrolyte, and anode made of an A metal, an A composite, or a material that can host A atoms. The battery has a single plateau charging curve, where a single plateau charging curve is defined as a constant charging voltage slope between 15% and 85% battery charge capacity. Fabrication methods are also provided.

7. 发明授权

US09660241B2 NASICON-polymer electrolyte structure 有权
公开(公告)号：US09660241B2
公开(公告)日：2017-05-23
申请号：US14198755
申请日：2014-03-06
申请人： Sharp Laboratories of America, Inc.
发明人： Long Wang , Yuhao Lu , Jong-Jan Lee , Sean Vail
IPC分类号： H01M4/58 , H01M2/16 , C01C3/12 , H01M4/136 , H01M4/04 , H01M4/62 , H02J7/00 , H01M4/134 , H01M4/1395 , C01B17/02 , C01B19/02 , C01B25/00 , C01B31/00 , C01B33/021 , C01D1/02 , C01D15/02 , H01M4/131 , H01M4/133 , H01M4/1391 , H01M4/38 , H01M4/485 , H01M4/505 , H01M4/56 , H01M4/587 , H01M10/054 , H01M10/0525 , H01M10/0565 , H01M4/1397 , H01M2/14 , H01M10/056 , H01M10/052
CPC分类号： H01M4/134 , B01J6/008 , C01B17/02 , C01B19/02 , C01B25/003 , C01B32/00 , C01B33/021 , C01C3/12 , C01D1/02 , C01D15/02 , C01P2002/72 , C01P2002/77 , C01P2002/88 , H01M2/14 , H01M2/1653 , H01M2/1686 , H01M4/04 , H01M4/0404 , H01M4/0416 , H01M4/0452 , H01M4/0471 , H01M4/049 , H01M4/0495 , H01M4/0497 , H01M4/131 , H01M4/133 , H01M4/136 , H01M4/1391 , H01M4/1395 , H01M4/1397 , H01M4/366 , H01M4/38 , H01M4/381 , H01M4/382 , H01M4/387 , H01M4/485 , H01M4/505 , H01M4/56 , H01M4/58 , H01M4/5815 , H01M4/5825 , H01M4/587 , H01M4/60 , H01M4/623 , H01M4/628 , H01M10/052 , H01M10/0525 , H01M10/054 , H01M10/056 , H01M10/0565 , H01M2004/027 , H02J7/0042 , Y02E60/122 , Y10T29/49108
摘要： A method is provided for forming a sodium-containing particle electrolyte structure. The method provides sodium-containing particles (e.g., NASICON), dispersed in a liquid phase polymer, to form a polymer film with sodium-containing particles distributed in the polymer film. The liquid phase polymer is a result of dissolving the polymer in a solvent or melting the polymer in an extrusion process. In one aspect, the method forms a plurality of polymer film layers, where each polymer film layer includes sodium-containing particles. For example, the plurality of polymer film layers may form a stack having a top layer and a bottom layer, where with percentage of sodium-containing particles in the polymer film layers increasing from the bottom layer to the top layer. In another aspect, the sodium-containing particles are coated with a dopant. A sodium-containing particle electrolyte structure and a battery made using the sodium-containing particle electrolyte structure are also presented.

8. 发明授权

US09531002B2 Transition metal cyanometallate cathode battery with metal plating anode 有权
标题翻译：过渡金属氰金属阴极电池与金属电镀阳极
公开(公告)号：US09531002B2
公开(公告)日：2016-12-27
申请号：US14668788
申请日：2015-03-25
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Long Wang , Jong-Jan Lee
IPC分类号： H01M4/136 , C01C3/12 , H01M4/04 , H01M4/1397 , H01M4/58 , H01M4/66 , H01M10/054
CPC分类号： H01M4/136 , C01C3/12 , H01M4/0404 , H01M4/0452 , H01M4/1397 , H01M4/58 , H01M4/661 , H01M4/663 , H01M4/667 , H01M4/668 , H01M10/054 , Y02E60/122
摘要： A method is provided for cycling power in a transition metal cyanometallate (TMCM) cathode battery. The method provides a battery with a TMCM cathode, an anode, and an electrolyte, where TMCM corresponds to the chemical formula of AXM1NM2M(CN)Y-d(H2O), where “A” is an alkali or alkaline earth metal, and where M1 and M2 are transition metals. The method charges the battery using a first charging current, or greater. In response to the charging current, a plating of “A” metal is formed overlying a plating surface of the anode. In response to discharging the battery, the “A” metal plating is removed from the anode plating surface. In one aspect, in an initial charging of the battery, a permanent solid electrolyte interphase (SEI) layer is formed overlying the anode plating surface. In subsequent charging and discharging cycles, the permanent SEI layer is maintained overlying the anode plating surface.
摘要翻译：提供了一种在过渡金属氰金属（TMCM）阴极电池中循环功率的方法。该方法提供具有TMCM阴极，阳极和电解质的电池，其中TMCM对应于AXM1NM2M（CN）Yd（H2O）的化学式，其中“A”是碱金属或碱土金属，并且其中M1和 M2是过渡金属。该方法使用第一充电电流或更高的电池充电。响应于充电电流，在阳极的电镀表面上形成覆盖“A”金属的电镀。响应于电池的放电，从阳极电镀表面去除“A”金属电镀。一方面，在电池的初始充电中，在阳极电镀表面上形成永久的固体电解质相（SEI）层。在随后的充放电循环中，永久性SEI层保持覆盖阳极电镀表面。

9. 发明授权

US09419278B2 Rechargeable metal-ion battery with non-aqueous hybrid ion electrolyte 有权
标题翻译：具有非水混合离子电解质的可充电金属离子电池
公开(公告)号：US09419278B2
公开(公告)日：2016-08-16
申请号：US14271498
申请日：2014-05-07
申请人： Sharp Laboratories of America, Inc.
发明人： Long Wang , Yuhao Lu , David Evans
IPC分类号： H01M2/00 , H01M4/58 , H01M10/058 , H01M10/44 , H01M10/0525 , H01M10/054 , H01M10/04 , H01M4/136 , H02J7/00
CPC分类号： H01M4/58 , H01M4/136 , H01M10/049 , H01M10/0525 , H01M10/054 , H01M10/058 , H01M10/44 , H02J7/0042 , Y02E60/122 , Y10T29/49108
摘要： A method is provided for forming a rechargeable metal-ion battery with a non-aqueous hybrid ion electrolyte. The method provides a transition metal hexacyanometallate (TMHCM) cathode (AXM1YM2Z(CN)N.MH2O), where “A” is from a first group of metals, and M1 and M2 are transition metals. The electrolyte includes a first type of cation from the first group of metals, different than “A”. The method connects the cathode and anode to external circuitry to perform initial charge/discharge operations. As a result, a hybrid ion electrolyte is formed including the first type of cation and “A” cations. Subsequently, cations are inserted into the anode during charging, which alternatively may be only “A” cations, only the first type of cation, or both the “A” cations and the first type of cation. Only “A” cations, only the first type, or both “A” and the first type of cation are inserted into the TMHCM during discharge.
摘要翻译：提供了一种用非水混合离子电解质形成可再充电金属离子电池的方法。该方法提供了过渡金属六金属金属酸盐（TMHCM）阴极（AXM1YM2Z（CN）N.MH2O），其中“A”来自第一组金属，M1和M2是过渡金属。电解质包含不同于“A”的第一类金属的第一类型的阳离子。该方法将阴极和阳极连接到外部电路以执行初始充电/放电操作。结果，形成包含第一种阳离子和“A”阳离子的混合离子电解质。随后，在充电期间将阳离子插入阳极中，或者可以仅仅是“A”阳离子，仅第一类型的阳离子，或者“A”阳离子和第一类型的阳离子。在放电期间，只有“A”阳离子，只有第一种类型，或“A”型和第一种类型的阳离子被插入到TMHCM中。

10. 发明授权

US09406919B2 Metal cyanometallate electrode with shield structure 有权
标题翻译：具有屏蔽结构的金属氰基金属电极
公开(公告)号：US09406919B2
公开(公告)日：2016-08-02
申请号：US14193501
申请日：2014-02-28
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Long Wang , Jong-Jan Lee
IPC分类号： H01M4/62 , H01M2/16 , H01M4/58 , C01C3/12 , H01M4/136 , H01M4/04 , H02J7/00 , H01M4/134 , H01M4/1395 , C01B17/02 , C01B19/02 , C01B25/00 , C01B31/00 , C01B33/021 , C01D1/02 , C01D15/02 , H01M4/131 , H01M4/133 , H01M4/1391 , H01M4/38 , H01M4/485 , H01M4/505 , H01M4/56 , H01M4/587 , H01M10/054 , H01M10/0525 , H01M10/0565 , H01M4/1397 , H01M10/052
CPC分类号： H01M4/134 , B01J6/008 , C01B17/02 , C01B19/02 , C01B25/003 , C01B32/00 , C01B33/021 , C01C3/12 , C01D1/02 , C01D15/02 , C01P2002/72 , C01P2002/77 , C01P2002/88 , H01M2/14 , H01M2/1653 , H01M2/1686 , H01M4/04 , H01M4/0404 , H01M4/0416 , H01M4/0452 , H01M4/0471 , H01M4/049 , H01M4/0495 , H01M4/0497 , H01M4/131 , H01M4/133 , H01M4/136 , H01M4/1391 , H01M4/1395 , H01M4/1397 , H01M4/366 , H01M4/38 , H01M4/381 , H01M4/382 , H01M4/387 , H01M4/485 , H01M4/505 , H01M4/56 , H01M4/58 , H01M4/5815 , H01M4/5825 , H01M4/587 , H01M4/60 , H01M4/623 , H01M4/628 , H01M10/052 , H01M10/0525 , H01M10/054 , H01M10/056 , H01M10/0565 , H01M2004/027 , H02J7/0042 , Y02E60/122 , Y10T29/49108
摘要： A mechanism is presented for shielding a cathode in a metal cyanometallate battery. A battery is provided with an anode, a cathode, an electrolyte, and an ion-permeable membrane separating the anode from the cathode. The cathode is made up of a plurality of metal cyanometallate layers overlying the current collector. At least one of the metal cyanometallate layers is an active layer formed from an active material AXM1YM2Z(CN)N·MH2O, where “A” is an alkali metal, alkaline earth metal, or combination thereof. At least one of the metal cyanometallate layers is a shield layer comprising less than 50 percent by weight (wt %) active material. In response to applying an external voltage potential between the cathode and the anode, the method charges the battery. Upon discharge, the shield layer blocks metal particles from contacting active layers. Simultaneously, the shield layer transports metal ions from the electrolyte to the active layers.
摘要翻译：提出了一种用于屏蔽金属氰酸金属电池中的阴极的机理。电池设置有将阳极与阴极分离的阳极，阴极，电解质和离子透过膜。阴极由覆盖在集电器上的多个金属金属氧化物层构成。至少一种金属氰酸金属盐层是由活性物质AXM1YM2Z（CN）N·MH2O形成的活性层，其中“A”是碱金属，碱土金属或其组合。至少一种金属氰酸金属盐层是包含小于50重量％（wt％）活性物质的屏蔽层。响应于在阴极和阳极之间施加外部电压电位，该方法对电池充电。在放电时，屏蔽层阻挡金属颗粒接触活性层。同时，屏蔽层将金属离子从电解质输送到活性层。

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