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1. 发明申请

US20160207934A1 Herbicidally active (alkynyl-phenyl)-substituted cyclic dione compounds and derivatives thereof 审中-公开
标题翻译：除草活性（炔基 - 苯基） - 取代环状二酮化合物及其衍生物
公开(公告)号：US20160207934A1
公开(公告)日：2016-07-21
申请号：US14894698
申请日：2014-05-29
申请人： SYNGENTA LIMITED
发明人： Janice Black , James Nicholas Scutt , Louisa Whalley , Nigel James Willets
IPC分类号： C07D493/08 , A01N35/06 , A01N43/90 , A01N43/16 , C07D311/96 , C07C49/517 , C07D309/32
摘要： The present invention relates to a compound of formula (I): wherein: X is methyl or chlorine; R1 is fluorine or bromine; R2 is ethynyl, C1-C3alkoxy, C1-C3haloalkoxy, or C1-C3alkoxy-C1-C3alkoxy-; and Q is a pyran-3,5-dione-4-yl, a thiopyran-3,5-dione-4-yl, a piperidine-3,5-dione-4-yl, a cyclopentane-1,3-dione-2-yl, a cyclohexane-1,3, 5-trione-2-yl, a cyclohexane-1,3-dione-2-yl, or a cycloheptane-1,3-dione-2-yl, or a derivative thereof (e.g. a fused such as fused bicyclic derivative, and/or a spirocyclic derivative), or an enol ketone tautomer derivative thereof, wherein Q is further defined herein; and wherein the compound of formula (I) is optionally present as an agrochemically acceptable salt thereof. Preferably, X is methyl; and/or R1 is fluorine; and/or R2 is —O—R2A, wherein R2A is methyl, ethyl, trifluoromethyl, difluoromethyl, trifluoroethyl, or —CH2CH2OCH3. These compounds are suitable for use as herbicides. The invention therefore also relates to a method of controlling weeds, especially grassy monocotyledonous weeds, in crops of useful plants, comprising applying a compound of formula (I), or a herbicidal composition comprising such a compound, to the weeds and/or to the plants and/or to the locus thereof.
摘要翻译：本发明涉及式（I）的化合物：其中：X为甲基或氯; R1是氟或溴; R2是乙炔基，C1-C3烷氧基，C1-C3卤代烷氧基或C1-C3烷氧基-C1-C3烷氧基; 并且Q是吡喃-3,5-二酮-4-基，噻喃-3,5-二酮-4-基，哌啶-3,5-二酮-4-基，环戊烷-1,3-二酮环己烷-1,3-二酮-2-基，环庚烷-1,3-二酮-2-基或环戊烷-1,3-二酮-2-基，或衍生物（例如稠合的双稠合稠合衍生物和/或螺环衍生物）或其烯醇酮互变异构体衍生物，其中Q在本文中进一步定义; 并且其中式（I）化合物任选作为农业化学上可接受的盐存在。优选地，X是甲基; 和/或R 1是氟; 和/或R2是-O-R2A，其中R2A是甲基，乙基，三氟甲基，二氟甲基，三氟乙基或-CH2CH2OCH3。这些化合物适合用作除草剂。因此，本发明还涉及在有用植物的作物中控制杂草，特别是禾本科植物单子叶杂草的方法，包括将式（I）化合物或包含这种化合物的除草组合物施用于杂草和/或植物和/或其基因座。

2. 发明申请

US20160143277A1 Herbicidally Active (alkynyl-phenyl)-Substituted Cyclic Dione Compounds and Derivatives Thereof 审中-公开
标题翻译：除草活性（炔基 - 苯基） - 取代的环状二酮化合物及其衍生物
公开(公告)号：US20160143277A1
公开(公告)日：2016-05-26
申请号：US14894842
申请日：2014-05-29
申请人： SYNGENTA LIMITED
发明人： Janice Black , James Nicholas Scutt , Louisa Whalley , Nigel James Willets
IPC分类号： A01N35/06 , C07C69/24 , A01N37/02 , A01N37/10 , A01N47/06 , C07C381/14 , C07C69/78 , C07C49/577 , C07C69/96
摘要： The present invention relates to a compound of formula (I): wherein: X is methyl or chlorine; R1 is fluorine or bromine; R2 is ethynyl, C1-C3alkoxy, C1-C3haloalkoxy, or C1-C3alkoxy-C1-C3alkoxy-; and Q is a pyran-3,5-dione-4-yl, a thiopyran-3,5-dione-4-yl, a piperidine-3,5-dione-4-yl, a cyclohexane-1,3,5-trione-2-yl, a cyclohexane-1,3-dione-2-yl, a cycloheptane-1,3-dione-2-yl, in which each cyclic dione is bridged by alkanediyl, or a derivative thereof (e.g. an enol ketone tautomer derivative thereof), wherein Q is further defined herein; and wherein the compound of formula (I) is optionally present as an agrochemically acceptable salt thereof. Preferably, X is methyl; and/or R1 is fluorine; and/or R2 is —O—R2A, wherein R2A is methyl, ethyl, trifluoromethyl, difluoromethyl, trifluoroethyl, or —CH2CH2OCH3. These compounds are suitable for use as herbicides. The invention therefore also relates to a method of controlling weeds, especially grassy monocotyledonous weeds, in crops of useful plants, comprising applying a compound of formula (I), or a herbicidal composition comprising such a compound, to the weeds and/or to the plants and/or to the locus thereof.
摘要翻译：本发明涉及式（I）的化合物：其中：X为甲基或氯; R1是氟或溴; R2是乙炔基，C1-C3烷氧基，C1-C3卤代烷氧基或C1-C3烷氧基-C1-C3烷氧基; 并且Q是吡喃-3,5-二酮-4-基，噻喃-3,5-二酮-4-基，哌啶-3,5-二酮-4-基，环己烷-1,3,5 - 三酮-2-基，环己烷-1,3-二酮-2-基，环庚烷-1,3-二酮-2-基，其中每个环二酮由烷二基桥接，或其衍生物（例如烯醇酮互变异构体衍生物），其中Q在本文中进一步定义; 并且其中式（I）化合物任选作为农业化学上可接受的盐存在。优选地，X是甲基; 和/或R 1是氟; 和/或R2是-O-R2A，其中R2A是甲基，乙基，三氟甲基，二氟甲基，三氟乙基或-CH2CH2OCH3。这些化合物适合用作除草剂。因此，本发明还涉及在有用植物的作物中控制杂草，特别是禾本科植物单子叶杂草的方法，包括将式（I）化合物或包含这种化合物的除草组合物施用于杂草和/或植物和/或其基因座。

3. 发明授权

US10590143B2 Herbicidally active (alkynyl-phenyl)-substituted cyclic dione compounds and derivatives thereof 有权
公开(公告)号：US10590143B2
公开(公告)日：2020-03-17
申请号：US14894842
申请日：2014-05-29
申请人： Syngenta Limited
发明人： Janice Black , James Nicholas Scutt , Louisa Whalley , Nigel James Willets
IPC分类号： C07C49/587 , A01N35/06 , C07D493/08 , A01N43/16 , C07D309/32 , C07D311/96 , A01N37/02 , A01N37/10 , A01N47/06 , C07C49/577 , C07C69/24 , C07C69/78 , C07C69/96 , C07C381/14 , A01N43/90 , C07C49/517
摘要： The present invention relates to a compound of formula (I): wherein: X is methyl or chlorine; R1 is fluorine or bromine; R2 is ethynyl, C1-C3alkoxy, C1-C3haloalkoxy, or C1-C3alkoxy-C1-C3alkoxy-; and Q is a pyran-3,5-dione-4-yl, a thiopyran-3,5-dione-4-yl, a piperidine-3,5-dione-4-yl, a cyclohexane-1,3,5-trione-2-yl, a cyclohexane-1,3-dione-2-yl, a cycloheptane-1,3-dione-2-yl, in which each cyclic dione is bridged by alkanediyl, or a derivative thereof (e.g. an enol ketone tautomer derivative thereof), wherein Q is further defined herein; and wherein the compound of formula (I) is optionally present as an agrochemically acceptable salt thereof. Preferably, X is methyl; and/or R1 is fluorine; and/or R2 is —O—R2A, wherein R2A is methyl, ethyl, trifluoromethyl, difluoromethyl, trifluoroethyl, or —CH2CH2OCH3. These compounds are suitable for use as herbicides. The invention therefore also relates to a method of controlling weeds, especially grassy monocotyledonous weeds, in crops of useful plants, comprising applying a compound of formula (I), or a herbicidal composition comprising such a compound, to the weeds and/or to the plants and/or to the locus thereof.

4. 发明授权

US10696686B2 Herbicidally active (alkynyl-phenyl)-substituted cyclic dione compounds and derivatives thereof 有权
公开(公告)号：US10696686B2
公开(公告)日：2020-06-30
申请号：US14894698
申请日：2014-05-29
申请人： Syngenta Limited
发明人： Janice Black , James Nicholas Scutt , Louisa Whalley , Nigel James Willets
IPC分类号： C07D493/08 , A01N43/16 , C07D309/32 , C07D311/96 , C07C49/753 , A01N43/18 , C07C323/22 , A01N43/40 , C07D307/42 , A01N35/06 , A01N37/02 , A01N37/10 , A01N47/06 , C07C49/577 , C07C69/24 , C07C69/78 , C07C69/96 , C07C381/14 , A01N43/90 , C07C49/517
摘要： The present invention relates to a compound of formula (I): wherein: X is methyl or chlorine; R1 is fluorine or bromine; R2 is ethynyl, C1-C3alkoxy, C1-C3haloalkoxy, or C1-C3alkoxy-C1-C3alkoxy-; and Q is a pyran-3,5-dione-4-yl, a thiopyran-3,5-dione-4-yl, a piperidine-3,5-dione-4-yl, a cyclopentane-1,3-dione-2-yl, a cyclohexane-1,3, 5-trione-2-yl, a cyclohexane-1,3-dione-2-yl, or a cycloheptane-1,3-dione-2-yl, or a derivative thereof (e.g. a fused such as fused bicyclic derivative, and/or a spirocyclic derivative), or an enol ketone tautomer derivative thereof, wherein Q is further defined herein; and wherein the compound of formula (I) is optionally present as an agrochemically acceptable salt thereof. Preferably, X is methyl; and/or R1 is fluorine; and/or R2 is —O—R2A, wherein R2A is methyl, ethyl, trifluoromethyl, difluoromethyl, trifluoroethyl, or —CH2CH2OCH3. These compounds are suitable for use as herbicides. The invention therefore also relates to a method of controlling weeds, especially grassy monocotyledonous weeds, in crops of useful plants, comprising applying a compound of formula (I), or a herbicidal composition comprising such a compound, to the weeds and/or to the plants and/or to the locus thereof.

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