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    • 4. 发明授权
    • Linear low density polyethylene with uniform or reversed comonomer composition distribution
    • 具有均匀或反相共聚单体组成分布的线性低密度聚乙烯
    • US08546499B2
    • 2013-10-01
    • US13318101
    • 2010-04-26
    • Thomas GarroffPaivi WaldvogelKallio KalleVirginie ErikssonAki AittolaEsa Kokko
    • Thomas GarroffPaivi WaldvogelKallio KalleVirginie ErikssonAki AittolaEsa Kokko
    • C08F4/44
    • C08F210/16C08L2314/02C08F210/08C08F2500/12C08F2500/18C08F2500/08C08F2500/10
    • Ziegler-Natta catalyzed linear low density polyethylene which satisfies the following conditions:a) a density, according to ISO 1183, of from 900 to 925 kg/m3,b) a C4-C10-comonomer content, determined by Fourier transform infrared spectroscopy, of 1 to 16 wt %c) a weight average molecular weight Mw, determined by gel permeation chromatography, of at least 200 000,d) wherein the linear low density polyethylene comprises, by Crystallisation Analysis Fractionation (CRYSTAF) an amorphous fraction soluble at a temperature below 30° C. of at most 10 wt % and a fraction crystallising between 60 to 75° C. of at least 35 wt % ande) by temperature rising elution fractionation (TREF) analysis, at least 70 wt % of a crystallising polymer component having an elution temperature range from 60° C. to 94° C. and less than 10 wt % of a crystallising polymer component having an elution temperature range from 30° C. to 60° C. and,f) by Gel Permeation chromatography coupled with Fourier transform infrared spectroscopy detector (GPC-FTIR), a substantially constant short chain branching profile across the molecular weight distribution (MWD) org) by Gel Permeation chromatography coupled with Fourier transform infrared spectroscopy instruments (GPC-FTIR), a reverse short chain branching profile across the molecular weight distribution (MWD),the linear low density polyethylene being produced in the presence of a special Ziegler-Natta procatalyst and a halogenated aluminium alkyl cocatalyst of the formula (IV) (C1-C4- alkyl)m-Al-X3−m, wherein X is chlorine, bromine, iodine or fluorine and m is 1 or 2.
    • 齐格勒 - 纳塔催化的线性低密度聚乙烯,其满足以下条件:a)根据ISO 1183的密度为900至925kg / m 3,b)通过傅立叶变换红外光谱测定的C 4 -C 10共聚单体含量, c)通过凝胶渗透色谱测定的至少200000重量平均分子量Mw,d)其中线性低密度聚乙烯通过结晶分析分馏(CRYSTAF)包含在 温度低于30℃,至多10重量%,并且在60至75℃之间结晶至少35重量%的级分,e)通过升温洗脱分级(TREF)分析,至少70重量%的结晶 具有洗脱温度范围为60℃至94℃且小于10重量%的具有洗脱温度范围为30℃至60℃的结晶聚合物组分的聚合物组分,以及f)通过凝胶渗透 色谱与傅里叶变换耦合 (GPC-FTIR),通过分子量分布(MWD)基本上恒定的短链支化分子,或g)通过凝胶渗透色谱法与傅立叶变换红外光谱仪(GPC-FTIR),反向短链支化 在分子量分布(MWD)的范围内,线性低密度聚乙烯是在特殊的齐格勒 - 纳塔前催化剂和式(Ⅳ)的卤化烷基铝助催化剂(C 1 -C 4烷基)m-Al- X3-m,其中X是氯,溴,碘或氟,m是1或2。
    • 5. 发明申请
    • LINEAR LOW DENSITY POLYETHYLENE WITH UNIFORM OR REVERSED COMONOMER COMPOSITION DISTRIBUTION
    • 线性低密度聚乙烯具有均匀或反转的人气组合物分布
    • US20120053308A1
    • 2012-03-01
    • US13318101
    • 2010-04-26
    • Thomas GarroffPaivi WaldvogelKallio KalleVirginie ErikssonAki AittolaEsa Kokko
    • Thomas GarroffPaivi WaldvogelKallio KalleVirginie ErikssonAki AittolaEsa Kokko
    • C08F4/646C08F210/16
    • C08F210/16C08L2314/02C08F210/08C08F2500/12C08F2500/18C08F2500/08C08F2500/10
    • Ziegler-Natta catalyzed linear low density polyethylene which satisfies the following conditions: a) a density, according to ISO 1183, of from 900 to 925 kg/m3, b) a C4-C10-comonomer content, determined by Fourier transform infrared spectroscopy, of 1 to 16 wt % c) a weight average molecular weight Mw, determined by gel permeation chromatography, of at least 200 000, d) wherein the linear low density polyethylene comprises, by Crystallisation Analysis Fractionation (CRYSTAF) an amorphous fraction soluble at a temperature below 30° C. of at most 10 wt % and a fraction crystallising between 60 to 75° C. of at least 35 wt % and e) by temperature rising elution fractionation (TREF) analysis, at least 70 wt % of a crystallising polymer component having an elution temperature range from 60° C. to 94° C. and less than 10 wt % of a crystallising polymer component having an elution temperature range from 30° C. to 60° and, f) by Gel Permeation chromatography using an Fourier transform infrared spectroscopy detector (GPC-FTIR), a substantially constant short chain branching profile across the molecular weight distribution (MWD) or g) by Gel Permeation chromatography coupled with Fourier transform infrared spectroscopy instruments (GPC-FTIR), a revers short chain branching profile across the molecular weight distribution (MWD), the linear low density polyethylene being produced in the presence of a special Ziegler-Natta procatalyst and a halogenated aluminium alkyl cocatalyst of the formula (IV) (C1-C4-alkyl)m-AI-X3-m1, wherein X is chlorine, bromine, iodine or fluorine and m is 1 or 2.
    • 齐格勒 - 纳塔催化的线性低密度聚乙烯,其满足以下条件:a)根据ISO 1183的密度为900至925kg / m 3,b)通过傅立叶变换红外光谱测定的C 4 -C 10共聚单体含量, c)通过凝胶渗透色谱测定的至少200000重量平均分子量Mw,d)其中线性低密度聚乙烯通过结晶分析分馏(CRYSTAF)包含在 温度低于30℃,至多10重量%,并且在60至75℃之间结晶至少35重量%的级分,e)通过升温洗脱分级(TREF)分析,至少70重量%的结晶 具有洗脱温度范围为60℃至94℃且小于10重量%的具有洗脱温度范围为30℃至60℃的结晶聚合物组分的聚合物组分,和f)通过凝胶渗透色谱法,使用 傅里叶变换inf (GPC-FTIR),通过与傅立叶变换红外光谱仪(GPC-FTIR)结合的凝胶渗透色谱法,通过分子量分布(MWD)基本恒定的短链支化谱,或g) 在分子量分布(MWD)下,在特殊的齐格勒 - 纳塔前催化剂和式(Ⅳ)的卤化烷基铝助催化剂(C 1 -C 4烷基)m-AI-X3存在下生产的线性低密度聚乙烯 -m1,其中X是氯,溴,碘或氟,m是1或2。
    • 6. 发明申请
    • IMPROVED ETHYLENE POLYMERIZATION CATALYST COMPOSITION
    • 改进的乙烯聚合催化剂组合物
    • US20120095172A1
    • 2012-04-19
    • US13263173
    • 2010-04-26
    • Thomas GaroffPaivi WaldvogelKalle KallioVirginie Eriksson
    • Thomas GaroffPaivi WaldvogelKalle KallioVirginie Eriksson
    • C08F4/646C08F4/648C08F210/14C08F2/00C08F210/08
    • C08F210/16C08F4/6555C08F210/08C08F2500/12C08F2500/18C08F2500/08
    • Ziegler-Natta catalyst composition capable of producing ethylene/alpha-olefins copolymers, particularly linear low density polyethylene; the composition having an improved stability of its behaviour during polymerization in respect to time. The Ziegler-Natta catalyst composition comprises: 1. Ziegler-Natta catalyst composition for the production of ethylene copolymers comprising A) a procatalyst, which procatalyst comprises a) an Al compound having the formula Al(alkyl)xCl3-x (I), where alkyl is an alkyl group with 1 to 12 and 0≦x≦3, b) a magnesium hydrocarbyloxy compound of formula Mg(OR1)2-n(R2)n (II), wherein each R1 and R2 is independently a C1-20 hydrocarbon residue which may optionally be substituted with halogen and 0≦n
    • 能够生产乙烯/α-烯烃共聚物,特别是线性低密度聚乙烯的齐格勒 - 纳塔催化剂组合物; 该组合物在聚合过程中相对于时间具有改进的其行为稳定性。 齐格勒 - 纳塔催化剂组合物包括:1.用于生产乙烯共聚物的齐格勒 - 纳塔催化剂组合物,其包含A)前催化剂,其前体催化剂包含a)具有式Al(烷基)xCl 3-x(I)的Al化合物,其中 烷基是具有1至12和0和nlE; x和nlE; 3,b)式Mg(OR 1)2-n(R 2)n(II)的镁烃氧基化合物的烷基,其中每个R 1和R 2独立地是C 1-20 可以任选被卤素取代的烃残基,n <2和c)式ClyTi(OR 3)4-y(III)的含氯钛化合物,其中R3是C2-20烃基,y是 1,2,3或4,化合物a),b)和c)负载在颗粒状无机载体上,B)式(Ⅳ)卤代烷基铝助催化剂(C 1 -C 4烷基)m-Al- X3-m,其中X是氯,溴,碘或氟,m是1或2。