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1. 发明申请

US20050202959A1 Solid catalytic component and catalytic system of the ziegler-natta type, process for their preparation and their use in the polymerisation of alk-1-enes 失效
标题翻译：齐格勒 - 纳塔型固体催化组分和催化体系，其制备方法及其在烷-1-烯的聚合中的应用
公开(公告)号：US20050202959A1
公开(公告)日：2005-09-15
申请号：US10504702
申请日：2003-01-28
申请人： Wolf Spaether , John Lynch , Joachim Rosch , Rainer Hemmerich
发明人： Wolf Spaether , John Lynch , Joachim Rosch , Rainer Hemmerich
IPC分类号： C08F10/00 , C08F4/64 , C08F4/658 , C08F10/06 , C08F110/06 , B01J31/00 , C08F4/44
CPC分类号： C08F110/06 , C08F4/651 , C08F4/025 , C08F4/6546 , C08F2500/12 , C08F2500/15 , C08F2500/24
摘要： The present invention relates to a new solid catalytic component, which can be used in combination with an aluminum compound as co-catalyst and optionally an external electron donor as additional co-catalyst to form a catalytic system of the Ziegler-Natta-catalyst-type. The solid catalytic system comprises titanium or vanadium compound, a compound of magnesium containing at least one halogen, a particulate porous support, and optionally an internal electron donor.
摘要翻译：本发明涉及一种新的固体催化组分，其可以与作为助催化剂的铝化合物和任选的外部电子给体一起用作另外的助催化剂以形成齐格勒 - 纳塔催化剂型催化体系。固体催化体系包括钛或钒化合物，含有至少一个卤素的镁的化合物，颗粒状多孔载体和任选的内部电子给体。

2. 发明授权

US5756621A 2-oxazolinyl-terminated polymers and oligomers useful as compatibilizers 失效
标题翻译：可用作增容剂的2-恶唑啉基封端的聚合物和低聚物
公开(公告)号：US5756621A
公开(公告)日：1998-05-26
申请号：US686909
申请日：1996-07-26
申请人： Joachim Rosch , Hans-Joachim Muller , Arthur Hohn , Rolf Muelhaupt , Christof Woerner
发明人： Joachim Rosch , Hans-Joachim Muller , Arthur Hohn , Rolf Muelhaupt , Christof Woerner
IPC分类号： C08F8/14 , C08F8/30 , C08F8/32 , C08F8/50 , C08F10/00 , C08F110/00 , C08F110/06 , C08G73/00 , C08G81/02 , C08F34/02 , C08F22/40 , C08F24/00
CPC分类号： C08F8/30
摘要： Polymers and oligomers of olefinically unsaturated C.sub.2 -C.sub.20 -hydrocarbons having one or two 2-oxazolinyl end groups have the structure (I) ##STR1## where A is a polymer or oligomer radical derived from the olefinically unsaturated C.sub.2 -C.sub.20 -hydrocarbons and the radicals R can be identical or different and have the following meanings: hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.10 -aryl, C.sub.3 -C.sub.6 -cycloalkyl.
摘要翻译：具有一个或两个2-恶唑啉基端基的烯属不饱和C 2 -C 20烃的聚合物和低聚物具有结构（I）其中A是衍生自烯属不饱和C 2 -C 20烃的聚合物或低聚物基团并且基团R可以相同或不同，具有以下含义：氢，C 1 -C 10 - 烷基，C 6 -C 10 - 芳基，C 3 -C 6环烷基。

3. 发明申请

US20070063189A1 Compounds based on fluoranthene and use thereof 有权
标题翻译：基于荧蒽的化合物及其用途
公开(公告)号：US20070063189A1
公开(公告)日：2007-03-22
申请号：US10571557
申请日：2004-09-09
申请人： Rienhold Schwalm , Yvonne Heischkel , Andreas Fechtenkotter , Joachim Rosch , Florian Dotz
发明人： Rienhold Schwalm , Yvonne Heischkel , Andreas Fechtenkotter , Joachim Rosch , Florian Dotz
IPC分类号： H01L51/00 , H01L29/08
CPC分类号： C07C205/06 , C07C13/66 , C07C25/22 , C07C2603/40 , C07D333/08 , C09K11/06 , C09K2211/1011 , H01L51/0054 , H01L51/0068 , H05B33/14
摘要： The invention relates to fluoranthene derivatives of the general formula (I) in which R1, R2, R3 and a are each defined according to the description, with the proviso that at least one of the R1 or R2 radicals is not hydrogen, to processes for their preparation and to the use of the fluoranthene derivatives as emitter molecules in organic light-emitting diodes (OLEDs), to a light-emitting layer comprising the inventive fluoranthene derivatives as emitter molecules, to an OLED comprising the inventive light-emitting layer and to devices comprising the inventive OLED.
摘要翻译：本发明涉及通式（I）的荧蒽衍生物，其中R 1，R 2，R 3和A各自定义如下：在描述中，条件是至少一个R 1或R 2基团不是氢，其制备方法和使用荧蒽衍生物作为有机发光二极管（OLED）中的发射极分子，涉及包含本发明的荧蒽衍生物作为发射体分子的发光层，涉及包含本发明的发光层的OLED和包含本发明的OLED的器件。

4. 发明授权

US6133209A Polyolefins and their functionalized derivatives 失效
标题翻译：聚烯烃及其官能化衍生物
公开(公告)号：US6133209A
公开(公告)日：2000-10-17
申请号：US297633
申请日：1999-07-27
申请人： Hans Peter Rath , Irene Trotsch-Schaller , Dietmar Posselt , Bernhard Geissler , Johann-Peter Melder , Joachim Rosch
发明人： Hans Peter Rath , Irene Trotsch-Schaller , Dietmar Posselt , Bernhard Geissler , Johann-Peter Melder , Joachim Rosch
IPC分类号： C10L1/234 , C08F4/14 , C08F4/642 , C08F8/00 , C08F8/30 , C08F10/00 , C08F210/16 , C10L1/16 , C10L1/198 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/00 , C10L10/08 , C10M143/00 , C10N40/25 , C10M133/52 , C10L1/22
CPC分类号： C10M143/00 , C08F10/00 , C08F8/00 , C10L1/1641 , C10L1/198 , C10L1/1985 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/08 , C08F210/16 , C10M2205/00 , C10M2215/04 , C10M2215/26 , C10M2217/046 , C10M2217/06
摘要： The present invention relates to at least simply unsaturated polyolefins with a number mean molecular weight in the range of 400 to 1,500 dalton and a dispersibility of M.sub.W /M.sub.N
摘要翻译： PCT No.PCT / EP97 / 06068 Sec。 371日期：1999年7月27日 102（e）日期1997年7月27日PCT 1997年11月3日PCT公布。 WO98 / 20053 PCT出版物日期：1998年5月14日本发明涉及数均分子量在400至1,500道尔顿的至少简单的不饱和聚烯烃和通过至少简单不饱和烯烃低聚物的催化二聚获得的MW / MN <1.2的分散性，以及其生产方法。本发明还涉及这些聚烯烃的衍生物，它们可以通过使至少一个聚烯烃的双链官能化而获得。本发明还涉及聚烯烃和/或官能化产品作为燃料或润滑剂的添加剂的用途。

5. 发明授权

US6096845A Preparation of crystalline polymers by dispersion polymerization in the presence of metallocene catalyst systems 失效
标题翻译：在茂金属催化剂体系的存在下通过分散聚合制备结晶聚合物
公开(公告)号：US6096845A
公开(公告)日：2000-08-01
申请号：US866162
申请日：1997-05-30
申请人： Joachim Rosch , Josef Wunsch
发明人： Joachim Rosch , Josef Wunsch
IPC分类号： C08F2/14 , C08F2/08 , C08F2/20 , C08F4/623 , C08F4/639 , C08F4/6392 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F4/68 , C08F8/00 , C08F10/00 , C08F10/02 , C08F10/06 , C08F32/00 , C08F110/06 , C08F4/44 , C08F2/00
CPC分类号： C08F10/00 , C08F110/06 , C08F32/00 , C08F4/63912 , C08F4/6392 , Y10S526/903 , Y10S526/943
摘要： Crystalline polymers of ethylene, propylene or cyclic olefins or mixtures thereof are prepared by a process in which polymerization is carried out in the presence of a metallocene catalyst system in a dispersion.
摘要翻译：乙烯，丙烯或环烯烃或其混合物的结晶聚合物是通过在分散体中在茂金属催化剂体系存在下进行聚合的方法制备的。

6. 发明授权

US5908903A Metallocene catalyst systems containing lewis bases 失效
标题翻译：含有路易斯碱的茂金属催化剂体系
公开(公告)号：US5908903A
公开(公告)日：1999-06-01
申请号：US777744
申请日：1996-12-20
申请人： Joachim Rosch
发明人： Joachim Rosch
IPC分类号： C07C2/32 , C07B61/00 , C08F4/629 , C08F4/639 , C08F4/6392 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C10G50/00
CPC分类号： C08F10/00 , C08F4/63908 , C08F4/63912 , C08F4/63922
摘要： Catalyst systems which are suitable for polymerizing olefinically unsaturated compounds comprise as active constituentsA) a metallocene complex of the metals of the fourth, fifth or sixth transition group of the Periodic Table of the Elements,B) a compound forming metallocenium ions andC) a sterically hindered, organic Lewis base.
摘要翻译：适用于聚合烯属不饱和化合物的催化剂体系包括作为活性成分的A）元素周期表第四，第五或第六转移基团的金属的茂金属络合物，B）形成金属茂离子的化合物和C）空间位阻，有机路易斯碱。

7. 发明授权

US5312875A Process for the manufacture of in situ polymer alloys and microcompounds, and use thereof 失效
标题翻译：原位聚合物合金和微型化合物的制造方法及其用途
公开(公告)号：US5312875A
公开(公告)日：1994-05-17
申请号：US109711
申请日：1993-08-20
申请人： Rolf Mulhaupt , Joachim Rosch , Siegfried Hopperdietzel , Ekkehard Weinberg , Herbert Klein
发明人： Rolf Mulhaupt , Joachim Rosch , Siegfried Hopperdietzel , Ekkehard Weinberg , Herbert Klein
IPC分类号： C08G69/14 , C08G69/04 , C08L23/02 , C08L23/26 , C08L77/00 , C08L77/02 , C08L101/00 , C09D177/00 , C09D177/02 , C09J123/26 , C09J177/00 , C09J177/02 , D01F6/46 , C08L77/10
CPC分类号： C08L77/02 , C08L101/00 , C08L23/02
摘要： A polymer mixture reinforced by an in situ, melt-polymerized microphase whereby the rigidity of the base material is increased, a process for manufacturing same, and use thereof for providing reinforced compositions and articles in which the polymer mixture is prepared by polymerizing a component B in a melt of a component A composed of at least one thermoplastic polymer. Component B is composed of at least one compound having the structure ##STR1## The reaction of component B in a melt of component A results in linear, branched or cross-linked, high or low molecular weight polymers constituting a microphase. Preferably, the microphases have the form of microfibers. In the structure of component B, X is NH.sub.2, NHR.sup.3, OH or an N-substituted, Y-activated lactam of the ##STR2## type which is activated with an electrophilic substituent Y, where Y is CO, SO.sub.2, or R.sup.5 P=O; R.sup.1, R.sup.2 and R.sup.4 are bivalent or multivalent aliphatic-, aromatic-, heterocyclic- or heteroatom-containing segments, with R.sup.2 and R.sup.4 preferably being bivalent aliphatic or aromatic radicals (CH.sub.2).sub.z in which 1
摘要翻译：通过原位，熔融聚合的微相增强的聚合物混合物，由此增加基材的刚性，其制备方法及其用于提供增强组合物和制品的用途，其中通过聚合组分B制备聚合物混合物在由至少一种热塑性聚合物组成的组分A的熔体中。组分B由至少一种具有结构的化合物组成。组分B在组分A的熔体中的反应产生构成微相的直链，支链或交联的高分子量或低分子量聚合物。优选地，微细管具有微纤维的形式。在组分B的结构中，X是NH 2，NHR 3，OH或N-取代的Y活化的具有亲电取代基Y活化的Y型活化的内酰胺，其中Y是CO，SO2或R5P = O ; R 1，R 2和R 4是二价或多价的脂族 - ，芳族 - ，杂环或含杂原子的链段，其中R 2和R 4优选是二价脂族或芳族基团（CH 2）z，其中1

8. 发明申请

US20070287821A1 Synthesis of Polynaphthalenes and Their Use 审中-公开
标题翻译：聚萘的合成及其用途
公开(公告)号：US20070287821A1
公开(公告)日：2007-12-13
申请号：US11574546
申请日：2005-09-05
申请人： Florian Doetz , Simon Nord , Horst Weiss , Joachim Rosch
发明人： Florian Doetz , Simon Nord , Horst Weiss , Joachim Rosch
IPC分类号： C08G61/10 , H01B1/12
CPC分类号： H01B1/128 , C08G61/02 , C08G61/10
摘要： The present invention relates to a process for preparing polynaphthalene derivatives comprising repeating units of the general formula Ia and/or Ib where R1, R2, R1′, R2′ are as defined in the description. The present invention further relates to polynaphthalene derivatives which can be prepared by the process of the invention, films comprising or consisting of at least one polynaphthalene derivative according to the invention, organic light-emitting diodes (OLEDs) comprising at least one polynaphthalene derivative according to the invention, a light-emitting layer comprising or consisting of at least one polynaphthalene derivative according to the invention, an OLED comprising the light-emitting layer of the invention, devices comprising an OLED according to the invention and the use of the polynaphthalene derivatives of the invention as emitter substances in OLEDs.
摘要翻译：本发明涉及一种制备聚萘衍生物的方法，其包含通式Ia和/或Ib的重复单元，其中R 1，R 2，R 1，，R“2”如说明书中所定义。本发明还涉及可以通过本发明的方法制备的聚萘衍生物，包含或由至少一种根据本发明的聚萘衍生物的膜组成的有机发光二极管（OLED）包含至少一种根据本发明的聚萘衍生物本发明包括由至少一种根据本发明的聚萘衍生物或由本发明的至少一种聚萘衍生物构成的发光层，包含本发明的发光层的OLED，包含根据本发明的OLED的器件和使用本发明作为OLED中的发射物质。

9. 发明申请

US20070069198A1 Synthesis of phenyl-substituted fluoranthenes by a diesel-alder reaction and the use thereof 有权
标题翻译：苯基取代的荧蒽通过狄尔斯 - 阿尔德反应合成及其应用
公开(公告)号：US20070069198A1
公开(公告)日：2007-03-29
申请号：US10573803
申请日：2004-09-28
申请人： Florian Dotz , Reinhold Schwalm , Joachim Rosch
发明人： Florian Dotz , Reinhold Schwalm , Joachim Rosch
IPC分类号： H01L51/00 , C07C69/52 , C07D213/84
CPC分类号： C07C13/66 , C07C2/867 , C07C2603/48 , C09K11/06 , C09K2211/1011 , H01L51/0054 , H01L51/0058 , H01L51/5012 , H05B33/14 , Y10S428/917
摘要： Fluoranthene derivatives of the general formula I where the symbols have the following meanings: R1, R2, R3, R4, R5 are each hydrogen, alkyl, an aromatic radical, a fused aromatic ring system, a heteroaromatic radical or —CH═CH2, (E)- or (Z)-CH═CH—C6H5, acryloyl, methacryloyl, methylstyryl, —O—CH═CH2 or glycidyl; where at least one of the radicals R1, R2 and/or R3 is not hydrogen; X is an alkyl radical, an aromatic radical, a fused aromatic ring system, a heteroaromatic radical or a radical of the formula (I′) or an oligophenyl group; n is from 1 to 10 or, in the case of X=oligophenyl group, 1-20; with the proviso that R1, R2, R3 and X are not at the same time phenyl when R4 and R5 are hydrogen. Furthermore, the invention relates to a process for preparing them and the use of fluoranthene derivatives as emitter molecule in organic light-emitting diodes (OLEDs), a light-emitting layer comprising the fluoranthene derivatives of the invention as emitter molecules, an OLED comprising the light-emitting layer of the invention and devices comprising the OLED of the invention.
摘要翻译：其中符号具有以下含义的通式I的荧蒽衍生物：R 1，R 2，R 3，R 4， R 5各自为氢，烷基，芳族基，稠合芳环系，杂芳族基或-CH-CH 2，（E） - 或（Z）-CH-CH-C 6 H 5，丙烯酰基，甲基丙烯酰基，甲基苯乙烯基，-O-CH-CH 2或缩水甘油基其中基团R 1，R 2和/或R 3中的至少一个不是氢; X是烷基，芳族基团，稠合芳族环系统，杂芳族基团或式（I'）的基团或低级苯基; n为1至10，或在X =低聚苯基的情况下为1-20; 条件是R 4，R 2，R 3和X不在同时为R 4时的苯基， SUP>和R 5是氢。此外，本发明涉及其制备方法以及在有机发光二极管（OLED）中使用荧蒽衍生物作为发射体分子的方法，包含本发明的荧蒽衍生物作为发射体分子的发光层，包含本发明的发光层和包含本发明的OLED的器件。

10. 发明申请

US20050038208A1 Highly flowable propylene block copolymers 有权
标题翻译：高流动性丙烯嵌段共聚物
公开(公告)号：US20050038208A1
公开(公告)日：2005-02-17
申请号：US10296256
申请日：2001-05-23
申请人： Ulrich Dahn , Wolfgang Bidell , Hans-Jurgen Zimmermann , Roland Hingmann , Joachim Rosch , Gunther Schweier , Jurgen Oelze
发明人： Ulrich Dahn , Wolfgang Bidell , Hans-Jurgen Zimmermann , Roland Hingmann , Joachim Rosch , Gunther Schweier , Jurgen Oelze
IPC分类号： C08J5/00 , C08F2/00 , C08F4/642 , C08F10/06 , C08F110/06 , C08F210/06 , C08F297/08 , C08L53/00 , D01F6/30
CPC分类号： C08F297/08 , C08F10/06 , C08F110/06 , C08F210/06 , C08L53/00 , C08F2/001 , C08F2/34 , C08L2666/02 , C08F2500/12 , C08F2500/17 , C08F210/16
摘要： The invention relates to highly flowable propylene block copolymers that comprise 50 to 80 wt.-% of a propylene homopolymer and 10 to 70 wt.-% of a propylene copolymer having 5 to 50 wt.-% of a C2-C8 alk-1-ene polymerized into it that is different from propylene, and that are obtainable from the gaseous phase by a two-step polymerization by means of a Ziegler-Natta catalyst system. In a first polymerization step, the propylene is polymerized at a pressure of 10 to 50 bar, a temperature of 50 to 100° C. and an average dwelling time of the reaction mixture of 0.3 to 5 hours in the presence of at least 2.0% by volume, based on the total volume, of hydrogen. The propylene homopolymer obtained in said first polymerization step is transferred together with the Ziegler-Natta catalyst system into an intermediate container, expanded for 0.01 to 5 minutes to less than 5 bar and maintained at a temperature of 10 to 80° C. The pressure in the intermediate container is then increased by 5 to 60 bar by introducing under pressure a gaseous mixture, and the propylene homopolymer is then transferred to a second polymerization step together with the Ziegler-Natta catalyst system. In said second polymerization step, a mixture from propylene and a C2-C8 alkylene is polymerized into the propylene homopolymer at a pressure of 10 to 50 bar, a temperature of 50 to 100° C. and an average dwelling time of 0.5 to 5 hours. The weight ratio between the monomers reacted in the first and those reacted in the second polymerization step are adjusted to be in the range of from 4:1 to 1:1.
摘要翻译：本发明涉及高流动性丙烯嵌段共聚物，其包含50至80重量％的丙烯均聚物和10至70重量％的丙烯共聚物，其具有5至50重量％的C 2 -C 8烷基-1 其与丙烯不同，并且可通过采用齐格勒 - 纳塔催化剂体系的两步聚合由气相获得。在第一聚合步骤中，丙烯在10至50巴的压力，50至100℃的温度和在至少2.0％的存在下反应混合物的平均停留时间为0.3至5小时的聚合反应，，基于总体积的氢气。将所述第一聚合步骤中获得的丙烯均聚物与齐格勒 - 纳塔催化剂体系一起转移到中间容器中，膨胀0.01至5分钟至小于5巴，并保持在10至80℃的温度。然后通过在压力下引入气体混合物将中间容器增加5至60巴，然后将丙烯均聚物与齐格勒 - 纳塔催化剂体系一起转移到第二聚合步骤。在所述第二聚合步骤中，将丙烯和C 2 -C 8亚烷基的混合物在10至50巴的压力，50至100℃的温度和0.5至5小时的平均停留时间内聚合成丙烯均聚物。在第一聚合步骤中反应的单体和在第二聚合步骤中反应的单体之间的重量比被调节至4:1至1:1的范围内。

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