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    • 8. 发明申请
    • BIDIRECTIONAL SHAPE-MEMORY POLYMER, METHOD OF ITS PRODUCTION AND ITS USE
    • 双向形状记忆聚合物,其生产方法及其用途
    • US20150344600A1
    • 2015-12-03
    • US14653941
    • 2013-12-20
    • HELMOHOLTZ-ZENTRUM GEESTHACHT ZENTRUM FÜR MATERIAL UNDKÜSTENFORSCHUNG GMBH
    • Marc BehlKarl KratzUlrich NoechelTilman SauterJoerg ZotzmannSrinivasa Reddy ChagantiAndreas Lendlein
    • C08F210/02H01F1/42C08G63/91C08G18/42C08G81/02
    • C08F210/02B29C61/003B29C61/06C08G18/4277C08G63/91C08G81/021C08G81/027C08G2280/00C08J3/248H01F1/42
    • The present invention relates to an article consisting of or comprising a bidirectional shape-memory polymer (bSMP), the bSMP comprising: first phase-segregated domains (AD) having a first transition temperature (Tt,AD) corresponding to a crystallization transition or glass transition of the first domains (AD), second phase-segregated domains (SD) having a second transition temperature (Tt,AD) corresponding to a crystallization transition or glass transition of the second domains (SD), the second transition temperature (Tt,SD) being higher than the first transition temperature (Tt,AD), and covalent or physical bonds cross-linking the polymer chains of the bSMP, and in this way interconnecting the first and second domains (AD, SD), wherein the second phase-separated domains (SD) form a skeleton which is at least partially embedded in the first phase-segregated domains (AD), and wherein polymer chain segments of the bSMP forming the first domains (AD) are substantially orientated in a common direction, such that the bSMP is able to undergo a reversible shape-shift between a first shape (A) at a first temperature (Thigh) and a second shape (B) at a second temperature (Tlow) upon variation of temperature between the first and second temperature (Thigh, Tlow) driven by the crystallization and melting or vitrification and melting of the first phase-separated domains (AD) and without application of an external stress, with Tlow
    • 本发明涉及由双向形状记忆聚合物(bSMP)组成或包含双边形状记忆聚合物(bSMP)的物品,所述bSMP包括:具有对应于结晶转变的第一转变温度(Tt,AD)的第一分相畴(AD)或玻璃 具有对应于第二结构域(SD)的结晶转变或玻璃化转变的第二转变温度(Tt,AD)的第一结构域(AD),第二分相畴(SD)的转变,第二转变温度(Tt, SD)高于第一转变温度(Tt,AD),并且共价或物理键交联bSMP的聚合物链,并且以这种方式互连第一和第二结构域(AD,SD),其中第二相 分离结构域(SD)形成至少部分地嵌入第一分相结构域(AD)中的骨架,并且其中形成第一结构域(AD)的bSMP的聚合物链段基本上定向于共 使得bSMP在第一温度(Thigh)的第一形状(A)和第二温度(Tlow)的第二形状(B)之间能够在第二温度(Tlow)之间经历可逆形状位移 第一和第二温度(Thigh,Tlow)由第一相分离结构域(AD)的结晶和熔化或玻璃化和熔化而驱动并且不施加外部应力,Tlow