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    • 5. 发明授权
    • Preparation of nanosized copper (I) compounds
    • 纳米尺寸铜(I)化合物的制备
    • US07700796B2
    • 2010-04-20
    • US10413754
    • 2003-04-16
    • Kenrick M. LewisChi-Lin O'Young
    • Kenrick M. LewisChi-Lin O'Young
    • C01G3/05
    • B82Y30/00C01C3/08C01C3/11C01G3/00C01G3/04C01G3/05C01P2002/72C01P2002/77C01P2002/82C01P2004/62C01P2004/64Y10S977/773Y10S977/81
    • A method of making nanosized copper (I) compounds, in particular, copper (I) halides, pseudohalides, and cyanocuprate complexes, in reverse micelles or microemulsions is disclosed herein. The method of the invention comprises (a) dissolving a copper (II) compound in the polar phase of a first reverse micelle or microemulsion, (b) dissolving a copper (II) to copper (I) reducing agent or a pseudohalide salt in the polar phase of a second sample of the same reverse micelle or microemulsion, (c) mixing the two reverse micelle/microemulsions samples to form nanometer sized copper (I) compounds and (d) recovering said nanometer sized copper (I) compounds. The present invention is also directed to the resultant nanosized copper (I) compounds, such as copper (I) chloride, copper (I) cyanide, and potassium cyanocuprate complexes having an average particle size of about 0.1 to 600 nanometers.
    • 本文公开了一种在反胶束或微乳液中制备纳米尺寸铜(I)化合物,特别是卤化铜(I),拟卤化物和氰基偶联物络合物的方法。 本发明的方法包括(a)将铜(II)化合物溶解在第一反胶束或微乳液的极性相中,(b)将铜(II)溶解在铜(I)还原剂或拟卤化物盐中, 相同反胶束或微乳液的第二样品的极性相,(c)混合两个反胶束/微乳液样品以形成纳米尺寸的铜(I)化合物和(d)回收所述纳米尺寸的铜(I)化合物。 本发明还涉及所得到的纳米尺度铜(I)化合物,例如氯化铜(I),氰化铜(I)和平均粒度约为0.1至600纳米的氰基钴酸钾配合物。
    • 9. 发明授权
    • Prussian blue analogue electrodes without zeolitic water content
    • 普鲁士蓝色模拟电极,无沸石含水量
    • US09478798B2
    • 2016-10-25
    • US14830838
    • 2015-08-20
    • Sharp Laboratories of America, Inc.
    • Yuhao LuJie SongJong-Jan Lee
    • H01M4/00H01M4/136H01M4/58C01C3/11
    • H01M4/136C01C3/11C01C3/12H01M4/58Y02E60/122
    • A battery is provided with a hexacyanometallate cathode. The battery cathode is made from hexacyanometallate particles overlying a current collector. The hexacyanometallate particles have the chemical formula AXM1MM2N(CN)Z.d[H2O]ZEO.e[H2O]BND, where A is a metal from Groups 1A, 2A, or 3A of the Periodic Table, where M1 and M2 are each a metal with 2+ or 3+ valance positions, where “ZEO” and “BND” indicate zeolitic and bound water, respectively, where d is 0, and e is greater than 0 and less than 8. The anode material may primarily be a material such as hard carbon, soft carbon, oxides, sulfides, nitrides, silicon, metals, or combinations thereof. The electrolyte is non-aqueous. A method is also provided for fabricating hexacyanometallate with no zeolitic water content in response to dehydration annealing at a temperature of greater than 120 degrees C. and less than 200 degrees C.
    • 电池具有六金属金属阴极。 电池阴极由覆盖集电器的六氰基金属盐颗粒制成。 六氰基金属盐颗粒具有化学式AXM1MM2N(CN)Zd [H2O] ZEO.e [H2O] BND,其中A是元素周期表第1A,2A或3A族的金属,其中M1和M2各自为金属, 2+或3+价位,其中“ZEO”和“BND”分别表示沸石和结合水,其中d为0,e大于0且小于8.阳极材料可主要为诸如 硬碳,软碳,氧化物,硫化物,氮化物,硅,金属或其组合。 电解质是非水的。 还提供了一种方法,用于在大于120℃和小于200℃的温度下响应于脱水退火而制备无沸石含水量的六氰基金属盐酸盐