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    • 9. 发明申请
    • LITHIUM-POROUS METAL OXIDE COMPOSITIONS AND LITHIUM REAGENT-POROUS METAL COMPOSITIONS
    • 锂金属氧化物组合物和锂试剂多孔金属组合物
    • US20120235084A1
    • 2012-09-20
    • US13469299
    • 2012-05-11
    • Michael LEFENFELDJames L. DYEPartha NANDIJames JACKSON
    • Michael LEFENFELDJames L. DYEPartha NANDIJames JACKSON
    • C09K3/00
    • C07F1/02C01C1/026C01D15/00C01P2002/86C01P2002/87C01P2002/89C01P2006/16Y02P20/52
    • The invention relates to lithium metal/porous metal oxide compositions. These lithium metal compositions are prepared by mixing liquid lithium metal with a porous metal oxide in an inert atmosphere under exothermic conditions sufficient to absorb the liquid lithium metal into the porous metal oxide pores. The lithium metal/porous metal oxide compositions of the invention are preferably loaded with lithium metal up to about 40% by weight, with about 20% to 40% by weight being the most preferred loading. The invention also relates to lithium reagent-porous metal oxide compositions having RLi absorbed into a porous oxide. In formula RLi, R is an alkyl group, an alkenyl group, an alkynyl group, an aryl group, an alkaryl group, or an NR1R2 group; R1 is an alkyl group, an alkenyl group, an alkynyl group, an aryl group, an alkaryl group; and R2 is hydrogen, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, and an alkaryl group. The preparation and use of these compositions are also described.
    • 本发明涉及锂金属/多孔金属氧化物组合物。 这些锂金属组合物通过在惰性气氛中将液态锂金属与多孔金属氧化物混合,在足以将液态锂金属吸收到多孔金属氧化物孔中的放热条件下来制备。 本发明的锂金属/多孔金属氧化物组合物优选负载高达约40重量%的锂金属,其中最优选的负载量为约20重量%至40重量%。 本发明还涉及具有吸收到多孔氧化物中的RLi的锂试剂多孔金属氧化物组合物。 在式RLi中,R是烷基,烯基,炔基,芳基,烷芳基或NR1R2基团; R1是烷基,烯基,炔基,芳基,烷芳基; R2是氢,烷基,烯基,炔基,芳基和烷芳基。 还描述了这些组合物的制备和用途。
    • 10. 发明申请
    • POLYHEDRALTRANSITION METAL COMPLEX, TRANSITION METAL COMPLEX CONTAINING ULTRAFINE PARTICLES THEREIN, AND PROCESS FOR PRODUCING SAME
    • 聚合金属复合物,其中含有超细颗粒的过渡金属络合物及其生产方法
    • US20120095196A1
    • 2012-04-19
    • US13255739
    • 2010-03-10
    • Makoto FujitaSota SatoKosuke Suzuki
    • Makoto FujitaSota SatoKosuke Suzuki
    • C07H23/00
    • C07H15/26C01B33/18C01F7/021C01G1/02C01G23/047C01G23/053C01G25/02C01P2002/85C01P2002/86C01P2002/89C01P2004/04C07H23/00
    • Provided is a polyhedral transition metal complex including a hollow shell, the hollow shell including n1 (where n1 is an integer from 6 to 60) transition metal atoms and 2(n1) bidentate organic ligands, the bidentate organic ligands including a group derived from a polyhydroxy compound via a linking group, and formed so that the group derived from the polyhydroxy compound is oriented toward an inner space of the hollow shell. Also provided are: an ultrafine particle-containing transition metal complex including the polyhedral transition metal complex, and ultrafine particles of a metal oxide, the ultrafine particles being included within the hollow shell of the polyhedral transition metal complex; a method of producing the same. The invention thus provides a polyhedral transition metal complex that makes it possible to efficiently produce metal oxide particles having a uniform particle size of several nanometers, an ultrafine particle-containing polyhedral transition metal complex in which metal oxide particles are included within a polyhedral structure and the method of producing the same.
    • 提供了包含中空壳体的多面体过渡金属络合物,中空壳体包括n1(其中n1为6至60的整数)过渡金属原子和2(n1)二齿有机配体,二齿有机配体包括衍生自 多羟基化合物通过连接基团形成,并且形成为使得来自多羟基化合物的基团朝向中空壳体的内部空间。 还提供:包含多面体过渡金属络合物的超细颗粒的过渡金属络合物和金属氧化物的超细颗粒,超细颗粒包含在多面体过渡金属络合物的中空壳内; 其制造方法。 因此,本发明提供了一种多面体过渡金属络合物,其可以有效地生产具有几纳米的均匀粒径的金属氧化物颗粒,其中在多面体结构内包含金属氧化物颗粒的超细颗粒的多面体过渡金属络合物, 制作方法