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    • 4. 发明授权
    • “No-bake” foundry mix with extended work time
    • “无烘焙”铸造与延长工作时间相结合
    • US09518143B2
    • 2016-12-13
    • US14406092
    • 2013-06-07
    • ASK CHEMICALS LP
    • Michael R. NoceraGregory P. SturtzJörg Kroker
    • C08G18/20B22C1/22C08G18/00C08G18/28C08G18/72
    • C08G18/2018B22C1/22B22C1/2273C08G18/00C08G18/28C08G18/72
    • A “no-bake” process allows the forming of larger metal castings, by providing longer work times, in the range of about 45 to about 60 minutes. This is achieved using a liquid curing catalyst that is a pyridine, substituted at the second or third position with a moiety having a molecular weight in the range of about 30 to about 100 mwu. Examples of the liquid curing catalyst include 2-ethanolpyridine, 3-chloropyridine and 2-methoxypyridine. When combined with a two-part polyurethane binder precursor and a foundry aggregate, the liquid curing catalyst provides not only the longer work time, but also a strip time that is less than about 167% of the work time, as measured from the point of activating the polyurethane precursors by mixing them in the presence of the curing catalyst.
    • “无烘烤”方法允许通过在约45至约60分钟的范围内提供更长的工作时间来形成更大的金属铸件。 这是使用作为吡啶的液体固化催化剂实现的,其在第二或第三位置被分子量在约30至约100mwu范围内的部分取代。 液体固化催化剂的实例包括2-乙基吡啶,3-氯吡啶和2-甲氧基吡啶。 当与两部分聚氨酯粘合剂前体和铸造骨料组合时,液体固化催化剂不仅提供更长的工作时间,而且提供小于工作时间的约167%的剥离时间,如从 通过在固化催化剂的存在下将它们混合来活化聚氨酯前体。