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1. 发明授权

US09315701B2 Two part hybrid adhesive 有权
标题翻译：两部分混合胶
公开(公告)号：US09315701B2
公开(公告)日：2016-04-19
申请号：US14266137
申请日：2014-04-30
申请人： Henkel IP & Holding GmbH
发明人： Yongxia Wang , Charles W. Paul
IPC分类号： C08G79/08 , C09J175/02 , C08G18/10 , C08G18/32 , C08G18/36 , C08G18/50 , C08G18/62 , C08G18/63 , C08G18/67 , C09J175/04 , C08K5/00 , C08K5/55 , C08L33/06
CPC分类号： C09J175/02 , C08G18/10 , C08G18/3268 , C08G18/36 , C08G18/5021 , C08G18/6225 , C08G18/637 , C08G18/672 , C08K5/0091 , C08K5/55 , C08L33/06 , C08L2666/04 , C09J175/04 , C08G18/6685
摘要： Provided are two part hybrid adhesives that comprise an organoborane amine complex, a polyamine, a component polymerizable by free radical polymerization, and a polyisocyanate component. An isocyanate terminated prepolymer can advantageously be used in the practice of the invention. The adhesive is particularly well suited for low surface energy plastic bonding.
摘要翻译：提供了两部分混合粘合剂，其包含有机硼烷胺络合物，多胺，通过自由基聚合可聚合的组分和多异氰酸酯组分。异氰酸酯封端的预聚物可以有利地用于本发明的实践中。粘合剂特别适用于低表面能塑料粘合。

2. 发明申请

US20120077929A1 POLYTRIMETHYLENE ETHER-BASED POLYURETHANE IONOMERS 审中-公开
标题翻译：聚偏二氟乙烯基聚氨酯离子
公开(公告)号：US20120077929A1
公开(公告)日：2012-03-29
申请号：US13080818
申请日：2011-04-06
申请人： Hari Babu Sunkara , C. Chad Roberts , Paul A. Colose, II
发明人： Hari Babu Sunkara , C. Chad Roberts , Paul A. Colose, II
IPC分类号： C08L75/08 , C08L75/14 , B82Y99/00
CPC分类号： C08G18/0823 , C08G18/0866 , C08G18/10 , C08G18/12 , C08G18/284 , C08G18/2865 , C08G18/2875 , C08G18/3206 , C08G18/3275 , C08G18/4018 , C08G18/4825 , C08G18/637 , C08G18/6625 , C08G18/755 , C08G18/7621 , C08G18/7628 , C08G18/348 , C08G18/3228
摘要： Disclosed is aqueous polyurethane dispersion with a polyurethane having a polymeric backbone with ionic and/or ionizable functionality incorporated into the polymeric backbone. The polymeric backbone consists essentially of one or more non-ionic segments derived from a reaction product of polytrimethylene ether glycol and a diisocyanate. The manufacture of such polyurethanes is also disclosed.
摘要翻译：公开了具有聚氨酯的水性聚氨酯分散体，其具有结合到聚合物主链中的具有离子和/或可离子化官能团的聚合物主链。聚合物主链基本上由一个或多个衍生自聚三亚甲基醚二醇和二异氰酸酯的反应产物的非离子链段组成。还公开了这种聚氨酯的制造。

3. 发明申请

US20090131546A1 Rigid, Closed-cell, Graft-polymer Foam; Rigid Flexible Cellular Foam; Rigid Flexible Cellular Foam Mixture; Rigid Flexible Cellular Foam Mixture; and Method for Manufacturing a Rigid, Closed-Cell, Graft-Polymer Foam 有权
标题翻译：刚性，闭孔，接枝聚合物泡沫; 刚性柔性泡沫泡沫; 刚性柔性泡沫混合物; 刚性柔性泡沫混合物; 和制造刚性，闭孔，接枝聚合物泡沫的方法
公开(公告)号：US20090131546A1
公开(公告)日：2009-05-21
申请号：US11942979
申请日：2007-11-20
申请人： Juan Miguel Vazquez
发明人： Juan Miguel Vazquez
IPC分类号： C08G18/40 , C08F2/46
CPC分类号： C08F2/48 , C08F259/00 , C08F259/04 , C08G18/637 , C08G2101/0058 , C08G2101/0066 , C08J9/04 , C08J2205/052 , C08J2327/22 , C08L27/06 , C08L51/003 , C08L2666/02
摘要： Expanded products, more specifically, rigid or semi-flexible foams of low density from 1.5 to 12 lbs/ft3 or more, with closed cells can be manufactured. The products have a PVC backbone with branches with methacrylate crosslinked with isocyanate through a reaction activated by ultraviolet or microwave radiation. The use of polyfunctional monomers that are sensitive to irradiation yields a higher cross-link density, which improves the physical and mechanical properties such as hardness, resistance to abrasion, ductility, and resistance to friction. The selection of monomers and oligomers allows the manufacturer to determine of the final properties of the foam. The process yields foams with extreme hardness and better shear factors making the foam an ideal product for aerospace and windmill use. These physical properties emerge during the post-curing process, preferably by use of compounds based on methacrylates in dispersion with PVC and isocyanates.
摘要翻译：可以制造具有闭孔的膨胀产品，更具体地，具有1.5至12磅/平方英尺或更小的低密度的刚性或半柔性泡沫。该产品具有通过紫外线或微波辐射激活的反应通过异氰酸酯与甲基丙烯酸酯交联的具有支链的PVC骨架。使用对辐射敏感的多官能单体产生更高的交联密度，这提高了物理和机械性能，例如硬度，耐磨性，延展性和耐摩擦性。单体和低聚物的选择允许制造商确定泡沫的最终性能。该方法产生具有极高硬度和更好的剪切因子的泡沫，使泡沫成为航空航天和风车使用的理想产品。这些物理性质在后固化过程中出现，优选通过使用与PVC和异氰酸酯分散的基于甲基丙烯酸酯的化合物。

4. 发明申请

US20090062453A1 CURABLE FILM-FORMING COMPOSITIONS DEMONSTRATING SELF-HEALING PROPERTIES 有权
标题翻译：可固化成膜组合物演示自我治疗性能
公开(公告)号：US20090062453A1
公开(公告)日：2009-03-05
申请号：US11846070
申请日：2007-08-28
申请人： Lyle L. Foringer , Constantine A. Kondos , Richard J. Sadvary , Kurt G. Olson , Dennis A. Simpson
发明人： Lyle L. Foringer , Constantine A. Kondos , Richard J. Sadvary , Kurt G. Olson , Dennis A. Simpson
IPC分类号： C08K11/00 , C08L67/00
CPC分类号： C08G18/637 , B05D5/005 , C08G18/4063 , C08G18/423 , C08G18/6254 , C08G18/792 , C08K3/36 , C08L33/08 , C08L67/00 , C09D133/08 , C09D175/16 , C08L2666/18
摘要： The present invention is directed to curable film-forming compositions comprising: (a) a polymeric binder comprising a polyester having hydroxyl functional groups; and (b) a curing agent comprising a polyisocyanate having at least three isocyanate functional groups. In certain embodiments, after application to a substrate as a coating and after curing, the compositions demonstrate a Fisher microhardness of at least 120 at ambient temperatures of 15 to 25° C. and a softening point greater than or equal to 35° C. Additionally, in certain embodiments, after application to a substrate as a coating and after curing, the compositions demonstrate a 20° gloss recovery of at least 75% when subjected to the DRY ABRASION TEST METHOD.
摘要翻译：本发明涉及可固化成膜组合物，其包含：（a）包含具有羟基官能团的聚酯的聚合物粘合剂; 和（b）包含具有至少三个异氰酸酯官能团的多异氰酸酯的固化剂。在某些实施方案中，作为涂层施用于基材并且在固化后，组合物在15至25℃的环境温度和大于或等于35℃的软化点下显示出至少120的Fisher显微硬度。另外在某些实施方案中，在作为涂层施加到基材上并且在固化之后，当进行干磨试验方法时，组合物显示出至少75％的20°光泽恢复。

5. 发明授权

US6093778A Organoborane polyamine complex initiator systems and polymerizable compositions made therewith 失效
标题翻译：有机硼烷多胺络合物引发剂体系和可聚合组合物
公开(公告)号：US6093778A
公开(公告)日：2000-07-25
申请号：US391542
申请日：1999-09-08
申请人： Alphonsus V. Pocius
发明人： Alphonsus V. Pocius
IPC分类号： C07F5/02 , C07F5/00 , C08G18/16 , C08G18/32 , C08G18/40 , C08G18/62 , C08G18/63 , C08G18/66 , C08K5/55 , C08L67/04 , C08L71/02 , C09J4/02 , C09J175/00 , C09J175/04 , C09J175/06 , C09J175/08 , C08F4/52 , C08L75/04
CPC分类号： C09J175/00 , C07F5/006 , C08G18/168 , C08G18/3268 , C08G18/6229 , C08G18/637 , C08G18/6651 , C09J175/04
摘要： A composition comprises organoborane polyamine complex and polyol. The composition can form a part of a polymerization initiator system that also includes polyisocyanate. The system can be used to initiate polymerization of acrylic monomer and to form a polyurethane/polyurea acrylic adhesive that has exceptionally good adhesion to low surface energy polymers.
摘要翻译：组合物包含有机硼烷多胺络合物和多元醇。组合物可以形成也包括聚异氰酸酯的聚合引发剂体系的一部分。该系统可用于引发丙烯酸单体的聚合并形成具有特别好的低表面能聚合物粘附性的聚氨酯/聚脲丙烯酸粘合剂。

6. 发明授权

US5498782A Distortion control additives for ultraviolet-curable compositions 失效
标题翻译：用于紫外线固化组合物的失真控制添加剂
公开(公告)号：US5498782A
公开(公告)日：1996-03-12
申请号：US118014
申请日：1993-09-08
申请人： Gary C. Rex
发明人： Gary C. Rex
IPC分类号： C08F283/00 , C08F290/06 , C08G18/63 , C09D4/00 , C08F8/30 , C08L75/04 , C08L75/06
CPC分类号： C08G18/637 , C08F283/006 , C08F290/067 , C09D4/00
摘要： Distortion control additives are disclosed which comprise a polyisocyanate, a polyol or polyol blend having a hydroxyl functionality of 2 to 3 hydroxyl groups per molecule and an average molecular weight of at least about 500 grams per gram mole, a diol chain extender having from about 2 to 35 carbon atoms per molecule and an acrylate or methacrylate having an acrylate functionality of from 1 to 5 acrylate groups per molecule. Ultraviolet-curable liquid compositions comprising an unsaturated polymeric resin, a monomer and the distortion control additives of the present invention are also disclosed. The distortion control additives can provide substantial reductions in distortion, e.g., shrinkage, of objects produced by ultraviolet curing, e.g., stereolithography.
摘要翻译：公开了失真控制添加剂，其包含每分子具有2-3个羟基官能团的多异氰酸酯，多元醇或多元醇共混物，平均分子量为至少约500克/克摩尔，二醇扩链剂具有约2 每分子具有35个碳原子的丙烯酸酯或甲基丙烯酸酯，丙烯酸酯官能度为每分子1至5个丙烯酸酯基团。还公开了包含本发明的不饱和聚合物树脂，单体和变形控制添加剂的紫外线固化液体组合物。变形控制添加剂可以显着减少通过紫外线固化产生的物体的变形，例如收缩，例如立体光刻。

7. 发明授权

US5326621A Energy-induced dual curable compositions 失效
标题翻译：能量双重固化组合物
公开(公告)号：US5326621A
公开(公告)日：1994-07-05
申请号：US932083
申请日：1992-08-19
申请人： Michael C. Palazzotto , Katherine A. Brown-Wensley , Robert J. DeVoe
发明人： Michael C. Palazzotto , Katherine A. Brown-Wensley , Robert J. DeVoe
IPC分类号： C08G18/58 , C08F2/50 , C08F4/42 , C08F4/44 , C08G18/16 , C08G18/22 , C08G18/63 , C08G59/34 , C08G59/68 , C08G65/12 , C08L63/00 , C08L75/04 , C09D175/00 , C09J175/00 , G03C1/735
CPC分类号： C08F4/44 , C08F2/50 , C08G18/161 , C08G18/22 , C08G18/637 , C08G59/68 , C08G65/12 , Y10S428/90 , Y10S428/901 , Y10S428/928 , Y10S428/932 , Y10S430/115 , Y10S430/122 , Y10S430/124 , Y10T428/24372 , Y10T428/24802 , Y10T428/24835 , Y10T428/24893 , Y10T428/24917
摘要： An energy polymerizable composition comprises at least one ethylenically-unsaturated monomer, one of polyurethane precursors, and at least one epoxy monomer, and a curing agent comprising an organometallic compound, and an onium salt.
摘要翻译：能量可聚合组合物包含至少一种烯属不饱和单体，聚氨酯前体之一和至少一种环氧单体，以及包含有机金属化合物和鎓盐的固化剂。

8. 发明授权

US5238744A Tough polymeric mixtures 失效
标题翻译：坚韧的聚合物混合物
公开(公告)号：US5238744A
公开(公告)日：1993-08-24
申请号：US819407
申请日：1992-01-10
申请人： Jerry W. Williams , Robert J. DeVoe
发明人： Jerry W. Williams , Robert J. DeVoe
IPC分类号： C08F2/48 , C08F2/50 , C08G18/63 , C09D4/00
CPC分类号： C08G18/637 , C08F2/48 , C09D4/00 , Y10T428/31507 , Y10T428/31551 , Y10T428/31645 , Y10T428/31678 , Y10T428/31692
摘要： A tough polymeric mixture comprises the polymerized product of admixture I or II, whereinadmixture I comprises 5 to 45 weight percent of a first monomer and a photoinitiator therefor, said first monomer being at least one free-radically polymerizable monomer, and 95 to 55 weight percent of a second monomer and a photoinitiator therefor, said second monomer being at least one set of polyurethane precursors, andadmixture II comprises 5 to 45 weight percent of a first monomer and a photoinitiator therefor, said first monomer being at least one set of polyurethane precursors, and 95 to 55 weight percent of a second monomer and a photoinitiator therefor, said second monomer being at least one free-radically polymerizable monomer,said polymeric mixture having been prepared by a process involving two sequential actinic radiations of wavelength ranges centered around .lambda..sub.1 and .lambda..sub.2, respectively, wherein .lambda..sub.1 and .lambda..sub.2 differ from each other by at least 30 nm, andwherein the actinic radiation centered around .lambda..sub.1 does not substantially polymerize the second monomer, andwherein the area under a stress-strain curve as determined by ASTM D638-89 for said polymeric mixture is at least 10 percent greater, preferably 20 percent greater, and more preferably at least 50 percent greater when said precursor monomers are cured by said sequential photoinitiation process compared to when the same mixture is cured by a single photostage cure.
摘要翻译：韧性聚合物混合物包含混合物I或II的聚合产物，其中混合物I包含5至45重量％的第一单体和其引发剂，所述第一单体为至少一种可自由基聚合的单体，和95至55重量份百分比的第二单体和光引发剂，所述第二单体是至少一组聚氨酯前体，并且混合物II包含5至45重量％的第一单体和其光引发剂，所述第一单体为至少一组聚氨酯前体和95至55重量％的第二单体及其光引发剂，所述第二单体是至少一个可自由基聚合的单体，所述聚合物混合物已经通过涉及以λ为中心的波长范围的两个连续光化辐射 1和λ2，其中λ1和λ2彼此不同至少30nm，并且其中以λ1为中心的光化辐射基本上不使第二单体聚合，并且其中根据ASTM D638-89对所述聚合物混合物测定的应力 - 应变曲线下的面积为至少10％，优选为20％，更优选为当所述前体单体通过所述顺序光引发过程固化时相比，通过单次光固化固化相同的混合物时，至少50％以上。

9. 发明授权

US5147900A Energy-induced dual curable compositions 失效
标题翻译：能量双重固化组合物
公开(公告)号：US5147900A
公开(公告)日：1992-09-15
申请号：US513610
申请日：1990-04-24
申请人： Michael C. Palazzotto , Katherine A. Brown-Wensley , Robert J. DeVoe
发明人： Michael C. Palazzotto , Katherine A. Brown-Wensley , Robert J. DeVoe
IPC分类号： C08F2/50 , C08F4/42 , C08F4/44 , C08G18/16 , C08G18/22 , C08G18/63 , C08G59/68 , C08G65/12
CPC分类号： C08F4/44 , C08F2/50 , C08G18/161 , C08G18/22 , C08G18/637 , C08G59/68 , C08G65/12 , Y10S430/115 , Y10S430/124
摘要： An energy polymerizable composition comprises at least one ethylenically-unsaturated monomer, one of polyurethane precursors, and at least one epoxy monomer, and a curing agent comprising an organometallic compound, and an onium salt.
摘要翻译：能量可聚合组合物包含至少一种烯属不饱和单体，聚氨酯前体之一和至少一种环氧单体，以及包含有机金属化合物和鎓盐的固化剂。

10. 发明授权

US5102924A Polymeric mixtures and process therefor 失效
标题翻译：聚合物混合物及其工艺
公开(公告)号：US5102924A
公开(公告)日：1992-04-07
申请号：US568088
申请日：1990-08-16
申请人： Jerry W. Williams , Robert J. DeVoe
发明人： Jerry W. Williams , Robert J. DeVoe
IPC分类号： C08F2/48 , C08F2/50 , C08F4/00 , C08G18/63 , C09D4/00
CPC分类号： C08G18/637 , C08F2/48 , C09D4/00
摘要： A tough polymeric mixture comprises the polymerized product of admixture I or II, whereinadmixture I comprises 5 to 45 weight percent of a first monomer and a photoinitiator therefor, said first monomer being at least one free-radically polymerizable monomer, and 95 to 55 weight percent of a second monomer and a photoinitiator therefor, said second monomer being at least one set of polyurethane precursors, andadmixture II comprises 5 to 45 weight percent of a first monomer and a photoinitiator therefor, said first monomer being at least one set of polyurethane precursors, and 95 to 55 weight percent of a second monomer and a photoinitiator therefor, said second monomer being at least one free-radically polymerizable monomer,said polymeric mixture having been prepared by a process involving two sequential actinic radiations of wavelengths ranges centered around .lambda..sub.1 and .lambda..sub.2, respectively, wherein .lambda..sub.1 and .lambda..sub.2 differ from each other by at least 30 nm, andwherein the actinic radiation centered .lambda..sub.1 does not substantialy polymerize the second monomer, andwherein the area under a stress-strain curve as determined by ASTM D638-89 for said polymeric mixture is at least 10 percent greater, preferably 20 percent greater, and more preferably at least 50 percent greater when said precursor monomers are cured by said sequential photoinitiation process compared to when the same mixture is cured by a single photostage cure.
摘要翻译：韧性聚合物混合物包含混合物I或II的聚合产物，其中混合物I包含5至45重量％的第一单体和其引发剂，所述第一单体为至少一种可自由基聚合的单体，和95至55重量份百分比的第二单体和光引发剂，所述第二单体是至少一组聚氨酯前体，并且混合物II包含5至45重量％的第一单体和其光引发剂，所述第一单体为至少一组聚氨酯前体和95至55重量％的第二单体及其光引发剂，所述第二单体是至少一个可自由基聚合的单体，所述聚合物混合物已经通过涉及波长范围以λ为中心的两个连续光化辐射的方法制备 1和λ2，其中λ1和λ2彼此不同至少30nm，并且其中光化辐射居中的λ1不会基本上聚合第二单体，并且其中通过ASTM D638-89测定的针对所述聚合物混合物的应力 - 应变曲线下的面积至少为10％，优选为20％，更优选为当所述前体单体通过所述顺序光引发过程固化时相比，通过单次光固化固化相同的混合物时，其最大50％更大。

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