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1. 发明申请

US20170349781A1 COATINGS CONTAINING POLYESTER MACROMERS CONTAINING 1,1-DICARBONYL-SUBSTITUTED 1 ALKENES 审中-公开
公开(公告)号：US20170349781A1
公开(公告)日：2017-12-07
申请号：US15638290
申请日：2017-06-29
申请人： SIRRUS, INC.
发明人： Aniruddha S. Palsule , Jeffrey M. Sullivan , Katherine E. Vanderpool , Alexander R. Holzer , Anushree Deshpande , John Klier
IPC分类号： C09D167/06 , C08L67/06 , C08G63/78 , C12P7/62 , C08G63/00
CPC分类号： C09D167/06 , C08G63/00 , C08G63/553 , C08G63/676 , C08G63/78 , C08L67/06 , C09D133/06 , C09D167/02 , C12P7/625 , C08L83/04 , C08L79/02
摘要： Compositions comprising a) one or more polyester macromers containing one or more chains of the residue of one or more diols and one or more diesters wherein the residue of the one or more diols and the one or more diesters alternate along the chain and a portion of the diesters are 1,1-diester-1-alkenes and at least one terminal end comprises the residue of one of the 1,1-diester-1 alkenes and wherein one or more terminal ends may comprise the residue of one or more diols; and b) one or more polymers having pendant Michael Addition donor groups. Disclosed are coating prepared from these compositions.

2. 发明申请

US20170327638A1 HIGH RECYCLE CONTENT POLYOLS FROM THERMOPLASTIC POLYESTERS AND LIGNIN OR TANNIN 审中-公开
公开(公告)号：US20170327638A1
公开(公告)日：2017-11-16
申请号：US15663881
申请日：2017-07-31
申请人： Resinate Materials Group, Inc.
发明人： Shakti Mukerjee , Kevin Anthony Rogers , Matthew James Beatty , Gary E. Spilman
IPC分类号： C08G63/91 , C09D167/03 , C08G18/32 , C09D167/02 , C08J11/24 , C08G63/676 , C08G63/668 , C08G63/133 , C08G18/75 , C08G18/73 , C08G18/66 , C08G18/64 , C08G18/42 , C09D175/06
CPC分类号： C08G63/916 , C08G18/3206 , C08G18/4225 , C08G18/6492 , C08G18/664 , C08G18/73 , C08G18/755 , C08G63/133 , C08G63/668 , C08G63/676 , C08G63/914 , C08J11/24 , C08J2367/02 , C09D167/02 , C09D167/03 , C09D175/06 , Y02P20/582 , Y02W30/706
摘要： Polyester polyols, processes for making them, and applications for the polyols are disclosed. In some aspects, the polyols comprise recurring units from a thermoplastic polyester or an aromatic polyacid source, a glycol, and a lignin, tannin, or mixture thereof. Optionally, the polyols incorporate recurring units of a hydrophobe. The polyols are made in one or multiple steps; in some aspects, the thermoplastic polyester or aromatic polyacid source and the glycol are reacted first, followed by reaction with the lignin, tannin, or mixture thereof. High-recycle-content polyols having desirable properties and attributes for formulating polyurethane products, including two-component polyurethane coatings, can be made. The polyols provide a sustainable alternative to bio- or petrochemical-based polyols.

3. 发明申请

US20170002138A1 HIGH RECYCLE CONTENT POLYOLS FROM THERMOPLASTIC POLYESTERS AND LIGNIN OR TANNIN 审中-公开
标题翻译：热塑性聚酯和木质素或鞣剂的高回收含量聚
公开(公告)号：US20170002138A1
公开(公告)日：2017-01-05
申请号：US15266247
申请日：2016-09-15
申请人： Resinate Materials Group, Inc.
发明人： Shakti Mukerjee , Kevin Anthony Rogers , Matthew James Beatty , Gary E. Spilman
IPC分类号： C08G63/91 , C08G63/676 , C08G18/32 , C08G18/73 , C08G18/64 , C09D175/06 , C09D167/02
CPC分类号： C08G63/916 , C08G18/3206 , C08G18/4225 , C08G18/6492 , C08G18/664 , C08G18/73 , C08G18/755 , C08G63/133 , C08G63/668 , C08G63/676 , C08G63/914 , C08J11/24 , C08J2367/02 , C09D167/02 , C09D167/03 , C09D175/06 , Y02P20/582 , Y02W30/706
摘要： Polyester polyols, processes for making them, and applications for the polyols are disclosed. In some aspects, the polyols comprise recurring units from a thermoplastic polyester or an aromatic polyacid source, a glycol, and a lignin, tannin, or mixture thereof. Optionally, the polyols incorporate recurring units of a hydrophobe. The polyols are made in one or multiple steps; in some aspects, the thermoplastic polyester or aromatic polyacid source and the glycol are reacted first, followed by reaction with the lignin, tannin, or mixture thereof. High-recycle-content polyols having desirable properties and attributes for formulating polyurethane products, including two-component polyurethane coatings, can be made. The polyols provide a sustainable alternative to bio- or petrochemical-based polyols.
摘要翻译：公开了聚酯多元醇，其制备方法和多元醇的应用。在一些方面，多元醇包含来自热塑性聚酯或芳族多酸源，二醇和木质素，单宁或其混合物的重复单元。任选地，多元醇包含疏水物的重复单元。多元醇制成一个或多个步骤; 在一些方面，首先使热塑性聚酯或芳族多酸源和二醇反应，然后与木质素，单宁或其混合物反应。可以制备具有用于配制聚氨酯产品，包括双组分聚氨酯涂料的所需性能和特性的高回收含量的多元醇。多元醇为生物或石油化学的多元醇提供了可持续的替代方案。

4. 发明授权

US09238711B2 Hydroxylamino polymer and method for the production thereof 有权
标题翻译：羟基氨基聚合物及其制备方法
公开(公告)号：US09238711B2
公开(公告)日：2016-01-19
申请号：US14366336
申请日：2012-12-17
申请人： Bayer Intellectual Property GmbH
发明人： Jorg Hofmann , Klaus Lorenz , Hartmut Nefzger
IPC分类号： C08G63/676 , C08G18/48 , C08G18/38 , C08G18/42 , C08G18/46 , C08G63/685 , C08G73/02
CPC分类号： C08G63/676 , C08G18/3821 , C08G18/4252 , C08G18/4615 , C08G18/4887 , C08G63/6854 , C08G73/02
摘要： The present invention relates to a process for the preparation of a hydroxy-amino polymer, comprising the steps: a) reacting an H-functional starter compound carrying at least one Zerewitinoff-active H atom with an unsaturated cyclic carboxylic acid anhydride to give a carboxyl-group-carrying prepolymer, b) reacting the carboxyl-group-carrying prepolymer with at least one epoxide compound to give a hydroxyl-group-carrying prepolymer, c) adding a primary amine and/or ammonia to the double bond of the hydroxyl-group-carrying prepolymer obtained according to step b) to give the hydroxy-amino polymer, wherein the ratio of the amount of carboxylic acid anhydride to the number of Zerewitinoff-active H atoms of the H-functional starter compound is so chosen that almost all the Zerewitinoff-active H atoms of the H-functional starter compound are reacted. The invention relates additionally to a hydroxy-amino polymer obtainable by the above-mentioned process, wherein the ratio of the amount of unsaturated cyclic carboxylic acid anhydride to the number of Zerewitinoff-active H atoms of the H-functional starter compound is at least approximately 0.9:1, and further to the use of this hydroxy-amino polymer in the preparation of a polyurethane urea polymer.
摘要翻译：本发明涉及一种制备羟基 - 氨基聚合物的方法，包括以下步骤：a）使带有至少一个Zerewitinoff活性H原子的H官能引发剂化合物与不饱和环状羧酸酐反应，得到羧基 - 携带载体的预聚物，b）使含羧基的预聚物与至少一种环氧化合物反应得到带羟基的预聚物，c）将伯胺和/或氨加到羟基 - 根据步骤b）获得的携带载体的预聚物得到羟基 - 氨基聚合物，其中羧酸酐的量与H官能起始化合物的Zerewitinoff活性H原子数的比例被选择为几乎全部 H功能起始化合物的Zerewitinoff活性H原子反应。本发明另外涉及通过上述方法获得的羟基 - 氨基聚合物，其中不饱和环状羧酸酐的量与H官能起始化合物的Zerewitinoff活性H原子数之比至少约为 0.9:1，进一步使用该羟基 - 氨基聚合物制备聚氨酯脲聚合物。

5. 发明授权

US09139689B1 Bioderived compatibilizer for biopolymers 有权
标题翻译：用于生物聚合物的生物活性增容剂
公开(公告)号：US09139689B1
公开(公告)日：2015-09-22
申请号：US13725802
申请日：2012-12-21
申请人： The United States of America, as represented by the Secretary of Agriculture , Lapol, LLC
发明人： Allison Flynn , Lennard F Torres , William J Orts , Artur Klamczynski
IPC分类号： C08G63/60 , C08L67/00 , C08G63/66 , C08G63/52 , C08L67/04 , C08L91/00
CPC分类号： C08G63/60 , C08G63/12 , C08G63/52 , C08G63/66 , C08G63/676 , C08L3/02 , C08L23/02 , C08L23/04 , C08L23/06 , C08L23/10 , C08L67/00 , C08L67/04 , C08L91/005 , C08L23/00
摘要： A bioderived plasticizer for biopolymers includes a compatibilizing unit and a polyester plasticizing unit. The plasticizer improves the flexibility of biopolymers while not adversely affecting the modulus of the biopolymer. The compatibilizing unit renders the plasticizer more miscible with the desired base biopolymer, and may increase crystallization and includes a lower alkyl (C3 to C7) organic acid including enantiomeric isomers of the base polymer. The polyester plasticizing unit is formed from monomers comprising a multifunctional alcohol and an aliphatic anhydride or its equivalent dicarboxylic acid and ester derivatives. The polyester plasticizing unit may optionally include one or more difunctional alcohols in combination with the multifunctional alcohol. The resulting bioderived plasticizer lowers glass transition temperature (Tg), can improve brittleness, may increases heat deflection temperature and improves melt viscosity.
摘要翻译：用于生物聚合物的生物活性增塑剂包括相容单元和聚酯增塑单元。增塑剂提高生物聚合物的柔韧性，同时不会对生物聚合物的模量产生不利影响。相容单元使增塑剂与所需的基础生物聚合物更易混溶，并且可以增加结晶，并且包括包含基础聚合物的对映体异构体的低级烷基（C 3至C 7）的有机酸。聚酯增塑单元由包含多官能醇和脂族酸酐或其等同的二羧酸和酯衍生物的单体形成。聚酯增塑单元可以任选地包括与多官能醇组合的一种或多种二官能醇。所得到的生物活性增塑剂降低了玻璃化转变温度（Tg），可以改善脆性，增加热变形温度并提高熔体粘度。

6. 发明申请

US20150080535A1 HYDROXYLAMINO POLYMER AND METHOD FOR THE PRODUCTION THEREOF 有权
标题翻译：羟丙基聚合物及其生产方法
公开(公告)号：US20150080535A1
公开(公告)日：2015-03-19
申请号：US14366336
申请日：2012-12-17
申请人： Bayer Intellectual Property GmbH
发明人： Jörg Hofmann , Klaus Lorenz , Hartmut Nefzger
IPC分类号： C08G73/02 , C08G63/685 , C08G18/46 , C08G18/64
CPC分类号： C08G63/676 , C08G18/3821 , C08G18/4252 , C08G18/4615 , C08G18/4887 , C08G63/6854 , C08G73/02
摘要： The present invention relates to a process for the preparation of a hydroxy-amino polymer, comprising the steps: a) reacting an H-functional starter compound carrying at least one Zerewitinoff-active H atom with an unsaturated cyclic carboxylic acid anhydride to give a carboxyl-group-carrying prepolymer, b) reacting the carboxyl-group-carrying prepolymer with at least one epoxide compound to give a hydroxyl-group-carrying prepolymer, c) adding a primary amine and/or ammonia to the double bond of the hydroxyl-group-carrying prepolymer obtained according to step b) to give the hydroxy-amino polymer, wherein the ratio of the amount of carboxylic acid anhydride to the number of Zerewitinoff-active H atoms of the H-functional starter compound is so chosen that almost all the Zerewitinoff-active H atoms of the H-functional starter compound are reacted. The invention relates additionally to a hydroxy-amino polymer obtainable by the above-mentioned process, wherein the ratio of the amount of unsaturated cyclic carboxylic acid anhydride to the number of Zerewitinoff-active H atoms of the H-functional starter compound is at least approximately 0.9:1, and further to the use of this hydroxy-amino polymer is the preparation of a polyurethane urea polymer.
摘要翻译：本发明涉及一种制备羟基 - 氨基聚合物的方法，包括以下步骤：a）使带有至少一个Zerewitinoff活性H原子的H官能引发剂化合物与不饱和环状羧酸酐反应，得到羧基 - 携带载体的预聚物，b）使含羧基的预聚物与至少一种环氧化合物反应得到带羟基的预聚物，c）将伯胺和/或氨加到羟基 - 根据步骤b）获得的携带载体的预聚物得到羟基 - 氨基聚合物，其中羧酸酐的量与H官能起始化合物的Zerewitinoff活性H原子数的比例被选择为几乎全部 H功能起始化合物的Zerewitinoff活性H原子反应。本发明另外涉及通过上述方法获得的羟基 - 氨基聚合物，其中不饱和环状羧酸酐的量与H官能起始化合物的Zerewitinoff活性H原子数之比至少约为 0.9：1，进一步使用该羟基 - 氨基聚合物是制备聚氨酯脲聚合物。

7. 发明授权

US08709693B2 Polyester resin for toner, electrostatic charge image developing toner, electrostatic charge image developer, toner cartridge, process cartridge, image forming apparatus, and image forming method 有权
标题翻译：用于调色剂的聚酯树脂，静电荷图像显影调色剂，静电荷图像显影剂，调色剂盒，处理盒，成像设备和成像方法
公开(公告)号：US08709693B2
公开(公告)日：2014-04-29
申请号：US13610117
申请日：2012-09-11
申请人： Sumiaki Yamasaki , Yuki Sasaki
发明人： Sumiaki Yamasaki , Yuki Sasaki
IPC分类号： G03G9/087
CPC分类号： C08G63/676 , C08G63/54 , C08G63/672 , G03G9/08755 , G03G9/08795 , G03G9/08797
摘要： A polyester resin for a toner is a polycondensate of a dicarboxylic acid component and an alcohol component including rosin diol that is represented by the following formula (1), and has a weight average molecular weight (Mw) of from 40000 to 150000, and a molecular weight distribution (Mw/Mn) of from 12 to 25: wherein, R1 and R2 each independently represents hydrogen or a methyl group; L1, L2, and L3 each independently represents a divalent linking group selected from a group consisting of a carbonyl group, a carboxyl group, an ether group, a sulfonyl group, a chain-like alkylene group which may have a substituent, a cyclic alkylene group which may have a substituent, an arylene group which may have a substituent, and combinations thereof, and L1 and L2 or L1 and L3 may form a ring; and A1 and A2 represent a rosin ester group.
摘要翻译：调色剂用聚酯树脂是由下式（1）表示的二羧酸成分和含有松香二醇的醇成分的缩聚物，重均分子量（Mw）为40000〜150000，分子量分布（Mw / Mn）为12〜25：其中，R 1和R 2各自独立地表示氢或甲基; L1，L2和L3各自独立地表示选自羰基，羧基，醚基，磺酰基，可以具有取代基的链状亚烷基的二价连接基团，环状亚烷基可以具有取代基的基团，可以具有取代基的亚芳基及其组合，L1和L2或L1和L3可以形成环; A1和A2表示松香酯基。

8. 发明申请

US20140065428A1 POLYMER IN MULTICOAT COLOR AND/OR EFFECT PAINT SYSTEMS 有权
标题翻译：聚合物颜色和/或效果涂料体系中的聚合物
公开(公告)号：US20140065428A1
公开(公告)日：2014-03-06
申请号：US14012198
申请日：2013-08-28
申请人： BASF Coatings GmbH
发明人： Peter Hoffmann , Bernhard Steinmetz , Jorn Lavalaye , Hardy Reuter
IPC分类号： C09D175/04 , C09D167/00 , B05D7/00 , C08G63/00
CPC分类号： C09D175/04 , B05D7/534 , C08G18/4252 , C08G63/00 , C08G63/676 , C09D167/00 , C09D167/08 , C09D175/06 , Y10T428/31551
摘要： Disclosed is a polymer which is prepared by reacting (a) dimer fatty acids with (b) at least one polyether of general structural formula (I) where R is a C3 to C6 alkylene radical and n is selected accordingly such that said polyether has a number-average molecular weight of 450 to 2200 g/mol, components (a) and (b) are used in a molar ratio of 0.7/2.3 to 1.3/1.7, and the resulting polymer has a number-average molecular weight of 1500 to 5000 g/mol and an acid number
摘要翻译：公开了通过使（a）二聚脂肪酸与（b）至少一种通式结构式（I）的聚醚（其中R是C 3至C 6亚烷基）反应制备的聚合物，并且相应地选择n，使得所述聚醚具有数均分子量为450〜2200g / mol，成分（a）和（b）的摩尔比为0.7 / 2.3〜1.3 / 1.7，所得聚合物的数均分子量为1500〜 5000g / mol，酸值<10mg KOH / g。还公开了包含该聚合物的着色水性底漆材料，以及所述聚合物在着色的底漆底漆材料中的用途。本发明还涉及一种用于生产多色漆系统的方法，还涉及通过所述方法可生产的多色漆系统。此外，本发明涉及对多涂漆系统上的缺陷区进行修补。

9. 发明申请

US20140045974A1 OIL IN WATER EMULSION 审中-公开
标题翻译：油在乳液中
公开(公告)号：US20140045974A1
公开(公告)日：2014-02-13
申请号：US13992923
申请日：2011-12-15
申请人： Nunzio Bonati , Massimo Zanolin , Johan Franz Gradus Anton Jansen
发明人： Nunzio Bonati , Massimo Zanolin , Johan Franz Gradus Anton Jansen
IPC分类号： C09J167/06 , D06M15/507 , C08K9/08
CPC分类号： C09J167/06 , C03C25/1095 , C08G63/676 , C08G63/914 , C08J5/043 , C08J5/08 , C08J5/24 , C08J2367/06 , C08K9/08 , C08L67/06 , C08L2201/52 , D06M15/507
摘要： The present invention relates to an oil-in-water emulsion, wherein the oil comprises an acid functional unsaturated polyester which acid functional unsaturated polyester comprises unsaturated dicarboxylic acid units, diol units, units of an emulsifier with HLB value of from 9 to 20 and further comprising chain extender units. The present invention further relates to a fibre mat comprising fibres and a binder comprising such acid functional unsaturated polyester.
摘要翻译：本发明涉及一种水包油乳液，其中油包含酸官能不饱和聚酯，其酸官能不饱和聚酯包括不饱和二羧酸单元，二醇单元，HLB值为9至20的乳化剂单元包括扩链剂单元。本发明还涉及包含纤维的纤维垫和包含这种酸官能不饱和聚酯的粘合剂。

10. 发明申请

US20130225784A1 POLYESTER RESIN, METHOD OF PRODUCING THE SAME, COMPOSITION FOR MOLDED ARTICLE AND MOLDED ARTICLE 审中-公开
标题翻译：聚酯树脂，其制造方法，成型品和成型品的组合物
公开(公告)号：US20130225784A1
公开(公告)日：2013-08-29
申请号：US13829138
申请日：2013-03-14
申请人： CANON KABUSHIKI KAISHA
发明人： Shinji Eritate
IPC分类号： C08G63/676
CPC分类号： C08G63/676 , C08G63/672
摘要： A polyester resin that can be used for producing a molded article having excellent impact resistance, and a method of producing the polyester resin. The polyester resin has structural units represented by general formulae (1) and (2), and contains the structural unit represented by the general formula (2) at a content of 50.1 mol % or more to 99.9 mol % or less with respect to the total of the structural units represented by the general formulae (1) and (2). The method of producing a polyester resin includes copolymerizing a furandicarboxylic acid or an ester thereof with ethylene glycol and diethylene glycol. In the formula, R1 represents an aromatic hydrocarbon group which may be substituted, or an aliphatic hydrocarbon group which may be substituted.
摘要翻译：可用于制造耐冲击性优异的成型体的聚酯树脂，以及聚酯树脂的制造方法。所述聚酯树脂具有由通式（1）和（2）表示的结构单元，并且含有由通式（2）表示的结构单元，其含量相对于所述结构单元为50.1mol％以上至99.9mol％以下总共由通式（1）和（2）表示的结构单元。聚酯树脂的制造方法包括使呋喃二羧酸或其酯与乙二醇和二甘醇共聚。式中，R 1表示可被取代的芳香族烃基或可以被取代的脂肪族烃基。

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