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    • 5. 发明申请
    • Organosilicon compound-containing polymerizable liquid-crystal composition
    • 含有机硅化合物的可聚合液晶组合物
    • US20050224754A1
    • 2005-10-13
    • US11002225
    • 2004-12-03
    • Yoshiharu HiraiTakashi Kato
    • Yoshiharu HiraiTakashi Kato
    • C09K19/20C09K19/32C09K19/38C09K19/52C09K19/54
    • C09K19/3833C09K19/2007C09K19/32C09K19/54C09K2019/0448Y10T428/10
    • An object of the invention is to provide a polymerizable liquid-crystal composition for obtaining a liquid-crystal film having good adhesiveness to supporting substrates. A polymerizable liquid-crystal layer of controlled alignment can be formed from the polymerizable liquid-crystal composition, and when the polymerizable liquid-crystal composition is polymerized, it gives a liquid-crystal film. The polymerizable liquid-crystal composition of the invention contains a polymerizable liquid-crystal compound represented by Formula (1) and a organosilicon compound having a primary amino group. wherein W is hydrogen, alkyl, alkenyl, halogen, —CN or -(G-Sp)r-P; P is a polymerizable group; Sp is alkylene; G is a bonding group; and MG is a mesogenic group represented by Formula (2): wherein T1 and T2 are ringed group; G1 is a bonding group; and f is an integer of 0 to 4. The symbols in these formulae are defined in detail in claim 2.
    • 本发明的目的是提供一种用于获得对支撑基材具有良好粘合性的液晶膜的聚合性液晶组合物。 可聚合性液晶组合物可以形成受控取向的可聚合液晶层,聚合后的液晶组合物聚合时,形成液晶膜。 本发明的聚合性液晶组合物含有由式(1)表示的聚合性液晶化合物和具有伯氨基的有机硅化合物。 其中W是氢,烷基,烯基,卤素,-CN或 - (G-Sp) P是可聚合基团; Sp为亚烷基; G是结合基团; 和MG是由式(2)表示的介晶基团:其中T 1和T 2是环基团; G 1是一个键合基团; f为0〜4的整数。 这些公式中的符号在权利要求2中详细定义。
    • 9. 发明授权
    • Liquid crystal polymers
    • 液晶聚合物
    • US6099752A
    • 2000-08-08
    • US66326
    • 1998-04-29
    • Alan William HallDavid LaceyIan Charles SageKeith Moray BlackwoodMichelle Jones
    • Alan William HallDavid LaceyIan Charles SageKeith Moray BlackwoodMichelle Jones
    • C08G61/00C09K19/38C09K19/42C09K19/30G02F1/13
    • C09K19/3833C08G61/00C09K19/3895
    • Compounds of formula ##STR1## are provided which may be used in a variety of devices including liquid crystal devices, piezoelectric devices, pyroelectric devices and in optical recording media, wherein X.sub.1 and X.sub.2 are independently selected from H, CN, COCH.sub.3, CO.sub.2 CH.sub.3, m=at least 5; X.sub.3 and X.sub.4 are independently selected from formula (IA), ##STR2## wherein Y is selected from COO, OCO, O, S, CHOH, CHF, CH.sub.2 ; Q=(CH.sub.2).sub.n wherein one or more non-adjacent methylenes may be replaced by O and n=1-20; Z is selected from O, S, single covalent bond, COO, OCO; when Y is CH2 then n may also be O; formula (A) ##STR3## represents any mesogenic group; X3 and X.sub.4 are also independently selected from H, OH, OCOR.sup.1, COOH, CO.sub.2 R.sup.1 (CH.sub.2).sub.p OH, (CH.sub.2).sub.p CO.sub.2 H, --(CH.sub.2).sub.p OR.sup.1 or --(CH.sub.2).sub.p CO.sub.2 R.sup.1 and p=1-20, R.sup.1 =H or C.sub.1=16 alkyl, when R.sup.1 =C.sub.2-16 alkyl the terminal Ch.sub.3 group may be replaced by Br or Cl; provided that at least one of X3 and X4 is selected from formula (IA).
    • PCT No.PCT / GB96 / 02650 Sec。 371日期:1998年4月29日 102(e)1998年4月29日PCT PCT 1996年10月31日PCT公布。 出版物WO97 / 16441 日期:1997年5月9日提供了可用于液晶装置,压电装置,热电装置和光学记录介质的各种装置的化合物,其中X1和X2独立地选自H,CN,COCH 3,CO 2 CH 3, m =至少5; X 3和X 4独立地选自式(IA),其中Y选自COO,OCO,O,S,CHOH,CHF,CH 2; Q =(CH 2)n,其中一个或多个不相邻亚甲基可被O代替,n = 1-20; Z选自O,S,单共价键,COO,OCO; 当Y是CH2时,n也可以是O; 式(A)表示任何介晶组; X3和X4也独立地选自H,OH,OCOR1,COOH,CO2R(CH2)pOH,(CH2)pCO2H, - (CH2)pOR1或 - (CH2)pCO2R1和p = 1-20,R1 = H或C1 = 16个烷基,当R1 = C2-16烷基时,末端Ch3基团可被Br或Cl取代; 条件是X3和X4中的至少一个选自式(IA)。