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    • 4. 发明授权
    • Emissive sensors and devices incorporating these sensors
    • 结合这些传感器的发射传感器和设备
    • US08367001B2
    • 2013-02-05
    • US12946685
    • 2010-11-15
    • Timothy M. SwagerShi-Wei Zhang
    • Timothy M. SwagerShi-Wei Zhang
    • G01N21/00
    • C09K11/06B82Y10/00C09K2211/1092C09K2211/1408C09K2211/1425H01L51/0035H01L51/0043H01L51/0044H01L51/0052H01L51/0062H01L51/0071H01L51/0545H01L51/0595H01L51/428H01L51/5012Y02E10/549Y10T436/163333Y10T436/17Y10T436/20
    • The present invention generally relates to luminescent and/or optically absorbing compositions and/or precursors to those compositions, including solid films incorporating these compositions/precursors, exhibiting increased luminescent lifetimes, quantum yields, enhanced stabilities and/or amplified emissions. The present invention also relates to sensors and methods for sensing analytes through luminescent and/or optically absorbing properties of these compositions and/or precursors. Examples of analytes detectable by the invention include electrophiles, alkylating agents, thionyl halides, and phosphate ester groups including phosphoryl halides, cyanides and thioates such as those found in certain chemical warfare agents. The present invention additionally relates to devices and methods for amplifying emissions, such as those produced using the above-described compositions and/or precursors, by incorporating the composition and/or precursor within a polymer having an energy migration pathway. In some cases, the compositions and/or precursors thereof include a compound capable of undergoing a cyclization reaction.
    • 本发明一般涉及这些组合物的发光和/或光学吸收组合物和/或前体,包括掺入这些组合物/前体的固体膜,显示增加的发光寿命,量子产率,增强的稳定性和/或放大的发射。 本发明还涉及通过这些组合物和/或前体的发光和/或光学吸收特性来感测分析物的传感器和方法。 可通过本发明检测的分析物的实例包括亲电试剂,烷化剂,亚硫酰卤和磷酸酯基,包括磷酰卤,氰化物和硫酸盐,例如在某些化学战剂中发现的那些。 本发明另外涉及通过将组合物和/或前体掺入具有能量迁移途径的聚合物中来扩大放射物的装置和方法,例如使用上述组合物和/或前体产生的那些。 在一些情况下,其组合物和/或其前体包括能够经历环化反应的化合物。